ATOMIC STRUCTURE AND GASEOUS STATE

F.M – 228 TIME – 3 HRS

ONLY ONE CORRECT OPTION : (+3, -1) Total – 20  3 = 60

1. Consider the following (P-T) graph for a fixed mass of gas:

3
P
4
2
1

Correct P-V graph is :

4
P 1 2 P
4
(A) (B)
3 3
1 2
V V
3
P P 1 2
(C) (D) 4
4 3
2 1
V V

2. Which of the following graphs is inconsistent with ideal gas behavior? (Assume n = constant)

T2 > T1
T2 > T1
P P T2
T1 T1
(A) T2 (B)

V V

P1
T2
P T1
V P2
(C) (D) T2 > T1
P2 > P1

T(K) 1
v

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3. Consider the given graphs:
Graph is plotted for 1 mole of gas at 400K. Find slope of the curve .(Take
: R = 0.08 atm l mole-1 K-1) P2
(A) (32)2 (B) (16)2
(C) (8)2 (D) (4)2


2
1
v

4. Z vs P graph is plotted for 1 mole of a hypothetical gas.

z
Volume of gas at this point(x) is : (x) 200 K
2
(Take R = 0.08 atm l K-1 mole-1)
(A) 0.01 litre (B) 0.09 litre 1
(C) 0.064 litre (D) 0.64 litre
500

P(atm)

5. In the given isobaric process shown by graph between T & V .

T B
Identify the correct statement.
(A) moles decreases throughout. C
(B) moles first increases and then decreases.
A
(C) moles first decreases and then increases
(0,0)
(D) moles cannot be predicates from graph. V

6. For one mole of a vander Waal’s gas when b = 0 and T = 300K, the 24.6

PV vs 1 plot is shown below. The value of vander Waal’s constant

(PV)23.6
(atm l mol-1)
v
a (atm l2 mole-2) is:
21.6
(A) 1.0 (B) 4.5
20.1
(C) 1.5 (D) 3.0
2 3
0 1 (l1mole)
v

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7. Gas A (1 mole) dissociates in a closed rigid container of volume 0.16 litre as per following reactions:
2A(g)  3B(g) + 2C (g) . If degree of dissociation of A is 0.4 and remains constant in entire range of
temperature, then the correct P vs T graph is :
(Given R = 0.08 lit atm K-1 mole-1)

p p
(atm) (atm)
(A) (B)

 = tan-1(0.75)  = tan-1(0.8)

T(K) T(K)

p p
(atm) (atm)
(C) (D)

 = tan-1(1.1)  = tan-1(0.4)

T(K) T(K)

8. Cl2O7 gas decomposes as Cl2O7  Cl2 + O2 (unbalanced equation) . A partially decomposed gaseous
mixture is allowed to effuse through a pin-hole and the gas coming out initially was analyzed. The mole
fraction of the O2 was found to be 0.60. The degree of dissociation of Cl2O7 will be :
(A) 0.1 (B) 0.2 (C) 0.4 (D) 0.6

9. The third virial coefficient of a real gas is 2  10-2 (l mole-1)2. The value of vander Waal’s constant ‘b’ is :
(A) 0.1414 l mole-1 (B) 0.0707 l mole-1
(C) 0.2828 l mole-1 (D) None of these

10. The critical density of the gas CO2 is 0.44 g cm-3 at a certain temperature. If r is the radio of the molecule, r 3
in cm3 is approximately: (N is Avogadro’s number)

(A) 25 (B) 100 (C) 6.25 (D) 12.5

N N N N

11. A graph is plotted between uncertainty in portion and inverse of

uncertainty in wave length for an electron. We get a straight line passing x
through the origin. Calculate voltage through which electron is (on A0)
accelerated with :
(A) 150 V (B) 75 V   tan1  1 

(C) 37.5 V (D) 300 V
1 (in A 0 1 )


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12. For a H-like species if a area A, is of ground state orbit and area An is of nth orbit, then the plot of An vs n2
A1
looks like :

An An
(A) A1 (B) A1

n2 n2

An An
(C) A1 (D) A1

n2 n2

13. Which of the following plots of radical probability function 4r22 is incorrectly labeled ?

(2s) (2p)
4r22 4r22
(A) (B)

r r

(3s) (3p)
4r22 4r22
(C) (D)

r r

14. Two bulbs A and B are emitting monochromatic light of wavelength such that A can just ionic H atom and B
can just ionize He+ ions. If the power of A and B are 30 W and 40 W respectively, the ratio of number of
photons emitted per second by bulb A to bulb B is:

