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The Automotive Battery

Construction and Service

After studying this chapter, you should be able to:

1. Discuss the construction and operation of a lead-acid storage battery.


2. Describe the chemical actions in the battery during charge and during
discharge.
3. Define and discuss battery ratings.
4. Explain why battery terminal voltage varies with temperature, charging
rate, discharge rate, and state of charge of the battery.

24-2 CHEMICALS IN BATTERY


24-1 THE BATTERY The chemicals in the battery are sponge
Battery (Fig. 24-1) supplies current to lead is solid, lead oxide (a paste), and
operate the starting motor and the ignition sulfuric acid (a liquid). These three sub-
system when the engine is being started. It stances are made to react chemically to
also acts as a voltage stabilizer by produce a flow of current. The lead oxide
supplying current for the lights, radio, and and sponge lead are held in plate prides to
other electrical accessories ‘when the form positive and negative and negative
alternator is not handling the load. The plates (Fig. 24-5).
battery is an electrochemical device. This The plate grid is a framework of
means it uses chemicals to produce lead alloy with horizontal and vertical
electricity. The amount of electricity it can bars. The plate grids are made into
produce is limited. As the chemicals in the plates by applying lead oxide paste.
battery are “used up” the battery runs down, The horizontal and vertical bars hold
or is discharged. It can be recharged by the paste in the plate.
supplying with electric current from a After the plates are assembled into
battery charger, or a vehicle alternator can the battery is given a “forming”
recharge it. The “used up” chemicals are charge. This changes the lead oxide
then returned to their original condition, so paste in the negative, or minus,
the battery becomes recharged. plate to sponge lead. It changes the
lead oxide paste in the positive, or
plus plate to lead peroxide.

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the internal connections are in place
24-3 BATTERY CONSTRUCTION the cover is put (Fig. 24-1 to 24-3). In
In the battery, several similar plates many batteries, the cover has
are properly spaced and welded, or openings through which liquid can be
lead-burned, to a strap. This forms a added water; the filler plug or vent
plate group. Plates of two types are caps are removed. After the liquid is
used, one for the positive plate added and the battery is given an
group, the other for the negative initial charge. It is ready for operation
plate group. A positive plate group is Maintenance-free batteries have no
nested with a negative plate group. vent caps
Separators are placed between the
plates to form an element (Fig. 24-3).
The separators hold the plates apart
so that they do not touch. At the
same time the separators are porous
enough to permit liquid in circulate
between the plates. Wooden sheets,
spun glass matted into sheets and
porous sponge rubber sheets have
been used as separators. Late- Fig.24-2 phantom view of a 12-volt
model batteries have separators battery with the terminals in the
made of acid-resistant polyvinyl state of the battery (Division of
chloride on polyethylene saturated General Motors Corporation).
cellulose.

Fig. 24-1 Two types of automotive Fig.24-3 Partly cut away and
batteries. The left battery it caps disassembled 12-volt battery(Ford
which can be removed to check the Motor Company)
battery state charge and add to Some batteries have the two main
water. If needed the right battery with terminals on the battery cover as in
side terminals is a sealed 24.3. Other batteries have the
maintenance free type and requires terminals in the side of the battery
no water. The charge indicator in the (Ford Motor Company) cover as in
top shows the state of charge of the Fig 24.3 Other batteries have the
battery. terminals in the side of the battery
The elements are placed in cells in case as in Fig 24.2 Figure 24.4
the battery case. Then heavy lead shows how the cables are connected
connectors are attached to the cell to a side terminal battery. It also
terminals to connect the series. After shows the battery-mounting

