MENDOZA, JOSEPH ANJELO N.

TAN, SAMANTHA NICOLE S.

1. Which of the following is the most adverse A. none of these.

factor challenging the choice of mercury B. inhibiting the growth of micro-organisms
electrolytic cell process for the production of without killing them.
caustic soda? C. killing of organisms present in it by heating
A. Pollution of water stream by mercury. it at controlled temperature without
B. Non-availability of high purity mercury. changing its natural characteristics.
C. High specific gravity of mercury. D. removal of fatty and albuminous substance
D. High cost of mercury. from it.
2. Which oil is preferred for paint manufacture ? 11. Calgon used in water treatment is chemically
A. Non-drying oil A. sodium phosphate
B. Drying oil B. sodium hexametaphosphate
C. Semi-drying oil C. calcium phosphate
D. Saturated oil D. tricresyl phosphate
3. Free alkali in a toilet soap is that in a 12. Polycaprolactum is commercially known as
laundry shop. A. nylon-66
A. more than B. nylon-6
B. less than C. rayon
C. none of these D. dacron
D. same 13. Raw materials used for producing
4. Dehydrogenation of isopropanol produces cement does not contain iron oxide.
A. acetone A. slag
B. propyl alcohol B. waterproof
C. formaldehyde C. white
D. trichloroethylene D. pozzolan
5. All enzymes are made of 14. The drug used in contraceptives is
A. fats A. methyl salicylate
B. proteins B. pencillin
C. carbohydrates C. sulphadizene
D. amino acids D. mestranol
6. Fusel oil is a/an 15. The type of high refractive index glass used in
A. mixture of higher molecular weight optical instruments is glass.
alcohols (a by-product obtained during A. pyrex
production of alcohol from molasses). B. flint
B. none of these. C. none of these
C. essential oil. D. crookes
D. extract from medicinal herbs. 16. Oxidation of ortho-xylene in presence of
7. Gun powder, which is an explosive comprises catalyst is done to produce phthalic anhydride
of charcoal, sulphur and on commercial scale.
A. nitro glycerine A. nickel
B. salt petre B. alumina
C. dynamite C. vanadium
D. glycerine D. iron
8. Glycerine is not used in the 17. Cumene is the starting material for the
A. none of these. production of
B. manufacture of pharmaceuticals. A. isoprene
C. manufacture of explosive. B. styrene
D. conditioning and humidification of tobacco. C. benzoic acid
9. Frasch process is for D. phenol and acetone
A. producing helium 18. process is used for the manufacture of sodium
B. making oxygen carbonate by ammonia soda process.
C. mining sulphur A. Ostwald's
D. making nitrogen B. Solvay
10. Pasteurisation of milk means C. Bosch
SLU | SEA | ChE | ChE 520L | Integrated ChE | ACTIVITY 12
Coverage: CPI | Materials Engg Second Semester 2019-2020