(A) 3 (B) 4 (C) 1 (D) 1

4 3

15. A hydrogen like species with atomic number Z is present in a higher excited state (n). This electron can make
transition to the first excited level by successively emitting two photons of energy 2.64 eV and 48.36 eV. This
electron can also make transition to third excited state by emitting three photons of energy 2.64 eV, 2.66eV
and 4.9 eV. Identify the hydrogen like species involved.
(A) He+ (B) Li+2 (C) Be+3 (D) B+4

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16. In an atom, two electrons move around the nucleus in circular orbits of radii R and 4R. The ratio of the time
taken by them to complete one revolution is:
(A) 1 : 4 (B) 4 : 1 (C) 1 : 8 (D) 8 : 1
17. Let v1 be the frequency of the series limit of the Lyman series, v 2 be the frequency of the first of the Lyman
series and v3 be the frequency of the series limit of Balmer series then

(A) v1 – v2 = v3 (B) v2 – v1 = v3 (C) v 3  1 (v 2  v1 ) (D) v1 + v2 = v3

2
18. An -particle has initial kinetic energy of 25 eV and it is accelerated through a potential difference of 150 volt.
If a proton has initial kinetic energy of 25 eV and it is accelerated through a potential difference of 25 volt,
then find the approximate ratio of the final wavelength associated with the proton and the -particle.
(A) 5 (B) 4 (C) 3 (D) 2
19. An orbital is found to contain total nodes = 3 and radial nodes = 1. Orbital angular momentum for the electron
present in this orbital will be:

(A) 0 (B) h 6 (C) h (D) h 6

2  2 4
20. Angular wave function of px orbital is : (Given  is angle from z-axis)
1/ 2 1/ 2 1/ 2 1/ 2
(A)  3  sin  sin  (B)  3  sin  cos  (C)  3  cos  (D)  15  sin  cos  cos 
 4   4   4   4 

One or more than one correct option (+4, -1. Total 20  4 = 80, +1 mark awarded from correct option in
complete answer, -1 mark if extra option attempted or wrong option attempted)

21. If critical temperature for the real gas is 500 k then from the
following graph:
Z
(A) Boyle’s temperature = 1687.5 K 400 K

(B) Vander Waal’s constant : a = 21.6 atm l2 mole-2

(C) Gas will show ideal behavior at high temperature and low  = tan-1(0.005)

pressure. z=1
P
(D) At Boyle’s temperature behavior of gas is always ideal.

22. For a vander Waal’s gas a = 4 atm l2 mole-2 and b = 0.02 k mole-1. Select the correct possible graph (s).
[Given R = 0.08 l atm K-1 mole-1].

z 1000K z 3000 K

1. 1.0
(A) (B)
0

P P

2500 K
z z

1.0 1.0
(C) (D)
2500K

P P

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23. Which of the following graph is parabolic for fixed mass of an ideal gas at constant temperature in closed
container?

(A) 1 vs P (B) P vs P (C) P vs V (D) P vs log V

v2 V V V

24. For an ideal gas, following observations is made as per Maxwell-Boltzman

distribution: dN
NdU

Choose the correct option(s):

(A) Urms  1.5  400ms1
400
(B) Uav  400 4 ms1 u(m/s)

(C) fraction of molecules moving between 400 to 401 m/s are more than
fraction of molecules moving between 452 to 453 ms-1.
(D) fraction of molecules moving between 400 to 401 ms -1 are equal with
fraction of molecules moving between 452 to 453 ms-1.

25. For the following process involving fixed moles of an ideal gas, select the
correct statement(s). (d = density of gas)
P
(A) TA > TB = TC (B) TA < TB = TC A

(C) dA  dB  dC (D) dA = dC < dB B

C
P

1
v

26. If the viral equation is written as : Z = 1 + A1P + A2P2 + …… for vander Waal’s equation then which of the
following will be true under limiting state of zero pressure ?

    A  
2
(A) Z  1 (B) A1  b  a  1 (C) A 2  b 2
(D) A 2  a 2b  a
1
RT RT RT (RT)3 RT

27. In which of the following case(s) is pressure of gas is less or equal to atmospheric pressure?

Gas Gas
19 cm Hg
(A) (B) 19 cm Hg

19 cm Hg
Gas
(C) (D)
Gas
19 cm Hg

28. When an equimolar mixture of two gases A and B [MA > MB] is allowed to effuse through a pin hole:
(A) B comes out at a faster rate.
(B) relative rate of effusion of A increases with time.
(C) rate of effusion of B will always be greater.
(D) initially, with equal molar ratio, rate of effusion of B is greater than rate of effusion of A.