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arrangement. On a top-terminal battery (Cadillac Motor Car Division
battery the positive terminal (or of General Motors Corporation) from
“post”) is larger than the negative the terminal where chemical activity
post. has collected them. They now
Many batteries are the through the circuit to the other from
maintenance-free type. They require terminal where the chemical activity
no special attention expect for an has removed them. Chemical
occasional check of the connections activities now begin again so the tire
and the built-in charge indicator (Fig 2-volt pressure is maintained. The
24-1 right) other batteries have vent current now continuous. The
caps (Figs 24-3 and 24-4), which can chemical action use up the sponge
be removed. Then you can look lead, lead peroxide and sulphuric
down into the battery cells to see acid. After a certain amount of
whether they need water. Also a current has been withdrawn the
hydrometer can be used to check the battery is discharged (“run down or
battery charge. dead”). It is not capable of delivering
any additional current. When the
24-4 CHEMICAL ACTIONS IN battery has reached this state, it may
BATTERY be recharged. This is done by
The liquid in a battery is called the supplying it with a flow of current
electrolyte. It is made up of about 40 from some external source. The
percent sulfuric acid and about 60 external source forces current back
percent water (in a fully charged through the battery.This reverses the
battery) when sulfuric acid is placed chemical activity in the battery.The
between the pieces chemical actions plates are restored to their original
takes place. These actions removed composition and battery becomes
electron from one group of plates recharged.It is then ready to deliver
and collect them at other. This additional current.
creates a pressure of 2.1 volts The Chemical action that take place
between the two terminals of the are rather complicated.The sponge
battery cell. If any circuit no connects lead(negative plate) and lead
the two terminals, no further peroxide(positive plate) change to
chemical activity takes place. lead sulphate during the discharge
However when the two terminals do process.The sulphate comes from
become connected by an electric sulphuric acid. The electrolyte loses
circuit, electrons (current will flow. acid and gains water as the sulfate
goes into the plates. Therefore
discharging the battery changes the
two different chemicals in the battery
pieces to a third chemical lead
sulfate. Recharging the battery
changes the lead sulfate back to
They flow Fig 24.4 Cable sponge lead in the negative plates,
connections for a side-terminal and to lead peroxide in the positive
plates. Meantime the sulphuric acid

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reappears in the electrolyte of the compare hour compare. This is the
battery. amount of current time a battery can
deliver for 2v hours witness the cell
24-5 CONNECTING CELLS voltage dropping below 1.75 volts
Automotive batteries are usually 12 with a electrolyte temperature 800F
volts: units. There are six cells in the 26.70C. For example battery that can
12-volt battery. The six cells are deliver current of 5 amperes lo: 20
connected in series. In series hours is rated as having a 100.
connections, the voltages add. Some amperes hour capacity 120x5= 100
special applications use 24-volt
batteries: these special-purpose 3.Cold Cranking Rate- One of the
batteries have 12 cells. two cold-cranking rate if the number
Although a battery cell at 800F will of appears that a battery can deliver
test on open circuit about 2.1 volts for 30 spreads when at OFF 178’C
when fully charged common practice without the cell volt ages ladling
is to cell 2 volts. Therefore a six-cell below 1.2 volts. A typical rating for a
battery is said to be a 12 volts battery with a reserve capacity of
battery rather than a 12.6 volt 125 minutes would be 430 amperes.
battery. This figure indicates the ability of the
battery to crank: the engine at low
24-6 BATTERY RATINGS temperature. The second cold-
The amount of current that a battery cranking rate is measured at – 200F
can deliver depends on the total area – 28.90C. In this the final voltage is
and volume of active plate material. allowed to drop to 1 volt per cell. A
It also depends on the amount and typical rating for a battery with a
strength of electrolyte. This is the reserve capacity of 125 minutes
percentage of sulfuric acid in the would be 320 amperes.
electrolyte. Factors that influence
battery capacity – its ability to deliver 4.Watts Delco- uses an additional
current – include the number of rating – watts. This is roughly
plates, the cell size, and the quantity equivalent to the battery cold-
of electrolyte. The ratings most cranking rating.
commonly used in referring to
battery capacity are discussed 24.7 BATTERY EFFICIENCY
below. The ability of the battery to deliver
current varies within wide limits. It
1.Reserve Capacity- Reserve depends on temperature and rate of
capacity is the length of time in a discharge. At low temperature
minute that a fully charged battery at chemical activities are greatly
800F can deliver 25 amperes. A reduced. The sulfuric acid cannot
typical rating would be 125 minutes. work as actively on the plates.
This figure tells how long a battery Therefore the battery is less efficient
can carry the electrical operating and cannot supply as much current
load if the alternator quits. for as long a time. High rates of
2.Ampere Hour Capacity- An older in discharge will not produce as many
the 20-hour rate also called the ampere-hours as low rates of