D. Haber’s 28. Phenol formaldehyde resin is used as an

19. Very fine suspended and colloidal impurities adhesive in making
are removed from water by a process called A. books
A. disinfection B. furniture
B. sedimentation C. laminates
C. softening D. card boxes
D. coagulation 29. Which of the following is an organo-metal-lic
20. Sulphur addition in soap is done to compound ?
A. improve the soap texture. A. Isopropyl alcohol
B. cure pimples & dandruff. B. Cumene
C. increase its cleansing action. C. Zeolite
D. fasten lather formation. D. Tetra-ethyl lead
21. Epoxy resin 30. Which oil is preferred for paint manufacture ?
A. is a good adhesive. A. Non-drying oil
B. is an elastomer. B. Drying oil
C. is a polyester C. Semi-drying oil
D. cannot be used for surface coatings. D. Saturated oil
22. Styrene butadiene rubber (SBR) is 31. Fusel oil is a/an
A. a synthetic polymer. A. mixture of higher molecular weight
B. a synthetic monomer. alcohols (a by-product obtained during
C. a natural rubber. production of alcohol from molasses).
D. another name of silicone rubber. B. none of these.
23. In the Lurgi coal gasifier C. essential oil.
A. large quantity of coal can be processed D. extract from medicinal herbs.
B. low carbon conversion efficiency is 32. Gun powder, which is an explosive comprises
achieved. of charcoal, sulphur and
C. coking coals cannot be used. A. nitro glycerine
D. entrainment of solids is higher. B. salt petre
24. Metallic soap (e.g. aluminum or calcium salts of C. dynamite
fatty acids) can be used D. glycerine
A. in hard water for cleaning of cloth. 33. Oils are partially hydrogenated (not fully) to
B. as a foam depressant in distillation column. manufacture vanaspati, because fully saturated
C. as a lubricant. solidified oils
D. as a rust preventive. A. are prone to rancid oxidation.
25. process is used for the commercial production B. cause cholesterol build up and blood
of nitric acid by the catalytic oxidation of clotting.
ammonia C. have affinity to retain harmful sulphur
A. Ostwald's compounds.
B. Solvay D. always contain some amount of nickel (as
C. Haber's their complete removal is very difficult).
D. none of these 34. Vulcanisation of rubber
26. Bleaching action of bleaching powder is due to A. increases its oil & solvent resistance.
its B. converts its plasticity into elasticity.
properties. C. increases its ozone & oxygen reactivity.
A. none of these D. decreases its tensile strength.
B. disinfecting 35. The process used for the manufacture of ethyl
C. oxidising alcohol from molasses is
D. reducing A. dehydration
27. A good quality coal should have B. dehydrogenation
A. high ash content C. none of these
B. low fusion point of ash D. distillation
C. none of these 36. Lurgi coal gasifier is a pressurised bed
D. high sulphur content reactor.
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moving
A. C. amorphous isotropic material.
fixed
B. D. supercooled liquid.
entrained
C. 46. Which of the following has sodium bicarbonate
fluidised
D. as its main constituent ?
37. Which of the following sugars is the sweetest? A. Baking powder
A. Sucrose B. Washing soda
B. Fructose C. Baking soda
C. Glucose D. none of these
D. Lactose 47. Esterification reaction produces
38. Haemoglobin is a/an A. soap
A. amino acid B. ethyl alcohol
B. biological catalyst C. mercaptans
C. enzyme D. detergent
D. protein 48. The chamber process is
39. Starting raw material for the manufacture of A. all of above
alum is B. preferred over contact process for
A. ammonium bicarbonate producing 98 to 100% H2SO4 and
B. bauxite various oleum.
C. gypsum C. none of these
D. alumina D. non-catalytic and operates only on pyrites.
49. Neoprene is the trade name of
40. Most widely and commonly used coagulant for
A. phenol formaldehyde
the removal of suspended impurities in water is
B. styrene-butadiene rubber
A. copper sulphate
C. polychloroprene
B. alum
D. polyurethane
C. slaked lime
D. bleaching powder 50. Zeolite used in water softening process (cation
41. Raw materials for ‘Solvay Process’ for exchange) is regenerated by washing with
manufacture of the soda ash are A. chloramines
A. salt, limestone and coke or gas. B. liquid chlorines
B. ammonia, salt and limestone. C. brine
C. none of these. D. sodium bisulphite
D. ammonia limestone and coke. 51. Lime and soda ash are added to water to remove
42. Heating of to 120°C, produces plaster A. undersirable taste and odour.
of paris. B. its corrosiveness.
A. blue vitriol C. bacteria
B. calcium sulphate D. bicarbonates & sulphates of calcium and
C. calcium silicate magnesium.
D. gypsum 52. Which of the following is not required in the
43. Carboxymethyl cellulose (CMC) is added in manufacture of soda ash by Solvay process ?
detergents to act as a/an A. Nitric acid
A. surfactant B. None of these
B. builder C. Ammonia
C. optical brightening agent D. Limestone
D. anti soil redeposition agent 53. The purpose of tanning in leather industry is to
44. In primitive days, was being A. smoothen the leather.
manufactured by Leblanc Process. B. stiffen the leather.
A. soda ash C. impart water resistance.
B. washing soda D. make it flexible.
C. calcium carbide 54. Which of the following is a detergent ?
D. alum A. Alkyl benzene sulphonate
45. Ordinary glass is not a/an B. Cellulose nitrate
A. electrical insulator. C. Benzene hexachloride
B. material with sharp definite melting point. D. Polytetraflouroethylene
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SLU | SEA | ChE | ChE 520L | Integrated ChE | ACTIVITY 12
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55. Zeolite removes both temporary as well as materials. A material is said to be refractory if