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29. Select the correct option(s) by analyzing the following figure valve
(A) Pressure in container – I is 3 atm before opening the valve.
(B) Pressure after opening the valve is 3.57 atm container container
I II
(C) Moles of gas in each compartment are same after opening the valve.
300K 2mole H 400K 1mole H
2 2
(D) Pressure in each compartment are same after opening the valve.
16.42 litre 8.21 litre

30. If distance (vander Waal’s) between two molecules is r and intermolecular force varies inversely with r x such

that lim 1 , then which of the following equations may be applicable ?

x 
rx
(A) Z = 1 (B) Z < 1 (C) Z > 1 (D) P Vm = RT

31. Which of the following statement(s) is/are correct with respect to (r) (y-axis) vs (x-axis) graph for H-atom?
(A) For a 3-d orbital, the graph will not intersect the X-axis at any finite, non zero value.
(B) For a 4-s orbital, the graph will intersect exactly three distinct, non-zero value.
(C) For 1-s orbital, the sign of the (r) will not change at any radial distance.
(D) For 3-p orbital, the graph will intersect X-axis at two non-zero distinct points.

32. Choose the correct relations on the basis of Bohr’s theory

(A) velocity of electron  1 (B) Frequency of revolution  1

n n3
(C) Radius of orbit  n2 Z (D) Force on electron  1
n4
33. Choose the correct statements from the following:
(A) A node is a point in space where the wave function () has zero amplitude
(B) Total number of nodes in an orbital is equal to n-1.
(C) 2 represents the probability density of finding an electron.
(D) Total number of angular nodes in 2Px orbital is one.

34. The wave function of 3s and 3Pz orbitals are given by:
1/ 2 3/2
3 s  1  1   z  (6  6   2 )e  / 2
 
9 3  4   a0 
1/ 2 3/2
 3Pz  1  3   z  (4   ) e  / 2 cos 
   
9 16  4    a0 

where   2Zr ; where a0 = 1st Bohr radius ,

na0
Z = charge number of nucleus, r = distance from nucleus.
From these information’s , we can conclude.
(A) Total number of nodal surface is same for 3s and 3Pz orbitals
(B) The angular nodal surface of 3Pz orbitals occur at  = /2
(C) The radial nodal surface of 3s and 3Pz orbitals are at equal distance from nucleus.
(D) 3s electron have greater penetrating power into the nucleus compared to 3P z electron.

35. If electron of hydrogen atom is replaced by another particle of some charge but of double mass then:
(A) Radii of orbits will increase (B) Ionization energy will increase
(C) Velocity of new particle will be more (D) Energy gap between two levels will be doubled

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36. For two Bohr orbit n1 and n2 which follow the relationship n22  n12   21 and n2  n1   3 . If an electron

makes transition from n2 to n1 directly then:

(A) 3rd longest wave length of Balmer series is emitted.
(B) Longest frequency of Lyman series is emitted
(C) Longest frequency of Balmer series is emitted
(D) Only one spectral line is emitted.

37. Select the correct statements:

(A) Over a boundary surface, value of probability density ||2 is constant for an orbital.
(B) Probability of finding an electron is 100% on an orbital.
(C) Number of angular nodes are n – l – 1.
(D) For 1s orbital the probability density is maximum near the nucleus.

38. The wave function for 2s orbital is given as:

 r / 2 a0
  3/2
   1   1   2  r 
 4 2   a0   a0 e

Where a0 = 1st Bohr’s radius in H-atom = 0.529 A0

Identify the correct statement(s):
(A) Number of radial nodes = 3
(B) Probability density is independent of direction.
(C) Probability density of finding electron at nucleus is non zero.
(D) The radial node occur at a distance of 2a0 from nucleus.

39. Radiational wavelength () = 124 nm falls on a metallic surface. If threshold wavelength = 248 nm, then the
kinetic energy of the ejected photoelectron(s) can be:
(A) 1eV (B) 2eV (C) 3eV (D) 5eV

h 3
40. The orbital angular momentum of an electron is . Which of the following should not be the permissible

value of orbit angular momentum of this electron revolving in Bohr orbit ?

(A) h (B) h (C) 3  h (D) 2  h

2  2 

Comprehension type problems (+3, -1) (Total 8  3 = 24)

Passage – 1

Two bulbs X and Y of equal volumes are connected through a stop cock. Each bulb contained 9.6 g of O 2 gas at
0.4 atm pressure and 300K. The first bulb X is then heated to 500K keeping bulb Y at 300 K.

