June 23, 2009 Test 2A Chemistry 110

Student’s Name:

Answers Formula used Answers Formula used

1. E 2. C

3. E 4. C

5. E 6. C

7. E 8. E

9. D 10. E

11. D 12. B

13. B 14. B

15. C 16. C

17. D 18. D

19. A 20. B

21. E 22. C

23. A 24. C

25. E 26. E

27. B
Short Answers
1. (5 pts) A compound consisting of C, H and O only, has a molar mass of 331.5 g/mol. Combustion of 0.1000 g of this
compound produced 0.2921 g of CO2 and 0.0951 g of H2O. What are the molecular and empirical formulas of this
compound?

CxHyOz + O2  CO2 + H2O

0.1000 g 0.2921 g 0.0951 g

Mass C = 0.2921 x 12.01 = 0.0797 g

44.01 g

Mass H = 0.0951 x 2.02 = 0.01066 g

18.02 g

Mass O = 0.100g – ( 0.0951 + 0.01066) = 0.00964 g

Moles of C = 0.0797g = 6.636 x10-3 mol

12.01g

Moles of H = 0.01066g = 1.055 x10-2 mol

1.01g

Moles of O = 0.00964g = 6.025 x10-4 mol

16.00

Ratios are (C : H : O) = (11 : 17.5 : 1) which is (22 : 35 : 2)

The empirical and Molecular formulas are C22H35O2

2. (6 pts) Consider the balanced equation:

Al2S3(s) + 6H2O (l)  2Al(OH)3(s) + 3H2S(g)
If 15.0g of aluminum sulfide and 10.0g of water are allowed to react as above, and assuming a complete reaction
a) by calculation, find out which is the limiting reagent.
b) calculate the maximum mass of H2S which can be formed from these reagents.
c) calculate the mass of excess reagent remaining after the reaction is complete.

15.0 g Al2S3 x 1 mol Al2S3 x 3 mol H2S x 34.08 g H2S = 10.2 g H2S
150.14 g 1 mol Al2S3 1 mol H2S

10.0 g H2O x 1 mol H2O x 3 mol H2S x 34.08 g H2S = 9.42 g H2S Limiting reactant
18.02 g 6 mol H2O mol H2S

a) H2O is the limiting Reactant

b) Mass of H2S formed is 9.42 g
c) Mass of Al2S3 that has reacted: 10.0 g H2O x 1 mol H2O x 1 mol Al2S3 x 150.14 g Al2S3 = 13.89 g Al2S3 reacted
18.02 g 6 mol H2O 1 mol Al2S3
Mass of Al2S3 leftover = 15.0 g – 13.89 g = 1.1 g of Al2S3 leftover.
 3. Give formulas for names and names for formulas (8 pts)

Names Formulas Formulas Names

Iron (II) Sulfate FeSO4 Hg2I2 Mercury (I) iodide

Cobalt (III) oxide Co2O3 HClO2 (aq) Chloric Acid

Potassium dichromate K2Cr2O7 P4O10 Tetraphosphorus decoxide

Lead (IV) sulfide PbS2 SO3 Sulfur trioxide

Magnesium sulfate heptahydrate MgSO4.7H2O NH4NO2 Ammonium nitrite

Titanium (IV) permanganate Ti(MnO4)4 AgCN Silver cyanide

Gold (III) Iodide AuI3 H2O2 Hydrogen peroxide

Hydrogen sulfide H2S H2SO3 (aq) Sulfurous acid