New acrylic PU hybrid dispersion

for excellent mechanical resistance

Joncryl® HYB 6340

Jürgen Kaczun, Anja Song, Leendert Berkhout

European Coatings Show 2015
Table of contents

Sustainability issues for furniture and flooring

Joncryl® HYB 6340: Performance highlights

Applications

Application properties
 Abrasion resistance
 Pendulum hardness
 Chemical resistance

Conclusion

® = Registered trademark of the BASF Group 2

Sustainability issues for furniture and flooring

Emission reduction Resistance

enabling better enabling durable
indoor air quality Joncryl®
coatings
HYB 6340

Durability
enabling cost savings
3
How to make an acrylic polyurethane hybrid?

Physical blend of PUD Chemically linked PUD /

and acrylic dispersion acrylic dispersion

PU PA
PU-phase

PA-phase

4
Joncryl HYB 6340: Performance highlights

 Excellent abrasion resistance

 High scratch resistance
 Fast hardness development and high final hardness
 Universal blending partner for acrylic dispersions
 Well-balanced formulation latitude
 Good chemical resistance
 Solvent free

5
Applications

Professional Medium to high 1K and 2K topcoats,

and DIY flooring quality furniture sealers and primers

6
Joncryl HYB 6340 at a glance

Chemistry Aliphatic urethane acrylate hybrid

Appearance White emulsion
Solid content 40 %
pH 7.6
MFT 45°C
Viscosity 40 mPas (25°C Brookfield)
Solvent Solvent-free

Sustainability category Accelerator, i.e. substantial contribution to sustainability

7
Excellent abrasion resistance
and early hardness development

Taber abrasion CS17 wheels [mg] Pendulum hardness [sec]

500 123 24h
1000 7d
2000 94 133
125
115 116 111
74
64 92 94
54 52 81
38
32 30
21

Joncryl Physical Joncryl Competitor- Joncryl Physical Joncryl Competitor-

HYB 6340 blend HYB 6336 Hybrid HYB 6340 blend HYB 6336 Hybrid

Formulation with 8% butyl glycol / DPnB 1:1

8
Higher performance than a physically mixed blend

Property overview Joncryl Blend of PU dispersion and

HYB 6340 self x-linking dispersion (1/1)

Scratch resistance + -

Hardness development + o

Chemical resistance + +

Abrasion ++ -

Costs o o

9
Universal blend component for acrylic dispersions
enabling tailored solutions

Starting point formulation:

Hard dispersion Medium hardness Soft dispersion Trade name Function
Parts by
weight
Joncryl 8331 Luhydran® A 849 S2 Acronal® EDGE 6283 Joncryl®1 HYB 6340 Hybrid dispersion 30.0
Hydropalat®1 WE
Wetting 0.3
3120
 Self x-linking  Self x-linking  Self x-linking Foamstar®1 SI 2293 Defoamer 0.3
ACEmat®2 TS 100 Matting agent 0.7
 MFT 59°C  MFT 39°C  MFT < 3°C Water 2.0
Rheovis®1 PU 1250 Thickener 0.1
 Solids 38.5%  Solids 44%  Solids 42% Let-down
Joncryl®1 HYB 6340 Hybrid dispersion 50.0-X
Blend dispersion Acrylic dispersion X
Propylenglycol Open time prolonger 1.5
DPnB Coalescent 4.0
Butyl glycol Coalescent 4.0
Foamstar®1 SI 2210 Defoamer 0.2
Rheovis®1 PU 1250 Thickener 0.2
Water 6.6
Ammonia till pH 8.2 0.1
®1 = Registered trademark of the BASF Group 100.0
®2 = Registered trademark of Evonik Industries 10
Increased hardness in blends
with medium and hard acrylic dispersions

Pendulum hardness 24 h 7d
[sec]

Blend partner: hard Blend partner: medium hard Blend partner: soft
134 130 132 134 134
110 103
102 102 98 102 102
92
77 74 74
64 66
55 60
42 45 38 42

Joncryl 1:1 1:3 Pure Joncryl 1:1 1:3 Pure Joncryl 1:1 1:3 Pure
HYB 6340 blend blend acrylic HYB 6340 blend blend acrylic HYB 6340 blend blend acrylic

11
Tailored abrasion resistance possible
depending on acrylic dispersion blending partner

Taber abrasion CS 17 500 1000 1500

[mg]

Blend partner: hard Blend partner: medium hard Blend partner: soft
260
245 240
210
175 185
160 160 170
150 143 150 150 140
127 125
97 85 97 88 97 87
70 81
66 65
49 49 49 43 29 45
13 0 0 0

Joncryl 1:1 1:3 Pure Joncryl 1:1 1:3 Pure Joncryl 1:1 1:3 Pure
HYB 6340 blend blend acrylic HYB 6340 blend blend acrylic HYB 6340 blend blend acrylic*

* too soft for measurement

12
Tailored chemical resistance possible
depending on acrylic dispersion blending partner

Chemical resistance Joncryl HYB 6340 1:1 blend 1:3 blend

Blend partner: hard Blend partner: medium hard Blend partner: soft
Water 24h Water 24h Water 24h

5 5 5
Aceton 4 Aceton 4 Aceton 4
Ethanol Ethanol Ethanol
2 min 3 2 min 3 2 min 3
1h 1h 1h
2 2 2
1 1 1

Hand cream Hand cream Hand cream

24h Coffee 24h Coffee 24h Coffee
16h 16h 16h

Red wine 6h Red wine 6h Red wine 6h

Evaluation in starting point formulation acc. to DIN 68861-1 1B, on beech veneer after 7 days drying at RT
13
Conclusion

Emission reduction Resistance

 Solvent-free for high  Good chemical
formulation flexibility resistance
 Fast hardness
Joncryl
HYB 6340
development for
faster reusability
Durability
 Excellent scratch resistance
 High abrasion resistance

14
Please get in touch
You are highly welcome at our booth No. 523, hall 7a

Jürgen Kaczun
Technical Marketing
juergen.kaczun@basf.com
150 years