Physical Chemistry JEE (Advanced) 2015 Practice Problems

PHYSICAL CHEMISTRY
TARGET : JEE (ADVANCED) 2015

 

INFORMA TIO
Course : VIJETA & VIJAY (ADP & ADR) Date : 28-04-2015

E EST
DPPDAILY PRACTICE PROBLEMS
NO. 07
TEST INFORMATION
DATE : 29.04.2015 PART TEST (PT) - 3
Syllabus : Inorganic : s & p-Block Element, Metallurgy Organic : Aromatic compound, Carbonyl
Compounds, Carboxylic acids & theri derivatives, Grignard Reagent.
DPP No. # 07 (JEE-ADVANCED)

Total Marks : 169 Max. Time : 137 min.
Single choice Objective (–1 negative marking) Q.1 to Q.15 (3 marks 2½ min.) [45, 37½]
Multiple choice objective (–1 negative marking) Q.16 to Q.20 (4 marks, 3 min.) [20, 15]
Assertion and Reason (‘–1’ negative marking) Q.21 to Q.23 (3 marks 2½ min.) [09, 7½]
Comprehension (–1 negative marking) Q.24 to Q.32 (3 marks 2½ min.) [27, 22½]
Match Listing (–1 negative marking) Q.33 (8 marks, 3 min.) [08, 08]
Single Digit Subjective Questions (no negative marking) Q.34 to Q.38 (4 marks 2½ min.) [20, 12½]
Double Digits Subjective Questions (no negative marking) Q.39 to 42 (4 marks 2½ min.) [16, 10]
Match the column (4 vs 4) (no negative marking) Q.43 to Q.45 (8 marks, 8 min.) [24, 24]
1. The time of decay for thermonuclear reaction is given by t = 5 × t1/2. The relation between mean life T
and time of decay t is given by :
(A) 2Tln2 (B) 5Tln2 (C) 2Tln2 (D) 1/2ln2
2. Two first order reaction have half-lives in the ratio 8:1.Calculate the ratio of time intervals t1 : t2. The time
th th
 1 st
3 nd
t1 and t2 are the time period for  4  completion of 1 reaction and  4  completion of 2 reaction
   
respectively.
(A) 1 : 0.301 (B) 0.125 : 0.602 (C) 1 : 0.62 (D) none of these
3. The reaction A(g) + 2B(g)  C(g) is an elementary reaction. In an experiment involving this reaction,
the initial partial pressures of A and B are PA = 0.40 atm and PB = 1.0 atm respectively. When pressure
of C becomes (PC) = 0.3 atm in the reaction the rate of the reaction relative to the initial rate is :
1 1 1
(A) 12 (B) 50 (C) 25 D) none of these
4. Initial concentration of reaction for nth order reaction is 'a'. Which of the following relations is correct
about t1/2 of the reaction ?
(A) l n t1/2 = l n (constant) – (n – 1) logea (B) l n t1/2 = l n (constant) – l n a
(C) t1/2 l n n = l n (constant) + l n a0 (D) l n t1/2 = n l n a0
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Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-1
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5. Heptene decomposes according to following reaction

C7H14  2C2H4 + C3H6
–4 –1
Rate constant was found to be 1 × 10 sec . In what time (approximately) molar ratio of heptene to
ethene in the reaction mixture will attain the value 1?
[log 2 = 0.3010, log 3 = 0.4771]
(A) 68 min (B) 4055 min (C) 1736 min (D) 228 min
6. When the concentration of A is doubled, the rate for the reaction : 2A + B  2C quadruples. When the
concentration of B is doubled the rate remains the same. Which mechanism below is consistent with
the experimental observations ?
(A) Step I : 2A D (fast equilibrium)
Step II : B + D  E (slow)
Step III : E  2C (fast)
(B) Step I : A + B D (fast equilibrium)
Step II : A + D  2C (slow)
(C) Step I : A + B  D (slow)
Step II : A + D 2C (fast equilibrium)
(D) Step I : 2A  D (slow)
Step II : B + D  E (fast)
Step III : E  2C (fast)
k k
7. The reaction A   Product, is zero order reaction while the reaction B   Product, is first order
reaction. For what initial concentration of A are the half lives of the two reactions equal ?
(A) (loge4) M (B) 2M (C) log 2M (D) ln 2 M
8. Which of the following statements are correct :

