Chemistery Experts: Basics of Coordination Compounds

@PMSSIR
Chemistery Experts
Basics
Of
Coordination Compounds
Level- 0
Piyush Maheshwari @PMSSIR

Basic Terminology
S Species O.S. of Configuration Charge on C.N. ligand Denticity EAN
no. CMI (P.V.) Of CMI Complex (S.V.) 0f Ligand
1. K2[NiCl4]
2. K2[Ni(CN)4]
3. K[CuCl3]
4. K2[NiF6]
5. [Cr(en)2Br2]
6. [Cr(gly)(en)2]2+
7. [Cr(en)3]3+
8. [CrCl2(NH3)4]NO3
9. [Cr(gly)3]
10. [CrF6]3–
11. [Cr(H2O)6]3+
12. [Cr(C2O4)3]3–
13. [CrBr(NO2)(H2O)4]+
14. [Cr(CN)6]4–
15. [Cr(en)3]2+
16. [Cr(CO)6]
17. [Cr(CN)6]3–
18. [Cr(H2O)6]2+
19. [Cr(H2O)6]2+
20. [MnF6]3–
21. [Mn(CN)6]4–
22. [Mn(H2O)6]2+
23. [Mn(NH3)6]2+
24. [MnF6]4–
To get extra 10% discount on uncademy subscription use code PMSSIR

@PMSSIR
1
To get extra 10% discount on uncademy subscription use code PMSSIR @PMSSIR
S Species O.S. of Configuration Charge on C.N. ligand Denticity
no. CMI (P.V.) Of CMI Complex (S.V.) 0f Ligand EAN
25. [Fe(NO2)2(en)2]
26. [Fe(CN)6]3–
27. FeF63–
28. [Fe(H2O)5NO]SO4
29. FeF64–
30. [Fe(EDTA)]¯
31. .[Fe(NH3)6]2+
32. [Fe(CN)6]4–
33. [Fe(NH3)6]3+
34. [Fe(en)3]2+
35. [Fe(NO2)6]4–
36. [Fe(NCS)6]4–
37. [Fe(H2O)2(NH3)4]2+
38. [Fe(en)3]3+
39. [Fe(H2O)6]2+
40. [Fe(H2O)6]3+
41. [Co(CO)4]¯
42. [CoCl3(NH3)3]
43. [CoCl4]2–
44. [Co(H2O)2F4]¯
45. [Co(NH3)6]2+
46. [Co(CN)2(NH3)4]Cl
47. [Co(OX)3]4–
48. [Co(H2O)3(NH3)3]+3
49. [Co(H2O)4F2]+
50. [Co(Ox)3]3–
2
no. CMI (P.V.) Of CMI Complex (S.V.) 0f Ligand
51. [CoCl2Br2]2–
52. [Co(dmg)2]
53. [Co(NH3)6]3+
54. [Co(NH3)5(NO2)]2+
55. [Co(en)2Cl2]+
56. [Co(H2O)6]2+
57. [Co(en)3]3+
58. [Co(en)3]2+
59. [CoF6]3–
60. [Co(H2O)6]3+
61. [Co(NH3)3(NO2)3]
62. [CoCl2(NH3)4]+
63. [Co(CN)6]4–
64. [Co(CN)6]3–
65. [HgI4]2–
66. [HgI3]¯
67. [PtCl4]2–
68. [Pt(gly)2]
69. [Pt(en)2Cl2]2+
70. [PtCl6]2–
71. [PtBr2(NO2)2(H2O)2]
72. [Pt(NH3)2(SCN)2]
73. [Pt(NH3)2Cl2]
74. [Pt(NH3)6]4+
75. [Pt(NO2)(gly)(NH3)]
3