permanent hardness of water by precipitating it:
calcium and magnesium present in water as A. resists the flow of electric current
insoluble zeolites. Used zeolite is regenerated B. has high refractive index
by flushing with the solution of C. retains its strength at high temperatures
A. magnesium chloride. D. All of the above
B. sodium chloride 63. Which of the following is true for polymers?
C. sodium sulphate A. They have very high molecular mass
D. calcium sulphate B. They do not have a linear stress-strain
56. Wood charcoal is used for decolouration of curve
sugar, because it the coloured materials. C. They have high strength to mass ratio
A. reduces D. All of the above
B. oxidises 64. Calcium is an isobar of Argon. They differ in:
C. adsorbs A. Atomic weight
D. converts B. Number of nucleons
57. Viscose rayon is chemically C. Number of neutrons
A. regenerated cellulose nitrate D. None of the mentioned
B. regenerated cellulose acetate 65. Allotropes differ in which of the following
C. cellulose nitrate properties:
D. cellulose acetate A. Atomic Number
58. Fusion of bauxite and produces B. Atomic Mass
high alumina cement. C. Crystal Structure
A. alum D. Electronegativity
B. limestone 66. Co-ordination number of a crystalline solid is:
C. coke A. Number of particles in the unit cell
D. quartz B. Number of nearest neighbours of a particle
59. Which of the following is not a raw C. Number of octahedral voids in a unit cell
material used for the manufacture of D. Number of tetrahedral voids in a unit cell
ordinary glass? 67. Packing efficiency of a crystal structure is the
A. Soda ash ratio of:
B. Iron oxide A. Volume occupied by particles to the total
C. Limestone volume of the unit cell
D. Silica B. Volume occupied by particles to that by
voids
60. Pick out the correct statement.
C. Total volume of the unit cell to the volume
A. There is no difference between a fat and an
occupied by particles
oil so far as its physical properties are
D. Volume occupied by voids to that by
concerned. particles
B. A fat is converted into oil by its 68. An octahedral void is surrounded by:
hydrogenation. A. 8 atoms
C. All vegetable oils except coconut oil, B. 18 atoms
contains fatty acids having more than
sixteen carbon atoms. C.6 atoms
D. Vegetable oils are classified as drying, non- D.16 atoms
drying and semi drying oils 69. Which of the following is a property of
depending upon their fatty acids amorphous solids?
content. A. Sharp melting point
61. In terms of which of the following properties, B. Isotropy
metals are better than ceramics? C. Long range order
A. Hardness D. Definite heat of fusion
B. Ductility 70. Which of the following is a crystalline solid?
C. Toughness A. Copper wire
D. Yield Strength B. Glass bottle
62. Ceramics make excellent refractory C. Polythene bag
D. Rubber ball
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SLU | SEA | ChE | ChE 520L | Integrated ChE | ACTIVITY 12
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71. Which of the following Bravais lattices exist C. Mass per unit cell
as face centered unit cell? D. All of the mentioned
A. Orthorhombic 80. The point coordinates of the vertex just
B. Monoclinic opposite to the origin are
C. Tetragonal A. 000
D. None of the above B. 001
72. Number of particles in a primitive cubic unit C. 011
cell is: D. 111
A. 1 81. If x, y, and z are three positive axes of the
B. 2 crystallographic coordinate system with origin
C. 3 at point A, then which line points in the
D. 4 direction [1 0 1] ?
73. Which of the following lattices has the highest A. AD
B. CH
void fraction?
A. Hexagonal close packed C. FB
D. GE
B. Body centered cubic
82. In cubic crystals, crystallographic directions
C. Face centered cubic
D. Primitive cubic are arranged in families. Which of the
following directions does not belong to the
74. Which of the following unit cells do not exist
for tetragonal lattices? family <110>?
A. [1 0 1]
A. Primitive centered unit cell B. [1 1 0]
B. Body centered unit cell C. [1 0 1̅]
C. Face centered unit cell D. None of the above
D. All of the mentioned exist 83. The ratio of the number of vacancies to a total
75. Coordination number of HCP and FCC number of lattice points for a metal near
lattices respectively are: melting temperature is of the order of 10-4.
A. 12, 12 For lower temperatures, the ratio:
B. 4, 4 A. increases
C. 12, 8 B. decreases
D. 8, 8
C. remains the same
76. Number of particles in one unit cell of HCP
D. may increase or decrease depending on the
lattice is:
metal
A. 1
84. Foreign species is present in which of the
B. 2
following defects?
C. 4
A. Interstitial
D. 6
B. Vacancy
77. The void fraction is the ratio of unfilled volume to total volume of a
structure. For ideal metallic FCC crystal, it is: C. Substitution
A. 0.22 D. All of the mentioned
B. 0.26 85. Which type of defect are point defects?
C. 0.32 A. One dimensional defect
D. 0.38 B. Zero dimensional defect
78. If N is the number of tetrahedral voids in a C. Two dimensional defect
close- packed structure, then the number of D. Three dimensional defect
octahedral voids is: 86. In which of the following defect the density of
N/4
A. the crystal is affected?
4N
B. A. Schottky defect
2N
C. B. Frenkel defect
N/2
D. C. Stone-Wales defect
79. Which of the following quantities is larger in D. Antisite defect
HCP as compared to FCC if the constituting 87. Schottky and Frenkel defects are
atoms are similar? A. Interstitial and vacancy defects
A. Number of particles per unit cell respectively
B. Volume per unit cell B. Vacancy and interstitial defect respectively
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C. Both interstitial defects B. 4

