ALLEN

TOPIC : Chemical Kinetics, Equilibrium, Ionic equilibrium.

46. For the reaction, 2N2O5(g) ® 4 NO2(g) + O2(g), the 46. vfHkfØ;k, 2N2O5(g) ® 4 NO2(g) + O2(g), ds fy, O2 ds
rate of formation of O2 is 0.032g hour–1, then rate fuekZ.k dh nj 0.032g hour–1 gS rks N2O5 ds ifjorZu dh
of conversion of N2O5 in g hour–1 is :- nj g hour–1 esa gS :-
(1) 0.216 (2) 0.098 (1) 0.216 (2) 0.098
(3) 0.627 (4) 0.313 (3) 0.627 (4) 0.313
47. For a reaction 2A + 2B + C ® products 47. vfHkfØ;k 2A + 2B + C ® mRikn] ds fy,
with the help of the following table, find order with fuEu lkj.kh dh lgk;rk ls A, B, C ds lkis{k dksfV gS &
respect to A, B, C [A] [B] [C] vfHkfØ;k
[A] [B] [C] rate of os x
reaction 0.010 0.005 0.010 5 × 10–3
0.010 0.005 0.010 5 × 10–3 0.010 0.005 0.015 5 × 10–3
0.010 0.005 0.015 5 × 10–3 0.010 0.010 0.010 1 × 10–2
0.010 0.010 0.010 1 × 10–2 0.005 0.005 0.010 2.5 × 10 –3
0.005 0.005 0.010 2.5 × 10 –3 (1) 3,2,0 (2) 1,1,0
(1) 3,2,0 (2) 1,1,0 (3) 3,2,1 (4) 2,2,1 (3) 3,2,1 (4) 2,2,1
48. Decomposition reaction of N2O5 follows first order 48. N2O5 dk fo?kVu izFke dksfV dk vuqlj.k djrk gS ftls fuEu
and is written as :- izdkj fy[kk x;k gS :-
2N2O5(g) ® 4NO2(g) + O2(g); rate = k[N2O5] 2N2O5(g) ® 4NO2(g) + O2(g); nj = k[N2O5]
N2O5(g) ® 2NO2(g) + O2(g); rate = k' [N2O5] N2O5(g) ® 2NO2(g) + O2(g); nj = k' [N2O5]
which of the following relation is true ? fuEu esa ls dkuS lk lEca/k lgh gS ?
(1) k = k' (2) k > k' (3) k > 2k' (4) 2k = k' (1) k = k' (2) k > k' (3) k > 2k' (4) 2k = k'
49. The mechanism of the reaction 2NO2 + F2 ® 2NO2F 49. vfHkfØ;k 2NO2 + F2 ® 2NO2F ds fy, fØ;kfof/k in
is :- fn, x, gaS&
(i) NO2 ¾¾¾
Slow
® NO + O /khek
(i) NO2 ¾¾¾ ® NO + O
(ii) F2 + O + NO ¾¾®
fast NO2F + F rhoz
(ii) F2 + O + NO ¾¾® NO2F + F
(iii) F + NO2 NO2F. rhoz
(iii) F + NO2 ¾¾®
¾¾®fast
NO2F.
Select the correct one lgh fodYi dks pqfu,&
(1) the reaction is of 3rd order (1) vfHkfØ;k dh dksfV 3 gAS
(2) the molecularity of the reaction is sum of (2) vfHkfØ;k dh vkf.odrk lHkh inksa dh vkf.odrk dk ;ksx
molecularities of all steps gksxkA
(3) reaction is zero order w.r.t. F 2 (3) vfHkfØ;k dh dksfV F2 ds lkis{k 'kwU; gAS
(4) half life of reaction depends upon initial (4) vfHkfØ;k dk v¼Z vk;qdky NO2 dh izkjfEHkd lkUnzrk
concentration of NO2. ij fuHkZj djrk gSA
50. If the slope of a line of the graph between time 50. 'kwU; dksfV vfHkfØ;k ds fy, le; (?kaVs es)a rFkk mRikn dh mRiUu
(in hour) and concentration of formed product for lkUnzrk ds e/; xzkQ dk <+ky 0.2 gaS rks fØ;kdkjd dh izkjfEHkd
zero order reaction is 0.2 then what will be the lkUnzrk eksy L–1 esa D;k gksxh ;fn 30 feuV i'pkr~ bldh lkUnzrk
initial concentration of reactant in mol L–1, if after 0.05 eksy L–1 gks &
30 minute its concentration is 0.05 mol L –1 : (1) 0.01 (2) 0.15
(1) 0.01 (2) 0.15 (3) 0.25 (4) 0.50 (3) 0.25 (4) 0.50
