Test ID : 623

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FULL PORTION TEST.

Std : LT, XII & CC-I Max. Marks: 500
Test Date : 20.07.2021 [AN] CHEMISTRY – II Time : 3 Hrs.
(2nd YEAR)
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 125 x 4 = 500
1. Find the secondary valency of a salt Which statement is correct?
“PtCl2.4NH3”, which forms 2 moles of AgCl 1) both are optically active
with excess of AgNO3
2) both are optically inactive
1) 6 2) 2
3) 3 4) 4 3) (a) is optically inactive
2. Correct statement(s) about EDTA
4-
ligand (b) is optically active
is/are 4) (a) is optically active
1) it is a hexadentate ligand (b) is optically inactive
2) it is a chelating ligand 2-
6. In complex [NiCl4] , the number of unpaired
3) it binds through two nitrogen and four electrons and magnetic nature are respectively
oxygen atoms to a central atom
1) zero, diamagnetic
4) all the above
3. The oxidation number of central atom in 2) two, paramagnetic
[Co(NH3)4(H2O)Cl]Cl2 is 3) two, diamagnetic
1) +2 2) +3 4) four, paramagnetic
3) -1 4) +6 7. The number of unpaired electrons in
4. The formula of
[Mn(CN)6]3- and [MnCl6]3- are respectively
amminebromidochloridonitrito -N-platinate(II)
1) 2, 2 2) 4, 2
1) [Pt(NH3)BrCl(ONO)]−
3) 3, 4 4) 2, 4
2) [Pt(NH3)2Cl2]NO2
8. Which is incorrect about short comings of
3) [Pt(NH3)BrCl(NO2)]−
4) [Pt(NH3)BrCl(NO2)] valence bond theory of co-ordination
5. Out of given two complexes compounds?
1) it does not give quantitative interpretation
of magnetic data
2) it does not explain the colour exhibited by
coordination compounds
3) it does not distinguish between weak and
strong ligands
4) it does not involve any assumptions
 2 Test ID : 623
9. Assertion (A) : In octahedral coordination 1) both show equal depression in freezing
entity with six ligands surrounding the metal point
ion, the d x 2 − y2 and d z 2 orbitals will be raised 2) benzene solution shows less depression in
in energy. freezing point than ethanol
Reason (R) : d x 2 − y2 and d z 2 orbitals which 3) benzene solution shows more depression
in freezing point than ethanol
point towards the axis along the direction of 4) can’t be predicted
ligand will experience more repulsion.
15. Which is incorrect match?
1) Both (A) and (R) are correct, (R) is correct
1) Isotonic solutions – No osmosis take place
explanation of (A)
2) Reverse osmosis – Pressure is less than the
2) Both (A) and (R) are correct but (R) is not
osmotic pressure applied to solution side
correct explanation of (A)
3) Edema – Swelling of blood cells
3) (A) is correct but (R) is wrong
4) Hypertonic solution – Water flow out from
4) (A) is wrong but (R) is correct
cells and they would shrink
10. If ∆o < P, then the distribution of electrons in
16. Amount of CaCl2 required to dissolve in 11.2L
octahedral complex of Fe+3 ion is
water such that osmotic pressure is 0.08 atm at
1) t2g4eg1 2) t2g5eg0
273 K. [i value for CaCl2 = 2.0]
3) t2g3eg2 4) t2g2eg3
1) 11.1g 2) 111g
11. Vapour pressure of pure chloroform is
3) 2.22g 4) 222g
200 mm and pure methylene chloride is
415 mm at 25°C. Calculate mole fraction of 17. Based on solute solvent interactions, arrange
chloroform in vapour phase, when the mole the following in the order of increasing
fraction of chloroform in solution is 0.4. solubility in n-octane.
