Q20/ Consider the following system in a 1.

00 L container: A(g) + B(g)    2C(g)

o
The equilibrium concentrations at 200 C were determined to be:
[A] = 0.200 M [B] = 3.00 M [C] = 0.500 M
How many moles of A must be added to increase the concentration of C to 0.700 M at
200oC?
(a) 0.225 mol
(b) 0.305 mol
(c) 0.417 mol
(d) 0.610 mol
(e) 0.700 mol
Solution:
A(g) + B(g)    2C(g)
K c =¿ ¿
x: moles of A are added to increase the concentration of C to 0.700.
According to reaction:
[A] = x (M)
[B] = x (M)
[C] = 0.700 – 0.500 = 0.200 (M)
x∗x
K c= =0.417 → x=√ 0.417∗0.200=0.309 moles
0.200

2. The lattice energy* of NaI is 686 kJ/mol, and the enthalpy of hydration is _694 kJ/mol.
Calculate the enthalpy of solution per mole of solid NaI.

NaI(s) NaI (aq)

,
Δ H solute=− Δ H lattice = 686 kJ/mol (This term must be positive because we need
energy to break down NaI)
∆ H hydration of ions=−694 kJ /mol

Solution energy = 686 – 694 = - 8 kJ/mol