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Energy 76 (2014) 276e283

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Energy
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Solar desalination system using spray evaporation


S.A. El-Agouz a, *, G.B. Abd El-Aziz b, A.M. Awad b
a
Mech. Eng. Dep., Faculty of Eng., Tanta Univ., Egypt
b
Mech. Dept., Faculty of Industrial Education, Suez University, Egypt

a r t i c l e i n f o a b s t r a c t

Article history: This paper evaluates a one-stage technique to improve fresh water production from salty water by
Received 31 January 2014 enhancing the evaporation and condensation. A pilot plant is designed and constructed in an arid area
Received in revised form with 1 m2 solar water collector area to evaluate the one-stage process. The effect of main parameters on
1 August 2014
fresh water production of the unit is studied. The results show that, the productivity, efficiency, pro-
Accepted 3 August 2014
Available online 26 September 2014
ductivity rate, and Gained Output Ratio of the desalination unit are strongly affected by the inlet hot
water temperature and flow rate. Within the studied ranges, the maximum daily productivity reached to
9 l/m2. According to these results, fresher water production of the present system is higher than that
Keywords:
Solar desalination system
solar humidificationedehumidification desalination system in the previous studies. The maximum daily
Spray evaporation efficiency in the desalination system is about 87%. A TDS (total dissolved solids) of fresher water is
Salty water 40 ppm. Finally, the cost of distilled water per liter is $0.029.
Experimentally © 2014 Elsevier Ltd. All rights reserved.

1. Introduction the solar central receiver and it was then entered into a desalina-
tion chamber. The air circulation in the humidification chamber
Desalination based on renewable energy such as solar energy, was provided by natural convection.
presents a sustainable and a zero-polluting alternative to fossil fuel The amount of distillate water produced by the unit depends on
based desalination, which aggravates environmental pollution the solar collector size. The performance of the collector depends
problems. It is cheap, allows energy diversification, available for mainly on the weather conditions, design and operating parame-
predictable periods of time, and helps avoid dependence on ters. However, to estimate the optimum values of these parameters
external energy supplies (Garcia-Rodriguez [1]). Solar still desali- in different weather conditions using full experiment was costly
nation uses a sustainable and pollution-free source to produce and time-consuming. Therefore, the development of a simulation
high-quality water. model offers a better alternative and has proven to be a powerful
Fresh water could be obtained from salty water through the tool in the evaluation of the performance of the system. Both air
solar HDH (humidificationedehumidification) cycle. In this pro- and water, solar collectors were the main components of a solar
cess, hot air supplied from a solar collector was circulated either by desalination unit and any improvement in their efficiency will have
a natural or a forced convection process over the water where it a direct bearing on the water production rate and the product cost
becomes humid. The humid air was then passed through a (Al-Hallaj and Selman [4]). The solar collectors that were used to
condenser or de-humidifier system where the desalinated water heat water and/or air were expensive and can reach in some cases
was obtained. Multi-effect humidification plants were the most from 25 to 30% of the total desalination unit cost by Ben Bacha et al.
effective units among solar desalination plants (Farid et al. [2]). [5]. The best known thermal processes for the desalination of
Many researchers have conducted studies on process and the seawater, namely MED (multi-effect desalination) and MSF
equipment's related to the (HDH) systems for water desalination. (multistage flash), make an efficient use of energy because the heat
Abdelkader [3] studied the solar desalination system with multi- released in each stage or effect was used in the next one, making
effect humidificationedehumidification cycles with couples cen- multiple use of energy. However, these processes require a very
tral solar receiver. In this system, saline water was warmed through precise control of temperature and pressure in each stage, which
must be constant in time in order to keep the conditions needed for
the boiling process (El-Dessouky and Ettouney [6]). This poses a
problem when coupling desalination with solar energy, due to the
* Corresponding author.
E-mail addresses: elagouz2002@yahoo.com, elagouz2011a@yahoo.com, intrinsic variability of insolation, thus requiring a thermal storage
elagouz2011@yahoo.com (S.A. El-Agouz).

http://dx.doi.org/10.1016/j.energy.2014.08.009
0360-5442/© 2014 Elsevier Ltd. All rights reserved.
S.A. El-Agouz et al. / Energy 76 (2014) 276e283 277