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51. At 300 K the half-life of a sample of a gaseous 51. 300 K ij] 1 atm nkc ij j[ks xSlh; ;kSfxd ds izfrn'kZ
compound intially at 1 atm is 100 s. When the dh v¼Z& vk;q 100 ld S .M gSA tc nkc 0.5 atm gS rks
pressure is 0.5 atm the half-life is 50 s. The order v¼Z&vk;q dky 50 ld S .M gAS ;kSfxd dh vfHkfØ;k dh dksfV
of reaction of compound is :- gS :-
(1) 0 (2) 1 (3) 2 (4) 3 (1) 0 (2) 1 (3) 2 (4) 3
52. A first order reaction is 50% completed in 20 min at 52. ,d izFke dksfV vfHkfØ;k 27ºC ij 20 feuV esa 50% iw.kZ gksrh
27ºC and in 5 min. at 47ºC. The energy of activation gS rFkk 47ºC ij 5 feuV esa 50% iw.kZ gksrh gSA vfHkfØ;k dh
of the reaction is :- lfØ;.k ÅtkZ g&S
(1) 43.85 KJ/mol (2) 55.3 KJ/mol (1) 43.85 KJ/mol (2) 55.3 KJ/mol
(3) 11.97 KJ/mol (4) 6.65 KJ/mol (3) 11.97 KJ/mol (4) 6.65 KJ/mol
53. The rate of reaction is expressed in different ways 53. fdlh vfHkfØ;k dh nj fuEu izdkj ls iznf'kZr dh tk ldrh
as follows : gS &
1 d[C] 1 d[D] 1 d[A] d[B] 1 d[C] 1 d[D] 1 d[A] d[B]
+ =- =+ =- + =- =+ =-
2 dt 3 dt 4 dt dt 2 dt 3 dt 4 dt dt
The reaction is : rks vfHkfØ;k gS &
(1) 4A + B ® 2C + 3D(2) B + 3D ® 4A + 2C (1) 4A + B ® 2C + 3D(2) B + 3D ® 4A + 2C
(3) A + B ® C + D (4) B + D ® A + C (3) A + B ® C + D (4) B + D ® A + C
54. For the reaction 2A ® B + 3C ; if 54. vfHkfØ;k 2A ¾® B + 3C ds fy, ;fn
d[A] d[B] d[C] d[A] d[B] d[C]
– = k1[A]2 ; = k 2 [A]2 ; = k 3[A]2 the – = k1[A]2 ; = k 2 [A]2 ; = k 3[A]2 gaS] rks
dt dt dt dt dt dt
correct relation between k1 , k2 and k3 is : k1, k2 rFkk k3 esa lgh lEcU/k g\
S
(1) k1 = k2 = k3 (2) 2k1 = k2 = 3k2 (1) k1 = k2 = k3 (2) 2k1 = k2 = 3k2
k1 k k1 k
(3) 4k1 = k2 = 3k2 (4) = k2 = 3 (3) 4k1 = k2 = 3k2 (4) = k2 = 3
2 3 2 3
55. For A(g) + B(g) ¾® C(g) ; rate = k[A]1/2[B]2, if initial 55. A(g) + B(g) ¾® C(g) ds fy, nj = k[A]1/2[B]2 gAS ;fn
concentration of A and B are increased by factors A o B dh izkjafHkd lkUnzrk,¡ Øe'k% 4 o 2 xquh dj nha tk;s
4 and 2 respectively, then the initial rate is changed rks izkjafHkd nj esa gksus okyh o`f¼ fdrus xquk g\
S
by the factor : (1) 4 (2) 6
(1) 4 (2) 6
(3) 8 (4) None of these (3) 8 (4) buesa ls dksbZ ugha
56. The reaction 2NO(g) + O2(g) ¾¾® 2NO2(g) is of 56. vfHkfØ;k 2NO(g) + O2(g) ¾¾® 2NO2(g) izFke dksfV dh
first order. If volume of reaction vessel is reduced gAS ;fn vfHkfØ;k ik= dk vk;ru 1/3 dj fn;k tk;s rks
to 1/3, the rate of reaction would be : vfHkfØ;k dh nj gS &
(1) 1/3 times (2) 2/3 times (1) 1/3 xquk (2) 2/3 xquk
(3) 3 times (4) 6 times (3) 3 xquk (4) 6 xquk
57. The molecularity of a complex reaction given 57. uhps nh x;h tfVy vfHkfØ;k dh v.kqla [;rk gS &
below is :
2N2O5 (g) ¾® 4NO2(g) + O2(g)
2N2O5 (g) ¾® 4NO2(g) + O2(g)
(1) 1 (2) 2 (1) 1 (2) 2
(3) 3 (4) has no meaning (3) 3 (4) dksbZ vFkZ ugha gAS

