Freundlich

Cu iniciales(mCu finales o equilibrio (mg/Cu inicial (mmCu final (mmol/l) qe (mmol/grapa)

5.12 0.21 0.08057916 0.003305 0.0077274158
10 0.49 0.15738118 0.00771168 0.01496695
20 1.91 0.31476235 0.0300598 0.028470255
29.98 4.12 0.47182877 0.06484105 0.0406987724
40.1 7 >>>>>>>>>> 0.63109852 0.11016682>>>>>>>>>>> 0.0520931697 >>>>>>>>>>
50.02 9.3 0.78722065 0.14636449 0.0640856154
60.3 14.56 0.9490085 0.22914699 0.0719861505
70.25 20.6 1.10560277 0.32420523 0.0781397545
81.46 30.98 1.28202707 0.48756689 0.0794460183
91.46 39.5 1.43940825 0.62165565 0.0817752597
100 48 1.57381177 0.75542965 0.0818382121

Cu-rapa
mismas condiciones que cinetica
0

EXPERIMENTO EN BATCH O DISCONTINUO

M = 63,54 g/mol
-0.5
0,1 g rapa de uva
10mL disolución = 0,01 L
log(qe)

pH=6 -1
f(x) = 0.431992968033595 x − 0.925424127057341
R² = 0.955884509585392

-1.5

-2

-2.5
-2.5 -2 -1.5 -1

log (Ce)

A partir de la regresión…y = 0,432x - 0,9254 logKf 1/n

R² = 0,95588 -0.9254 0.432
kf n
0.12
0.11874081 2.31481481

0.1

0.08
/ g rapa)
 0.1

0.08

qe (mmol Cu / g rapa)
qe (mmol/graCu final (mmoqteorica (mmol/g rapa)
0.00772742 0.003305 0.01006659
0.06
0.01496695 0.00771168 0.01451605
0.02847025 0.0300598 0.02612703
0.04069877 0.06484105 0.03641826
0.05209317 0.11016682 0.04578951 0.04
0.06408562 0.14636449 0.05176882
0.07198615 0.22914699 0.06283033
0.07813975 0.32420523 0.07299183
0.02
0.07944602 0.48756689 0.08706243
0.08177526 0.62165565 0.09669712
0.08183821 0.75542965 0.1051913
0
0 0.1

LANGMUIR

Cu iniciales(mCu finales o equilibrio (mg/Cu inicial (mmCu final (mmol/l) qe (mmol/grapCe/qe

5.12 0.21 0.08057916 0.003305 0.0077274158 0.42769857
10 0.49 0.15738118 0.00771168 0.01496695 0.51524711
20 1.91 0.31476235 0.0300598 0.028470255 1.05583195
29.98 4.12 0.47182877 0.06484105 0.0406987724 1.59319412
40.1 7 0.63109852 0.11016682 0.0520931697 2.11480363
50.02 9.3 0.78722065 0.14636449 0.0640856154 2.28388998
60.3 14.56 0.9490085 0.22914699 0.0719861505 3.18320944
70.25 20.6 1.10560277 0.32420523 0.0781397545 4.1490433
81.46 30.98 1.28202707 0.48756689 0.0794460183 6.13708399
91.46 39.5 1.43940825 0.62165565 0.0817752597 7.60200154
100 48 1.57381177 0.75542965 0.0818382121 9.23076923

10
9
f(x) = 11.32243787853 x + 0.61920578075677
8 R² = 0.997233977077283
7
Ce/qe (g rapa / L)

6
5
4
3
2
1
 7

Ce/qe (g rapa / L)
6
5
4
3
2
1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Ce (mmol Cu / g rapa)

Por regresión lineal: y = 11,322x + 0,6192 1/qmax 11.322 A partir de la recta, se obtienen los distinto
R² = 0,99723 qmax 0.08832362
1/(b*qmax) 0.6192
b 18.2848837

A partir de la ecuación de Langmuir obtenemos la q teórica…

qe (mmol/graCu final (mmoqt(mmol/grapa)
0.00772742 0.00330501 0.00503337
0.01496695 0.00771168 0.01091515
0.02847026 0.03005981 0.0313274 0.09
0.04069877 0.06484105 0.04791221 0.08
0.05209317 0.11016682 0.05902294
0.06408562 0.1463645 0.0642982 0.07
qe (mmol Cu / g rapa)

0.07198615 0.22914699 0.07130534 0.06

0.07813975 0.32420523 0.07557493 0.05
0.07944602 0.48756689 0.07941563
0.04 Experimen
0.08177526 0.62165565 0.08118168
0.08183821 0.75542965 0.08236102 0.03 Langmuir
0.02
0.01
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Ce (mmol Cu / g rapa)