Nomenclature ho Hot outlet


S Solar water collector
A Area, m2 w Water
h Enthalpy, (kJ/kg)
H Solar radiation, (W/m2) Abbreviations
L Latent heat of water, (J/kg) CC Cooling coil
m Flow rate, (l/h) CV Control value
M Productivity, (l/h) EC Condensation tower
Pp Pump power, (W) ET Evaporation tower
T Temperature,  C FM Flow meter
FWR Fresh water reservoir
Greek letters GOR Gain output ratio
h Efficiency HDH Humidificationedehumidification
HEX Heat exchanger
Subscripts MED Multiple effect distillation
Av Average MSF Multi stage flash
ci Cold inlet PR Productivity rate
co Cold outlet SWC Solar water collector
d Daily TC Thermocouples
h Hourly TDS Total dissolved solids
hi Hot Inlet TES Thermal Energy Storage

tank and/or a supplementary heat source from fossil fuels (Blanco desalination system using solar collectors augmented by thermal
and Alarcon [7]). energy storage. A solar collector area was 15 m2 with 1 m3 of TES
In order to enhance utilization efficiency of the latent heat of (Thermal Energy Storage) volume or 18 m2 with 3 m3 of TES vol-
condensation, gain more fresh water output per square meter area ume. The results show that the fresh water production can reach
of solar collector and reduce the energy loss of the humid- 6.67 l/m2 of solar collector area. Zamen et al. [15] experimentally
ificationedehumidification desalination unit, a series of designs of evaluated the two-stage technique to improve the humid-
multi-effect solar humidificationedehumidification desalination ificationedehumidification process in fresh water production from
system were presented by some researchers. salty water. A two-stage pilot plant was designed and constructed
Zhani and Ben Bacha [8] presented an experimental investiga- in an arid area with 80 m2 solar collectors. The results show that,
tion and an economic analysis on a solar desalination prototype fresh water production can reach 7.25 l/m2 of solar collector area.
functioning by HD (Humidification/Dehumidification) of air. The The main limitation of solar stills was their low productivity
experimental results also that the outlet and the inlet temperatures compared to conventional desalination processes. The operating
at different component levels were the same trends as solar radi- efficiency was low due to main two limitations: (i) the rejection to
ation and the ambient air temperature was an insignificant effect the atmosphere of the latent heat of condensation and (ii) the
on thermal performance of the unit. The cost of distilled water per difficulty of raising the evaporation temperature and decrease
liter was $0.107. condensation temperature as heating, evaporation and condensa-
Al-Hallaj et al. [9] studied the solar driven (HDH) desalination tion take place in one container (He and Yan [16]).
system and the daily fresh water production rate ranged from It has been inferred from the literatures that most of the pre-
approximately 2.25 to 5.0 l/m2 of solar collector area, depending on vious works have used heated water spray during the humidifica-
the average daily solar flux. Muller-Holst et al. [10] fabricated the tion process where air used as a carrier gas to evaporate water from
solar (HDH) desalination system for operation in Munich, Germany. the saline feed and to form fresh water by subsequent condensa-
The system performance showed the average daily fresh water tion. On the fact that the vapor carrying capability of air increases
production in June was approximately 7.5 l/m2 while that in with temperature:1 kg of dry air can carry 0.5 kg of vapor and about
January was approximately 1.2 l/m2 solar collector area. Dai and 2805 kJ when its temperature increases from 30 to 80  C (Parekh
Zhang [11] presented the solar desalination unit with humidifica- et al. [17]). Therefore, the solar desalination requires efficient
tion and dehumidification. They found that the performance of the methods of evaporation and condensation at relatively low tem-
system was strongly dependent on the mass flow rate of salt water, peratures up to 70  C. Initially for small quantity, as in the earlier
the mass flow rate of the process air, and the inlet salt water designs the condenser is an integral part of the system. In addition,
temperature to the humidifier. The results showed that the pro- Multi-effect solar still was suggested as an efficient method for the
ductivity achieved was around 6.2 l/m2 of solar collector area. Yuan production of desalinated water.
et al. [12] investigated a 1200 l/day (HDH) desalination unit. This The present system is based on the generation of vapor from
system was composed of a 100 m2 solar air heater field, a 12 m2 salty water when it enters an evaporator tower and condensation of
solar water collector. The results showed that water production of vapor is accomplished by regenerative heating of the feed water.
the system can reach 10.7 l/m2 of solar collector area, when the The main objectives of the present work are to describe the design
average solar radiation was 550 W/m2. Zhani et al. [13] developed for solar distillation system coupled with a solar water heater to
the modeling and the experimental solar desalination unit using air enhance productivity and efficiency. The paper presents the results
and water solar collectors. They were found that the two- of a solar distillation system, with the water working in a closed
temperature mathematical model describes more precisely the loop. The distillation chamber consists of evaporation and
real behavior of the water solar collector than the one-temperature condensation towers. The system is designed to improve the
mathematical model. Gude et al. [14] designed the low temperature evaporation rate by spraying water at low temperature.
278 S.A. El-Agouz et al. / Energy 76 (2014) 276e283