(1) Order of a reaction can be known from experimental results and not from the stoichiometry of
reaction.
(2) Molecularity a reaction refers to (i) each of the elementary steps in (an overall mechanism of) a
complex reaction or (ii) a single step reaction.
(3) Overall order of a reaction mA + nB ABx is m + n.
Select the correct answer using the following codes.
(A) 2 and 3 (B) 1, 2 and 3 (C) 1, 3 (D) 1 , 2
9. Electromagnetic radiation of wavelength 242 nm is just sufficient to ionize sodium atom . Then
ionisation energy of sodium atom :
(A) 494.73 kJ/mol (B) 494. 73 kJ/atom
(C) 637.2 kJ/mol (D) 637.2 kJ/atom
10. The Schrodinger wave equation for an orbital in hydrogen atom is given as
3/2
1  Z 
(radial)  


 [( – 1)( 2 – 8  12)]e –  / 2
16 4   0 
2Zr
Where 0 and Z are the constant in which answer can be expressed and = , then nearest and
0
farthest position of radial nodes from nucleus are ……… respectively.
 0 3 0 0 0  0 3 0  0 4 0
(A) , (B) , (C) , (D) ,
Z Z 2Z Z 2Z Z 2Z Z
PAGE NO.-2
st
11. Consider the 1 order reactions :
k k k k
A 
1
 B ; 2A 
4
D ; B 
2
C ; D 
3
2C .
E1 E4 E2 E3
E1, E2, E3 and E4 are respective activation energies and k1, k2, k3 and k4 are respective rate constants.
Which of the following is not correct ?
d[B] d[C]
(A)  k1[A]  k 2 [B] (B)  k 2 [B]  2k 3 [D]
dt dt
k1E1  k 4E4
(C) Average activation energy of A  (D) None of these
k1  k 4
12. Difference between nth and (n + 1)th Bohr’s radius of H-atom is equal to its (n – 1)th Bohr’s radius. The
value of n is :
(A) 1 (B) 2 (C) 3 (D) 4
13. The half-life of 99Tc is 6.0 h. The total residual activity in a patient after receiving an injection containing
99Tc must not be more than 0.01 Ci, after 36.0 hours. What is the maximum activity (in Ci) that the
sample injected can have ?

