KIMIA ORGANIK

Genap 2020/2021_1 Februari 2021

(http://facstaff.uwa.edu/rcollison/CH_102_powerpoint.htm)
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PERBEDAAN
SENYAWA KARBON DAN SENYAWA HIDROKARBON

senyawa yang mengandung senyawa yang

tidak hanya unsur C dan H mengandung hanya
tetapi juga unsur lain seperti C dan H saja
O , N , S , P atau halogen

* Alkanol Alkana
* Alkoksi alkana Alkena
* Alkanal Alkuna
* Alkanon
* Alkanoat
* Alkil alkanoat

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 Perbedaan senyawa organik and anorganik

KRITERIA ORGANIK ANORGANIK

Unsur yg terkandung Terutama C, H, O, N, Hampir semuaunsur,

P, S, F, Cl, Br , I unsur C sedikit

Ikatan Kovalen Ion

Isomer Ada Tidak ada

Titik didih Rendah Tinggi

Kelarutan Umumnya sukar larut Umumnya mudah larut

dalam air dalam air
Sumber Kebanyakan berasal Kebanyakan dari batu-
dari makhluk hidup batuan

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Ikatan Kimia Karbon

Boundary surfaces of a 1s and 2s orbital Boundary surfaces of the 2p orbitals

Figure 1.3 Figure 1.4

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved. Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Molecular models of methane A wedge-and-dash drawing of the structure
Figure 1.7 of methane
Figure 1.8

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved. Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Shape of a molecule in terms of its atoms Representations of the trigonal planar geometry
Figure 1.9 of boron trifluoride
Figure 1.10

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved. Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Models of formaldehyde showing the trigonal planar Linear geometry of carbon dioxide
geometry of the bonds to carbon Figure 1.12
Figure 1.11

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved. Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Contribution of individual bond dipole moments to
molecular dipole moments
Figure 1.13

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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sp3-Hybridization of carbon
Figure 1.20

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Orbital overlaps involved in  bonds of methane
Figure 1.22

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Orbital overlap description
Figure 1.23

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Atoms of ethylene
Figure 1.24

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.
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sp2-Hybridization of carbon
Figure 1.25

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.
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Orbital overlaps and
bonding in ethylene
Figure 1.27

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Acetylene is a linear molecule
Figure 1.28

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.
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sp-Hybridization of carbon
Figure 1.29

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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Orbital overlaps and bonding in acetylene
Figure 1.31

Francis A. Carey, Organic Chemistry, Fourth Edition. Copyright © 2000 The McGraw-Hill Companies, Inc. All rights reserved.

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