1) 0.40 2) 0.80 Cyclohexane, KCl, methanol, methyl cyanide
3) 0.61 4) 0.24 1) Cyclohexane < KCl < methanol < methyl
12. Which pair is positive deviated non-ideal cyanide
solution? 2) KCl < CH3OH < Methyl cyanide <
1) n-hexane and n-heptane Cyclohexane
2) Ethanol and acetone 3) Methanol < Cyclohexane < KCl < methyl
3) Chloroform and acetone cyanide
4) Benzene and toluene 4) Methyl cyanide < Methanol < Cyclohexane
13. Boiling point of solution is 373.202 K when < KCl
‘x’ grams of glucose added to 1kg of water at 18. Which is/are correct statement(s) about
normal pressure. Find value of ‘x’. Galvanic cell?
[Kb for water is 0.52 K kg mol-1 and normal a) The half cell in which oxidation takes place
boiling point of water 373.15K]. called anode.
1) 18 g 2) 36 g b) Anode has a negative potential with respect
3) 90 g 4) 45 g to solution
For same molal solution, which show more 2+ -
14. c) Cu (aq ) + 2e → Cu(s) is called oxidation half
depression in freezing point in two solvents
reaction
ethanol and benzene?
d) Electrons flow from cathode to anode
(Kf for ethanol is 1.99 K kg mol-1 Kf for
1) a & d 2) a & b
benzene is 5.12 K kg mol-1)
3) c & d 4) a & c
 3 Test ID : 623
19. The E 0
values of Cr, Mn, Fe and Co are 25. Cell constant G* is equal to
M +3 /M +2

-0.41V, +1.57V, +0.77V and +1.97V 1) Conductivity × Resistance

respectively. For which one of these metals Conductivity
2)
the change in oxidation state from +2 to +3 is Resistance
easiest? a
3)
1) Cr 2) Mn l
4) both (1) & (3)
3) Fe 4) Co
26. Λ°m of acetic acid is 390 S cm2 mol-1, molar
20. Find Ecell for the cell reaction.
conductivity at 0.001 M concentration is
2Ag+(0.1 M) + Mg(s) → Mg2+(0.01M) + 2Ag(s) 39 S cm2 mol-1. What is percentage of degree
Given that E°cell = 3.17 V of dissociation?
1) 3.22 V 2) 3.12 V 1) 0.1 % 2) 10%
3) 3.17 V 4) 2.97 V 3) 0.01 % 4) 100 %
21. log Kc is equal to 27. Time taken for 6.3g copper to be deposited
from CuSO4 solution when 5 amperes of
E ocell × 2.303RT current is passed? (Atomic wt. of Cu = 63)
1)
nF 1) 3600 secs 2) 965 secs
E ocell × nF 3) 1930 secs 4) 3860 secs
2)
2.303RT 28. The products obtained during electrolysis of
3) E°cell × 2.303 RT × nF aqueous sodium chloride are
1) HCl, Cl2, O2 2) NaOH, Cl2, O2
2.303RT
4) 3) NaOH, H2, O2 4) NaOH, Cl2, H2
E ocell × nF 29. E° value for A |A is -2.93V, B+|B is 0.80 V,
+

22. For the cell reaction, Kc is 1010, C2+|C is 0.69 V, D2+|D is -2.37 V. The correct
Cu(s) + 2Ag+(aq) → Cu2+(aq) + 2Ag(s) increasing order of reducing power of the
metals A, B, C & D is
Find E°cell
1) A < B < C < D 2) B < C < D < A
1) 0.295 V 2) 0.59 V
3) B < C < A < D 4) B < A < C < D
3) 0.0591 V 4) 0.0295 V 30. For the reaction
23. Calculate the standard free energy change for 2N2O5(g) → 4NO2(g) + O2(g)
the cell reaction in which number of electrons The ratio of the rate of disappearance of N2O5
involved is two and E°cell is 1.1V [1F ~ 96500 to the rate of appearance of NO2 is given as
coulombs] 3
1) 2) 1
1) -212.3 kJ 2) +212.3 kJ 4
3) -96.5 kJ 4) -193.0 kJ 1 1
3) 4)
24. The conductivity of electrolyte solution 2 4
depends on 31. Find the initial rate for the reaction.
