Ea

ln k = ln A - R (T )

Ea
ln k = ln A - ……..(1)
R (295)
Ea
ln 27k = ln A - ….(2)
R (325)
(2)-(1)

−Ea −Ea
ln 27k – ln k = -
R (325) R (295)
27 k Ea 1
ln =- ¿- )
k R 295
Ea
ln 27 = - (-6/19175)
R
 rate = k [A]x[B]y

Exp 1 & 2: (2) 4r = k [2a]x[b]y Exp 1 & 2: (3) r = k [a]x[2b]y

(1) r = k [a]x[b]y (1) r = k [a]x[b]y

2 divided by 1 3 divided 1

4 = [2]x x = 2, second order for [A]2 1 = [2]y, y = 0 [B]0

Conc ↓, value of
gradient, k = +
 Autocatalysis = product is also the catalyst
Reactant is used up as catalyst,
r.o.r (conc decrease, cat = form , r.o.r increase)
Do you need much catalyst?
No (conc decreasing, cat = max, r.o.r slowly decrease)

At very first, r.o.r is high = fast = ada catalyst

At final, r.o.r is low, conc is low, cat = max,
cat doesn’t affect r.o.r anymore.

b.Rate = k [X][Y]2 a. new rate = (0.16)(0.2/4)(0.1/4)2 d. moldm-3s-1 = k (moldm-3)3

3.2e-4 = k [0.2][0.1]2 = 5e-6 k = mol-2dm3s-1

k = 0.16

c. Bimolecular = 2 reactants combine to form transition state

unimolecular = 1 reactant

rate = k [H+]1[C3H8]1

pH = 1 pH = 2 Rate1/Rate2 = 0.1/0.01 = 10/1

-log [H+] = 1, [H+] = 0.1 [H+] = 0.01

Rate1 = k(0.1)(1) Rate2 = k (0.01)(1) 3. Rate order of I2 = 0, Rate Unaffected by I2

Doesn’t dictate= not r.d.s

 rate = k [A]1

First-order reaction

-k = gradient = m = y2 – y1/x2-x1 Foam is formed faster when…

= -4 –(-4.5) / 50 – 350 = -1/600, k = 1/600 s -1
Colourless soln turns brown
followed by colourless solution
t0.5 = 415.8 s again.

Rate of reaction = k [N2O5]

H2O2 → H2O + O2