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discharge. At high discharge rates c. Decreasing temperature. Lower
the chemical activities take place battery temperatures resource a
only on the surfaces of the plates. higher voltage to maintain charging
They do not have time to penetrate rate
the plates and to use the materials 2. The terminal voltage of a battery
below the plate surfaces. The chart that being discharge decreases with:
below relates battery efficiency to a. Increasing discharge rate. As the
battery temperatures. However these rate of discharge proof or chemical
are only approximations. activities increase and cannot
penetrate plates so effectively.
Therefore voltage reduced.
Efficiency Battery b. Decreasing state or charge. With
Percent Temperature less of the active mate takes place
Deglees F(C) and voltage drops.
100 80|[26.7] c. Decreasing temperature. With
65 32[0] lower temperature the chemical
50 0[-17.8] activities cannot go on as effectively
10 -45[-42.8] and the voltage drops.

24-8 VARIATIONS IN TERMINAL BATTERY MAINTENANCE AND


VOLTAGE SERVICE
Because the battery produces
voltage by chemical means voltage 24-9 BATTERY MAINTENANCE
varies according to a number of Complete battery maintenance includes
conditions. These conditions and the following:
their effect on battery voltage may be
summed up as follows 1. Visually check the battery.
1. Terminal voltage pattern being 2. Check electrolyte level in cells
charged increases with on batteries with caps.
a. Increasing charging rate. To 3. Add water if the level is low (vent-
increase charging rate (ampere cap batteries).
input) the terminal voltage must go 4. Clean off corrosion around
up. battery terminals and from top of
b. Increasing state of charge. As batteries with top terminals (Fig
state of charge goes up voltage must 24-3)
go up to maintain charging rate For 5. Check battery condition by
example a voltage of approximately testing its state of charge
2.6 volts per cell is required to force (explained later).
a current through a fully charged 6. Recharge battery if it is low.
battery. This is the reason that
voltage regulators are set to operate 24.10 CAUTIONS FOR BATERY
at 15 volts – slightly below the SERVICE
voltage required to charge a fully These are the important cautions to
charged battery. This setting protects observe when working with batteries
the battery from overcharge.

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1. The sulfuric acid in the electrolyte battery terminals and tops missing
is very corrosive. It can destroy vent caps and loose or missing hold-
most things it touches it will eat down clamps. Leakage causes white
holes in cloth. It can cause corrosion on the battery carrier and
serious burns if it gets on your surrounding metal parts. Leakage is
skin. If it gets in your eye due to a crackled battery case or top.
protection when working around The remedy is to install a new
batteries. If you get battery acid battery.
on your skin. Flush it out at once The top of the battery can be
with water over and over Fig 2-12 crackled if the wrong wrench is used
Then get to a doctor at once. to disconnect or install cable clamps
2. Gases form in the battery when it top terminals. The case can be
is being charged. These gases cracked if the hold-down clamps are
are highly explosive. Never light a over tightened.
match or a cigarette when
working around batteries. You 24.12 CHECKING ELECTOLYTE
might cause an explosion that LEVEL AND ADDING WATER
could seriously harm you. On vent cap batteries the electrolyte
3. The battery can supply a very level can be checked by removing
high current. Never wear rings the caps, Some batteries have a spilt
bracelets, watches or hanging ring which indicates the electrolyte
necklaces when working around level (Fig 24.5). If the level is low add
batteries. If a metal ring or other water. Some batteries have an
ornament should accidentally electrolyte-level indicator (a “Delco
short a battery a very high current Eye”). It gives a visual indication of
will flow. This could turn the ring the electrolyte level (Fig 24.6). Black
white-hot in an instant and you means the level is okay. White
could get a serious burn. means the level is low.
4. When jump-starting a car follow
the instructions and caution in 25- Careful : Do not add too much water.
9. A wrong step can damage the This can cause electrolyte to leak out
electrical system and cause you and corrode the battery carrier and
to get hurt. other metal nearby.
5. When disconnecting a battery
always disconnect the cable from 24.13 CLEANING CORROSION
the grounded the insulted OFF BATERY
terminal or any terminal or wire On batteries with the terminals on
that is hot (connected to the top the terminals and cable clamps
insulted terminal you will not be sometimes corrode. This corrosion
making a direct short across the can be cleaned off disconnecting the
battery. clamps and cleaning the terminal
and clamps with special wire
24.11 VISUAL INSPECTION OF brushes (Fig 24-7). Battery-top
BATTERY corrosion can be cleaned off by
Look for signs of leakage a crackled brushing the top with baking soda
case or top corrosion buildup on solution. After the foaming stops,