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58. A first order reaction is 75% completed in 58. izFke dksfV dh ,d vfHkfØ;k 100 feuV esa 75% iw.kZ gks
100 minutes. How long time will it take for it's tkrh gAS vfHkfØ;k ds 87.5% iw.kZ gksus esa yxus okyk le;
87.5% completion ? gksxk&
(1) 125 min (2) 150 min (1) 125 min (2) 150 min
(3) 175 min (4) 200 min (3) 175 min (4) 200 min
59. Rate constant for a chemical reaction takes place 59. 500 K ij gks jgh ,d vfHkfØ;k ds fy, nj fLFkjka d
at 500 K is expressed as K = A. e –1000 . The K = A. e–1000 gAS vfHkfØ;k dh lfØ;.k ÅtkZ gS &
activation energy of the reaction is : (1) 100 dSyksjh@eksy (2) 1000 fdyks dSyksjh@eksy
(1) 100 cal/mol (2) 1000 kcal/mol
4
(3) 10 kcal/mol (4) 106 kcal/mol (3) 10 fdyks dSyksjh@eksy (4) 106 fdyks dSyksjh@eksy
4

60. Which of the following represents the expression 60. fuEufyf[kr esa ls dkSulk O;atd fdlh izFke dksfV dh vfHkfØ;k
3 3
for th life of first order reaction ? ds iw.kZ gksus esa yxus okys le; dks iznf'kZr djrk gS &
4 4

k 2.303 k 2.303
(1) log 4 / 3 (2) log 3 / 4 (1) log 4 / 3 (2) log 3 / 4
2.303 k 2.303 k

2.303 2.303 2.303 2.303

(3) log 4 (4) log 3 (3) log 4 (4) log 3
k k k k
61. The minimum energy for molecules required to 61. v.kqvksa dh izHkkoh VDdjksa ds fy, vko';d U;wure ÅtkZ dgykrh
give effective collision is called : gSA
(1) Kinetic energy (2) Potential energy (1) xfrt ÅtkZ (2) fLFkfrt ÅtkZ
(3) Threshold energy (4) Activation energy (3) nsgyh ÅtkZ (4) lfØ;.k ÅtkZ
62. An endothermic reaction A ® B has an activation 62. ,d Å"ek'kks"kh vfHkfØ;k A ® B dh lfØ;.k ÅtkZ
energy 15 k cal/mol and the heat of reaction is 15 kcal/mol gS vkSj vfHkfØ;k Å"ek 5 fd- dSyksjh@eksy gS
5 k cal/mol. What will be the threshold energy vfHkfØ;k B ® A dh nsgyh ÅtkZ D;k gksxh ;fn mRikn dh
of the reaction B ® A if potential energy of fLFkfrt ÅtkZ 10 fd- dSyksjh@eksy g%S
product is 10 kcal/mol :- (1) 20 fd- dSyksjh@eksy (2) 15 fd- dSyksjh@eksy
(1) 20 k cal/mol (2) 15 k cal/mol
(3) 10 k cal/mol (4) Zero (3) 10 fd- dSyksjh@eksy (4) 'kw U;
63. For a certain gaseous reaction rise of temperature 63. ,d xSlh; vfHkfØ;k ds fy, rki 25° C ls 35° C rd c<+kus
from 25° C to 35° C doubles the rate of reaction. ij vfHkfØ;k dh nj nks xquk gks tkrh gAS lfØ;.k ÅtkZ dk eku
What is the value of activation energy :– D;k gS %&
10 10
(1) (1)
2.303R ´ 298 ´ 308 2.303R ´ 298 ´ 308
2.303 ´ 10 2.303 ´ 10
(2) (2)
298 ´ 308R 298 ´ 308R
0.693R ´ 10 0.693R ´ 10
(3) (3)
290 ´ 308 290 ´ 308
0.693R ´ 298 ´ 308 0.693R ´ 298 ´ 308
(4) (4)
10 10
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64. For a reaction 64. vfHkfØ;k
+ - -
6H + 5Br + BrO ¾¾
® 3Br2 + 6H 2 O
3 6H + + 5Br - + BrO3- ¾¾
® 3Br2 + 6H 2 O
If rate of consumption of BrO3- is x mol L–1 s–1 ds fy, ;fn BrO3- ds iz;qDr gksus dh nj x eksy L–1s–1 gS rks
then calculate rate of formation of Br2 :- Br2 ds cuuss dh nj Kkr djks :-
x 2x x x 2x x
(1) (2) (3) (4) 3x (1) (2) (3) (4) 3x
3 3 4 3 3 4
65. Arrhenius equation may not be written as :– 65. vkjsfu;l lehdj.k dks ugha fy[kk tk ldrk gS :–
E Ea
- a -
(1) K = Ae RT
(1) K = Ae RT

