Solutions

(Average Marks:2.67)
For: KCET 2021

1. Which of the following pair of solutions is 9. When the pure solvent diffuses out of the
isotonic ? (2020) solution through the semipermeable
a) 0.01M BaCl2 and 0.015M NaCl membrane then the process is called (2017)
b) 0.001M Al2(SO4)3 and 0.01 M BaCl2 a) Sorption b) Dialysis
c) 0.001M CaCl2 and 0.001M Al2(SO4)3 c) Osmosis d) Reverse osmosis
d) 0.01M BaCl2 and 0.001M CaCl2 10. The van’t Hoff factor ‘i’ accounts for
2. Solute ‘X’ dimerises in water to the extent
a) Extent of dissolution of solute (2017)
of 80%. 2.5g of ‘X’ in 100g of water
b) Extent of dissociation of solute
increases the boiling point by 0.3 0C. The
molar mass of ‘X’ is [Kb=0.52K kg mol-1] c) Extent of mobility of solute
(2020) d) Extent of solubility of solute
a) 13 b) 52 c) 65 d) 26 11. Which of the following is not a colligative
3. Relative lowering of vapour pressure of a property? (2016)
dilute solution of glucose dissolved in 1 kg a) Osmotic pressure
of water is 0.002. the molality of the b) Optical activity
solution is (2019) c) Deposition in freezing point
a) 0.004 b) 0.222 d) Elevation in boiling point
c) 0.111 d) 0.021 12. When an electrolyte is dissociated in
4. A non-volatile solute ‘A’ tetramerises in solution, the vant’s Hoff factor(i) is, (2016)
water to the extent of 80%, 2.5 g of ‘A’ in a) > 1 b) < 1
100 g of water, lowers the freezing point by c) = 0 d) = 1
0.3 0C. The molar mass of A in mol L-1 is 13. Osmotic pressure of the solution can be
(Kf for water = 1.86 K kg mol-1) (2019) increased by (2016)
a) 62 b) 221 a) Increasing the temperature of the
c) 155 d) 354 solution
5. Solution ‘A’ contains acetone dissolved in b) Decreasing the temperature of the
chloroform and solution ‘B’ contains solution
acetone dissolved in carbon disulphide. The c) Increasing the volume of the vessel
type of deviations from Raoult’s law shown d) Diluting of solutions
by shown by solutions A and B, 14. After adding non-volatile solute freezing
respectively are (2019) point of water decreases to -0.1860C.
a) Positive and positive Calculate ∆Tb if Kf = 1.86 K kg mol-1 and
b) Positive and negative Kb = 0.521 K kg mol-1 (2015)
c) Negative and negative a) 0.0521 K b) 0.0186 K
d) Negative and Positive c) 0.521 K d) 1.86 K
6. Which of the following aqueous solutions 15. 0.06% (w/v) aqueous solution of urea is
should have the highest boiling point(2018) isotonic with (2015)
a) 1.0 M NaOH b) 1.0 M Na2SO4 a) 0.6% glucose solution
c) 1.0 M NH2NO3 d) 1.0 M KNO3 b) 0.1 M glucose solution
7. Isotonic solutions are having the same c) 0.06% glucose solution
a) Surface tension b)Vapour pressure d) 0.01 M glucose solution
c) Osmotic pressure d) Viscosity (2018) 16. Which of the following aqueous solutions
8. Which of the following aqueous solutions has the highest freezing point? (2015)
has highest freezing point? (2017) a) 0.01 M NaCl b) 0.01 M Na2SO4c)
a) 0.1 molal Al2(SO4)3 b) 0.1 molal BaCl2 0.1 M Sucrose d) 0.1 M NaCl
c) 0.1 molal AlCl3 d) 0.1 molal NH4Cl

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