1) nature of the electrolyte 2A + B → A2B, where R = k[A][B]2 and
2) concentration of the electrolyte k = 2 x 10-6 mol-2 L2 sec-1,
3) the nature and viscosity of solvent [A] = 0.1 mol L-1 ; [B] = 0.1 mol L-1
1) 2 x 10-3 2) 1 x 10-9
4) all of the above
3) 0.5 x 10-9 4) 2 x 10-9
 4 Test ID : 623
32. A reaction is first order with respect to A and 37. For a reaction, activation energy Ea = 0 and
second order with respect to B. How is the rate the rate constant at 200K is 1.6 x 106s-1. The
effected when the concentrations of both A rate constant at 400 K will be [Given that gas
and B are doubled? constant, R = 8.314 J K-1 mol-1]
1) Rate decreased by two times 1) 3.2 x 104 s-1 2) 1.6 x 106 s-1
2) Rate increased by eight times 3) 1.6 x 103 s-1 4) 3.2 x 106 s-1
3) Rate increased by four times 38. For 99.9% decomposition of a first order
4) Rate decreased by four times reaction is 3 hours. What is the half life
33. Identify the correct statements. period?
a) Order is a experimental quantity 1) 30 mins 2) 1 hr.
b) For complex reactions, slowest step is the 1
3) 18 mins 4) hr
rate determining step. 2
c) For complex reactions molecularity has lot 39. The rate constant for the decomposition of
of meaning hydrocarbon is 4.5 x 1011 e-28000/T sec-1. The
d) Unit of rate of reaction is sec-1 pre exponential factor is
1) a & d only 2) c & d only 1) -28000 J 2) e-28000/T
3) b, c & d only 4) a & b only 3) 4.5 x 1011 sec-1 4) log 4.5 x 1011
34. Incorrect match is 40. The correct statements about adsorption is/are
1) NH4NO2 → N2 + 2H2O : Unimolecular a) ∆H of adsorption is always negative
reaction b) ∆S of adsorption is positive
2) 2HI → H2 + I2 : Bimolecular reaction c) There is always a decrease in residual force
3) 2NO + O2 → 2NO2 : Trimolecular reaction during adsorption
4) Reactions with molecularity three or more 1) a & b only 2) a only
: Usually very familiar 3) a & c only 4) a, b & c
T3K
35. In the graph,
x T2K
m

41.
T1K

P
The correct order about temperature, T1, T2
and T3 is
The intercept and slope are respectively
1) T1 > T2 > T3 2) T3 > T2 > T1
1) ln[R0] & -k 2) ln[R0] & k
3) T2 > T1 > T3 4) T1 > T3 > T2
1
3) ln[R0] & 4) ln[R] & k 42. Which is wrong match ?
k
1) Adsorption theory – Heterogeneous
36. t1/2 for sucrose decomposition into glucose and catalysis
fructose is 3 hrs. What percentage of sample
2) Ostwald’s process – Ammonia to Nitrogen
left after 9 hours?
3) Haber’s process – Ammonia synthesis
1) 75% 2) 25%
4) Hydrolysis of methyl acetate by using acid
3) 87.5% 4) 12.5%
– Homogeneous catalysis
 5 Test ID : 623
43. Assertion (A) : Brownian movement has
some cause for stability of sols.
Reason (R) : Brownian movement has a 3)
stirring effect and has continuous zig-zag
movement. Br
1) Both (A) and (R) are correct (R) is correct CH3
reason for (A) 4)
2) Both (A) and (R) are correct (R) is not
correct explanation of (A) CH CH2 CH3
3) (A) is correct (R) is wrong CH3
4) (A) is wrong (R) is correct 48. The order of reactivity of alcohols with a
44.