(A) 0.06 B) 0.16 (C) 0.32 (D) 0.64
14. The angular momentum of an electron in a Bohr’s orbit of H-atom is 4.2178 × 10–34 kgm2/sec. Calculate
the wavelength of the spectral line emitted when electrons falls from this level to next lower level.
(A) 1.8 × 10–5 cm (B) 1.8 × 10–4 cm (C) 1.8 × 10–4 (D) 1.8 × 10–5 m
15. The uncertainity in speed of a moving atom of mass 200 amu is 100 m/s. What is the minimum
–24 –34
uncertainity in the measurement of its position ? (1 amu = 1.6 × 10 g ; h = 6.4 × 10 J sec)
–10 –12 –8 –6
(A) 1.1 × 10 m (B) 1.59 × 10 m (C) 1.01 × 10 m (D) 1.53 × 10 m
16. For a certain reaction A  products, the t½ as a function of [A]0 is given as below :
[A]0 (M) : 0.1 0.025
t½ (min.) : 100 50
Which of the following is/are true ?
1
(A) The order is (B) t½ would be 100 10 min for [A]0 = 1 M
2
(C) The order is 1 (D) t½ would be 100 min for [A]0 = 1 M
17. Consider the following first order decomposition and the accompanying concentration – time plot :
A4(g)  4 A (g) (log 2 = 0.3, log 5 = 0.7)
[A]
Conc.
[A4]
30 Hour
Time
Which of the following statements regarding the decomposition reaction is/are true ?
(A) At 30 hrs , only 20 %reaction is complete.
(B) Half –life of the reaction is 90 hrs (approximately).
(C) Rate of decomposition decreases linearly with time.
(D) Changing initial concentration will change the time at which the two curves are intersecting.
PAGE NO.-3
18. Element 'A' has principal quantum number 2 for last electron and it has 3 electron in valence shell and
element 'B' has principal quantum number 3 for last electron and it has seven electrons in the valence
shell. The atomic number of an element X is equal to sum of atomic numbers of A and B.
Which of the following statement is/are correct for X ?
(A) M shell contain 10 electrons
(B) Total number of electrons with l=1 are 12
(C) Total number of electrons with m=0 may be 14
(D) It can show back bonding in which d orbitals are involved.
19. Which of the following do not represent ground state configuration of given element ?
3 0 2 2
(A) Sc– [Ar] 3d 4s (Z=21) (B) Si– [Ne] 3s 3p (Z=14)
9 2 2 1
(C) Cu– [Ar] 3d 4s (Z=29) (D) La– [Xe] 6s 4f (Z=57)
n+
20. The magnetic moment of X is 24 BM. Hence, the species can be
2+ 2+ 2+ 3+
(A) Fe (B) Cr (C) Mn (D) Co
21. Statement-1 : For zero order reaction (AB), successive half life of reaction decreases with the
progress of reaction.
Statement-2 : Rate of zero order reaction remains unchanged with the progress of reaction.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True
22. Statement-1: The maximum degeneracy of an electron for which azimuthal quantum number is l is
(2l + 1).
Statement-2 : For a given value of l , the magnetic quantum number (m) can have any integral value in
the range of –1-------0--------+1.
23. Statement-1 : The shortest wavelength of transition of Lyman series is observed when electron jumps
from orbit no. n =  to n =1.
hc
Statement-2: The wavelength of transition is given by  
E
Comprehension # 1
DEFINITION VALID FOR SINGLE ELECTRON SYSTEM :
Z2 th
En =–13.6 2
eV / atom (Energy of electron in n orbit of hydrogen like species having atomic
n
number Z)
(i) Ground state :

Lowest energy state of any atom or ion is called ground state of the atom It is n = 1.
PAGE NO.-4
(ii) Excited State :
States of atom other than the ground state are called excited states :
n=2 first excited state
n=3 second excited state
n=4 third excited state
n=n+1 nth excited state
(iii) Ionisation energy (E) :
Minimum energy required to move an electron from ground state to
n =  is called ionisation energy of the atom or ion.
(iv) Excitation Energy :
Energy required to move an electron from ground state of the atom to any other state of the atom is
called
excitation energy of that state.
Excitation energy of 2nd state = excitation energy of 1st excited state = 1st excitation energy = E2 – E1
(v) Binding Energy ‘or’ Seperation Energy :
Energy required to move an electron from any state to n =  is called binding energy of that state.
Binding energy of ground state = .E. of atom or on.
The third excitation energy of a hydrogen like species is 204 eV.
24. Identify the hydrogen like species.

