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Psicrometria
Resultados de aprendizaje
►Describir la composición de una mezcla de gases
ideales en términos de fracciones de masa o
molares.
►Usar el modelo de Dalton para relacionar
presión, volumen, y temperatura y para calcular
cambios en U, H, y S para mezclas de gases
ideales.
►Aplicar balances de masa, energía, y entropía a
sistemas que involucran mezclas de gases
ideales, incluyendo procesos de mezclado.
Resultados de aprendizaje, cont.
►Demostrar entendimiento y Usar terminología de
psicrometría, incluyendo, relación de humedad,
humedad relativa, entalpía de mezcla, y
temperatura de punto de rocío.
►Usar la carta psicrométrica para representar
procesos comunes de acondicionamiento de aire.
►Aplicar balances de masa, energía, y entropía
para analizar procesos de acondicionamiento de
aire y torres de enfriamiento.
Engineering Applications of Ideal Gas
Mixtures
►We encounter ideal gas mixtures in many
important areas of application. Two of these are:
1. Systems involving chemical reactions and, in
particular, combustion. For these applications we
typically work on a molar basis. Combustion
systems are considered in Chapter 13.
2. Systems for air-conditioning and other
applications requiring close control of water vapor in
gas mixtures. For these applications we typically
work on a mass basis. Systems of this type are
considered in the second part of Chapter 12.
Psychrometric Applications
►The remainder of the section centers on systems
involving moist air. A condensed water phase may
also be present in such systems.
►The term moist air refers to a mixture of dry air
and water vapor in which the dry air is treated as a
pure component.
►The Dalton model applies to moist air.
►By identifying gas 1 with dry air and gas 2
with water vapor, Table 12.2 gives moist air
property relations on a mass basis.
►The study of systems involving moist air is known
as psychrometrics.
Evaluating U, H, and S for Ideal Gas Mixtures
(Mass Basis)
►When working on a mass basis the expressions for U, H, S,
and specific heats of a mixture consisting of two components
– a binary mixture – are:
Moist Air (1 of 4)
►Consider a closed system
consisting of moist air occupying
a volume V at mixture pressure p
and mixture temperature T.
►In moist air the amount of
water vapor present is much
less than the amount of dry air:
mv << ma nv << na.
►The Dalton model applies to the mixture of dry air
and water vapor:
Moist Air (2 of 4)
1. The overall mixture and each component, dry air
and water vapor, obey the ideal gas equation of state.
2. Dry air and water vapor within the mixture are
considered as if they each exist alone in volume V at
the mixture temperature T while each exerts part of
the mixture pressure.
3. The partial pressures pa and pv of dry air and
water vapor are, respectively
pa = ya p pv = yv p (Eq. 12.41b)
where ya and yv are the mole fractions of the dry air and
water vapor, respectively. These moist air expressions
conform to Eqs. (c) of Table 12.2.
Moist Air (3 of 4)
4. The mixture pressure is the sum of the partial
pressures of the dry air and the water vapor:
p = pa + pv
Mixture pressure, p
5. A typical state of water
vapor in moist air is fixed
,
using partial pressure pv T
saturated.
7. The ratio of pv and pg
is called the relative
humidity, φ:
p
φ= v (Eq. 12.44) (De φ = mv/msat= pvV/RvT / pgV/RvT
pg
T , p para gas ideal)
Relative humidity is usually expressed as a percent and
ranges as dry air only
0 ≤ φ ≤ 100% saturated air
(pv = 0) (pv = pg)
Humidity Ratio (aka specific humidity)
►The humidity ratio ω of a moist air sample is the
ratio of the mass of the water vapor to the mass of
the dry air. mv
ω= (Eq. 12.42)
ma
Since mv << ma, the value of ω is typically << 1.
►Using the ideal gas equation of state and the
relationship pa = p – pv 18.02/28.97 = 0.622
mv M v p vV / R T M v p v M v p v
ω= = = =
ma M a p aV / R T
M a pa M a p − p v
pv
ω = 0.622 (Eq. 12.43)
p − pv
Dew Point Temperature (1 of 4)
►When moist air is cooled, partial condensation of the water
vapor initially present can occur. This is observed in
condensation of vapor on window panes, pipes carrying cold
water, and formation of dew on grass.
►An important special case is cooling of moist air at constant
mixture pressure, p.
►The figure shows a sample of moist air, initially at State 1,
where the water vapor is superheated. The accompanying T-v
diagram locates
states of water.
►Let’s study this
system as it is
cooled in stages
from its initial
temperature.
Dew Point Temperature (2 of 4)
►In the first part of the cooling process, the mixture pressure
and water vapor mole fraction remain constant.
►Since pv = yv p, the partial pressure of the water vapor
remains constant.
►Accordingly, the water vapor cools at constant pv from
state 1 to state d, called the dew point.
►The temperature at state d is called the dew point
temperature.
►As the system cools
below the dew point
temperature, some of
the water vapor initially
present condenses.