+
For coagulating AgI/Ag sol, the most given halo acid is
effective ion among the following : 1) n-butyl alcohol > tert.butyl alcohol >
Al3+, SO42-, PO43-, Ba2+, Na+, Cl- sec. butyl alcohol
1) SO42- 2) PO43- 2) tert.butyl alcohol > sec.butyl alcohol >
n-butyl alcohol
3) Al3+ 4) Ba2+
3) sec.butyl alcohol > tert.butyl alcohol >
45. Which set represents liquid aerosol?
n-butyl alcohol
1) Pumice stone, Foam rubber, Butter, Milk
4) tert.butyl alcohol > n-butyl alcohol >
2) Milk, Hair cream, Cheese, Fog sec.butyl alcohol
3) Fog, Mist, Cloud, Sprays 49. Which is/are incorrect statement about
4) Froth, Cream, Paints, Dust addition of bromine in CCl4 to an alkene?
46. Isobutyl chloride is 1) Addition of bromine to alkene resulting in
1) Primary halide discharge of reddish brown colour
2) Tertiary halide 2) It is a method to detect unsaturation
3) Secondary halide 3) The product is vic-dibromide
4) Quaternary halide 4) Vicinal dibromide is brown in colour
47. Correct structure of 1-Bromo-4-sec.butyl-2-
methylbenzene
50.

1) What is X?

Br
CH3 1) 2)
2)

H3C C CH3
CH3 3) 4)
 6 Test ID : 623
51. CH3CH=C(CH3)2 + HBr → X(major) ; X is 57. Choose the correct statements about alcohols.
1) CH3CH2CH2CH2CH2Br 1) The high boiling point of alcohols is mainly
2) CH3CH2C(CH3)2Br due to presence of intermolecular hydrogen
3) CH3CHBrCH(CH3)2 bonding
4) (CH3)2CHCH2CH2Br 2) Alcohols are neutralized by NaOH.
52. Predict the major product that would be 3) The acidic nature of alcohols order is
formed by dehydrohalogenation of 3° > 2° > 1°
2,2,3-trimethyl-3-bromopentane with sodium 4) Both (1) & (2)
ethoxide
58. Assertion (A) : C2H5O− + HOH → C2H5OH
1) 3, 4, 4-Trimethyl pent-2-ene
+ OH−
2) 3, 3, 4-Trimethyl pent-1-ene
3) 2-Methyl hept-1-ene Reason (R) : Ethanol is weak acidic than water
4) 3, 3-Dimethyl hex-1-ene 1) Both (A) and (R) are correct (R) is correct
dry ether explanation of (A)
53. X + 2Na → Diphenyl. Identify X.
1) Phenol 2) Benzyl chloride 2) Both (A) and (R) are correct (R) is not
3) Chlorobenzene 4) Benzoic acid correct explanation of (A)
54. IUPAC name of p-cresol is 3) (A) is correct (R) is wrong
1) 2-Methylphenol 4) (A) is wrong (R) is correct
X
2) 3-Methylbenzoic acid 59. RCH2OH  → RCOOH
3) 4-Methylphenol Y
RCH2OH  → RCHO
4) 4-Hydroxyphenol X and Y are respectively
55. Give IUPAC name of product obtained from
1) H2/Ni, anhyd. CrO3
reaction of propanone with ethyl magnesium
2) K2Cr2O7/H+, LiAlH4
bromide followed by hydrolysis
1) 2-Methyl-2-propanol 3) LiAlH4, PCC
2) 2-Methyl-2-butanol 4) K2Cr2O7/H+, anhyd. CrO3
3) 2, 2-Dimethyl-1-propanol 60. Which is major product obtained when
4) 2-Pentanol dinitration of 3-methyl phenol?
