Page 1 FIITJEE

Revision CoPP - 11
Syllabus : Full syllabus

PHYSICAL/INORGANIC CHEMISTRY
Total Marks : 100 Max. Time : 70 min.
Single correct Objective ('–1' negative marking) Q.1 to Q.8 (3 marks, 2 min.) [24, 16]
CONCEPT PRACTISE PROBLEM

One or more correct objective (no negative marking) Q.9 to Q.11 (4 marks, 2 min.) [12, 06]
Single digit integer type ('–1' negative marking) Q.12 to Q.14 (4 marks, 3 min.) [12, 09]
Double digit integer type (no negative marking) Q.15 to Q.17 (4 marks, 3 min.) [12, 09]
Assertion and Reason ('–1' negative marking) Q.18 to Q.19 (3 marks, 3 min.) [06, 06]
Comprehension ('–1' negative marking) Q.20 to Q.25 (3 marks, 2 min.) [18, 12]
Match the Following (no negative marking) Q.26 to Q.27 (8 marks, 6 min.) [16, 12]
ORGANIC CHEMISTRY
Total Marks : 69 Max. Time : 48 min.
Single correct Objective ('–1' negative marking) Q.28 to Q.34 (3 marks, 2 min.) [21, 14]
One or more correct objective (no negative marking) Q.35 to Q.36 (4 marks, 2 min.) [08, 04]
Single digit integer type ('–1' negative marking) Q.37 to Q.38 (4 marks, 3 min.) [08, 06]
Double digit integer type (no negative marking) Q.39 (4 marks, 3 min.) [04, 03]
Assertion and Reason ('–1' negative marking) Q.40 (3 marks, 3 min.) [03, 03]
Comprehension ('–1' negative marking) Q.41 to Q.43 (3 marks, 2 min.) [09, 06]
Match the Following (no negative marking) Q.44 to Q.45 (8 marks, 6 min.) [16, 12]

PHYSICAL / INORGANIC
40
1. The variation of rate constant with temperature follows the equation ln K =30– + 20 T2 – 30ln T
T
based on this information, identify the most appropriate option.
(A) EA at 300 K is approximately equal to 1.08 × 109 R
(B) EA will remain constant at all temperatures.
(C) There is some temperature greater than 50 K where EA will become negative.
(D) Rate constant will follows Arrhenius equation.

2. For the two reactions

Reaction I : A  B
Reaction II : C  D
following curves are plotted
which of the following is incorrect option :

2 3
(A) (t100%)reaction I = (t ) (B) [A] = [C] at t = minutes
3 100% reaction II 4
1
(C) When [B] = [A] at that time [C] = [D] (D) If both [A]0 and [C]0 are 1 M then (t50%)I = (t )
3 50% II

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3. Following data of osmotic prssure () is obtained when different moles C17H35COONa are mixed in 1L solution
at 25°C :
Moles 0 0.01 0.02 0.03 0.04

(moles/liter) 0 0.02 0.04 0.058 0.076
RT
Select the incorrect nature of mixture at different concentration.
(A) Upto 0.02 M concentration, the mixture is true solution.
(B) After 0.03 M concentration, the mixture is a colloidal.
(C) At 0.04 M concentration, the mixture is homogenous.
CONCEPT PRACTISE PROBLEM

(D) The critical micelle concentration (CMC) of C17H35COONa may be 0.03 M.

4. A solid crystallises as cubic close packing of O2– ions. Ax+ ions occupy 25% of the tetrahedral voids and By+
ions occupy 50% of the octahedral voids. The suitable values of 'x' and 'y' are :
(A) x = 1, y = 3 (B) x = 2, y = 1 (C) x = 3, y = 2 (D) x = 1, y = 2

