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Class : XI (J-Batch)
Time : 100 min Max. Marks : 75
INSTRUCTIONS
General Remarks:
1. The question paper contain 13 questions and 24 pages. All questions are compulsory.
Please ensure that the Question Paper you have received contains all the QUESTIONS and
Pages. If you found some mistake like missing questions or pages then contact immediately to
the Invigilator.
2. Each question should be done only in the space provided for it, otherwise the solution will not be
checked.
3. Use of Calculator, Log table and Mobile is not permitted.
4. Legibility and clarity in answering the question will be appreciated.
5. Put a cross ( × ) on the rough work done by you.
6. Write your final answer(s) in the box given in the last of each question. Otherwise marks
will NOT be awarded.
USEFUL DATA
Atomic weights: O = 16, H = 1, N = 14, C = 12, Ca = 40
Q.No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Marks
Q.1 Calculate rms velocity of dust particles if mass of one particle of dust 8.31×10–12 g at 329.3°C assuming
kinetic theory of gases is applicable. [3]
Q.2 7 g of an organic compound on treatment with NaOH gave NH3 which when passed through
1
200 ml of M H2SO4 completely neutralized it. Calculate % of nitrogen in the organic compound.
2
2NH3 + H2SO4 (NH4)2SO4
[3]
Q.3 A tube of uniform cross-section of length 100 cm is divided into two parts by a weightless and frictionless
piston. One part contains 4 moles of hydrogen at 2 atm at equilibrium and other part contains 1 mole of
nitrogen at the same temperature. Assume volume of piston to be negligible.
(a) Calculate the length of each compartment if the tube was placed horizontally.
(b) The tube is then held at angle of 45° with the horizontal keeping the nitrogen end upwards. Find the
length of each compartment. [1.5+1.5]
Q.4(a) Find molality of Ca2+ and NO3 in 2 M Ca(NO3)2 aqueous solution of density 1.328 g/mL.
(b) Also find mole fraction of solvent in solution. [3+2]
Q.5 A 7.38 L vessel containing N2 at 1 atm and 27°C is connected to a 8.2 L vessel containing N2 at 4 atm
and 127°C thourgh a stopcock. When stopcock is opened, keeping both vessels at their original
temperatures, calculate
(a) Final pressure
(b) Moles of N2 in each vessel. [5]
Q.6 A common method of working of temperature scales is by assigning temperatures for steam point (Boiling
point of water) and absolute zero. A temperature scale commonly used by engineers is the Rankine (R)
scale on which absolute zero is 0 R and steam point is 671.4 R. Taking linear variation in temperatur
scales.
(a) Calculate ice point (melting point of water) on Rankine scale.
(b) Express 1800 R in Kelvin units. [5]
Q.7 A container holds 3L of N2(g) & liquid water at 300 K at a pressure of 1 atm. The water in container is
1
instantaneously split into H2 & O2 by electrolysis : H2O(l) H2(g) + O (g). After the completion
2 2
of reaction, the total pressure was 1.698 atm. Calculate mass of water taken initially in the container.
Given : Aqueous tension of water at 300 K is 0.04 atm. [6]
Q.8 Compressbility factor Z vs P plot for four real gases A, B, C & D are shown at 300 K
[3+3+3]
ROUGH