2. Process description and instrumentation of condensation and it is pulverized into the thermal storage tank
at (8) and the drain at (9). The distilled water at (10) is collected in
2.1. Process description a basin at the bottom of the condensation tower and leaves to the
FWR (fresh water reservoir). The HEX (heat exchanger) is con-
Figs. 1 and 2 show, respectively, a schematic diagram and a structed from two co-axial cylindrical of galvanized steel sheet
photo of the experimental setup of the solar water desalination with thickness 1 mm. The diameter of two co-axial cylindrical are
unit. The developed unit operates at atmospheric pressure using 0.5 and 0.51 m while the height 0.7 and 0.65 m. The heat
spraying water to production vapor. Three compartments consti- exchanger insulated by a glass wool layer with thickness of
tute the installation: ET (evaporation tower) and CT (condensation 30 mm, with thermal conductivity of 0.036 W/m K. A conical cover
tower), SWC (solar water collector), and TST (thermal storage tank). is put in the top of heat exchanger. The cooling coil is made of
The principle of functioning of this desalination process is as copper tube with 1.56 mm diameter that is wrapped in the form of
follows. The salty water at (1) is pumped to the solar water collector a helix.
through CV (control value) that heated and then recycled to ther-
mal storage tank at (2). The solar water collector of 1 m2 as shown 2.2. Instrumentation
in Fig. 2 is the major component of the unit. It has an absorber plate
containing uniformly spaced parallel copper pipes with it supper As shown in Fig. 1, the thermocouples at points (1, 2, 4, 5, 6,
surface painted black to increase the absorptivity of the system. The and 7) is measured the temperature of salty water of inlet and
solar collector inclination is nearly 30 horizontal and orientation is outlet of evaporation tower, condensation tower, and solar water
kept in the south direction to receive maximum solar radiation collector. They are attached to a Digit-Sense 12 Channel Scanning
throughout the year The thermal storage tank is made of galvanized Bench Top Thermometer with scale division of 0.1  C that is
steel sheet with volume 43 l and it is covered by glass wool connected to a computer and the temperature are recorded every
insulation. 60 S. Water flow rate of evaporation tower, condensation tower,
The salty water is heated by the solar collectors as much as and solar water collector is regulated manually by control value
possible. Then, the hot water at (3) is pumped to the top of the and is measured by flow meters with a range of 0e450 l/h. The
evaporation tower through CV (control value) and FM (flow meter). voltage and current of the pumps (max. power 180 W) are
The hot water enters to sprinklers (4) which causes a spray of water measured by using digital clamp meter type (KSR-266). The
as vapor. Salty water remaining at the bottom of the evaporation desalinated water volume is measured by using a graduate tank
tower at (5) is directed to the thermal storage tank where it is with a range of 0e15 l with an accuracy of ±0.01 l. TDS (Total
further heated and redirected to the sprinklers (4). The evaporation dissolved solids) of salty and fresher water is measured by YSI
tower of diameter 32 cm and height 38 cm is insulated by a layer of model 556 MPS.
thermal flex insulating tape 1 cm thick and covered by an To estimate the uncertainties in the results presented in this
aluminum layer. work, the approach described by Barford [18] is applied. Assuming
The cold salty water at (6) feds to the CC (cooling coil) and HEX that a desired result is derived from n independent variables or
(heat exchanger) at different rates to condense the water vapor in simultaneous measurements [e.g., R ¼ R(X1;X2;Xn) ] and letting u1,
the evaporation tower and then it is exited at (7). Salty water, u2,…, un be the uncertainties in the independent variables, we can
which is preheated in the condensation tower, by the latent heat derive an expression for the uncertainty in the result, uR as:

Cold salty water


6
TC
CV
SWC

TC FM
2 CC

TC 4
Drain 7 TC
CV
9 HEX
CT ET
CV FM FM
8

5
CV 10
TC
CV
TST FWR
TC
P P
1 3

TST thermal storage tank CV control value FM flow meter


SWC solar water collector ET evaporation tower CT condensation tower
FWR fresh water reservoir P pump TC Thermocouples

Fig. 1. Schematic diagram of solar water desalination unit.