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flush off the battery top with water.
Terminals can be coated with an anti
corrosion compound to retard
corrosion.

24.14 CHECKING BATTERY


CONDITION
On vent-cap batteries, the battery
can be checked with a hydrometer to
determine its condition. Other Fig 24.5 Appearance of the
methods use testing instruments, as electrolyte and split ring when the
explained later. These other electrolyte is too low and when it is
methods are for the maintenance- correct (Delco-Remy Division of
iree batteries but can also be used General Motors Corporation) of the
on the vent-cap type. electrolyte (Fig 24.9). The height of
the stem above the electrolyte tells
24.15 HYDROMETER TEST you the battery state of charge. Here
The hydrometer tests the specific is what the readings mean.
gravity of the battery electrolyte. 1.265 – 1.299 Fully charged battery
There are two types of hydrometer 1.235 – 1.265 Three-fourths charged
(Fig 24-8). One uses a series of 1.205 – 1.235 One half charged
plastic balls, the other a glass float 1.170 – 1.205 One fourth charged
with a stem on top. To use a ball- 1.140 – 1.170 Barely operated 1.110
type hydrometer, stick the rubber 1.110 - 1.140 Completely charged.
tube in the electrolyte. Then squeeze
and release the rubber bulb. This
draws electrolyte up into the glass
tube. The number of balls that float
tells you the battery state of charge.
If all ball float the cell fully charged. If
none float the cell is discharged.

Careful : Do not drip electrolyte on


the car or on yourself Electrolyte will
damage the paint on the car and eat
hole in your clothes. See caution 1 in
24-10

The float type hydrometer (right in


Fig 24-8) has a float with a stem that
sticks up above the electrolyte level
in tubs. They float stem is marked to
indicate the spare.

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Fig 24.7 Using battery terminal
brush to clean the battery terminal
posis and cable clamps Black Motor
Fig 24.6 A battery cell with Division of General Motor
electrolyte level indicator(top).The Corporation
electrolyte at one correct level
and(bottom)low electrolyte
level.(Delco-Remy Division of
General Motor Corporation).

If some cells test considerably lower


than others, it means there is
something wrong with those cells. It
could be that a cracked case has
allowed electrolyte leakage or
perhaps there is internal damage to
the plates or separators. If the
variation is only a few specific-gravity
points, then there is probably no
cause for alarm. But if the low cells
measure 50 points lower then those
cells are defective and the battery
should be replaced.
Some 12-volt batteries for passenger
cars have a slightly lower specific Fig.24-8 Battery hydrometers to
gravity when charged For example check electrolyte specific gravity.
one type is fully charged with a
specific gravity of 1.270. Other
batteries such as those used in hot
climates have a specific gravity of
1.225 when fully charged.
The decimal point is not normally
referred to in a discussion of specific
gravity. For example “twelve twenty
twenty-five means 1.225 and eleven
fifty means 1.150.