+ 2+ 3+ 4+
(A) He (B) Li (C) Be (D) B
25. What is the binding energy of efrom second state in the given species ?
(A) 13.6 eV (B) 54.4 eV (C) 122.2 eV (D) 17 eV
26. If ionisation energy is 'a' eV then ionisation potential is 'a' V. Using this information, find the ionisation
potential of given species.
(A) 54.4 V (B) 217.6 V (C) 122.4 V (D) 13.6 V
Comprehension # 2
For a particular reaction at constant temperature , A(g) + 2B(g)  products
Following rate information were recorded :
–1
Exp No. Initial [A] Initial [B] Initial rate [M min ]
1. 1.00 1.00 1.00
2. 2.00 4.00 8.00
3. 3.00 9.00 27.00
4. 4.00 2.00 ?
On the basis of following observation give the answer of the following questions
27. Which of the following is the correct rate law for the given reaction ?
2 2 2 1/2 1/2 2
(A) R = k[A] [B] (B) R = k[A] [B] (C) R = k[A] [B] (D) R = k[A] [B]
th
28. What is the rate of reaction in the 4 experiment ?
–1 –1 –1 –1
(A) 15.3 M min (B) 22.4 M min (C) 29.4 M min (D) 36 M min
Comprehension # 3
A definite volume of H2O2 undergoing decomposition required 22.8 mL of standard KMnO4 solution for
titration. After 10 and 20 min, the volumes of permanganate required were 13.8 and 8.25 mL,
respectively.
228 2280
Given ln  0.05 and ln  1.01
138 825
PAGE NO.-5
29. Find order of reaction.
(A) 1 (B) 2 (C) 3 (D) 3/2
30. Calculate the time (in. min) required for the decomposition to be half completed.
(A) 1.8 (B) 7.6 (C) 13.7 (D) 20.4
Comprehension # 4
Oxidation of metals is generally a slow electrochemical reaction involving many steps. These steps
involve
electron transfer reactions. A particular type of oxidation involve overall first order kinetics with respect
to fraction of unoxidized metal surface thickness (1–f) relative to the maximum thickness (T) of oxidized
surface, when metal surface is exposed to air for a considerable period of time.
df
Rate law : = k(1 – f ),
dt
where f = x / T,
x = thickness of the oxide film at time ' t '
and T= thickness of the oxide film at t = 
For the oxidation of a particular metal, a graph is shown in the figure.
O 200 h
t
–3
ln (1–f)
31. The time taken for thickness to grow 50% of T is

(A) 23.1 h (B) 46.2 h (C) 100 h (D) 92.4 h
32. The exponential variation of f with t (h) is

–3t/200 –3t/200 –3t/200 3t/200
(A) f = (1 – e ) (B) f = (1 – e –1) (C) f = e (D) f = e
33.
Match the following column :

Column-I Column-II
(P) Activation energy of forward reaction (1) 70 kJ mol–1
(Q) Threshold energy (2) 30 kJ mol–1
(R) Activation energy for backward reaction (3) 15 kJ mol–1
(S) Enthalpy change of the reaction (4) 45 kJ mol–1
P Q R S P Q R S
(A) 1 4 3 2 (B) 2 1 4 3
(C) 1 2 3 4 (D) 2 1 3 4
PAGE NO.-6
34. For zero order reaction A  3B plot of concentration vs time is as follows.
Conc.
A
0 2 4 6 8
t(min)
Find half life period in minutes if the initial concentration of A be 1 M.
12 139
35. Find the total number of alpha particles and neutrons emitted when C is bombarded on 57 La to
147
produce 63 Eu .(Assume no other particles are produced)
1
36. Calculate the maximum total number of electrons in Gallium, with spin + and which occupy orbitals
2
having minimum one radial node.
238 b 238
37. 92 U is bombarded with aX particle to produce 93 Np and two neutrons. The Np thus formed is
238
unstable and decays to produce 94 Pu along with a particle dc Y . Find a + b + c + d
K1 K1
st
38. A reversible reaction which is I order in both direction A B. For which value of following
K2 K2
graph will be correct (where a is initial amount of reactant A)
a
4a/5
Conc.
a/5
Time
39. Consider the first order parallel reactions, starting with 1 M of A.