S.A. El-Agouz et al. / Energy 76 (2014) 276e283 279

1Xn
hd ¼ h (4)
n 1 h


Lw$av ¼ 103  2501:9  2:40706Tw þ 1:192217  103 Tw
2
 (5)
 1:5863  105 Tw
3

Where hh and hd are the hourly and daily efficiency, Mw is the


hourly productivity, Lw$av is the average of the latent heat of
vaporization of water (El-Dessouky and Ettouney [6]), ASWC is the
solar water collector area, H is the incident solar radiation on the
horizontal surface, Pp ¼ I  V is the power of pumps that are
measured with different flow rate of hot and cold water, and n is the
number of effective running hours (duration of producing desali-
nated water).
The PR (productivity rate) is defined as the ratio of the fresh
water production rate of the inlet salty water flow rate and it is
calculated as (Zamen et al. [15]):
  
PR ¼ 100  Mw mw;hi (6)

The GOR (Gained Output Ratio) is a measure of the latent heat of


water produced per unit of heat input; the following expression for
GOR is (obtained McGovern et al. [19]):

Mw  Lw;av
GOR ¼ h i (7)
ðm  hÞw;hi  ðm  hÞw;ho

Where Mw is the fresh water production, mw,hi is the hot water flow
rate entering the system, Lw,av is the average latent heat of vapor-
ization at the ambient condition, and ½ðm  hÞw;hi  ðm  hÞw;ho  is
the total enthalpy difference between leaving and entering the
system for hot water. The hot water flow rate leaving the system is
calculated as:

mw;ho ¼ mw;hi  Mw (8)

Fig. 2. Photo of the experimental setup of solar water desalination unit. The desalination unit is tested in a certain period of time,
including hot and cold days. Examining the performance of setup
for each test takes one day in real conditions of various days and in
" each test in the early hours of the day. Desalination unit starts when
2     #0:5
vR vR 2 vR 2 water in the storage tank reaches an appropriate temperature and
WR ¼ u1 þ u2 þ … þ un (1) fresh water production begins. The productivity can start early in
vX1 vX2 vXn
the morning before 10.5 AM when the hot water temperature of the
The relative uncertainty in the result, R can be calculated as tank reaches 70  C. The solar radiation and temperature variation of
follows: the inlet and outlet of solar collector, evaporation tower, and the
condensation tower at different hot water flow rate are shown in
ER ¼ WR =R (2) Fig. 3. The average temperature difference of solar collector, evap-
Accordingly, the resulting errors of the calculated temperature oration tower, and condensation tower is about 1.6, 6, and 3  C
difference, the mass of water in the heated water tank, efficiency, respectively. Variation of hot water temperature is shown in Fig. 4.
productivity rate, and Gained Output Ratio of the desalination It is noticeable that the hot water temperature follows the same
system, respectively are ± 0.29%, ±0.7%, ±1.6%, ±0.75% and ±1.2%. trends as solar radiation.
The hourly productivity of the unit on hot and cold days is
shown in Fig. 5. On both of these days, the unit starts at 10.5 AM.
3. Results and discussion Because of higher solar intensity of hot days, the productivity on
these days is higher than that on cold days. The hourly productivity
This section describes the limits upon the hourly efficiency (hh), depends on hot water temperature of the storage tank and reduces
daily efficiency (hd), PR (productivity rate), and GOR (Gained Output when it drops as shown in Fig. 3. On cold days, because of lower
Ratio) of the desalination unit. These limits serve to bind the per- solar intensity and thus, reduction of the temperature of the storage
formance achieved in real systems. The hourly and daily efficiencies tank, productivity sharply reduces after about 2 h from the start
are calculated as: time, but, sharply productivity reduces after about 4 h from the
start time on hot days. The maximum hourly productivity is about
ðMw  Lw$av Þ=3600
hh ¼ 100    (3) 0.5, 0.7, 0.72 and 1.6 l/h at 57.6, 133.2, 214.2, and 288 l/h for hot
AS H þ Pp water flow, respectively.
280 S.A. El-Agouz et al. / Energy 76 (2014) 276e283

Fig. 3. Solar radiation and temperature variation in different hot water flow rate.

Fig. 4. Hot water temperature at different hot water flow rate.


Hot day
Hot day

Hot day Hot day

Cold day Cold day

Fig. 5. Hourly productivity at different hot water flow rate.