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battery wears out and must be
replaced.
24-18 LOSS OF SPECIFIC
GRAVITY FROM SELF-
DESCHARGE
If a battery stands idle for a long
time, it will gradually run down. This
is due to the chemical actions
between the electrolyte and the
battery plates. The higher the
temperature the more rapid this self-
discharge.
24-19 FREEZING TEMPERATURE
OF ELECTROLYTE
Fig.24-9 Using a float hydrometer to
check a battery cell. Reading must The higher the specific gravity of the
be taken at eye level. The higher the electrolyte the lower the temperature
float stem stick out of the electrolyte, must be before the electrolyte
the higher the state of charge of the freezes. The battery must be kept
battery. sufficiently charged in cold-weather
to prevent freezing. Freezing may
24-16 VARIATIONS OF SPECIFIC run the battery (Fig 24-10).
GRAVITY WITH TEMPERATURE
The electrolyte thickens (gains 24-20 CHARGE INDICATOR ON
specific gravity) as it coos. It loses MAINTENANCE FREE BATTERIES
specific gravity, as it gets hot. On the Many maintenance free batteries
ball hydrometer this is not important. have a charge indicator on their top
But on the float hydrometer (Fig 24-11) The appearance of the
correction of the specific gravity charge indicator shows the state of
reading should be made if the charge of the battery.
electrolyte temperature is well above CAUTION If the charge indicator
or below the 800F [270C] standard. shows yellow do not attempt to
Specific gravity changes about four recharge or test the battery. It is
points for every 100F change in close to failure and should be
temperature. A reading of 1.250 at replaced. Never attempt to jump-
1200F (48.90C ) would correct to start the car if the charge indicator
1.266 (add 0.016 or 4x 0.004) A shows yellow (25-9)
reading of 1.230 at 200F (-6.70C)
would correct to 1.206 (subtract 6x 24-21 BATTERY-CAPACITY (HIGH
0.004 or 0.024). DISCHARGE) TEST
For this test a special tester is used.
24-17 LOSS OF SPECIFIC It places a load on the battery
GRAVITY FROM AGE voltage can be measured while a
As a battery ages the electrolyte
gradually loses specific gravity. This
loss is due to aging and nothing can
be done about it. Eventually the

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Specific gravity Freezing 24-22 BATTERY SERVICE
Temperature Battery service can be divided into
Degrees F(C) four parts visual inspection testing
1.100 18 [-8.2] charging and care of batteries in
1.100 1[-17.2] stock.
1.200 -17[-27.3]
1.320 -31[-35] 24-23 BATTERY TESTING AND
1.260 -75[-59.4] ANALYSIS
1.300 -95[-70.5] Battery testing includes a check of
the condition of the battery. It should
Fig 24-10 Specific gravities and also include analysis of any
freezing temperatures for battery abnormality found so that corrections
electrolyte. can be made. This will prevent a
repetition of trouble. Following are
various battery troubles and their
possible causes. These apply mainly
to vent-plug batteries
1.Overcharging -If the battery
frequently requires after, it is
probably being over being
overcharged. Too much current is
Fig 24-11 being supplied to the battery. This is
Appearance of the charge indicator in the a damaging condition that overworks
top of some maintenance-free batteries (A)
the active materials in the battery
If the green dot shows the battery is charged
(B) If the indicator shows black the battery and shortens battery life. In addition
low and should be charged before testing overcharging causes more rapid loss
(C) If the indicator shows light yellow the of water from the battery electrolyte.
battery is dead and should be discarded. Unless this water is replaced
High current flowing out of the frequently the electrolyte level is
battery. Specifications for this test likely to fall below the tops of the
vary. Follow the procedure in the plates. This exposes the plates and
tester operating instructions. the separators to the air and may run
Specifications for voltage and battery them. Also battery overcharge
capacity are in the manufacturer’s causes the battery plates to buckle
service manual. In general a load of and crumble. Therefore a battery
three times the battery ampere-hour subjected to severe overcharging will
capacity is placed on the battery. soon be ruined Where overcharging
You can also use one-half of the is experienced or suspected the
cold-cranking rate at 00F (- 17.80C). charging system should be checked.
At the end of 15 seconds a good It should be serviced if necessary to
battery should show a voltage of 9.6 prevent overcharging (Chap 26).
volts or together. If the voltage is 2.Undercharging- If the battery is
less than 9.6 volts and the battery discharged, it should be recharged
has removable vent plugs check the as outlined later in this chapter. In
specific gravity of each cell if there is addition an attempt should be made
more than a 50-point difference
between cells replace the battery.

