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27. The ratio of the shortest wavelength of two spectral 4a0 4a0
series of hydrogen spectrum is found to be about (1) (2)
3 9
9. The spectral series are [JEE (Main)-2019] 2a0 2a0
(3) (4)
(1) Paschen and Pfund (2) Brackett and Pfund 3 9
(3) Lyman and Paschen (4) Balmer and Brackett 33. The de Broglie wavelength of an electron in the 4th
Bohr orbit is [JEE (Main)-2020]
28. The electrons are more likely to be found
(1) 4a0 (2) 6a0
[JEE (Main)-2019] (3) 8a0 (4) 2a0
34. The figure that is not a direct manifestation of the
a  (x) quantum nature of atoms is [JEE (Main)-2020]
 Increasing wavelength
b x
–x
(1)
c

Absorption spectrum
(1) In the region a and c (2) Only in the region c
Internal
(3) Only in the region a (4) In the region a and b energy
(2) of
29. Among the following, the energy of 2s orbital is Ar 300 400 500 600
lowest in [JEE (Main)-2019]
Temperature (K)
(1) Li (2) K
(3) H (4) Na T2 > T1
Intensity
30. The number of orbitals associated with quantum of black body
(3) radiation T1
1
numbers n = 5, ms =  is [JEE (Main)-2020]
2 Wavelength

(1) 15 (2) 50 Rb K
Na
Kinetic
(3) 25 (4) 11 energy of
(4) photoelectrons
31. For the Balmer series in the spectrum of H atom,
Frequency of incident
⎪⎧ 1 1 ⎪⎫ radiation
  RH ⎨ 2  2 ⎬ , the correct statements among (I)
⎪⎩ n1 n2 ⎪⎭ 35. The number of subshells associated with n = 4 and
m = –2 quantum numbers is [JEE (Main)-2020]
to (VI) are
(1) 2 (2) 8
(I) As wavelength decreases, the lines in the (3) 4 (4) 16
series converge
36. The region in the electromagnetic spectrum where
(II) The integer n1 is equal to 2 the Balmar series lines appear is
(III) The lines of longest wavelength corresponds to [JEE (Main)-2020]
n2 = 3 (1) Microwave (2) Ultraviolet
(IV) The ionization energy of hydrogen can be (3) Visible (4) Infrared
calculated from wave number of these lines 37. The shortest wavelength of H atom in the Lyman
series is 1. The longest wavelength in the Balmar
[JEE (Main)-2020]
series of He+ is [JEE (Main)-2020]
(1) (I), (II), (III) (2) (II), (III), (IV)
51 361
(3) (I), (III), (IV) (4) (I), (II), (IV) (1) (2)
9 5
32. The radius of the second Bohr orbit, in terms of the 271 91
Bohr radius, a0, in Li2+ is [JEE (Main)-2020] (3) (4)
5 5