3k 2k k
A  B ; A   2C ; A  3D
If [C] is x M, find 100 x.
24
40. 11 Na (half-life = 15 hrs) is known to contain some radioactive impurity (half-life = 3 hrs) in a sample.
This sample has an initial activity of 1000 counts per minute, and after 30 hrs it shows an activity of 200
counts per minute. What percent of the initial activity was due to the impurity
58
41. Zn decays by two paths. By path (I), it produce daughter nuclide 'X' along with a positron and proton.
By path(II) it produce daughter nuclide 'Y' along with a positron. Find the sum of neutrons in X and Y.
42. The hydration of ethylene oxide (C2H4O) in aqueous solution proceeds with first order kinetics such that
ethylene glycol is formed. The kinetics of the equation is determined by measuring the change in
volume of the liquid system. The change in volume is noted by measurement of height at various
instants in a thin capillary tube. From the data, calculate the rate of disappearance of ethylene dioxide
at an initial concentration of 22 g/L. Express answer in terms of M/day.
Time 0 3600 
Height (mm) 11 10 1
1
e
PAGE NO.-7
43. Match the following :
En = total energy
th
n = angular momentum in n orbit
Kn = K.E. , Vn = P.E.
Tn = time period, rn = radius of nth orbit
Column () Column ()

1
(a) En–y  rn then y, for a fixed Z, is (p)
2
(b) n  nx then x is (q) – 2
En
(c) is (r) – 3
Vn
Zt
(d) Tn  , t and m respectively are (s) 1
nm
44. Match entries in column-I with those in column-II for a radioactive sample :
Column-I Column-II
(A) Activity of sample (p) varies with time
(B) Half life of sample (q) varies with temperature.
(C) Number of radioactive nuclei (r) is a constant for a given species at any time
and temperature
(D) Decay constant (s) its log vs time graph is a straight line
45. Match the following :
Column-I Column- II
(a) t1/2 a
–1
(a = initial concentration of (p) Ef < Eb (Ef and Eb are activation
reactants) energies of forward and backward
reaction)
–1 –1
(b) Rate constant (k) has unit = L mol s (q) Order of reaction is 0.
(c) Equilibrium constant (K) has infinitely large (r) Order of reaction is 2.
value.
(d) t1/2 decreases linearly with time (s) [ A ]0
[A] =
1  kt[ A ]0
[A]0 = initial concentration ,
[A] = instantaneous concentration ,
k = rate constant.
PAGE NO.-8
Solution of DPP # 7
TARGET : JEE (ADVANCED) 2015
Course : VIJETA & VIJAY (ADP & ADR)
CHEMISTRY
ln2
1. t = 5 × t1/2 = 5 × = 5 Tln2

Hence, (B) is the correct answer .
( t1/ 2 )1  1  ( t 1/ 2 )2  1  t1 8 ln ( 4 / 3 )
2. t1 = ln   ; t2 = ln   ; t 2 = 1 × ln ( 4 ) = 1 : 0.62
0.693  1 – (1 / 4 )  0.693  1– 3 / 4 
3. A(g) + 2B(g)  C(g)

t=0 0.4 atm 1 atm 0 atm
t=t (0.4 –0.3)atm (1 – 0.6)atm 0.3 atm
Since reaction is elementary.
So, Rate of reaction w.r.t. A & B will be of order equal to stoichiometric coefficient
Rate = K [A] [B]2 ; Rate(Initial) = K [0.4] [1]2 ; Rate(after t = t) = K [0.1][0.4]2
2 1
R( t  t ) K[0.1] [0.4]
= =
R( t o ) K [ 0.4] [1] 25
1 1
4. t1/ 2  n 1
; t1/ 2  k n1
; ln t1/2 = ln k – (n – 1) loge a.
a a
Hence, (A) is the correct answer.
5. C7H14  2C2H4 + C3H6

a 0 0
a–x 2x x
a–x a 2.303 a
=1,x= ; 1 × 10–4 = log ; t = 67.59 min.
2x 3 t 2a /3
6. The information suggest that rate = k[A]2
This is satisfied by (D),
In (A) and (C) B is involved in slow step, ; In (B), if we solve,B will appears in rate law.
a a
7. For zero order reaction, x = kt ;   k  t1/ 2 i.e. t1/ 2  ....(i)
2 2k
loge 2
For first order reaction, t1/ 2  ....(ii)
k
a loge 2
From (i) and (ii),  ; a = loge4 M ; Hence, (A) is the correct answer.
2k k
nhc (6.022  10 23 )  (6.62  10 –34 )