5. 1 mole of a compound Co(NH3)5Cl2Br gives 2 moles of curdy white precipitate, when treated with excess of
AgNO3 solution. Which of the following is incorrect about the compound ?
(A) The compound may be represented as [Co(NH3)5Br] Cl2.
(B) The Van’t Hoffs factor (i) is 3, when  = 1.0
(C) The boiling point of 1M – aq. solution of Co(NH3)5Cl2Br should be triple of its value, when it were
non-electrolyte.
(D) None of these
6. Incorrect option regarding SO2Cl2 is :
(A) OŜO  OŜCl  CIŜCl (Bond angle)
(B) Number of p-p bond is less than number of p-d bonds.
(C) Number of p-p bonds is more than p-d bonds.
(D) Hybridisation of central atom ‘S’ is sp3.
7. For dissociation of NH3 giving N2 and H2 gases, the partial pressures at equilibrium are 100, 80, 80 torr
respectively. If some N2 gas is removed and at new equilibrium partial pressure of H2 becomes 128 torr then
the partial pressure of N2 remaining will be approx.
(A) 9 torr (B) 71 torr (C) 8 torr (D) 72 torr
8. Which of the following plot will obtained for a conductomeric titration of strong acid against a weak base.

(A) (B) (C) (D)

9.* For a reaction represented by AB, which of the following options do not give the value of order of the
reaction.
ROR = Rate of reaction C = Concentration of reaction A
C0 = Concentration of reactant A t = 0 P = Concentration of product B
t1/2 = Half life of A.
log(ROR)2  log(ROR)1  log t1' / 2  log t1/ 2 
(A) (B) 1   
log C2  log C1  log C'0  log C0 
(C) Slope of In ROR vs In C graph (D) “y-intercept” of log ROR vs log C graph
10*. From the following options select the options which are correct respect the adsorption.
(A) The “y-intercept” of log x/m vs log P as per Freundlich theory is greater for O2 as compared to H2 at
same temperature.
(B) Adsorption of gas on a solid is an enthalpy driven process.
(C) Decrease in pressure cause desorption in case of chemisorption.
(D) Adsorption isobars keeps on decreasing with increase in temperature if there is only Vender Wall
interactions between adsorbent and adsorbate.
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11.* A nonvolatile solute ‘X’ completely dismerises in water, if the temperature is below –3.72°C and the solute
completely dissociates as X  Y + Z, if the temperature is above 100.26°C. In between these
temperature,(including both temperature) ‘X’ is neither dissociated nor associated. One mole of ‘X’ is dissolved
in 1kg water.
Given : Kb of water = 0.52 K.Kg mol–1 ; Kf of water = 1.86 K.Kg mol–1
Which of the following statement(s) is/are true regarding the solution ?
(A) The freezing point of solution is – 1.86°C.
(B) The boiling point of solution is 101.04°C.
(C) When the solution is cooled to –7.44°C, 75% of water present intially will separate as ice.
CONCEPT PRACTISE PROBLEM

(D) When the solution is heated to 102.08°C,50% of water present intially will escape out as vapor.
12. Find the number of molecules which are planar :
(a) CIF3 (b) SF6 (c) XeF6 (d) XeF2 (e) XeF4 (f) H2O
(g) H2S (h) NH3 (i) PH3 (j) PCI5 (k) PCI3 (l) OCI2
13.

Find the sum of number of p- p and p- dbonds in trimer of 'C'.
14. A metal 'A' exists in the bcc structure having uncovered length along the edge equal to 1.2 Å. If molar mass
of the metal is 307.2 gm/mole then calculate density of the crystal in g/mL.
[Use : NA= 6 × 1023 and 3 = 1.7 ]
15. A crystal arrangement is formed such that it consists of A atoms forming cubic close packing and B occupy
all the octahedral voids. Assuming no distortion, calculate packing efficiency of the crystal.

Express answer in percentage. [Use : [1+(0.414)3] = 1.07, = 0.74]
3 2
16. Total number of isomers (including stereoisomers) for the complex [Pd(NH3)(H2O)(NO2)2] are :

17. An oxy–acid of phosphorus is prepared by hydrolysis and oxidation of yellow phosphorus by water and air.
How many replaceable hydrogen are there in the oxy-acid of phosphorus ?
18. Statement-1 : Knowing K a1 of CO2 , pH can be determined of an aqueous solution of Na2CO3 of known
concentration.
Statement-2 : Only first hydrolysis of CO32 ion is significant because for most of dibasic acids, K a1  K a2
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

19. Statement-1 : Both gases are at same temperature.

Statement-2 : Boyle temperature of gas x is less than gas y.