D. Both vacancy defects C. 6
88. In which of the following case the first D. 8
element can occupy both lattice position and
interstitial position?
A. Cu in FCC-Ni
B. C in FCC-Fe
C. B in steel
D. Al in FCC-Fe
89. Which type of diffusion occurs due to the
exchange of an atom with vacancies?
A. Substitution diffusion
B. Elimination diffusion
C. Passive diffusion
D. Facilated diffusion
90. Under condition of very slow deformation and
high temperature, it is possible to have plastic
flow in a crystal at shear stresses lower than
the critical shear stress. What is this
phenomenon called?
A. slip
B. twinning
C. creep
D. bending
For the following questions, show pertinent
solutions and enclose your final answers.
91. Calculate temperature of copper at which
equilibrium number of vacancies per cubic
meter is 2.2x10^20 vacancies/m3. The energy
of vacancy formation is 0.7ev/atom and total
number of atom is 2x10^30 atom/m3.
A. 3541.4k
B. 300k
C. 354.14k
D. 2.82*10-3k
92. The unit cell for uranium has orthorhombic
symmetry, with a, b, and c lattice parameters
of 0.286, 0.587, and 0.495 nm, respectively. If
its density, atomic weight, and atomic radius
are 19.05 g/cm3, 238.03 g/mol, and 0.1385 nm,
respectively, compute the atomic packing
factor.
A. 0.447
B. 0.486
C. 0.536
D. 0.562
Linkage
Problem:
Indium has a tetragonal unit cell for which the a and c
lattice parameters are 0.459 and 0.495 nm, respectively.
93. If the atomic packing factor and atomic radius
are 0.693 and 0.1625 nm, respectively,
determine the number of atoms in each unit
cell.
A. 2
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Problems:
Beryllium has an HCP unit cell for which the ratio of
the lattice parameters is 1.568. If the radius of the Be
atom is 0.1143 nm,
94. Determine the unit cell volume
A. 3.33 x 10^-23 cm3/unit cell
B. 4.87 x 10^-23 cm3/unit cell
C. 5.01 x 10^-23 cm3/unit cell
D. 5.34 x 10^-23 cm3/unit cell
95. Calculate the theoretical density
of Be A. 1.76 g/cm3
B. 1.80 g/cm3
C. 1.84 g/cm3
D. 1.88 g/cm3
96. Magnesium has an HCP crystal structure, a
ratio of 1.624, and a density of 1.74 g/cm3.
Compute the atomic radius for Mg.
A. 0.130 nm
B. 0.140 nm
C. 0.150 nm
D. 0.160 nm
97. Gold forms a substitutional solid solution with
silver. Compute the weight percent of gold that
must be added to silver to yield an alloy that
contains 5.5 x 10^21 Au atoms per cubic
centimeter. The densities of pure Au and Ag
are 19.32 and 10.49 g/cm3, respectively.
A. 13.2%
B. 14.7%
C. 15.9%
D. 16.4%
Linkage Problem:
The diffusion coefficients for carbon in nickel
are given at two temperatures:

98. Determine the values of D0

A. 1.05 x 10^-5 m2/s
B. 1.12 x 10^-5 m2/s
C. 1.45 x 10^-5 m2/s
D. 1.52 x 10^-5 m2/s
99. (b) What is the magnitude of D at 850 ºC?
A. 3.6 x 10^-12 m2/s
B. 3.8 x 10^-12 m2/s
C. 4.0 x 10^-12 m2/s
D. 4.2 x 10^-12 m2/s

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SLU | SEA | ChE | ChE 520L | Integrated ChE | ACTIVITY 12
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Answers to problems

91.
Nv= Nexp(-Qv/RT)
K= 8.62*10^-5 ev/Atom-F
2.2*10^20 = 2*10^30 e(-0.7/8.62*10^-5T)
T= 354.1412 K = C.

92. Given: a= 0.286 nm

b= 0.587 nm
c= 0.495 nm
ρ= 19.05 g/cm3
MW=238.03 g/mol
R=0.1385 nm

Vc= abc= (0.286 nm)(0.587 mnm)(0.495 nm)= 0.0831 nm3

𝑔 𝑎𝑡𝑜𝑚
19.05 (0.0831𝑥10−21 𝑐𝑚3 )(6.022𝑥1023 )
𝑐𝑚3 𝑚𝑜𝑙
N= 𝑔 = 4 atoms/cell
238.03
𝑚𝑜𝑙

𝑎𝑡𝑜𝑚 4
4 ( 𝜋) (0.1385𝑛𝑚)3
𝑐𝑒𝑙𝑙 3
APF= = 0.5357 (C)
0.0831 𝑛𝑚3

93. Given: Indium (tetragonal unit cell)

a= 0.459 nm
c= 0.495 nm
APF=0.693
R=0.1625 nm
MW=114.82 g/mol
4
𝑁( 𝜋) (0.1625𝑛𝑚)3
3
0.693= = 4.0208 atoms/unit cell(B)
(0.459𝑛𝑚)(0.459𝑛𝑚)(0.495𝑛𝑚)

𝑎𝑡𝑜𝑚 𝑔
4
(114.82 ) 𝒈
94. ρ= 𝑐𝑒𝑙𝑙 𝑚𝑜𝑙
𝑎𝑡𝑜𝑚 = 7.3132 (B)
(0.459𝑥0.459𝑛𝑚𝑥0.495 𝑥 10 −21 𝑐𝑚3 )(6.022𝑥1023 ) 𝒄𝒎𝟑
𝑚𝑜𝑙

95. Given: Beryllium (HCP)

Ratio of lattice (c/a) = 1.568
R=0.1143 nm

3√3 𝑥10−21 𝑐𝑚3 𝒄𝒎𝟑

Vc= (1.568𝑥8)(0.1143 𝑛𝑚)3 ( ) = 𝟒. 𝟖𝟔𝟔𝟕𝒙 𝟏𝟎−𝟐𝟑 (𝑩)
2 𝑛𝑚3 𝒖𝒏𝒊𝒕 𝒄𝒆𝒍𝒍

𝑎𝑡𝑜𝑚 𝑔
6 (9 ) 𝒈
96. ρ= 𝑐𝑒𝑙𝑙
𝑐𝑚3
𝑚𝑜𝑙
= 1.8426 (C)
4.8667𝑥 10−23 (6.022𝑥1023
𝑎𝑡𝑜𝑚
) 𝒄𝒎𝟑
𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙 𝑚𝑜𝑙

97. Given: Magnesiun(HPC)

Ratio of lattice (c/a) = 1.624
𝑔
ρ=1.74 3
𝑐𝑚
3√3
. (𝑎)2 (𝑐)= MW(ρ)(Avogadros no.)
2

𝑔 𝑎𝑡𝑜𝑚
3√3 24.3
(6 )
. (𝑎)3 (1.624)= 𝑔
𝑚𝑜𝑙 𝑐𝑒𝑙𝑙
𝑎𝑡𝑜𝑚
2 1.74 3 (6.022𝑥1023 )
𝑐𝑚 𝑚𝑜𝑙
A
A= 320 𝑝𝑚
A=2R
R=160 pm =0.160 nm (D)

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SLU | SEA | ChE | ChE 520L | Integrated ChE | ACTIVITY 12
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98.
Solution:
100
= 15.9%
6.022𝑥1023 ∗ 10.49 10.491
1+ −
5.5𝑥1021 ∗ 196.97 19.32

99.
Solution:
3.9𝑥10−13 ((600 + 273) ∗ (700 + 273))
𝑄 = 8.314 ln ( ) = 138.3
5.5𝑥10−14 700 − 600

5.5𝑥10−14
𝐷𝑜 = 138300 = 1.04𝑥10−5
−
𝑒 8.314∗600+273
100.
5.5𝑥10−14
𝐷𝑜 = 138300 = 3.82𝑥10−12
−
𝑒 8.314∗850+273

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