Ea Ea
(2) lnK = lnA - 2.303RT (2) lnK = lnA - 2.303RT

a E a E
(3) logK = logA - 2.303RT (3) logK = logA - 2.303RT

d Ea d Ea
(4) (ln K) = (4) (ln K) =
dT RT 2 dT RT 2
66. ˆˆˆ†
2A(g) + B(g) ‡ˆˆˆ Product, is an elementary reaction, 66. 2A(g) + B(g) ˆˆˆ†
mRikn] ,d izkjfEHkd vfHkfØ;k gS
‡ˆˆˆ
If pressure is increased three times of the initial mijksä fØ;k ds fy, ;fn nkc dks izkjfEHkd nkc dk rhu xquk
pressure, the velocity of forward reaction will be dj nsa rks vxz fØ;k dk osx igys osx dk---------gks tk;sxk%
------ of the previous velocity:- (1) 9 xquk (2) 27 xquk
(1) 9 times (2) 27 times
1 1
1 1 (3)
9
xq uk (4)
27
xq uk
(3) times (4) times
9 27
Kp Kp
67. log K + log RT = 0 is true relationship for the 67. log K + log RT = 0, fuEu vfHkfØ;k ds fy;s lgh lEcaèk
c c
following reaction:-
gksxk%
(1) PCl5 ƒ PCl3 + Cl2 (2) 2SO2 + O2 ƒ 2SO3
(1) PCl5 ƒ PCl3 + Cl2 (2) 2SO2 + O2 ƒ 2SO3
(3) N2 + 3H2 ƒ 2NH3 (4) (2) and (3) both
(3) N2 + 3H2 ƒ 2NH3 (4) (2) rFkk (3) nksuksa
68. PCl5 (g) ƒ PCl3 (g) + Cl2 (g)
In above reaction, at equilibrium condition mole 68. vfHkfØ;k PCl5(g) ‡ˆˆˆ† ˆ PCl3(g) + Cl2(g) esa lkE; voLFkk
fraction of PCl5 is 0.4 and mole fraction of Cl2 is ij PCl5 dh eksy fHkUu 0.4 rFkk Cl2 dh eksy fHkUu 0.3 g]S
0.3. Then find out mole fraction of PCl 3 rks PCl3 dh eksy fHkUu gksxh%
(1) 0.3 (2) 0.7 (3) 0.4 (4) 0.6 (1) 0.3 (2) 0.7 (3) 0.4 (4) 0.6
69. Given the reaction between 2 gases represented 69. A2 rFkk B2 }kjk iznf'kZr dh xbZ nks xSlksa ds e/; vfHkfØ;k gksus
by A2 and B2 to give the compound AB(g). ij AB(g) ;kSfxd curk gAS
A2(g) + B2(g) = 2AB(g). A2(g) + B2(g) = 2AB(g).
At equilibrium, the concentration lkE; ij
of A2 = 3.0 × 10–3 M A2 dh lkUærk 3.0 × 10–3 M
of B2 = 4.2 × 10–3 M B2 dh lkUærk 4.2 × 10–3 M
of AB = 2.8 × 10–3 M AB dh lkUærk 2.8 × 10–3 M
If the reaction takes place in a sealed vessel at ;fn 527°C ij vfHkfØ;k ,d can ik= esa gksrh gS rks KC dk
527°C, then the value of KC will be :- eku gksxk :-
(1) 0.62 (2) 4.5 (3) 2.0 (4) 1.9 (1) 0.62 (2) 4.5 (3) 2.0 (4) 1.9
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70. For the reaction C(s) + CO2(g) ƒ 2CO(g) the partial 70. vfHkfØ;k C(s) + CO2(g) ƒ 2CO(g) ds fy;s lkE; ij
pressure of CO and CO 2 are 2.0 and 4.0 atm. CO rFkk CO2 ds vkaf'kd nkc Øe'k% 2.0 rFkk 4.0 ok;qe.My
respectively at equilibrium. The KP for the reaction is gaAS vfHkfØ;k ds fy;s KP gS :-
(1) 0.5 (2) 4.0 (1) 0.5 (2) 4.0
(3) 8.0 (4) 1 (3) 8.0 (4) 1
71. For the equilibrium SO2Cl2(g) ƒ SO2(g) + Cl2(g) what 71. SO2Cl2(g) ƒ SO2(g) + Cl2(g) vfHkfØ;k esa fdl rki ij
KP KP
is the temperature at which =1? = 1 gksxk\
KC KC
(1) 36.54 K (2) 273 K (1) 36.54 K (2) 273 K
