CHEMISTRY ARCHIVE - JEE (Main)

18. Heat treatment of muscular pain involves radiation of The correct order of their increasing energies will
wavelength of about 900 nm. Which spectral line of be [JEE (Main)-2019]
H-atom is suitable for this purpose? (1) IV < II < III < I (2) I < III < II < IV
[RH= 1 × 105 cm, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1] (3) IV < III < II < I (4) I < II < III < IV
[JEE (Main)-2019]
23. If p is the momentum of the fastest electron
(1) Balmer,  2 (2) Lyman,  1 ejected from a metal surface after the irradiation of
(3) Paschen, 5  3 (4) Paschen,  3 light having wavelength , then for 1.5 p momentum
of the photoelectron, the wavelength of the light
19. The de Broglie wavelength () associated with a should be
photoelectron varies with the frequency () of the
incident radiation as, [0 is threshold frequency] (Assume kinetic energy of ejected photoelectron to be
very high in comparison to work function):
[JEE (Main)-2019]
[JEE (Main)-2019]
1 1
(1)   (2)   3 4
   0     0  4
1
(1)  (2) 
4 9

1 1 2 1
(3)   1
(4)   3 (3)  (4) 
3 2
 
 0 2   0 2 
24. For any given series of spectral lines of atomic
20. What is the work function of the metal if the light
hydrogen, let   max  min be the difference in
of wavelength 4000 Å generates photoelectrons of
velocity 6 × 105 ms–1 from it? maximum and minimum frequencies in cm–1. The

(Mass of electron = 9 × 10–31 kg ratio Lyman / Balmer is [JEE (Main)-2019]

Velocity of light = 3 × 108 ms–1 (1) 9 : 4 (2) 27 : 5
Planck’s constant = 6.626 × 10–34 Js (3) 4 : 1 (4) 5 : 4
Charge of electron = 1.6 × 10–19 JeV–1) 25. Which one of the following about an electron
[JEE (Main)-2019] occupying the 1s orbital in a hydrogen atom is
incorrect? (The Bohr radius is represented by a0)
(1) 4.0 eV (2) 2.1 eV
[JEE (Main)-2019]
(3) 3.1 eV (4) 0.9 eV
(1) The probability density of finding the electron is
21. If the de Broglie wavelength of the electron in nth maximum at the nucleus
Bohr orbit in a hydrogenic atom is equal to 1.5 a0
(a0 is Bohr radius), then the value of n/z is (2) The electron can be found at a distance 2a0
from the nucleus
[JEE (Main)-2019]
(3) The magnitude of the potential energy is double
(1) 0.40 (2) 1.50 that of its kinetic energy on an average
(3) 0.75 (4) 1.0 (4) The total energy of the electron is maximum
22. The quantum number of four electrons are given when it is at a distance a0 from the nucleus
below 26. The graph between ||2 and r(radial distance) is
1 shown below. This represents [JEE (Main)-2019]
(I) n = 4, l = 2, ml = –2, ms = 
2
1
(II) n = 3, l = 2, ml = 1, ms =  ||2
2
1
(III) n = 4, l = 1, ml = 0, ms = 
2 r

1 (1) 1s orbital (2) 2s orbital

(IV) n = 3, l = 1, ml = 1, ms = 
2 (3) 2p orbital (4) 3s orbital