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to determining the cause of the spraying of battery electrolyte is
trouble. It could be caused by: natural as the battery is being
a. Charging-system malfunctioning. charged. The battery holder may
b. Defective connections in the become corroded from the effects of
charging circuit between the the electrolyte. Such corrosion may
alternator and the battery. be cleaned off, with the battery
c. Excessive load demands on the removed. Use a wire brush and a
battery. solution of baking soda and water.
d. A defective battery. 8.Dirty Battery Top- The top of the
e. Permitting the battery to stand battery may become covered with
idle for long periods so that it self dirt and grime mixed with electrolyte
discharges excessively. sprayed from the battery. This
In addition an old battery may have a should be cleaned off periodically
low specific-gravity reading because (24.13).
it is approaching failure. 9.Discharge to Metallic Hold-
3. Sulfation -The active materials in Down-
the plates are converted into active If the hold down clamps are the
material during recharge. However if uncovered metallic type, a show
the battery stands for long periods in discharge may occur from the
a discharged condition the lead insulted terminal to the hold down
sulfate is converted into hard clamp. This is more apt to occur with
crystalline substance. This a dirty battery top across which
substance is difficult to reconvert into current can leak. The remedy to
active materials by normal charging keep the battery top clean and dry.
processes. Such a battery should be
charged at half the normal rate for 60 24-24 REMOVING AND
to 100 hours. Even though this long REPLACING BATTERY
charging period may convert the To remove a battery from a car first
sulfate to active material, the battery take off the grounded battery-
may still remain in a damaged terminal cable clamp. This prevents
condition. The crystalline sulfate, as accidental grounding of the insulted
it forms tends to break the plate terminal when it is disconnected To
grids. remove a nut-and-bolt type of cable
4.Cracked Case- A cracked case loosen the clamp out about 3/6 inch
may result from excessively loose (9.5 mm) Use a box wrench or
tight hold-down champs, from battery special cable pliers. Do not use
freezing or from flying stones. ordinary pliers or an open-end
5.Bulged Cases - Bulged cases wrench. Either of these might break
result from tight hold-down clamps cell cover when swung ground. If the
from high temperatures. clamp sticks, use a clamp puller. Do
6.Corroded Terminals and Cable not use a screwdriver or bar to pry
Clamps -The condition occurs on the clamp. This could damage the
naturally on batteries. Excessive battery cell all or cover. To detach
corrosion should be removed from the spring-ring type of clamp
cable clamps and terminals(24-13) squeeze the ends of the rings apart
7.Corroded Battery Holdo- Some with Vise-Grip or Cannel lock pliers.