no. CMI Of CMI Complex (S.V.) 0f Ligand
(P.V.)
76. [Pt(SCN)2(OX)2]2–
77. [Ti(H2O)6]4+
78. [Ru(dipy)3]3+
79. [Ru(acac)2(NO2)(NH3)]
80. [IrBr2(SCN)(NH3)3]
81. [Ir(acac)(CN)4]2–
82. [Sc(H2O)6]3+
84. Zn(gly)2
85. [Zn(CN)4]2–
86. [Zn(gly)(en)]+
87. [Zn(NH3)4]2+
88. [Zn(H2O)4]2+
89. [Zn(gly)(NH3)2(H2O)2]+
90. [AuCl4]¯
91. [Au(CN)2]¯
92. [Ni(CO)4]
93. [Ni(H2O)6]2+
94. [Ni(CN)5]3–
95. [Ni(dmg)2]
96. [NiBr(H2O)(en)2]NO3
97. [Ni(py)4]
98. [Ni(pph3)2Cl2]
99. [Pt(py)4]
100. [Ni(CN)4]4–
4
S.No. ligand Name of Ligand Comments (Flexidentate/Ambidentate/

Symmetrical / unsymmetrical)
1. H¯
2. F¯
3. Cl¯
4. Br¯
5. I¯
6. O22–
7. O2¯
8. O2–
9. OH¯
10. CH3O¯
11. OCN¯
12. NCO¯
13. SCN¯
14. NCS¯
15. SO42–
16. SO32–
17. OSO22–
18. S2O32–
19. N3¯ , [NNN]¯
20. N3–
5
. To get extra 10% discount on uncademy subscription use code PMSSIR @PMSSIR

21. NH2¯
22. NH2–
23. NO2¯
24. ONO¯
25. NO3¯
26. CN¯
27. NC¯
28. CH3COO¯
29. C2O42–
30. CO32–
31. CH3¯
32. CH3CH2¯
33. C6H5¯
34. SnCl3¯
35. NH3
36. H2O
37. CO
38. NO
39. O2
40. N2
6
41. PH3
42. PMe3
43. PPh3
44. N2H4
45. N2H2
46. MeNH2
47. EtNH2
48. NO+
49. N2H5+
50. Me2S
51. Me2O
52. PO43–
53. S2C2O22–
54. O2C2S22–
55. C2F4
56.
N
57. NH2–CH2–CH2–NH2
58.
N N
59. N N
60. NH2–CH2–COO¯
7
61. CH 3–C=CH–C–CH 3
O¯ O
62. CH3–C=CH–C–Ph
O¯ O
63. PMe2–CH2–CH2–PMe2
64. NH2–CH–CH–NH2
H3C CH3
65. H2C–CH–CH3
H2N NH2
66. CH 3–C=N–OH
H3C–C=N–O¯
67. EDTA4–
68. NOS¯
69. SNO¯
70. ONS¯
71. CH2=CH2
72.
73.
74.
75.
76. H
H B H
N N
B B
H N H
H
77. CH 2=CH–CH 2:

78. [CH2 CH CH2]
79. CH2 CH CH CH2
80. H
H
H
:
H H
8
Werner’s work
S.No. Werner Formula Modern Formula No. of Ions in Electrolyte
Aqueous
Medium
1. Cr.6NH3.Cl3
2. Cr.5NH3.Cl3
3. Cr.4NH3.Cl3
4. Cr.3NH3.Cl3
5. Pt.6NH3.Cl4
6. Pt.5NH3.Cl4
7. Pt.4NH3.Cl4
8. Pt.3NH3.Cl4
9. Pt.2NH3.Cl4
10. Pt.4NH3.Cl2
11. Pt.3NH3.Cl2
12. Pt.2NH3.Cl2
13. NiCl2.6H2O
14. PtCl4.2HCl
9
IUPAC Naming - I
1. [Co(NCS)(NH3)5]Cl2   Pentaamminethiocyanato–N–cobalt (III) chloride
2. K2[HgI4]   Potassium tetraiodomercurate (II)
3. [CoBr(ONO)(en)2]+1   Bromobis(ethylenediamine) nitrito cobalt (III) ion (nitro-O)
4. K2[Mo(CN)6]   Potassium hexacyanomolybdate (IV)
5. K[Au(CN)2]   Potassium dicyanoaurate (I)
6. [Fe(en)3]Cl3   Tris (ethylenediamine) iron (III) chloride
7. [Co(NH3)6]Cl3   Hexaamminecobalt (III) chloride
8. [Co(H2O)(NH3)5]Cl2   Pentaammineaquacobalt (II) chloride
9. K4[Fe(NO2)6]   Potassium hexanitroferrate (II) (nitro-N)
10. LiAlH4   Lithium tetrahydridoaluminate (III)
11. NaBH4   Sodium tetrahydridoborate (III)
12. [PtCl2(NH3)2]   Diamminedichloroplatinum (II)
13. [CoI(NH3)5]SO4   Pentaammineiodocobalt (III) sulphate
14. K2[Pt Cl6]   Potassium hexachloroplatinate (IV)
15. [Co(NH3)6] [Co(ONO)6]   Hexaammine cobalt (III) hexanitro–O cobaltate (III)
16. K3[Ir(C2O4)3]   Potassium trisoxalatoiridate (III)
17. (NH4)2[Pt(SCN)6]   Ammonium hexathiocyanato–S platinate (IV)
18. [Co(ONO)(NH3)5]SO4  Pentaamminenitro–O cobalt (III) sulphate(nitrito)
19. [Co(NO2)3(NH3)3]   Triamminetrinitrocobalt (III)
20. (NH4)3[Cr(NCS)6]   Ammonium hexaisothiocyanatochromate (III)
21. Na2[SiF6]   Sodium hexafluorosilicate (IV)
22. K3[Fe(CN)6]   Potassium hexacyanoferrate (III)
23. [Pt(NH3)4][PtCl4]   Tetraammine Platinum (II) tetrachloroplatinate (II)
24. (NH4)4[Mo(CN)8]   Ammonium octacyanomolybdate (IV)
25. [FeF6]3 –   Hexafluoroferrate (III) ion
26. [CoCO3(NH3)5]Cl   Pentaamminecarbonatocobalt (III) chloride
27. K3[Fe(NH2)6]   Potassium hexaamidoferrate (III)
28. [PtCl3(SnCl3)]2–   Trichlorotrichloro stannitoplatinate(II)ion
29. Na3[Co(NO2)6]   Sodium hexanitro–N cobaltate(III)
30. [PtCl4(NH3)2]  Diamminetetrachloroplatinum (IV)
31. [PtCl2(NH3)4] [PtCl4]  Tetraamminedichloroplatinum (IV) tetrachloroplatinate(II)
32. K3[Fe(CN)5NO]  Potassium pentacyanonitrosylferrate (II)
33. [PdI2(ONO)2(H2O)2]  Diaquadiiododinitro–N palladium (IV)
34. KAl(SO4)2.12H2O  Potassium aluminium sulphate. 12water
35. [CoCl(ONO)(en)2]  Chlorobis(ethylenediamine) nitro–O cobalt (II)/nitrito
36. [Ag(CN)2]—  Dicyanoargentate (I) ion
37. [CoCl2(en)2]2SO4  Dichlorobis (ethylenediamine) cobalt (III) sulphate
10
38. [Cr(CO)5(PPh3)]  Pentacarbonyltriphenylphosphinechromium (O)

39. K[BF4]  Potassium tetrafluoroborate (III)
40. Na2[Ni(EDTA)]  Sodium ethylenediaminetetraacetatonickelate (II)
41. [Co(en)3]2(SO4)3  Tris (ethylenediamine) cobalt (III) sulphate
42. [(NH3)5Co-NH2-Co(NH3)4(H2O)]Cl5  Pentaammine cobalt (III) –amido tetraammineaqua
cobalt (III) chloride
43. [Cr(H2O)6]Cl3  Hexaaquachromium (III) chloride
44. [Cu(NH3)4]SO4  Tetraammine copper (II) sulphate
45. Na2[CrOF4]  Sodium tetrafluorooxochromate (IV)
46.  –amido –superoxo bis tetraamminedicobalt (III) ion