O OH OH
CH2COOCH3 NO2 CH3
56. NaBH4 1) 2)
P ; P is
CH3 NO2
NO2 NO2
1) 2)

O OH
3) 4)
CH2CH2CH3 CH2COCH3
3) 4)
O
 7 Test ID : 623
61. Assertion (A) : 1) Both (A) and (R) are correct (R) is correct
C2H5ONa+ (CH3)3CCl → tert.butyl ethyl ether explanation of (A)
(major) 2) Both (A) and (R) are correct (R) is not
Reason (R) : 3° alkyl halides prefer to correct explanation of (A)
undergo elimination in presence of alkoxides 3) (A) is correct (R) is wrong
over substitution. 4) (A) is wrong (R) is correct
1) Both (A) and (R) are correct (R) is correct 66. Toluene converted to benzaldehyde using
explanation of (A) chromyl chloride is called
2) Both (A) and (R) are correct (R) is not 1) Stephen reaction
correct explanation of (A) 2) Gattermann-Koch reaction
3) (A) is correct (R) is wrong 3) Etard reaction
4) (A) is wrong (R) is correct 4) Friedel-Craft’s reaction
62. 3-methyl butan-2-ol is treated with HBr, the
major product formed is
1) 67.

2) CH3CH2CH2CH2CH2Br A & B are respectively

1) Benzaldehyde, Benzoic acid
3) 2) Benzoic acid, Benzene
3) Benzoic acid, Sodium benzoate
4) 4) Benzaldehyde, Benzyl alcohol
O3 /H 2 O 2
68. Cyclohexene  → A ; A is
63. About the hybridization of carbon in carbonyl 1) Cyclohexane 2) Benzoic acid
group, the correct statement/s is/are 3) Butanoic acid 4) Adipic acid
1) It is sp2 hybridised 69. Order of reactivity of following compounds
2) The bond angle is approximately 120° towards nucleophilic addition is
3) The π bond is formed between pure CHO
p-orbital of carbon and pure p-orbital of
oxygen a) b)
4) All of the above
64. The alkyne which gives acetaldehyde with
addition of water in the presence of H2SO4 and
HgSO4 is
1) Propyne 2) 2-butyne
c) d)
3) 1-butyne 4) Ethyne
65. Assertion (A) : Ethane nitrile converted into
ethanal using DIBAL-H.
Reason (R) : DIBAL-H is Diisobutylaluminium 1) b > a > c > d 2) a > d > c > b
hydride. 3) a > d > b > c 4) a > b > d > c
 8 Test ID : 623
70. Acetal is produced by reacting alcohol in the 3) order of pKb
presence of dry HCl with C6H5NH2 > NH3 > C2H5NH2
1) Acetophenone 2) Diethyl ether 4) order of boiling point
3) Acetaldehyde 4) Phenol
(CH3)2NH > C2H5NH2 > C2H5OH
i) O3
71. X 
→ 2
ii) Zn /H 2 O 77. Which of the following property of glucose
cannot be explained by the open chain
What is X?
structure?
1) 1) It forms pentaacetate with acetic anhydride
2) It forms n-hexane with HI
2) 3) The penta acetate of glucose does not react
with hydroxylamine
3) 4) Glucose reacts with hydroxylamine to
form an oxime
4) 78. What are expected products of hydrolysis of
lactose?
72. During ammonolysis of alkyl halides, which
1) β-D-galactose and β-D-glucose
is/are correct statements?
1) It is gives mixture of amines 2) 2 units of α-D (+) glucose
2) Reactivity order is RI > RBr > RCl 3) α-D-glucose and β-D-fructose
3) This reaction is a nucleophilic 4) 2 units of β-D-glucose
substitution reaction
79. Which of the following is a major function of
4) All the above
nucleic acids?
73. Incorrect match.
1) Primary amine – More hydrogen bonding 1) Structural support in both plants and
2) Diethylamine – Secondary amine animals
3) Sec.butyl amine – Secondary amine 2) Storage and transfer of genetic information
4) All the above 3) Catalysis of virtually all biological
74. Most basic compound among the following is reactions
1) Benzyl amine 2) Aniline 4) Both (1) and (3)
3) p-nitro aniline 4) Acetanilide 80. Which of the following set represents non-
75. Which of the following can give carbylamine essential amino acids?
reaction?