(3) 12.18 K (4) 0 K (3) 12.18 K (4) 0 K
72. At a certain temperature, the equilibrium constant 72. fdlh rki ij fuEu vfHkfØ;k
KC is 25 for the reaction A2(g) + B2(g) ƒ C2(g) + D2(g)
A2(g) + B2(g) ƒ C2(g) + D2(g) dk KC dk eku 25 gAS ;fn izR;sd xl S ds 1 eksy 1 L ik=
If we take 1 mol of each of the four gases in a esa fy;k tk, rks A2 dh lkE; ij lkaærk D;k gksxh\
1 L container, what would be equilibrium (1) 0.33
concentration of A2 ? (2) 0.133
(1) 0.33 (2) 0.133 (3) 0.033
(3) 0.033 (4) 1.33 (4) 1.33
73. In equation N 2(g) + O2(g) ƒ 2NO(g), KC = 10–40 73. N2(g) + O2(g) ƒ 2NO(g), KC = 10–40
Initially 0.4 mole of N2 and 0.9 mole of O2 were izkjEHk esa 0.4 eksy N2 rFkk 0.9 eksy O2 fefJr fd;s x;sA
mixed then moles of N2, O2 and NO at equilibrium lkE;koLFkk ij N2, O2 o NO ds eksy gksaxs (yxHkx) :-
are (approximate) :- (1) 0.4, 0.9, 6 × 10–21
(1) 0.4, 0.9, 6 × 10–21
(2) 4 × 10–21, 6 × 10–21, 6 × 10–21
(2) 4 × 10–21, 6 × 10–21, 6 × 10–21
(3) 0.4, 0.9, 0.9 (3) 0.4, 0.9, 0.9
(4) 6 × 10–21 , 0.4, 0.9 (4) 6 × 10–21 , 0.4, 0.9
74. At 200°C, nitrogen oxide reacts with oxygen to 74. 200°C rki ij ukbVªkstu vkWDlkbM] O2 ds lkFk fØ;k dj
form nitrogen dioxide as follows : fuEukuqlkj NO2 cukrk gS :
2NO + O2 ƒ 2NO2 , KC = 3 × 106 2NO + O2 ƒ 2NO2 , KC = 3 × 106
In a mixture of the three species at equilibrium,
lkE;koLFkk ij rhuksa Lih'kht ds feJ.k ds ckjs esa dkSulk dFku
we can accurately predict that
fcYdqy lgh gS
(1) The concentrations of both NO and O2 will be
(1) NO rFkk O2 nksuksa dh lkUærk,¡ NO2 dh lkUærk ls cgqr
much larger than the concentration of NO2
(2) The concentrations of both NO and O2 will be
vf/kd gSaA
much smaller than the concentration of NO2 (2) NO rFkk O2 nksuksa dh lkUærk,¡ NO2 dh lkUærk ls cgqr
(3) The concentrations of either NO or O 2 and de jgrh gaAS
possibly both will be much smaller than the (3) NO ;k O2 dh lkUærk vFkok NO rFkk O2 nksuksa dh lkUnzrk
concentration of NO2 NO2 dh lkUnzrk ls cgqr de gAS
(4) The concentration of O2 will be exactly one (4) O2 dh lkUærk, NO dh lkUærk dh fcYdq y vk/kh
half the concentration of NO gSA
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75. For the reaction N2(g) + 3H2(g) ƒ 2NH3(g) initial 75. N2(g) + 3H2(g) ƒ 2NH3(g) vfHkfØ;k ds fy;s izkjEHk
N2 and H2 were taken in the mole ratio of 1 : 3. At esa N2 : H2 dk eksy vuqikr 1 : 3 fy;k x;kA lkE; igq¡pus
the point of equilibrium 40% of each reactant has rd izR;sd dk 40% vfHkd`r gks pqdk gksrk gAS ;fn lkE; ij
been reacted. If the total pressure at equilibrium was dqy nkc P gks rks NH3 dk vkaf'kd nkc gksxk-
P. The partial pressure of NH3 will be -
P P
P P (1) (2)
(1) (2) 3 6
3 6