(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

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Comprehension-1
A reversible reaction achieves equilibrium when the rates of forward and backward reactions becomes equal.
At equilibrium, the ratio of molar concentrations of product to molar concentrations of reactants,each raised
to the powers equal to their stoichiometric coefficients,becomes constant.Incase of gaseous reactions, the
partial pressure of gases may be used in place of their molar concentration.
20. If 1 mole of PCl5(g) and 1 mole of Cl2 (g) is taken in a 10L vessel, then the equilibrium concentration of PCl3(g)
will be :
20 –1
CONCEPT PRACTISE PROBLEM

PCl3(g) + Cl2 (g) PCl5(g) ; KC = m

3
(A) 0.05 (B) 0.04 (C) 0.06 (D) 0.025
21. The equilibrium partial pressure of N2O4(g) and NO2(g) are 4 and 2 atm, respectively. Now, at constant
temperature, the pressure of system is increased to 60 atm. The new equilibriums partial pressure of N2O4(g)
becomes :
(A) 40 atm (B) 46.6 atm (C) 20 atm (D) 33.4 atm
22. H2 (g) + I2 (g) 2HI(g)
Incorrect statement is :
(A) On increasing volume, concentration of all species will decrease.
(B) On increasing pressure, mass of HI will Increase.
(C) Once equilibrium is established then Qp is not affected by volume change.
(D) Catalyst effect Kf and Kb.
Comprehension-2
Two liquids A and B mix to form an ideal binary liquid solution, On adding solid solute C to the solution A starts
polymerising into a hexamer soluble solid 'A6' following zero order kinetics with a rate constant = 10–1 moles/
min. If initially 10 moles of A and 20 moles of B were taken to form liquid solution and 5 moles of C were
added then answer the following questions based on above information and data given below:
[Data: vapor pressure of pure A = 100 torr, vapor pressure of pure B = 90 torr]
23. The vapor pressure of the solution 1 hrs. after solid C is added will be given by :
220 2200 2200
(A) torr (B) 98 torr (C) torr (D) torr
3 29 24
24. Which of the following statements is incorrect regarding the above process ?
(A) The vapor pressure will keep on decreasing initially.
(B) The vapor pressure will become constant 100 min. after addition of C.
(C) Two hours after addition of C, the vapor pressure will become 72 torr.
(D) Four hours after addition of C, the vapor pressure will become 67.5 torr.
25. If C is not added so there is no polymerisation of A then mol fraction of A in vapour phase will be :
(A) 5/14 (B) 9/14 (C) 1/3 (D) 2/3
26. The standard reduction potential data at 25ºC is given below.
Eº (Fe3+.Fe2+) = + 0.77 V ; Eº (Fe2+.Fe) = – 0.44 V ;
2+
Eº (Cu .Cu) = + 0.34 V ; Eº (Cu+.Cu) = + 0.52 V ;
+
Eº (O2(g) + 4H + 4e  2H2O) = + 1.23 V ;
–
Eº (O2(g) + 2H2O + 4e–  4OH) = + 0.40 V
Eº (Cr3+.Cr) = – 0.74 V ; Eº (Cr2+.Cr) = – 0.91 V
Match Eº of the rebox pair in List I with the values given in List II and select the correct answer using the code
given below the lists :
List I List II
3+,
P. Eº (Fe Fe) 1. – 0.18 V
Q. Eº (4H2O 4H+ + 4OH–) 2. –0.4 V
R. Eº (Cu2+ + Cu  2Cu+) 3. –0.04 V
S. Eº(Cr3+, Cr+2) 4. –0.83 V

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Codes :
P Q R S P Q R S
(A) 4 1 2 3 (B) 2 3 4 1
(C) 1 2 3 4 (D) 3 4 1 2
27. Column-I Column-II
(A) Mohr's salt (aq.) + Na2O2 (p) Colored solution
(B) CuSO4 + NaN3 (q) White and insoluble product posssible
(C) Chrome alum(aq.) + Na2O2 (r) Colored and insoluble product possible
(D) Pb3O4 + HNO3 (s) Colorless solution
CONCEPT PRACTISE PROBLEM

(t) evolution of gas possible on heating.

ORGANIC
28. Which of the following structures are superimposable ?

(A) I & II (B) II & III (C) III & IV (D) II & IV
29. The main positions of electrophilic attack for the given reactions are respectively.