1) Proline, Histidine, Glutamine, Valine
1) Aniline 2) N-methylaniline
3) N,N-dimethylaniline 4) Dimethylamine 2) Glycine, Alanine, Proline, Serine
76. Which is incorrect about given property 3) Serine, Cysteine, Lysine, Isoleucine
against it? 4) Argenine, Methionine, Alanine, Aspartic
1) basic strength in gas phase acid
(C2H5)3N > (C2H5)2NH > C2H5NH2 > NH3 81. Convulsions disease is due to deficiency of
2) order of solubility in water 1) Vitamin A 2) Vitamin C
C2H5OH > C2H5NH2 > (CH3)2NH
3) Vitamin B6 4) Vitamin D
 9 Test ID : 623
82. The type of bond that is most important in 88. Incorrect match.
maintaining secondary structure of a protein is 1) SO2 - Antioxidant for wine and beer
1) vander waal’s forces 2) Liquid dish wash detergents - Non-ionic type
2) disulphide linkages
3) Aspartame - stable at cooking temperature
3) dative bonds
4) Sodium benzoate - Food preservative
4) hydrogen bonding within back bone
89. Set which showing bactericidal antibiotics
83. Assertion (A) : Hydrolysis of proteins yield
1) Pencillin, Aminoglycosides, Ofloxacin
α-amino acids.
Reason (R) : Glycine is optically inactive 2) Pencillin, Erythromycin, Tetracycline
1) Both (A) and (R) are correct (R) is correct 3) Pencillin, Chloramphenicol, Ofloxacin
explanation of (A) 4) Erythromycin, Tetracyclin, Chloramphenicol
2) Both (A) and (R) are correct (R) is not 90. Which of the following is a component of
correct explanation of (A) dettol?
3) (A) is correct (R) is wrong 1) Bithional 2) Glycerol
4) (A) is wrong (R) is correct 3) Chloroethanol 4) Terpineol
84. Correct statements about low density
91. Which is the incorrect statement about
polythene is
crystalline solid?
1) it is a linear chain polymer
1) Melt at a sharp and characteristic
2) it is obtained through free radical addition
temperature
3) Zeigler-Natta catalyst is used in its preparation
2) Isotropic in nature
4) it is a co-polymer
3) True solids
85. Write the names of monomers of
Nylon-2-Nylon-6. 4) Long range order of constituent particles
1) adipic acid, hexa methylene diamine 92. Which one of the following is covalent
2) glycol and terephthalic acid crystalline solid, based on the nature of
3) glycine and amino caproic acid intermolecular forces operating in them?
4) 3-hydroxybutanoic acid and 3-hydroxy 1) Potassium sulphate 2) Tin
pentanoic acid 3) Silicon carbide 4) Benzene
86. Identify the set which are elastomers. 93. The edge lengths and axial angles respectively
1) Terylene, Bakelite, Buna-S, Nylon-6,6 for the rhombic sulphur crystal are
2) Buna-S, Buna-N, Neoprene, Polyisoprene 1) a = b ≠ c, α = β = γ = 90°
3) Polythene, Polypropylene, PAN,
2) a ≠ b ≠ c, α = β = γ = 90°
Nylon-2-Nylon-6
3) a = b ≠ c, α = β = 90, γ = 120°
4) Urea formaldehyde, Novalac, Glyptal,
Polystyrene 4) a = b = c, α = β = γ ≠ 90°
87. Monomer used to prepare orlon is 94. Hardness of water is estimated by
1) CH2=CHCN 2) CH2=CHCl 1) DMG 2) Na2EDTA
3) CH2=CCl2 4) CH2=CHF 3) Ca(OH)2 4) Na2CO3
 10 Test ID : 623
95. Match the crystal system in column-I with the
packing efficiency given in column-II.