P P P
P (3) (4)
(3) (4) 4 8
4 8
76. BOH is a weak monoacidic base (Kb = 1.5 × 10–5). 76. ,dy vEyh; nqcZy {kkj BOH ds fy, Kb = 1.5 × 10–5 gAS
BOH dh eksyj lkUnzrk Kkr djks tks 1.5 × 10–3 M [OH–]
The molar concentration of BOH that provides éëOH ùû
iznku dj ldsA
of 1.5 × 10–3 M will be :-
(1) 0.15 (2) 0.0015
(1) 0.15 (2) 0.0015
(3) 1.5 × 10 –5
(4) 0.015 (3) 1.5 × 10–5 (4) 0.015
77. Which of the following salt will give cationic 77. fuEu esa ls dkSulk yo.k /kuk;fud ty vi?kVu nsxk\
hydrolysis ? (1) CH3COONa
(1) CH3COONa
N N
N N (2) 100 ml NH4OH + 100 ml HCl
(2) 100 ml NH4OH + 100 ml HCl 10 10
10 10
N N
N N (3) 100 ml NH4OH + 100 ml HCl
(3) 100 ml NH4OH + 100 ml HCl 10 20
10 20
N N N N
(4) 100 ml NaOH + 100 ml HCl (4) 100 ml NaOH + 100 ml HCl
10 10 10 10
78. Out of the following statements the correct 78. fuEu dFkuksa esa ls dkSulk dFku lgh gS :-
+
statement is :- (a) H+ ikuh esa H9O4 cukrk gAS
+
(a) H+ form H9O4 in H2O (b) 0.1 M HCl dh rqyuk esa] 0.1 M CH3COOH ls H+
(b) H+ from 0.1 M CH3COOH is less than 0.1 M HCl de izkIr gksrk gAS
(c) 0.2 M NaCN + 0.1 M HCl forms buffer (c) 0.2 M NaCN + 0.1 M HCl cQj foy;u cukrs gaSA
(d) Compounds in which OH– is present is known (d) os ;kfS xd ftuesa OH– mifLFkr gksrs ga]S dsoy os gh {kkj
as bases only dgykrs gaAS
(1) a,b,c only (1) dsoy a,b,c
(2) b,c,d only (2) dsoy b,c,d
(3) a,b,c,d (3) a,b,c,d
(4) a,b only (4) dsoy a,b
79. The equilibrium constant for the reaction. 79. fuEu vfHkfØ;k ds fy, lkE; fu;rkad
OCl–(aq) + H2O(g) ƒ HOCl(aq) + OH–(aq) is 3.6×10–7 OCl–(aq) + H2O(g) ƒ HOCl(aq) + OH–(aq) 3.6 × 10–7
hence Ka for HOCl is :- gS vr% HOCl ds fy, Ka gksxk :-
(1) 3.6 × 10–7 (2) 6 × 10–1 (1) 3.6 × 10–7 (2) 6 × 10–1
(3) 2.8 × 106 (4) 2.8 × 10–8 (3) 2.8 × 106 (4) 2.8 × 10–8
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80. The precipitate of Ag 2CrO 4 (K SP = 1×10 –8 ) is 80. Ag2CrO4 (KSP = 1×10–8) dk vo{ksi fuEu vk;uksa ds leku
obtained when equal volume of following are mixed? vk;ruksa dks feykus ij izkIr gksrk gS &
(1) 10–4 M Ag+ + 10–4 M CrO42– (1) 10–4 M Ag+ + 10–4 M CrO42–
(2) 10–2 M Ag+ + 10–3 M CrO42– (2) 10–2 M Ag+ + 10–3 M CrO42–
(3) 10–5 M Ag+ + 10–3 M CrO42– (3) 10–5 M Ag+ + 10–3 M CrO42–
(4) 10–2 M Ag+ + 10–5 M CrO42– (4) 10–2 M Ag+ + 10–5 M CrO42–
81. Which ions will have highest Ksp values of their 81. fuEu vk;uksa esa ls fduds lYQkbZM yo.kksa dk Ksp eku lokZfèkd
sulphides. gksxk?
(1) Zn2+ Cu2+ (2) Pb2+ Hg2+ (1) Zn2+ Cu2+ (2) Pb2+ Hg2+
(3) Zn2+ Mn2+ (4) Cd2+ Bi3+ (3) Zn2+ Mn2+ (4) Cd2+ Bi3+
82. At 25°C, the dissociation constant of CH3COOH 82. 25°C ij ,flfVd vEy rFkk NH4OH ds tyh; foy;u esa
and NH4OH in aqueous solution are almost the fo;kstu fLFkjkad ds eku yxHkx leku gSaA 25°C rki ij
same. The pH of a solution 0.01 N CH3COOH is 0.01 N CH3COOH foy;u dh pH = 4 gks rks blh rki
4.0 at 25°C. The pOH of 0.01 N NH4OH solution ij 0.01 N NH4OH dh pOH Kkr djks :-
at the same temperature would be :- (1) 3.0 (2) 4.0
(1) 3.0 (2) 4.0 (3) 10.0 (4) 10.5 (3) 10.0 (4) 10.5
83. A weak acid, HA with an ionization constant of 83. ,d nq c Z y vEy HA, ftldk vk;uu fLFkjka d yxHkx
approximately 10 –4 , is prepared in a 1.0 molar 10–4 gS] dk 1.0 eksyj tyh; foy;u cuk;k tkrk gSA bl
aqueous solution. What will happen to the foy;u esa vfrfjDr 'kq¼ ty feykus ij izfr'kr fo;kstu ij D;k
percentage dissociation of this acid as more pure izHkko gksxk ?
water is added to the solution ? (1) izfr'kr fo;kstu vifjofrZr jgrk gAS
(1) Percentage dissociation remains unchanged
(2) izfr'kr fo;kstu c<+sxkA
(2) Percentage dissociation will increase
(3) izfr'kr fo;kstu ?kVsxkA
(3) Percentage dissociation will decrease
(4) The ionization constant will increase (4) vk;uu fLFkjkad c<+sxkA
84. The [OH–] in 0.01 M aqueous solution of NaOCN 84. 0.01 M, NaOCN ds tyh; foy;u esa [OH–] dh lkUnzrk
(Kb for OCN– = 10–10) will be :- gksxh (OCN– ds fy, Kb = 10–10) :-
(1) 10–6 M (2) 10–3 M (1) 10–6 M (2) 10–3 M
(3) 10–8 M (4) None of these (3) 10–8 M (4) buesa ls dksbZ ugha
85. A 100 mL portion of water is added to each of the 85. 100 mL ty fuEu nks foy;uksa (izR ;sd esa ) feyk;k tkrk
following two solutions :- gS :-
(i) 100 mL of 0.02 M KCN (i) 100 mL 0.02 M KCN foy;u
(ii) 100 mL of 0.02 M HCl (ii) 100 mL 0.02 M HCl foy;u
Which of the following statements is correct ? fuEu esa ls dkuS lk dFku lgh gS ?
(1) There will be no change in pH of solution (i) (1) foy;u (i) rFkk (ii) dh pH es a dks b Z ifjorZ u ugha
and (ii) gksxkA
(2) The pH of solution (i) will decrease but pH of (2) foy;u (i) dh pH ?kVsxh rFkk foy;u (ii) dh pH
solution (ii) will increase c<+sxhA
(3) The pH of solution (i) will remain same but of (3) foy;u (i) dh pH vifjofrZr jgsxh rFkk foy;u (ii) dh
solution (ii) will decrease pH ?kVsxhA
(4) The pH of solution (ii) will remain same but (4) foy;u (ii) dh pH vifjofrZr jgsxh rFkk foy;u (i) dh
of solution (i) will increase pH c<+sxhA

