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Question 1
1(c)(i) Final volumes:
Titration 1: 25.60 cm3
Titration 2: 26.30 cm3
Titration 3: 24.50 cm3
1(c)(ii) Volume used:
Titration 1: 24.60 cm3
Titration 2: 24.25 cm3
Titration 3: 24.35 cm3
1(c)(iv) 0.000244 mol
0.000243 mol
1(d)(i) 0.001220 mol
0.001215 mol
1(d)(ii) 0.01220 mol
0.01215 mol
1(e) 1.85 g
1.85 g
1(f) 1.31 g
1.31 g
1(g) 0.07278 mol
0.07278 mol
1(i) The solution goes from pale green to very pale pink/purple.
1(j) The unreacted potassium permanganate present show that the end point has
been reached because its colour does not disappear.
1(k)(ii) Precipitate slowly changes colour from dirty green to dirty brown/rust
brown.
Question 2
Anodizing of aluminium.
2(b)(i)
3(a)(iv)
3(a)(v) A glass rod when dipped in (concentrated) aqueous ammonia and placed
in the gaseous by-product, produces dense white fumes.
So carbon-12 and carbon-13 have the same number of protons (6) and different
numbers of neutrons (6 and 7 respectively). They are therefore isotopes of
carbon.
4(c)(ii) The compound will dissolve in water. This is because it consists of positive
and negative ions whose charges result in ion-dipole attractions with water, a
polar solvent. In reality, this compound, CaF2 is one of a small number of
insoluble fluorides so the correct answer is that it is insoluble in water, but a
CSEC student normally does not know how to explain why a compound is
insoluble. I can only guess what would be done in a case where this question
was answered correctly in terms of lattice and hydration enthalpies.
Question 5
5(a) Ammonia is a colourless gas with a pungent odour.
5(b)(i)
5(b)(iii) Ammonia gas is a weak base and will react, in a neutralization reaction ,
with sulfuric acid. Hence calcium oxide (CaO(s)) can be used as the drying agent
since CaO is basic and will not react with/neutralize the ammonia gas.
5(c) Moist red litmus when placed in contact with ammonia gas turns blue.
Question 6
6(a) 1. Water is a very good solvent as it dissolves both ionic and covalent
compounds. Since chemical reactions occur much more readily when in solution,
water is important for metabolic processes such as digestion and respiration. The
ability of water to dissolve oxygen is necessary for the survival of aquatic life.
2. Water has a high specific heat capacity and can absorb a large amount of heat
without a large change in temperature. This helps living organisms, which contain
approximately 70% water, to maintain a relatively constant body temperature.
6(c) Hard water is water that does not readily form a lather with soap.
Soft water is water that readily forms a lather with soap.
To distinguish between hard and soft water samples, the following method can
be used. Equal volumes of both samples are added to identical test tubes and the
test tubes labelled. 1 cm3 of soap solution is added to both water samples and
shaken for 30 seconds. The height of lather produced by each sample is
measured. The water sample giving the greater height of lather is the soft water.
The hard water may either give a lower height of lather, or no lather at all
depending on the degree of hardness.