Column-I Column-II
π
A) SC i) x 100
3 2
3π
B) BCC ii) x 100 1) Function of the nature of the gas
8
π 2) Increases with increase of temperature
C) CCP iii) x 100
6 3) Inversely proportional to solubility
1) A-i, B-ii, C-iii 2) A-iii, B-i, C-ii 4) Independent on temperature
3) A-i, B-iii, C-i 4) A-iii, B-ii, C-i 101. Theprinciple behind the purification of metals
96. An element has a bcc structure with a cell by zone refining is
edge of 200pm. The density of the element is 1) difference in adsorption power
7.2 g/cm3. How many atoms are present in 2) difference between boiling points of pure
200g of the element? and impure metals
1) 2.42 x 1024 2) 1.21 x 1024 3) the impurities are more soluble in the melt
24 23 than in the solid state of the metal
3) 6.94 x 10 4) 2.42 x 10
97. If AgCl is dopped with 10-3 mol % of CdCl2, 4) the impurities are less soluble in the melt
the concentration of cation vacancies will than the solid state of the metal
1) 6.02 x 1017 mol-1 2) 6.02 x 1020 mol-1 102. Brass,bronze and coinage alloys are made
3) 6.02 x 1018 mol-1 4) 12.04x 1018 mol-1 from copper mixing with
98. When crystals of NaCl are heated in an 1) Zinc, Iron and Nickel respectively
atmosphere of sodium vapour, which impart 2) Tin, Zinc and Nickel respectively
yellow colour to the crystals of NaCl. This is 3) Zinc, Tin and Nickel respectively
due to 4) Zinc, Chromium and Silver respectively
1) metal deficiency defect 103. Which is not carbonate ore(s)?
2) the presence of extra anions 1) Siderite 2) Magnetite
3) F-centres 3) Calamine 4) Both (1) & (3)
4) impurity defect 104. Which is(are) correct statement(s) about
-3
99. A litre of sea water contains about 6 x 10 g of leaching of alumina from bauxite?
dissolved oxygen (O2). The amount of 1) Bauxite is the principal ore of aluminium
dissolved oxygen in the sea water in terms of 2) The process is also called digestion
µg mL-1 is 3) Al2O3 is extracted out as sodium aluminate
1) 6 2) 5.8 x 101 4) All the above
2 3
3) 6 x 10 4) 5.8 x 10 105. Themetal (or) elements used to reduce ZnO to
100. From the graph, incorrect statement about the Zn at 1273K from the Ellingham diagram
slope is given below is/are
 11 Test ID : 623
1) Hydrogen bonding in H2O is strong
2) All the hydrides except water possess
reducing properties
3) All elements except oxygen form hexa
chlorides and hexa bromides
4) Both (1) and (2)
110. Whichof the following element doesn’t react
with O2 directly?
1) Fe 2) C
3) Mg 4) Au
111. About brown ring test the false statement is
1) Mg, Al & Cu 2) Fe, Mg & Al
1) It is test for NO3− ion
3) Mg, Al & C 4) Mg, Al & CO
2) Fe2+ is used as reducing agent
106. Which is incorrect statement about oxidation
state of group 15 elements? 3) The brown ring complex formula is
1) In case of nitrogen all oxidation states [Fe(H2O)5NO]2+
from +1 to +4 tend to undergo 4) The charge on NO in brown ring complex is
disproportionation in acid solution zero
2) In case of phosphorous nearly all 112. Regardingstructure of sulphur which is
intermediate oxidation state disproportionate correct match?