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86. Which of the following aqueous solutions is a 86. fuEu esa ls dkuS lk tyh; foy;u] pH = 7.0 ls vf/kd dk
buffer with a pH greater than 7.0 ? For HNO2 , cQj gAS HNO2 ds fy, Ka = 4.6 × 10–4 rFkk NH3 ds fy,
Ka = 4.6 × 10–4 , and for NH3 , Kb = 1.8 × 10–5 . Kb = 1.8 × 10–5 .
(1) 10 mL of 0.1 M NH3(aq) + 10 mL of 0.1 M (1) 10 mL of 0.1 M NH3(aq) + 10 mL of 0.1 M
HCl (aq) HCl (aq)
(2) 10 mL of 0.1 M HNO2(aq) + 5.0 mL of 0.1 M (2) 10 mL of 0.1 M HNO2(aq) + 5.0 mL of 0.1 M
NaOH (aq) NaOH (aq)
(3) 10 mL of 0.1 M HNO2(aq) + 10 mL of 0.1 M (3) 10 mL of 0.1 M HNO2(aq) + 10 mL of 0.1 M
NaOH (aq) NaOH (aq)
(4) 10 mL of 0.1 M NH3 (aq) + 5.0 mL of 0.1 M (4) 10 mL of 0.1 M NH3 (aq) + 5.0 mL of 0.1 M
HCl (aq) HCl (aq)
87. In a saturated solution of H2S decreasing the pH 87. H2S ds lar`Ir foy;u esa] pH de djus ij :-
of the solution will cause :-
(1) S2– dh lkUærk ?kVsxh
(1) The S 2–
concentration to decrease
(2) H2S dh lkUærk ?kVsxh
(2) The H2 S concentration to decrease
(3) S2– dh lkUærk c<+sxh
(3) The S 2– concentration to increase
(4) No change in either the H2S or S2–concentration (4) H2S ;k S2– dh lkUærk esa dksbZ ifjorZu ugha gksxkA