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After the grounded cable is charging current. At the same time,
disconnected disconnect the the current input gradually tapers off.
insulted-terminal cable. Clean both When the battery is fully charged the
battery terminals and cable clamps current input has been reduced to a
(24.7) Loosen the battery hold- few amperes. The battery electrolyte
downs and take out the battery. temperature must remain within
When installing a battery do not limits. If the battery electrolyte
reverse terminal connections. temperature increases greatly the
Reconnect the insulted-terminal resistance of the battery will remain
cable Apply corrosion inhibitor to low. Then the battery will be
clamps and terminals. Install and damaged by overcharging unless it
tighten the hold-downs. Avoid is quickly removed from the charger.
overtightening. Before charging battery check the
Careful -Make sure the cable clamps electrolyte level If the level is low, the
are light and make good connections battery can be damaged. If the level
with the terminal posts (top terminal is too high the electrolyte can
battery) If the jaws of fine clamp overflow because of gassing and
touch together the clamp is not tight heat. Here are cautions to observe.
on the post. Shave the clamp jaws 1. The gases released by batteries
with a file until there is a gap when under charger are very explosive.
the clamp is installed. Be sure the area is well
ventilated. Do not smoke on have
24-25 BATTERY ADDITIVES open flames around charging
Certain chemical compounds when batteries This could cause an
added to the battery cells are explosion
supposed to restore a battery to a 2. Be sure to disconnect the battery
charged condition. Such chemicals ground step if the battery being
should never added the battery. charged in a car Otherwise you
Their use may void the battery can damage the electrical
guarantee and cause battery failure. equipment in the car
24-26 BATERY SLOW CHARGING 3. Most manufacturers
Two methods of slow charging recommended leaving the cell
batteries are in use, the constant- caps in place. But make sure the
current and the constant-voltage vent holes are open. Cover the
methods. In the constant-current caps with a cloth during the
method, the current input to the charging procedure Some
battery is adjusted to the manufacturers recommended
manufacturer’s specifications. The removing the caps and coving the
charging is continued until the openings with a cloth
battery is gassing freely and there is 4. Do not charge a battery that is
no rise in specific gravity for 2 hours. frozen. It could explode
In the constant-voltage method, the 5. Always wear some type of eye
charging voltage is held at a protection
constant value. The battery, as it 6. If the charger indicator of a
approaches a charged condition maintenance-free battery shows
increases in resistance to the yellow on clear, do not charge it.

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The electrolyte level is low, and Likewise a badly sullated battery
charging it could cause an should not be quick charged. Such
explosion. The battery should be batteries may be near failure but
discharged they may give additional service if
7. Do not turn the charger on until slow charged However quick
the charger cables are connected charging might damage them further.
to the battery. Turn the charger During quick charging check the
off before disconnecting the color of the electrolyte Stop charging
cables if it becomes discolored as a result of
8. Check the specific gravity and the stirring up of washed-out active
temperature of the electrolyte plate material Likewise cell voltages
periodically during charge. If the should be checked every few
temperature goes above 1250F minutes Charging should be stopped
(51.70C) stop the charge. it cell voltages vary more than 0.2
9. The battery is fully charged when volt.
the specific gravity shows no Careful -When quick charging a
increase for 3 hours. Also the battery in a car disconnect the
cells should be gassing freely battery ground strap to protect the
10. After charging, wash and dry the electrical system from damage due
battery top. This removes any to high voltage. If the charge
electrolyte that might have indicator in a maintenance free
spewed out during charge. battery shows yellow do not try to
quick charge it(24-20)
24-27 QUICK CHARGERS
The quick charger can be wheeled
up to the car and connected to the
battery in the car (Fig 24.12) Here
are some special points to watch
when using a quick charger. These
chargers can supply a fast charge of
up to 100 amperes (for some types)
Normally you would set the charging
rate for about 40 to 50 amperes and
charge the battery for about 30 to 45
minutes. This boosts the battery with
up to 38 ampere does not go above 24.12 Quick charger connected to a
1250F (51.70C) battery in the car. The grounded
Quick charging usually cannot bring battery cable should be
the battery to full charge in a short disconnected before charger cables
time. To bring it up to full charge, the are connected( Chryster
battery should be given a slow Corporation).
charge after the quick charge.
Careful -A battery with discolored A very low battery may not accept a
electrolyte (from cycling) or with fast charge. The electrolyte in a very
gravity readings more than 25 points low battery does not have very much
apart should not be quick charged. sulfuric acid in it. Therefore, the