(A) 3, 1 (B) 6 , 3 (C) 6 , 4 (D) 3, 6

30. The reactant X & Y of following reactions are

HO O
OH–
X + Y  
H2O

(A) + CH3CHO (B)

(C) (D)

31. Observe the following reaction I and II k1, k1, k2 and k2 are rate constants. Select the correct option.

(I) CH3 – I

(II) CH3  CH  CH3

|
I
(A) k1 > k1 (B) k2k2 (C) k1 < k2 (D) k1<k2

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32. The product of the following reaction does not show positive test with

3NH Br / NaOH
  2  product.
 
CONCEPT PRACTISE PROBLEM

(A) (CHCl3 + KOH)/(Carbyl amine test) (B) HNO2, (-naphthol test)

(C) Ph–SO2Cl/NaOH (Hinsberg test) (D) Neutral FeCl3 Test

33. CCl3–CH=O reacts with chlorobenzene in presence of sulphuric acid & produces :

(A) (B)

(C) (D)

x y
34. Ph—CC—Ph  

The reagents x and y are respectively :

(A) Br2 / CCl4 , H2 / Ni (B) HBr , HBr
(C) Na / NH3 () , Br2 / CCl4 (D) Br2 / CCl4 , Lindlar's hydrogenation

35. Select the correct statements out of the following :

(A) -D(+) glucopyranose is more stable than -D(+) glucopyranose.
(B) Sucrose is laevorotatory sugar.
(C) Although fructose is a ketone but it gives positive Tollen's test.
(D) Starch contains -glycosidic linkage whereas cellulose contains -glycosidic linkage.
36. 2-Phenylbutan-2-ol can be prepared by :

ether 
(A) PhMgBr + H
 
 

O

ether
(B) CH3MgBr + Ph—C—C2H5  H
 
 
O

ether
(C) C2H5MgBr + Ph—C—CH 3  H
 
 

ether 
H
(D) CH3CH2CH2MgBr + PhCHO  
 

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37. (G)

How many total products of (G) are formed?

38. How many of the following are stronger bases than aniline ?
CONCEPT PRACTISE PROBLEM

39. 3-Amino-2,3-dimethylbutan-2-ol when treated with NaNO2/HCl gives product (X). (X) on treatment with LiAlH4
forms (Y). (Y) on heating with conc. H2SO4 forms (Z). Calculate the molecular weight of (Z).

40. Statement-1 : Nitration of benzene and hexadeuterobenzene occurs almost at the same rate.
Statement-2 : Cleavage of C–H bond takes faster than C–D bond.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

Comprehension-1
Compound (X) (C8H7N) on treatment with cold SnCl2/dil.HCl (aqueous), produces Y (C8H8O). (Y) on heating
with sodium acetate in acetic anhydride followed by acidification forms (Z) (C10H10O2). All these compounds
(X,Y,Z) on oxidation under severe conditions form a diacid which gives only one mononitro isomer in nitrating
mixture.

41. What is structure of (X) :

(A) (B) (C) (D)

42. What is not true about (Y) :

(A) It cannot gives fehling solution test (B) It gives Iodoform test positive
(C) It gives Tollen's test positive (D) It gives 2, 4-DNP test positive

43. The reductive ozonolysis products of (Z) are :

(A) CHO + CHO (B) H 3C CHO + COOH

COOH COOH
CH3

(C) COOH + CHO (D) H3C CHO + CHO

COOH COOH
CH3

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44. Match list I (reaction) with II (products) and then select the correct answer from the codes given below the
lists :
List I List II
(A) Phenol + NaOH + CH3 (p) Phenolphthalein
(B) Phenol + NaOH +CHCI3 (q) Salicylic acid
CONCEPT PRACTISE PROBLEM

(C) Phenol + Phthalic anhydride + conc. H2SO4 (r) Anisole

(D) Phenol + CO2 + NaOH (s) Salicylaldehyde

45. Column-I Column-II

(A) OH (p) Aromatic ring substitution




(B) CH CHO / OH

3     (q) Nucleophilic addition


(C) HNO H SO (r) Condensation reaction

32
4

(D) KCN / H (s) Formation of more than one organic products

  


(E) Alcoholic KCN

    

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