88. The strongest conjugate base is – 88. çcyre la;qXeh {kkj gS –

–
(1) NO3
–
(2) Cl– (1) NO3 (2) Cl–
–2
(3) SO4
–2
(4) CH3COO– (3) SO4 (4) CH3COO–

N N N N
89. 200 mL, HNO3, 100 mL H SO , 300 mL 89. 200 mL, HNO3, 100 mL H SO , 300 mL
20 20 2 4 20 20 2 4

M M
HCl, 50 mL, 0.1M Ba(OH) 2 and 250 mL
30
HCl, 50 mL, 0.1M Ba(OH) 2 rFkk 250 mL,
30

M M
NaCl, solutions were mixed then value of pH NaCl, foy;u fefJr fd;s x;s rks ifj.kkeh foy;u dh
10 10
of resultant solution is :- pH dk eku gksxk :-
(1)1.65 (2) 2.0 (1)1.65 (2) 2.0
(3) 1.78 (4) 0.16 (3) 1.78 (4) 0.16
90. 1M NaCl and 1M NaOH are present in an aqueous 90. fdlh tyh; foy;u esa 1M NaCl o 1M NaOH gS] rks
solution. The solution is :– foy;u :–
(1) Not a buffer solution with pH < 7 (1) pH < 7 ;qDr cQj foy;u ugha gAS
(2) Not a buffer solution with pH > 7 (2) pH > 7 ;qDr cQj foy;u ugha gAS
(3) A buffer solution with pH < 7 (3) pH < 7 ;qDr cQj foy;u gAS
(4) A buffer solution with pH > 7 (4) pH > 7 ;qDr cQj foy;u gAS
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