Tetraammine cobalt (III) –amido –superoxo tetraammine cobalt (III)
–amido –superoxo bis {tetraammine cobalt (III)}
47. [Cr (OH )(HEDTA )]  Ethylenediamine triacetato hydroxo chromium (III) ion
48. [Be4O(CH3COO)6]  Hexa –– acetato–4 – oxo –tetra beryllium(II)
49. [CuCl(H2O)4]Cl  Tetraquachlorocopper (II) chloride
50. [CoBr(H2O)(NH3)4](NO3)2  Tetraammineaquabromocobalt (III) nitrate
11
IUPAC Naming - II
Write I.U.P.A.C. name for the following:
1. Na[B(NO3)4]  Sodium tetranitratoborate (III)
2. [Zn4O(CH3COO)6]  Hexa--acetate-4-oxo-tetrazinc (II)
3. [VO(acac)2]  Bis (acetylacetonato) oxovandium (IV)
4. Mn3(CO)12  Dodecacarbonyl trimanganese (O)
5. [(C6H5)3PCl Pd Cl2 PdCl(C6H5)3P] 
 Chlorotriphenyl phosphine palladium (II) –dichlorochloro triphenyl phosphine palladium (II)
 –dichlorodichlorobis (triphenylphosphine) di palladium (II)
 –dichlorobis{chlorotriphenyl phosphine palladium (II)}
 bis {–chloro chlorotriphenyl phosphine palladium (II)}
6. H2[PtCl6]    Hydrogen hexachloro platinate (IV)
7. [(Cl3Sn)2RhCl2Rh(SnCl3)2]4— 
SnCl2 + Cl–   SnCl3–
Stannous chloride trichlorostannite
 Bis(trichlorostannito) rhodate (I) di –chloro bis(trichlorostannito) rhodate(I) ion
 Di––chlorotetrakis(trichlorostannito) dirhodate(I) ion
 Di––chloro bis{bis(trichlorostannito) rhodate (I)}ion
8. Ni(CO)4  Tetracarbonylnickel (O)
9. Mn2(CO)10  Decacarbonyl dimanganese (O)
10. [Co(en)3]Cl3  Tris(ethylenediamine) cobalt (III) chloride
11. Na3[Fe(C2O4)3]  Sodium trisoxalatoferrate (III)
12. Na[Au(CN)2]  Sodium dicyanoaurate (I)
13. (CH3)4N[Cr(SCN)4(NO)2]  Tetramethylammoniumdinitro-Ntetrathiocyanatochromium(V)
14. [Cu(NH3)4][PtCl4]   Tetraaminecopper (II) tetrachloro platinate (II)
15. [W(en)3]Cl3  Tris (ethylenediamine) tungston (III)chloride
16. K2[Pt(SCN)6]  Potassium hexathiocyanato–S platinate (IV)
17. K3[Co(NCS)6]  Potassium hexathiocyanato–N cobaltate (III)
18. Na3[AIF6]  Sodium hexafluoroaluminate (III)
19. K2[Zn(OH)4]  Potassium tetrahydroxozincate (II)
20. K[Ag(CN)2]  Potassium dicyanoargentate (I)
21. [RhCl(CO)2]2  Bis dicarbonylchloro rhodium (I)
22. [Pt(NH3)4][Cr(NCS)(NO2)2(NH3)2Py]  Tetrammine platinum (II) diammine dinitro-N pyridine
thiocyanato-N chromate (I)
23. Na3[Co(NH2)6]  Sodium hexaamidocobaltate (III)
24. K2[Cd(CN)4]  Potassium tetracyanocadmate (II)
25. [CrCl2(H2O)4]Cl  Tetraaquodichlorochromium (III) chloride
26. Hg[Co(CNS)4]  Mercury tetrathiocyanato–S cobaltate (II)
27. [NiI4 ]2—  Tetraiodonickelate (II) ion
12
28. [Ag(NH3)2]Cl  Diammine silver (I) chloride
29. [CoBr(HEDTA)]–  Bromoethylenediaminetriacetatocobaltate (III) ion
30. K[SbCl5(C6H5)]  Potassium pentachlorophenylantimonate (V)
31. [RuBr2(NH3)4]NO3  Tetraamminedibromoruthenium (III) nitrate
32. Ca2[Fe(CN)6]  Calcium hexacyanoferrate (II)
33. NH4[Cr(NCS)4(NH3)2]  Ammonium diamminetetrathiocyanato–N chromate (III)
34. [CoCl(NO3)(NH3)4] [Au(CN)2] Tetraamminechloronitratocobalt (III) dicyanoaurate (I)
35. [PtCl(NO2)(en)(NH3)2] Cl2  Diamminechloroethylenediaminenitro–N platinum (IV)
36. [Ni(CN)4]2—  Tetracyanonickelate (II) ion
37. [(NH3)5Cr-OH-Cr(NH3)5]Cl5 
   Pentaammine chromium (III) –hydroxo pentaammine chromium (III) chloride
 –hydroxo bis {pentaammine chromium (III)}chloride
38. [(H2O)4Fe(OH)2Fe(H2O)4]SO4 
   Tetraaquoiron (II) di –hydroxo tetraaquo iron (II) sulphate
 –dihydroxooctaaquodi iron (II) sulphate
 –dihydroxo bis {tetraaquoiron (II)} sulphate
 bis {–hydroxotetraaquoiron (II)} sulphate
39. [Br2Pt(SMe2)2PtBr2]  (Me2O  dimethyl ether/ Me2S Dimethyl thioehter)
 Dibromoplatinum (II) bis  (dimethyl thioether) dibromoplatinum (II)
 Bis[( (dimethylthioether) dibromo platinum ] (II)
 bis –dimethyl thioether tetrabromo diplatinum (II)
40. [PtCl2(Et3P)2]   Dichlorobis (triethylphosphine) platinum (II)
41. [CuCl2(Et2NH)2]   Dichlorobis (diethylamine) copper (II)
42. [CoCl2(en)2]Cl   Dichlorobis (ethylenediamine) cobalt (III) chloride
43. K[PtCl3(C2H4)]   Potassium trichloro (2 – ethylene) platinate (II)
44. K2[OsCl5N]   Potassium pentachloronitridoosmate (VI)
45. Na3[Ag(S2O3)2]   Sodium bisthiosulphatoargentate (I)
46. Na2[Fe(CN)5(NO)]   Sodium pentacyanonitrosonium ferrate (II)
47. K3[Fe(CN)5(CO)]   Potassium carbonyl pentacyanoferrate (II)
48. K2[Ni(CN)4]   Potassium tetracyanonickelate (II)
49. K3[Co(NO2)6]   Potassium heranitro–N cobaltate (III) (nitrito)
50. K3[Cr(C2O4)3]   Potassium trisoxalatochromate (III)
13
IUPAC Naming - III

