PHYSICAL CHEMISTRY

(NURTURE)
DPP # 21
M.M. : 30 MAX. TIME : 30 Min.
ONLY ONE OPTION CORRECT TYPE
1. The amount of arsenic pentasulhide that can be obtained when 35.5 g arsenic acid is treated with
excess H2S in the presence of conc. HCl (assuming 100% conversion) is : [3]
(A) 0.25 mol (B) 0.50 mol (C) 0.125 mol (D) 0.333 mol

2. An organic compound contains C, H and S. The minimum molecular weight of the compound
containing 8% sulphur is : (atomic weight of S = 32 amu) [3]
–1 –1 –1 –1
(A) 300 g mol (B) 400 g mol (C) 200 g mol (D) 600 g mol

3. At very high pressure, the compressibility factor of one mole of a gas is given by : [3]
pb b pb pb
(A) 1 + (B) 1 – (C) 1 – (D)
RT (VRT) RT RT

4. 5 L of an alkane requires 25 L of oxygen for its complete combustion. If all volumes are measured
at constant temperature and pressure, the alkane is : [3]
(A) Butane (B) Isobutane (C) Propane (D) Ethane

5. Initially the root mean square (rms) velocity of N 2 molecules at certain temperature is u. If this
temperature is doubled and all the nitrogen molecules dissociate into nitrogen atoms, then the new
rms velocity will be : [3]
(A) u/2 (B) 4u (C) 14u (D) 2u

Assertion Reason
6. Statement-1: The total kinetic energy of vapours formed over liquid H 2O(l) in two closed
container A & B having free space 1 litre & 2 litre respectively over H 2O(l) at the same
temperature is in the ratio 1 : 2. (Assuming ideal gas behaviour of vapours.)
Statement-2: Vapour pressure of a substance depends only on temperature.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Mob. 0744-2799900 Online Partner Unacademy 1
 PHYSICAL CHEMISTRY
(NURTURE)
INTEGER / SUBJECTIVE

7. The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this solution is the same as
its molality. Density of this solution at 298 K is 2.0 g cm–3. The ratio of the molecular weights of
 MWsolute
the solute and solvent,  , is [3]
 MWsolvent

8. The diffusion coefficient of an ideal gas is proportional to its mean free path and mean speed. The
absolute temperature of an ideal gas is increased 4 times and its pressure is increased 2 times. As a
result, the diffusion coefficient of this gas increases x times. The value of x is [3]

9. A bulb of constant volume is attached to a very thin manometer tube as shown in figure. Gas starts
leaking through a small hole in the bulb causing change in pressure as

Where k is constant and P is pressure at any instant.

Initial height difference 'h' was 76 cm and after 10 min 'h' was 38 cm.
Calculate the value of k in unit of atm–1 Hr–1.

10. A mixture of sodium chloride (NaCl) and anhydrous sodium carbonate (Na 2CO3) has a mole ratio
2 : 1. It is dissolved in water and treated with BaCl2 solution. The mass of BaCO3 precipitated is
98.5 gm. Calculate the mass (in gm) of NaCl in the mixture. [3]
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.

C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Mob. 0744-2799900 Online Partner Unacademy 2