The rest remains a
vapor.
Dew Point Temperature (3 of 4)
►At the final temperature, the system consists of the dry air
initially present plus saturated water vapor and saturated liquid.
►Since some of the water vapor initially present has
condensed, the partial pressure of the water vapor at the final
state, pg2, is less than the partial pressure initially, pv1.
►The amount of water that condenses, mw, equals the
difference in the initial and final amounts of water vapor:
mw = mv1 – mv2
Dew Point Temperature (4 of 4)
►Using mv = ωma and the fact that the amount of dry
air remains constant, the amount of water condensed
per unit mass of dry air is
mw
= ω1 − ω 2
ma
where
p v1 pg2
ω1 = 0.622
ω 2 = 0.622
p − p p − pg2
v1
∙
•Solving for Qcv
Q cv
= (ha2 − ha1 ) + ω (hv2 − hv1 )
m a
Heating Moist Air in a Duct (5 of 5)
Q cv
= (ha2 − ha1 ) + ω (hv2 − hv1 )
m a
For the dry air, ha1 and ha2 For the water vapor, hv1 and hv2 are
are obtained from ideal gas obtained from steam table Table A-2
table Table A-22 at 10oC and at 10oC and 30oC, respectively, using
30oC, respectively. hv ≈ hg
Q cv kJ
= (303.2 − 283.1) + The
m a kg (dry air) contribution of
the water vapor
kg (vapor) kJ
0.00616 (2556.3 − 2519.8) to the heat
kg (dry air) kg (vapor) transfer
magnitude is
Q cv kJ kJ relatively
= (20.1 + 0.22) = 20.32 minor.
m a kg (dry air) kg (dry air)
Dry-bulb Temperature and
Wet-bulb Temperature (1 of 3)
►In engineering applications involving moist air, two
readily-measured temperatures are commonly used:
the dry-bulb and wet-bulb temperatures.
►The dry-bulb temperature, Tdb, is simply the
temperature measured by an ordinary
thermometer placed in contact with the moist air.
►The wet-bulb temperature, Twb, is the
temperature measured by a thermometer whose
bulb is enclosed by a wick moistened with water.
Dry-bulb Temperature and
Wet-bulb Temperature (2 of 3)
►The figure shows wet-bulb and dry-bulb
thermometers mounted on an instrument called a
psychrometer. Flow of moist air over the two
thermometers is induced by a battery-operated fan.
►Owing to evaporation
from the wet wick to the
moist air, the wet-bulb
temperature reading is
Moist
Air in
Moist air
state
Tdb
Psychrometric Chart (3 of 10)
►Humidity ratio, ω.
Moist air
state
ω
Psychrometric Chart (4 of 10)
►Dew point temperature, Tdp.
►Since the dew point is the state where moist air
becomes saturated when cooled at constant pressure, the
dew point for a given state is determined from the chart by
following a line of constant ω (constant pv) to the
saturation line where φ = 100%.
Moist air
state
Tdp
Psychrometric Chart (5 of 10)
►Relative humidity, φ.
Moist air
state
Psychrometric Chart (6 of 10)
►Mixture enthalpy per unit mass of dry air, (ha + ωhv).
The value of (ha + ωhv) is calculated using
ha = cpaT
Fig. 12.9: T in oC, cpa = 1.005 kJ/kg-K
Fig. 12.9E: T in oF, cpa = 0.24 Btu/lb-R
(ha + ωhv)
Moist air
state
Psychrometric Chart (7 of 10)
►Wet-bulb temperature, Twb.
►Lines of constant wet-bulb temperature are
approximately lines of constant mixture enthalpy.
Twb
Moist air
state
Psychrometric Chart (8 of 10)
►Volume per unit mass of dry air, V/ma.
►Lines giving V/ma can be interpreted as the volume of
dry air or of water vapor (each per unit mass of dry air)
because in keeping with the Dalton model each
component is considered to fill the entire volume.
Moist air
state
V/ma
Psychrometric Chart (9 of 10)
Example: Using Fig. A-9, determine relative humidity,
humidity ratio, and mixture enthalpy, in kJ/kg (dry air)
corresponding to dry-bulb and wet-bulb temperatures of 30oC
and 25oC, respectively.
Psychrometric Chart (10 of 10)
Solution:
φ = 67%
25oC
ω = 0.0181 kg water/kg dry air
49
Reprinted by permission of the Society of Heating and Air-Conditioning Engineers, Inc., Atlanta, Ga; used with permission.
Analyzing Air-Conditioning Systems
m∙ w
T3 = T2
Dehumidification (4 of 6)
►Mass rate balances. At steady state, mass rate balances
for the dry air and water are, respectively
m a1 = m a 2 (dry air)
m v1 = m w + m v 2 (water) 1 2
Q cv
= (ha + ωhv ) 2 − (ha + ωhv )1 + (ω1 − ω 2 )hw (3)
m a
Since heat transfer occurs from the moist air to the cooling
∙
coil, Qcv/m∙ a will be negative in value.