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conductivity of the electrolyte is too 2. Remove the lid from the
low to allow a high current to flow electrolyte container. Unfold the
through the battery. You might think top of the plastic bag, and cut a
a battery that refuses to make a high small opening in one corner of
charge is torn out. However, it may the bag
be possible to restore the battery to 3. Use a glass acid-proof funnel and
a charged condition. First slow fill each battery cell. Wear
charge it for a few minutes to see goggles and observe all cautions
whether it starts coming up to already noted regaraging sulfuric
charge. If does, then it can be put on acid. Wait a few minutes and
fast charge. then add more electrolyte if
necessary. Some electrolyte will
24-28 CARE OF BATTERIES IN probably be left. Do not attempt
STOCK to use it all. Do not overfill the
Wet batteries (new batteries shipped battery.
with electrolyte in them) their 4. Before discharging the container,
perishable. They are subject to self- empty it Rinse the bag thoroughly
discharge. If allowed to prevent this with water. Otherwise someone
batteries in stock should be who handles the carton might be
recharged every 30 days. They severely burned.
should not be stacked on top each
other without additional support. The
weight of one battery is enough to
collapse the plate assemblies.

24-29 DRY-CHARGED BATTERIES


Dry-charged batteries contain fully
charged positive and negative plates
but no electrolyte. The batteries are
sealed with rubber or plastic seals
placed in the vent plugs. Since the
batteries contain no moisture
practically no chemical action can
take place in them. This means that
they will remain in good condition for
as long as 36 months.
Dry-charged battery manufacturers
supply ready-mixed electrolyte in
special cartons. The carton contains
an acid proof plastic bag, which
holds the electrolyte. The following
steps are performed to activate a
dry-charged battery
1. Remove the vent plugs, and take
out the plastic seals

14
a. supply current for cranking
the engine
b. supply current when the
charging system can’t
handle the complete
electrical load
c. both of the above
d. neither of the above
5. The length of time in minutes that
a fully charged battery at 800F
(26.70C) can deliver 25 amperes
is called the (24-6)
*****REVIEW QUESTIONS******* a. charging rate
Select the one correct. best or most b. reserve capacity
probable answer to each question. c. Cold-cranking rate
You can find the answers in the d. ampere-hour rate
section indicated at the end of each 6. The number of amperes that the
question. battery can deliver for 30
1.When working around batteries seconds when it is at 00F (1-
remember that (24-10) 17.80C) before the battery voltage
a. battery electrolyte contains a very falls to 7.2 volts is called the (24-
corrosive acid. 6)
b. explosive gas forms in the battery a. charging rate
which it is being charged. b. reserve capacity
c. the battery can furnish a very high c. cold-cranking rate
current if it is shorted. d. ampere-hour rate
d. all of the above. 7. If you must add water to the
2. When disconnecting a battery always battery every few days, the
(24-10) battery probably (24-23
a. remove the vent plugs first a. overloaded
b. disconnect the insulated – b. overcharged
terminal cable first c. sulfated
c. disconnect the grounded- d. old
terminal cable first 8. A loose battery-cable clamp
d. put the transmission in PARK could cause (24-23)
or REVERSE. a. battery overcharged
3. The battery is an b. high battery voltage
electrochemical device. This c. overheating
means that the battery(24-1) d. run down battery
a. makes chemicals by 9. On a top-terminal battery, the
mechanical means negative terminal post is (24-3)
b. uses chemical action to provide a. Smaller than the positive
electricity. terminal post
c. has curved instead of flat plates b. Larger than the positive
d. does not use an electrolyte. terminal post
4.The purpose of the battery is to(24-1)

15
c. The same size as the
positive terminal post
d. None of the above
10. You can quick charge the battery
at as much as 50 amperes
provided (24-27)
a. the electrolyte does not
get too hot
b. you do not charge for
more than 5 minutes
c. you make sure the battery
is fully charged
d. It remains connected to
the electrical system.

16

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