into +5 and -3 in alkali and acid i) S8 form a) Paramagnetic form
3) +5 oxidation state of arsenic, antimony
ii) About 1000 K b) Chair form
and bismuth becomes stable with respect
to disproportionation iii) S6 form c) Puckered ring structure
4) Nitrogen restricted to a maximum iv) At 369 K d) both rhombic and
covalency of 4 monoclinic sulphurs are
107. Regarding oxides of group 15 elements of the stable
type E2O3, the increasing order of acidic 1) i-a, ii-b, iii-c, iv-d
nature 2) i-c, ii-d, iii-b, iv-a
1) N2O3 < P2O3 < As2O3 < Sb2O3 < Bi2O3 3) i-c, ii-a, iii-b, iv-d
2) Bi2O3 < Sb2O3 < As2O3 < P2O3 < N2O3
4) i-c, ii-a, iii-d, iv-b
3) Bi2O3 < N2O3 < Sb2O3 < As2O3 < P2O3
113. Sulphuricacid is mainly used in all chemical
4) P2O3 < As2O3 < Sb2O3 < N2O3 < Bi2O3
2+ reactions due to
108. Ammonia reacts with solution of Cu gives
deep blue complex of the formula a) ability as a reducing agent
1) [Cu(NH3)2]2+ 2) [Cu(NH3)4]+ b) high volatility
3) [Cu(NH3)4]2+ 4) [Cu(NH3)4]2- c) strong acidic character
109. The consequences of anomalous behaviour of d) strong affinity for water
oxygen compare to other elements of same 1) a & b only 2) a & c only
group is/are 3) c & d only 4) a, b, c & d
 12 Test ID : 623
114. For monovalent metal ‘M’ decreasing the Reason (R) : The ability of fluorine to
ionic character of halides in the order of stabilize CoF3 is due to higher lattice enthalpy.
1) MF > MCl > MBr > MI 1) Both (A) and (R) are correct, (R) is correct
2) MI > MBr > MCl > MF reason for (A)
3) MCl > MI > MF > MBr 2) Both (A) and (R) are correct but (R) is not
4) MF > MCl > MI > MBr correct explanation of (A)
115. Which is incorrect equation? 3) (A) is correct (R) is wrong
1) XeF2 + PF5 → [XeF]−[PF6]+ 4) (A) is wrong (R) is correct
2) XeF6 + 3H2O → XeO3 + 6HF 121. Among the following species identify only
reducing agents Co3+, Ti2+, V2+, Cr2+, Mn+7,
3) XeF6 + H2O → XeOF4 + 2HF
Mn+3, Cr+6
4) 2XeF2(s)+ 2H2O(l) → 2Xe(g) + 4HF(aq) + O2(g)
1) Mn3+, Ti2+, Cr+6
116. Which is incorrect match about shape?
2) Mn+3, Mn+7, Co3+
1) IF5 : Square pyramidal
3) Ti2+, Cr6+, Co3+
2) ClF3 : Bent T shaped
4) Ti2+, V2+, Cr2+
3) XeF4 : Square planar
122. Pick out the colourless ions (set) from the
4) XeF2 : Pyramidal
following ions.
117. General electronic configuration of f-block
Ti3+, V3+, Sc3+, Zn2+, Fe3+, Co3+, Ti4+
elements is
1) Ti3+, Sc3+, Fe3+
1) nf1-14 nd0-1ns2
2) Sc3+, Zn2+, Ti4+
2) (n-2)f1-14(n-1)d2ns2
3) Fe3+, Ti4+, Co3+
3) (n-2)f1-14(n-1)d0-1ns2
4) Ti3+, Sc3+, Zn2+
4) (n-2)f1-14(n-1)d0-1ns0
123. About Na2Cr2O7 and K2Cr2O7, the incorrect
118. Calculate the magnetic moment of a divalent
statement is
ion in aqueous solution if its atomic number is
1) both are strong oxidizing agents
25.
2) both are equally soluble in water
1) 1.73 BM 2) 5.92 BM
3) sodium dichromate is more soluble than
3) 4.90 BM 4) 3.87 BM
potassium dichromate
119. Incorrect match about oxidation state of
4) potassium dichromate converted into
transition elements
potassium chromate in basic medium
1) Scandium → does not show variable
124. The consequence of lanthanoid contraction
oxidation state
makes
2) Middle of each series → more number of
1) both Zr and Hf have almost same radii
oxidation states
2) they occur together in nature
3) Highest oxidation state of 3d-series
3) difficult to separate them
elements → +8
4) all of the above
4) Ni(CO)4 → oxidation state of Ni is zero 125. Number of bridged CO ligands in [Co2(CO)8]
120. Assertion (A) : Fluorine is a powerful and [Mn2(CO)10] respectively
reducing agent. 1) 2, 0 2) 0, 2
3) 2, 1 4) 2, 2
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