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Mustafa TS, El Hariri MOR, Khalafalla MS and Said Y Paper 1900170 structures/materials technology
Application of nanosilica in reinforced concrete beams. Received 21/08/2019;
Proceedings of the Institution of Civil Engineers – Structures and Buildings, Accepted 27/05/2020
https://doi.org/10.1680/jstbu.19.00170
ICE Publishing: All rights reserved
The partial replacement of cement with nanomaterials such as nanosilica (NS) particles in concrete improves its
strength and other properties. In this study, the effect of NS as a partial replacement of cement for concrete mixes
and concrete beams was examined. The studied response characteristics of reinforced concrete beams included the
compressive strength, failure mechanisms, load-carrying capacity and load–deflection behaviour. The results showed
that compressive strength increased with an increase in NS content up to 2.0% replacement of cement weight. The
rate of increase in compressive strength was no longer significant beyond 2.0% replacement, indeed there was a
slight decrease in compressive strength for NS content of 3.0%. The effect of increased NS content on the flexural
behaviour of beams was also studied. Increased NS content led to increases in the first-cracking and ultimate loads
and reductions in the deflection at cracking and ultimate load levels. No major differences in the structural response
parameters were observed for test beams with zoning of NS in the bottom tension or top compression zones. An
increase in NS content led to a slight increase in the ultimate strain associated with the ultimate load. Good
agreement was found between experimental and theoretical ultimate moments.
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Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
the diagonal cracking and ultimate shear strengths by 35.7% contents were examined: 0%, 1.0%, 2.0% and 3.0% bwoc. The
and 25.1%, respectively. NS powder used in this experimental investigation was
synthetic amorphous silica with a bulk density of 2 kN/m3.
These previous studies involved testing concrete mixtures to Additionally, a superplasticiser (SP) (Sika ViscoCrete-3425)
evaluate the mechanical properties without focusing on the was used to ensure uniform dispersion of the nanoparticles
structural behaviour of the concrete elements. Accordingly, and and to maintain the workability of the concrete mixes. This SP
to reduce the gap between the available experimental studies is an aqueous solution of modified polycarboxylates. It is a
on concrete mixtures and the required studies on the structural clear liquid with a density of 1.08 kg/l and does not contain
behaviour of RC beams, the current study evaluated the chlorides or other ingredients that would promote corrosion of
behaviour of RC beams containing different NS ratios (0%, steel reinforcements. It is thus suitable for use in RC without
1.0%, 2.0% and 3.0% by weight of cement (bwoc)). The study any restriction.
investigated the effect of experimental variables on the
response characteristics of the beams and their related failure 3.2 Mix proportions
mechanisms, load-carrying capacity and load–deflection The experimental programme involved testing four concrete
behaviour. mixes with different cement replacement ratios (NS contents of
0%, 1.0%, 2.0% and 3.0% bwoc). The compositions of the con-
2. Research significance crete mixes are provided in Table 1. The mixes were designed
The aim of this study was to practically investigate the to achieve a target compressive strength of 35 MPa at age
structural behaviour of RC beams with different percentages of 28 days. Two beams (100 200 900 mm) and six standard
NS as cement replacement. The experiments had two objec- cubes (150 150 150 mm) were prepared from each
tives: the first was to study the mechanical properties of the concrete mix.
concrete mixes and the second was to study the structural
behaviour of RC beams in terms of their flexural behaviour, A laboratory concrete mixer of 0.15 m3 capacity was used mix
load–deflection behaviour, cracking loads and ultimate loads. the concretes. Dry Portland cement, sand and gravel were
This work lays a foundation to develop and evaluate equations placed in the concrete mixer and mixed for 2 min until a hom-
for nano-modified concrete. ogenous colour was observed. During the dry mixing of the
cement and aggregates, the NS was mixed in its powder state
3. Experimental programme with SP and part of the mixing water in a rotary machine for
3.1 Materials 2 min. The remaining mixing water and the NS mixture were
The target compressive strength of the concrete used in this gradually added to the dry mixture in the concrete mixer. The
study was 35 MPa. The cement used in the concrete mix was concrete was mixed for about 4 min until complete homogen-
ordinary Portland cement type CEM I 42.5N. Fresh drinking eity of the constituents was achieved. The difference between
water was used for mixing and curing the concrete cubes and the bulk density of cement and NS was negligible due to the
beam specimens. The water/cement ratio was 0.4. The coarse relatively small percentages of NS replacement.
