Exam of general and inorganic chemistry

28th September 2016

First Name
Last name
ID number:

1) Calculate the vapour pressure of water above a solution prepared by adding 22.5
g of lactose (C12H22O11) to 200 g of water at 338K. The solution of lactose has a
density of 1.03 g/mL. Prepare a solution containing Na 3PO4 having the same
osmotic pressure of the lactose solution.

2) You dissolve 0.460 g of NaOH in 2.00L of a buffer solution that has [H 2PO4-] =
[HPO42-] = 0.206 M. What is the pH of the solution before adding NaOH? After the
adding? (K1 = 7.5 x 10-3; K2 = 6.2 x 10-8; K3 = 3.6 x 10-13)

3) Gaseous iodine pentafluoride can be prepared by the reaction of solid iodine and
gaseous fluorine.
a) Write the formal chemical equation and balance it
b) Describe which kind of reaction is
c) A 5 L flask containing 10 g of I2 is charged with 10 g of Fluorine. The reaction
proceeds to completeness. The final temperature is 125°C. What is the partial
pressure of iodine pentafluoride in the flask? What is the mole fraction of the
iodine pentafluoride in the flask?