1. K2[Co(N3)4]  Potassium tetraazidocobaltate (II)
2. [NiCl2(Ph3P)2]  Dichlorobis(triphenylphosphine) nickel (II)
3. [Cr(acac)3]  Tris(acetylacetanato) chromium (III)
4. [IrCl(CO)(Ph3P)2]  Carbonylchlorobis(triphenylphosphine) iridium (I)
5. [Co(NCS)(NH3)5]Cl2  Pentaammine thiocyanato–N cobalt (III) chloride
6. [Pt(C5H5N)4] [PtCl4]  Tetrapyridine platinum (II) tetrachloroplatinate (II)
7. [CrCl(ONO)(NH3)4] NO3  Tetraammine chloronitro–O–chromium (III) nitrate
8. [Co(NH3)6][CuCl5]  Hexaamminecobalt (III) pentachlorocuprate (II)
9. [Ca(EDTA)]2—  Ethylenediaminetetraacetato calcate (II) ion
10. [Fe(H2O)5(NO)]Cl2  Pentaaquanitrosonium iron (I) chloride [brown ring unstable]
11. K4[Ni(CN)4]  Potassium tetracyanonickelate (O)
12. [CoCl2CO3(NH3)3]—  Triamminecarbonatodichlorocobaltate (III) ion
13. [Al(OH)(H2O)5]SO4  Pentaaquohydroxoaluminium (III) sulphate
14. [VBr2(H2O)(NH3)]Br  Ammineaquodibromovanadium (III) bromide
15. K4[MnF6]  Potassium hexafluoromanganate (II)
16. [Fe(H2O)6]SO4  Hexaaquoiron (II) sulphate
17. [PtCl(NO2)(NH3)4]SO4  Tetraaminechloronitro–N platinum (IV) sulphate
18. Na[Co(CO)4]  Sodium tetracarbonylcobaltate (–I)
[Co (en ) 2 ( I)(H 2O )]( NO 3 ) 2
19.  Aquabis(ethylenediamine) iodocobalt (III) nitrate
20. Ca2[Fe(CN)6]  Calcium hexacyanoferrate (II)
21. Fe4[Fe(CN)6]3  Iron (III) hexacyanoferrate (II)
22. [Cr(en)3] [Ni(CN)5]  Tris (ethylenediamine) chromium (III) pentacyano nickelate (II)
23. [CoCl(ONO)(en)2]Cl  Chlorobis (ethylenediamine) nitro–O cobalt (III) chloride
24. NH4[Cr(NCS)4(NH3)2]  Ammonium diamminetetrathiocyanato–N chromate (III)
25. [(NH3)4CoNH2NO2Co(NH3)4](NO3)4  –amido –nitro bis {tetraammine cobalt (III)} nitrate
 Tetraammine cobalt (III) –amido –nitro tetraammine
cobalt (III) nitrate
 –amido –nitro–octamminedicobalt (III) nitrate
Fe3 (CO )12
26.  Dodecacarbonyl tri iron (O)
27. K[B(C2H5)4]  Potassium tetraethyl borate (III)
28. Na[B(NO3)4]  Sodium tetranitratoborate (III)
29. Ba[BF4]2  Barium tetrafluoroborate (III)
30. (NH4)[B(NO2)4]  Ammonium tetranitro–N borate (III)
31. [PtBr(NH3)3] NO3  Triamminebromoplatinum (II) nitrate
32. trans-[PtCl2(NH3)2]  Trans–diammine dichloroplatinum (II)
33. Na3[Ag(S2O3)2]  Sodium bisthiosulphatoargentate (I)
14
34. NH4[Cr(NCS)4(NH3)2]  Ammonium diamminetetrathiocyanato–N chromate (III)