aggregate was well-graded natural gravel with a nominal
maximum size of 20 mm. The fine aggregate was natural sand For each concrete mix, two steel beam moulds (100 200
with a rounded particle shape and smooth texture, with a fine- 900 mm) and six standard cube moulds (150 150 150 mm)
ness modulus of 3.0. The specific gravities of the gravel and were cleaned and coated with a thin layer of an insulating
sand were 2.7 and 2.61, respectively. All the test beams were material to ease mould removal after concrete setting. Figure 1
reinforced with locally produced mild steel reinforcement, with shows the casting procedure for the test beams. 24 h after
diameters of 8 mm and 6 mm respectively for the longitudinal casting, the concrete beams and cubes were removed from their
reinforcement (top and bottom) and vertical stirrups. The yield moulds and placed in water-curing tanks until the age of
and ultimate strengths of the steel were 240 MPa and testing.
350 MPa, respectively.
3.3 Specimen details
Silicon dioxide with an average particle size of less than 75 nm Six simply supported RC rectangular beams were cast and
(NS) was used as a partial replacement for cement. Four NS tested. Details of the test beams and loading setup are shown
Table 1. Composition of concrete mixtures
Cement: kg/m3 NS: kg/m3 SP: % Fine aggregates: kg/m3 Coarse aggregates: kg/m3 Water: kg/m3
2
Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
Jack
Load cell
Steel beam
2 T8
200
T6 @200
200
Strain gauge
2 T8
LVDT 100
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Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
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Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
were reported by Gopinath et al. (2012). This indicates that the 5.2 Load–deflection relationships
optimum NS replacement is 2.0% bwoc, as also concluded by The ultimate load (Pu) was defined as the maximum recorded
Gao et al. (2015) and Sarade et al. (2017). load during the testing of each beam, with a corresponding
deflection of Δu. The first cracking load (Pcr) and the
corresponding cracking deflection (Δcr) were also recorded.
5. Experimental results: beams The load–mid-span deflection relationships of all the test
5.1 Crack patterns and failure modes beams are shown in Figures 7 and 8 and the structural test
Figure 6 shows the crack patterns of all the test beams. They results are summarised in Table 2.
all exhibited conventional flexural failure in which the beam
failed through yielding of the steel reinforcement followed by 5.2.1 Effect of increasing NS replacement
concrete crushing at large strains. The first crack occurred in Figure 7 shows the effect of increasing the cement replacement
the flexural region perpendicular to the direction of the by NS on the load–deflection curves. Analysis of the data from
maximum principal tensile stress induced by pure moment. this figure and Table 2 shows that an increase in NS content
Compared with the control specimen B1 without NS, speci- led to increments in the ultimate and cracking loads and
mens B2, B3 and B4 with 1.0%, 2.0% and 3.0% NS replace- reductions in the corresponding deflections. Compared with
ment bwoc respectively showed higher values of the first the control beam B1 (0% NS), the increase in NS content to
cracking load. An increasing in NS content led to an increase 1.0% bwoc for B2, 2.0% for B3 and 3.0% for B4 led to
in the first cracking load due to the filling effect of the NS increases in Pu by 5.5%, 11.5% and 19.2%, respectively, and
particles in the concrete mix. At a higher load level, shear decreases in the associated deflection Δu by 6.0%, 12.5% and
stresses became dominant, which induced inclined cracks in 23.0%, respectively. An increase in NS content to 3.0% resulted
the test beams. The effect of combined shear and bending in greater enhancement in the flexural parameters compared
stresses led to propagation of the cracks. All of the tensile with the compressive strength. This may be attributed to the
reinforcements in these specimens yielded and all of the speci- improved bond between concrete and reinforcement due to the
mens showed flexural failure due to the relatively low ratio of increased NS percentage. Compared with the control beam
the longitudinal tensile reinforcement. Similar findings have (B1), the first cracking load (Pcr) of beams B2, B3 and B4
been reported elsewhere (Alyousif et al., 2015; Sarwary et al., (Pcr) increased by 11.8%, 17.8% and 20.3%, respectively. The
2019). Approaching the failure load level, shear cracks started deflections at the first cracking load also decreased by 6.5%,
from the support and propagated diagonally towards the point 13.1% and 22.9% for the same beams in comparison with the
load, as shown in Figure 6. control beam.