8. Fact based 9. I.E. = = × 3×108 = 494.730 kJ/mol
 242  10 – 9
10. At nodes,  = 0
 ( – 1) (2 – 8 + 12) = 12  = 1 and (– 6) ( – 2) = 0

2Zr
 =6  = 2 ; Nearest radial node  = 1  1
0
0 3 0
 r Farthest radial node =6 ;  r
2Z Z
PAGE NO.-1
11. The listed reactions are first order reactions
d[B]
 k1[A]  k 2 [B]
dt
d[C] d[A]
 k 2 [B]  2k 3 [D] ;   k1[A]  2k 4 [A] ; keff = k1 + 2k4
dt dt
k E  2k 4E4
 Eeff = 1 1
k1  2k 4
12. r n  n2
But rn + 1 – rn = rn – 1 ; (n + 1)2 – n2 = (n – 1)2 ; n=4
Hence. (D) is the correct answer.
A0 A0
13. Activity after ‘n’ half lives = n
so, 0.01 = Hence A0 = 0.64 Ci
2 26
nh
14. mvr =
2
nh 4.1278  10 34  2  3.14 1  1 1

 4.2178  10 34 ; n 34
4 ;  R 2  2 
2 6.625  10   n1 n2 
The wavelength for transition from n = 4 to n = 3

1  1 1
 109678  2  2  ;  = 1.8 × 10–4 cm.
 3 4 
15. p = mv
= 200 × 1.6 ×10–24 × 10–3 × 100 = 3.2 × 10–23 kgm/sec
h h 6.4  10 –34
x. p  ;  x   x 
4 4 p 4  3.14  3.2  10 –23
 x 1.59 ×10–12 m


16. A  Products.
1– n
100  0 .1 
t½ = [conc.] 1-n
; n  order of reaction. =  0.025  2 = 2 – 2n  2n = 1
50  
1/ 2
1 1 100  0 .1 
 n= order of reaction is ; =  
2 2 t 1/ 2  1 
 t½ = 100 10 min for [A0] = 1M. (t½ = 100 10 min [A0] = 1M)