Cu inicial (mmol/l) RL
0.08057916 0.40430494 0.45
0.15738118 0.25788506
0.4
0.31476235 0.14802988
0.47182877 0.10387091 0.35
0.63109852 0.0797476
0.3
0.78722065 0.06495937
0.9490085 0.05448846 0.25
1.10560277 0.04713464
RL

1.28202707 0.04091366 0.2

1.43940825 0.03660401 0.15
1.57381177 0.03358301
0.1

0.05

0
0 0.2 0.4 0.6 0.8 1 1.2
Ci (mmol Cu / L)
 0.1

0.05

0
0 0.2 0.4 0.6 0.8 1 1.2
Ci (mmol Cu / L)
 log qe log ce final ce es la concentración de cobre en equiilibrio = c cobre final
-2.11196572 -2.48082792
-1.82486669 -2.11285113
-1.54560864 -1.52201384
-1.39041869 -1.18814999
-1.28321922 -0.95794917
-1.19323944 -0.83456426
-1.14275105 -0.63988584
-1.10712796 -0.48917999
-1.09992786 -0.3119658
-1.08737807 -0.20645011
-1.08704387 -0.12180597
x − 0.925424127057341
-1.5 -1 -0.5
og (Ce)
0.12
0.1
0.08
/ g rapa)
EXPERIMENTOS EN BATCH (DISCONTINUO)
0,1 g deraspo de uva en contacto con 10 mL de disoluciones de metal de distintas
Cu i(mg/l) Cu f (mg/l) Cu f (mols/l) qe (mol/g) log qe
5.12 0.21 3.30448E-06 7.7262E-06 -5.11203406
10 0.49 7.71046E-06 1.49646E-05 -4.82493504
20 1.91 3.00551E-05 2.84658E-05 -4.54567699
29.98 4.12 6.48308E-05 4.06924E-05 -4.39048703
40.1 7 0.00011015 5.2085E-05 -4.28328756
50.02 9.3 0.00014634 6.40755E-05 -4.19330779
60.3 14.56 0.00022911 7.19748E-05 -4.14281939
70.25 20.6 0.00032415 7.81275E-05 -4.1071963
81.46 30.98 0.00048749 7.94335E-05 -4.09999621
91.46 39.5 0.00062156 8.17624E-05 -4.08744641
100 48 0.00075531 8.18253E-05 -4.08711221
0
 0.1

0.08
qe (mmol Cu / g rapa)

0.06
Experimental
Freundlich
Langmuir
0.04

0.02

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Ce (mmol Cu / L)
 0.7 0.8

ta, se obtienen los distintos parámetros para Langmuir

Experimental
Langmuir

0.7 0.8

0.8 1 1.2 1.4 1.6 1.8

Ci (mmol Cu / L)
 0.8 1 1.2 1.4 1.6 1.8
Ci (mmol Cu / L)
iones de metal de distintas concentraciones
log Cu f 1/qe 1/Cu f Qfreun qlang
-5.48089626 129429.735 302619.048 1.00636E-05 7.60922E-06
-5.11291947 66824.3954 129693.878 1.45117E-05 1.55045E-05
-4.52208219 35129.906 33272.2513 2.61192E-05 3.67886E-05
-4.18821834 24574.6326 15424.7573 3.64074E-05 4.93209E-05
-3.95801751 19199.3958 9078.57143 4.57759E-05 5.61186E-05
-3.83463261 15606.5815 6833.33333 5.17534E-05 5.89953E-05
-3.63995418 13893.7473 4364.6978 6.28116E-05 6.2519E-05
-3.48924833 12799.5972 3084.95146 7.29701E-05 6.45166E-05
-3.31203414 12589.1442 2051.32343 8.70365E-05 6.62258E-05
-3.20651846 12230.562 1608.86076 9.66683E-05 6.69854E-05
-3.12187432 12221.1538 1323.95833 0.00010516 6.74838E-05
Pb-Rapa

mismas ocndiciones que con cinetica o,1 g de rapa, 15 mL

C iniciales (mg /L) C finales (mg /L)
33.26 0.11
63.60 0.21
105.20 0.52
155.86 0.829
173.80 1.05
251.77 3.11
265.87 5.01
305.30 10.42
334.13 25.90
353.50 41.5
3.63 50.8
377.85 62.2
Cd Oliva 15 mL 0,2 g mismas condiciones que cinetica

Cinicial (mg/L) Cfinal (mg/l)

31.07 10.23
43.88 22.52
64.34 36.53
89.76 57.34
128.09 91.28
154.21 110.4
186.55 144.53
250.26 203.87
416.16 354.44
570.23 500.07
633.9 550.33