Fig. 6. Accumulated productivity at different hot water flow rate.


282 S.A. El-Agouz et al. / Energy 76 (2014) 276e283

Table 1
Comparisons of the productivity rate for present system and Zamen et al. [15].

Hot water flow rate, l/h Productivity rate, %, at Thi,av ¼ 70  C

Present system Zamen et al. [15]

57.6 1.33 0.094


133.2 1.25 0.089
214.2 0.69 0.084
288.0 0.64 0.080

productivity is about 5.8 l, 7.22, 7.27 and 9 l/m2 at 57.6, 133.2, 214.2,
and 288 l/h for hot water flow, respectively.
Fig. 7 shows the effect of the average hot water temperature on
daily productivity, daily efficiency and GOR at different inlet hot
water flow rate. It can be noticed that by increasing the salty water
temperature, the productivity and efficiency increases. It can be
seen that the heating temperature and the feed seawater mass flow
rate have a significant influence on the unit productivity. This
finding can be explained as follows: the increase of heating tem-
perature increases the vapor due to decrease the latent heat of
vaporization. Consequently, the amount of fresh water obtained
from the system is increased. At the same average hot water tem-
perature, it can be seen that an increase in hot water flow rate in-
creases daily productivity and efficiency. Daily productivity changes
from 2.8 to 9 l/m2 depending on hot water flow rate and
temperatures.
At the hot water flow rate 57.6 l/h, the maximum daily pro-
ductivity can reach 5.8 l/m2 at Thi)av ¼ 68.6  C, at the hot water flow
rate 133.2 l/h, the maximum daily productivity can reach 7.22 l/m2
at Thi)av ¼ 61  C. At the hot water flow rate 214.2 l/h, the maximum
daily productivity can reach 7.27 l/m2 at Thi)av ¼ 59.7  C and at the
hot water flow rate 288 l/h, the maximum daily productivity can
reach 9 l/m2 at Thi)av ¼ 58  C. The maximum efficiencies for present
are 68, 85, 80, and 87% at 57.6, 133.2, 214.2, and 288 l/h for hot water
flow, respectively. It can be seen that increasing the hot water flow
rate five times yields twice the productivity at Thi)av ¼ 58  C.
The GOR increases with increasing hot water temperature and
flow rate. A larger value of GOR in a desalination system means
higher energy efficiency and better distillate production
performance.
Fig. 8 shows the effect of the inlet hot water flow rate on pro-
duction rate. It can be seen that an increase in inlet hot water flow
rate decreases the productivity rate while an increase in average
Fig. 7. Effect of average hot water temperature on daily productivity, daily efficiency hot water temperature increases productivity rate. The hot water
and GOR at different inlet hot water flow rate. flow rate change from 60 to 70  C, the productivity rate increase by
about 70%.
Fig. 6 shows daily productivity at different hot water flow rate. It TDS (Total dissolve solids) of salty feed water in village is more
can be seen that daily productivity increases with the increase of than 3500 ppm and TDS of fresh water during the test period is less
hot water temperature as shown in Fig. 4. That is because of than 40 ppm. This shows the ability of this process in desalination
increasing the temperature difference between evaporation and of salty water to produce potable water in arid areas.
condensation in which the evaporation rate is increased by Comparison of productivity rate for present system and Zamen
increasing the temperature difference. The maximum daily et al. [15] is tabulated in Table 1 as a function of inlet hot water flow
rate, mw,hi, at Thi)av ¼ 70  C. It can be seen that an increase in water
flow rate decreases productivity rate. The results showed that the
productivity rate of the present system is higher than that for the
Zamen et al. [15] which uses a two-stage process at the same
condition.

Table 2
The average of Thi,av, Mw,av, hd,av, and CPL at different mw,hi.

mw,hi, l/h Thi,av,  C Mw,av, l/m2 hd,av, % CPL, $/l

57.6 62.0 4.04 49.2 0.049


133.2 57.8 4.92 60.0 0.040
214.2 57.0 6.00 61.1 0.033
288.0 53.4 6.70 63.0 0.029
Fig. 8. Effect of inlet hot water flow rate on productivity rate.
S.A. El-Agouz et al. / Energy 76 (2014) 276e283 283

4. Economic analysis  TDS (Total dissolved solids) of salty water after desalination is
40 ppm.
The calculation methodology is based on; the salvage value of  The cost of distilled water per liter is $0.029.
the units will be zero at the end of the amortization period. The
operator and maintenance costs are 20% of plant annual payment
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