41. Final pressure in ‘X’ is:

(A) 0.2 atm (B) 0.3 atm (C) 0.5 atm (D) 0.75 atm

42. Final number of moles of O2 in vessel  would be:

(A) 0.225 (B) 0.275 (C) 0.375 (D) 0.425

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 Passage – 2

For a non ideal gas, the compressibility factor (Z) is defined as : Z  PVm . Compressibility of an unknown gas at
RT
600K and 1.0 at was found to be 1.2 . Also, this gas was found to effuse 1.58 times slower than the pure methane gas
under identical condition. [Take R = 0.0821 atm l K-1 mole-1]

43. Density of the gas in the above mentioned experimental condition is:
(A) 0.98g 1 (B) 0.68g 1 (C) 1.02g 1 (D) 1.47g 1

44. Molar volume of the gas in the given experimental condition is:
(A) 41.0 (B) 39.4 (C) 59.1 (D) 27.3

Passage – 3

A hydrogen like species is in a spherical symmetrical orbital S1 having 3 radial nodes. It gets de-excited to another
level S2 having no radial node. Energy at S2 orbital is 2.25 times energy of 1st Bohr orbit of hydrogen atom.

45. What is the orbital angular momentum quantum number of S2?

(A) 1 (B) 0 (C) 2 (D) h

2

46. What is the combined total number of nodes (radial + angular) in S1 and S2?
(A) 4 (B) 3 (C) 5 (D) 6

Passage – 4

From hydrogen gas discharge tube, light is emitted . Emitted light is used to emit electron from sodium metal of
 = 1.82 eV.

47. If the fastest photoelectron has KE = 0.73eV , the wavelength of incident radiation on the sodium metal is:
(A) 5627.63 A0 (B) 4862.74 A0 (C) 3384 A0 (D) 9872 A0

48. The transition in hydrogen atom takes place from:

(A) n1 = 4 to n2 = 1 (B) n1 = 4 to n2 = 3 (C) n1 = 3 to n2 = 1 (D) n1 = 4 to n2 = 2

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Matching type problems (+8, 0 +2 marks will be awarded for individually correct matching). (Total , 4  8 = 32)

49. The following graphs are plotted for an ideal gas taken from state A to state B and then to state C, maintaing
volume constant.

Column – I Column – II

B
C
P
(A) A (P) Moles first increases and then further increases.

C
(B) P2/T A B (Q) Moles first remains constant and then decreases.

A
T
(C) C (R) Moles first decreases and then remains constant.
B
P

C
PT A
(D) (S) Moles first decreases and then increases
B

T2

50. Match the following

Column – I Column – II

(A) At low pressure (P) Z  1  Pb

RT

Z  1 a
(B) At high pressure (Q)
VmRT

(C) At low density of gas (R) Gas is more compressible than ideal gas

(D) For H2 and He at 00C (S) Gas is less compressible than ideal gas.

51. Match the following

Column – I Column – II

(A) e- moving in 2nd orbit of He+ (P) Radius of orbit in which e- is moving = 0.529 A0
(B) e- moving in 3rd orbit of H atom (Q) Total energy of e- = -13.6  9 eV

Velocity of e  2.188  10 ms1

6
(C) e- moving in 1st orbit of Li+2 ion (R)
3

de Broglie wavelength of e  150 A 0

(D) e- moving in 2nd orbit of Be+3 ion (S)
13.6

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52. Match the following

Column – I Column – II

(A) Angular probability is independent of  and  (P) 5d

4r2R2
(B) (Q) 5p

(C) Two maximum in 4r2R2 vs r graph (R) 4s

r

(D) (S) 3p

Numerical Type Problems (4, 0) Total 8  4 = 32

53. Two moles of an ideal gas undergoes the process depicted below.

Given that  P   x  10  , then (y - x) = ____________

 T v

P(atm)
3

-273 27
t0(c)

54. Two gases A and B having molecular weights 60 and 45 respectively are enclosed in a vessel. The weight of
A is 0.5 g and that of B is 0.2g . The total pressure of the mixture is 750 mm. Calculate the partial pressure
(in mm) of gas A

55. 22.4 litre C2H6 gas at 00C and 1atm is burnt in excess of O2 gas. The products are passes through 5 litre of
2M KOH solution. The maximum moles of K2CO3 which may form in the solution is _____________.

56. If the mean free path is 10 cm at one bar pressure, then its value in cm at 5 bar pressure, if temperature is
kept constant will be __________.

57. Which state of Be+3 has the same orbit radius as that of ground state of hydrogen atom?

58. The uncertainity in position and velocity of the particle are 0.1 nm and 5.27  10-24 ms-1 respectively , then find
the approximate integral mass of the particle (in gram) (h = 6.625  10-34 Js)

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59. Calculate minimum value of uncertainty position of a particle whose de Broglie wavelength is  A 0 and
uncertainity in de Broglie wavelength is 0.05 A0, Express your answer in A0.

60. -particle at 3.6 MeV is fired towards nucleus Z XA at point of closet separation, distance between -particle
and X is 1.6  10-4m. Calculate atomic number of X.

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