17. A4   4A
a 0
a-x 4x
At 30 hrs, a – x = 4x
a = 5x
a
x Hence reaction is 20% complete.
5
1 a 1 5
k ln ; k ln
30 4a / 5 30 4
ln 2 ln 2  30 log2  30 0.3  30 9
 t1/2=  = = =  90hrs
k ln5  ln 4 log5  log 4 0.7  0.6 0.1
 rate follows exponential decay with time.
In first order reaction, tx% is independent of initial concentration.
PAGE NO.-2
18. Element A = 1s2 2s2 2p1
Element B = 1s2 2s2 2p6 3s2 3p5 ; atomic number of X = 5 + 17 = 22
X is Ti
1s2 2s2 2p6 3s2 3p6 3d2 4s2 ; M shell contain 2 + 6 + 2 = 10 electron
Total number of electron with l = 1
= 6 + 6 = 12
Total number of electrons with m = 0
= 2 + 2 + 2 + 2 + 2 + 2 + 1 = 13
As d orbitals contain electrons, so d orbitals can be involved in back bonding.
19. (A) [Ar] 3d14s2 (B) [Ar] 3d104s1 (D) [Xe] 6s25d1
20. n(n  2)  24  n = 4
Hence, 4 unpaired electron. ; Fe2+ 4 unpaired electron (3d6)
Cr2+ 3d4 (4 unpaired electron) ; Mn2+ 3d5 (5 unpaired electron)
Co3+ 3d6 (4 unpaired electron) ; n(n  2)  24  n = 4
26. E4 –E1 = 204 eV
13.6  Z 2 15
  13.6Z 2 = 204  Z2 × 13.6 × = 204
42 16
16 1
 Z2 = 204 ×   Z=4
15 13.6
 42 
B.E. (2nd State) = 0 – E2 = 0   13.6  2 
 2 
= 13.6 × 4 = 54.4 eV
42
I.E. = 0 – E1 = –E1 = +13.6 × = 217.6 eV  Ionisation potential = 217.6 V
12
27. r = k[A]x [B]y
1=k .....(1)
8 = k(2)x (4)y .....(2)
27 = k(3)x 9)y .....(3)
PAGE NO.-3
1 1 1 1
   x + 2y = 3 and   x + 2y = 3
8 2x.22y 27 3 x 32y
x = 1, y = 2 does not satisfy this relation. ; x = 2, y = 1 does not satisfy this relation.
x = 2, y = 1/2 satisfy this relation ; x = 1/2, y = 2 does not satisfy this relation.
So, ans is r = k[A]2 [B]1/2
r = k[A]x [B]y
1=k .....(1) 8 = k(2)x (4)y .....(2) 27 = k(3)x 9)y .....(3)
1 1
   x + 2y = 3
8 2x.22y
28. r = 1 × [4]2 [2]1/2
= 16 2 = 22.6 M/min.
29. Let the order be first order. Then
1 0  22.8 1 228 1 114
K ln = ln  ln
10 0  13.8 10 138 10 69
1 1 22.8 1
=  0.50  0.05 ; and k ln =  1.01 = 0.05
10 20 8.25 20
As both K are similar, assumption is correct. It is a first order reaction.
ln 2 0.693 df
30. t1/ 2 
K
=
0.05
= 13.86 minutes. 32.  1 f   kdt
34. A  3B
t=0 1 0
t=t 1 – x 3x
at t = 4, 1 – x = 3x
x = 1/4
for zero order reaction
3 1 1 C
Ct = C0 – kt ; =1–k×4 ; 4k = ;k= and t1/2 = 0 .
4 4 16 2k
1
t1/2 = =8
1
2
16
12 139
35. 6 C  57 La  147 4 1
63 Eu  a 2 He  b 0 n
6 + 57 = 63 + 2a
a=0 and 139 + 12 = 147 + b  b = 4
Hence a + b =4.
36. 31Ga = 1s22s22p63s23p64s23d104p1
Orbitals having atleast one radial node = 2s,3s,3p,4s,4p
1
Hence maximum electrons with spin +
2
= 1+1+3+1+1=7
31Ga = 1s22s22p63s23p64s23d104p1
PAGE NO.-4
238 b
37. 92 U  a X  238
93 Np  2 01n
238
b=2 , a =1 ;  238
93 Np  94 Pu   dc Y ; c = –1 , d=0  a + b + c + d = 2
38.
t=0 a 0
t=t a-x x
t = teq a-xeq xeq
x eq K1 K1
at equilibrium  ; From graph 4
a  x eq K2 K2
39. [A]t = A0 e–6kt

4k 4k 2
[C] t = [1 – e–bkt] ; [C] = [1 – e–] = = 0.67
3k  2k  k 6k 3
40. Let the activity due to impurity be ‘a’ cpm.