Dehumidification (6 of 6)
Q cv
= (ha + ωhv ) 2 − (ha + ωhv )1 + (ω1 − ω 2 )hw (3)
m a
►For the condensate, hw = hf (T2), where hf is obtained from
Table A-2.
►Options for evaluating the underlined terms of Eq. (3) include
►ω1 and ω2 are known. Since T1 and
T2 are also known, ha1 and ha2 can be
obtained from ideal gas table Table
A-22, while hv1 and hv2 can be (ha + ωhv)1
W∙ cv = 0, Q∙ cv = 0
∙
ma1
h3, m∙ 3
Humidification (3 of 8)
►For adiabatic operation, the accompanying
psychrometric charts show states 1 and 2 for each
case.
►With relatively high-temperature steam injection, the
temperature of the moist air increases.
►With liquid injection the temperature of the moist air may
decrease because the liquid is vaporized by the moist air
into which it is injected.
W∙ cv = 0, Q∙ cv = 0
∙
ma1
h3, m∙ 3
Humidification (4 of 8)
►For the control volume, let us evaluate
►The humidity ratio, ω2, and
►The temperature, T2.
W∙ cv = 0, Q∙ cv = 0
∙
ma1
h3, m∙ 3
Humidification (5 of 8)
►Mass rate balances. At steady state, mass rate balances
for the dry air and water are, respectively
m a1 = m a 2 (dry air)
m v1 + m 3 = m v 2 (water)
state.
(ha1 + ω1hv1)
•Since the second term on the 2
ω2
right is known, the value of
(ha2 + ω2hv2) can be calculated.
ω1
•This value together with ω2 fixes 1
72
The psychrometric diagram is
Psychrometric Diagram
0.050
0.035
0.8
Humidity Ratio
0.030 30 C
0.025 0.6
Q in = m a (h2 − h1 )
74
Now to find the m a and h's using the psychrometric chart.
At T1 = 50C, φ1 = 90%, and T2 = 24oC:
76
Apply conservation of mass and conservation of energy to
process 2-3. Conservation of mass for the steady-flow control
volume is
∑ m = ∑ m
inlets
i
exits
e
m a (ω 3 − ω 2 )hs = m a (h3 − h2 )
h3 − h2
hs =
ω3 −ω2
78
kJ
(48 − 37)
kg a
hs =
kg v
(0.0089 − 0.0049)
kg a
kJ
= 2750
kg v
79
EVAPORATIVE COOLING
Alternatively
m a1 ω3 − ω 2
= (1)
m a2 ω1 − ω3
Using known data, this equation can be solved for (ha + ωhg)3,
from which T3 can be evaluated.
Adiabatic Mixing of Two Moist Air Streams (4 of 7)
►From study of Eqs. (1) and (2) we conclude that on
a psychrometric chart state 3 lies on a straight line
connecting states 1 and 2, as shown in the figure
m a1 ω3 − ω 2
= (1)
m a2 ω1 − ω3
T3 = 19oC
Adiabatic Mixing of Two Moist Air Streams (7 of 7)
Solution:
(a) Inserting known values in Eq. (1),
497 ω3 − 0.002
=
180 0.0094 − ω3
T3 = 19oC
TORRES DE ENFRIAMIENTO
• En las centrales térmicas, y en las industrias de gran
consumo energético que no estén localizadas a orillas
de un gran cuerpo de agua, el agua de enfriamiento (si
la carga térmica es grande siempre se tiene que usar un
circuito de enfriamiento por agua) resulta cara y debe
reciclarse, siendo necesario transmitir el calor del agua
al aire atmosférico.
• Como la utilización de intercambiadores de calor sería
muy ineficiente por los pequeños saltos térmicos y la
baja conductividad del aire, hay que recurrir al
enfriamiento del agua por evaporación en contacto
directo con el aire en una torre húmeda (Figura 9.14a) o
en un pequeño estanque artificial (Figura 9.14b) sobre
el que se dispersa el agua
En el caso de la Figura 9.14b, el agua del estanque estará a una temperatura
cercana a la de saturación adiabática del aire ambiente. En cualquiera de estos
casos es necesario reponer el agua que se pierde por evaporación, que será una
pequeña fracción respecto a la que se necesitaría en circuito abierto.
Aunque el impacto ecológico de estos sistemas es menor, hay que prever la
posibilidad de aparición de grandes nieblas en días húmedos, así como la
formación de hielo en el caso de la Figura 9.14b.
En las torres de enfriamiento la circulación del aire puede ser por
tiro natural (con alto costo de instalación, porque se necesitan
alturas de hasta 100 m en las grandes centrales) o por tiro forzado
con un ventilador tiro forzado o tiro inducido (son las más
compactas, y para pequeñas cargas puede incluso ponerse en las
terrazas en ambientes urbanos).