(a) (b)
(c) (d)
(e) (f)
Figure 6. Crack patterns of test beams: (a) B1; (b) B2; (c) B3; (d) B4; (e) B5; (f) B6
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Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
35
30
25
20
Load: kN
15
B4 3.0% NS
10 B3 2.0% NS
B2 1.0% NS
5 B1 0% NS
0
0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5
Deflection: mm
20
in ultimate load was 2.0% and the increase in ultimate
15 deflection was 7.8%.
10 B3 2.0% NS
5.3 Load–steel strain relationship
B5 2.0% NS Bottom
5 The effects of increasing NS content and zoning of NS
B6 2.0% NS Top
concrete on the measured load–steel strain behaviour for the
0
0 1 2 3 4 5 bottom and top reinforcement cases are illustrated in
Deflection: mm Figures 9–12.
Table 2. Comparison between experimental and theoretical results of the tested beams
Pcr: kN Pu: kN Mcr: kN.m Mu: kN.m Δcr: mm Δu: mm εu × 10−3 MuACI: kN.m Mu/MuACI
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Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
35
30
25
20
Load: kN
15
B4 3.0% NS
10 B3 2.0% NS
B2 1.0% NS
5 B1 0% NS
0
0 500 1000 1500 2000 2500 3000 3500 4000
Bottom steel strain × 10–6
35
30
25
20
Load: kN
15
B4 3.0% NS
10 B3 2.0% NS
B2 1.0% NS
5 B1 0% NS
0
0 200 400 600 800 1000 1200
Top steel strain × 10–6
Figure 10. Effect of increasing NS content on load–steel strain curves of top reinforcement
ultimate load (εu). Increasing the NS content from 0% to 5.3.2 Effect of NS zoning in the beam section
1.0%, 2.0% and 3.0% bwoc led to an increase in εu by 2.4%, The effect of NS concrete zoning on the measured load–
4.1%, and 5.8%, respectively. The bottom reinforcement in all steel strain curves for beams containing 2.0% NS concrete
the beams reached the yield load level with considerable strain is shown in Figures 11 and 12 for the bottom and top
ductility due to the under-reinforced design of the beam reinforcement, respectively. These figures compare the
sections. behaviour of beam B3 with full NS concrete and beams B5
and B6 with partially replaced NS concrete. The results shown
The experimental load–strain curves for the top reinforcement in these figures indicate that, similar to the fully replaced NS
of beams B1, B2, B3 and B4 are shown in Figure 10. beam (B3), the load–strain behaviour of beams B5 and B6
Generally, the top reinforcement did not reach the yield level (with partially placement of NS concrete) showed limited
because of the higher value of the compression steel compared effect on the ultimate strain. The partial inclusion of NS
with the bottom tension steel. All the test results showed concrete had a minor effect on the ascending branches for
similarities in the ascending branch and up to the ultimate all beams and up to ultimate load level. Compared with
load level. beam B3, the steel strains of the bottom and top
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Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
35
30
25
20
Load: kN
15
10 B3 2.0% NS
B5 2.0% NS Bottom
5
B6 2.0% NS Top
0
0 500 1000 1500 2000 2500 3000 3500 4000
Bottom steel strain × 10–6
35
30
25
Load: kN
20
15
B3 2.0% NS
10
B5 2.0% NS Bottom
5 B6 2.0% NS Top
0
0 200 400 600 800 1000 1200 1400
Top steel strain × 10–6
reinforcement at the ultimate load level (εu) showed almost the purpose, these key parameters were statistically related to the
same values. experimental data of the concrete cubes. It was generally found
that a least-squares fitting linear relation was quite acceptable
and simple. The general form used was
6. Evaluation of ultimate flexural moment
1: fcuNS ¼ fcu ða þ bwÞ
6.1 Evaluation of compressive strength of NS concrete
Six concrete cubes without NS and eighteen cubes with
different NS contents were tested after 28 days in the standard where fcuNS and fcu are, respectively, the compressive strength
compression machine. To determine the strength gain of con- of concrete with and without NS and w is the percentage NS
crete containing NS, an analytical expression was sought in replacement. The constants a and b are the slope and intercept
terms of the NS replacement percentage and the compressive of the linear fitting equation, respectively. From statistical
strength of concrete matrix without NS replacement. For this analysis of the experimental results, the following linear
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Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
4.7 of the pozzolanic and filling nature of the NS. The rate
of increase in the compressive strength was no longer
Mu (experimental): kN.m
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Structures and Buildings Application of nanosilica in reinforced
concrete beams
Mustafa, El Hariri, Khalafalla and Said
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