 due to Na it is (1000 – a) cpm.
10
 1
After 30 hrs ‘a’ would be reduced to   a cpm
2
1
and (1000 – a) would be reduced to (1000 – a) cpm
4
10
 1 1
 total activity after 30 hrs would be ;   a + (1000 – a) = 200 (given)
2 4
solving we get
1 1
250 – a  200  a = 50  a = 200
4 4
Hence 20% activity was due to impurity.
58
41. 30 Zn  57 0 1
28 X  1 e  1p
Neutrons = 57 –28 = 29
58
30 Zn  58
29Y  0
1e
neutrons
=29
 total neutrons in X and Y = 29 +29 =58
1 h  h0 1 1  11
42. K= ln  = ln
t h  h t 3600 10
1  1
e
1 1 1
= ln e  /sec = × 60 × 60 × 24 = 24 /day
3600 3600 3600
22
 rate = K.[C2H4O] = 24× = 12 M/day.
44
–ln (1-f) = kt + c t=0, f=0 –ln (1-f) = kt
3 200
From Figure k   f = (1 – e–3t/200) ; For 50% grow t   ln(0.5 )  46.20 h
200 3
PAGE NO.-5
43. (a) En–y  rn
 Z2   n2 
  13.6 eV     0.529 Å 
 n2   Z 
   
y=1
(b) n  nx
nh
 nx
2
x=1
(c) Potential energy = 2 total energy
n3
(d) Tn  t=–2 m=–3
z2
44. In radioactive species
(A) Activity = N = N0e–t and  is independent of temperature and time.
t
So, Activity varies with time and log(activity) = log N0 –
2.303
Hence graph is linear.
(B) t1/2 is independent of time and also temperature.
(C) N = N0e–t
Hence, N depends on time and its log vs time graph is straight line.
(D) Explained in (A)
1
45. (A) t1/ 2 
a
[A 0 ]
order is second and [A] 
1  kt[A 0 ]
[A 0 ]
(B) Unit of k suggest that order is second and [A] 
1  kt [A 0 ]
kf
(C) K  is infinitely large when kf > kb. This happens when Ea of forward reaction is less than of
kb
backward reaction.
(D) Addition of catalyst increases the rate greatly when the uncatalysed reaction is very slow. i.e. when
its activation energy is very large.
PAGE NO.-6

Physical Chemistry JEE (Advanced) 2015 Practice Problems

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Physical Chemistry JEE (Advanced) 2015 Practice Problems

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PHYSICAL CHEMISTRY

TARGET : JEE (ADVANCED) 2015

Course : VIJETA & VIJAY (ADP & ADR) Date : 28-04-2015

DATE : 29.04.2015 PART TEST (PT) - 3

DPP No. # 07 (JEE-ADVANCED)

8. Which of the following statements are correct :

sample injected can have ?

(i) Ground state :

The third excitation energy of a hydrogen like species is 204 eV.

24. Identify the hydrogen like species.

31. The time taken for thickness to grow 50% of T is

32. The exponential variation of f with t (h) is

Match the following column :

39. Consider the first order parallel reactions, starting with 1 M of A.

Column () Column ()

(b) n  nx then x is (q) – 2

(A) Activity of sample (p) varies with time

(B) Half life of sample (q) varies with temperature.

45. Match the following :

3. A(g) + 2B(g)  C(g)

5. C7H14  2C2H4 + C3H6

nhc (6.022  10 23 )  (6.62  10 –34 )

nh 4.1278  10 34  2  3.14 1  1 1

The wavelength for transition from n = 4 to n = 3

Element B = 1s2 2s2 2p6 3s2 3p5 ; atomic number of X = 5 + 17 = 22

Total number of electron with l = 1

Total number of electrons with m = 0

As d orbitals contain electrons, so d orbitals can be involved in back bonding.

Hence, 4 unpaired electron. ; Fe2+ 4 unpaired electron (3d6)

Cr2+ 3d4 (4 unpaired electron) ; Mn2+ 3d5 (5 unpaired electron)

Co3+ 3d6 (4 unpaired electron) ; n(n  2)  24  n = 4

26. E4 –E1 = 204 eV

27. r = k[A]x [B]y

8 = k(2)x (4)y .....(2)

27 = k(3)x 9)y .....(3)

36. 31Ga = 1s22s22p63s23p64s23d104p1

Orbitals having atleast one radial node = 2s,3s,3p,4s,4p

39. [A]t = A0 e–6kt

40. Let the activity due to impurity be ‘a’ cpm.

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