[(Ph 3P) 2 Ir(CO )]Cl
35.  Carbonyl bis (triphenylphosphine) iridium (I) chloride
RhCl (PPh 3 )3
36.  Chlorotris (triphenylphosphine) rhodium (I)
37. [CrCl2(H2O)4] NO3  Tetraaquodi chlorochromium (III) nitrate
38. [Cu(NH3)4]2+  Tetraamminecopper (II) ion
39. [Ni(dmg)2]  Bis (dimethylglyoximato) nickel (II)
40. NH4[Cr(CNS)4(NO)2]  Ammonium dinitrosyltetrathiocyanato–S chromate (III)
41. K4[Fe(CN)6]  Potassium hexacyanoferrate (II)
42. [PdI2(ONO)2(H2O)2]  Diaquadiiododinitro–O palladium (IV)
43. [Co(NH3)6][Cr(CN)6]  Hexaamminecobalt (III) hexacyanochromate (III)
44. (–C4H4)2Ni  bis 4- cyclobutadiene nickel (0)
45. [CoCl(NCS)(NH3)4]+  Tetraamminechlorothiocyanato–N cobalt (III) ion
46. [CrOH(H2O)3(NH3)2] (NO3)2  Diamminetriaquohydroxochromium (III) nitrate
47. [PtCl4(en)]  Tetrachloroethylenediamine platinum (IV)
K 3 [Fe(CN ) 5 ( NO )].2H 2 O
48.  Potassium pentacyanonitrosylferrate (II) dihydrate
49. [CoBrCl(en)(NH3)2] NO3  Diamminebromochloroethylenediamine cobalt (III) nitrate
50. [Mo(CN)8] 4 —  Octacyanomolybdate (IV) ion
15
Synergic Bonding
Single correct :
Q.1 Select the carbonyl species having highest CO bond length.
(A) Fe(CO)6 (B) Mn(CO)5– (C) Co(CO)5– (D) All have same
Q.2 Decrease in bond order of ligand is higher in :

   
(A) M  CO (B) M  N2 (C) M  PPh3 (D) M  PF3
Q.3 CO bond length is longest in

(A) [Mn(CO)6]+ (B) [V(CO)6]– (C) Cr(CO)6 (D) [Ti(CO)6]2–
Q.4 Which of the following complex compound has minimum CO bond order?
(A) [Fe(CO)4]2– (B) [Co(CO)4]– (C) [Cr(CO)6] (D) [Ni(CO)4]
Q.5 Which of the following ligands can not form synergic bonding with d-block metals.
(A) CO (B) NH3 (C) CN– (D) NO
Q.6 Which of the following orbital does not participate in synergic bonding of Fe(CO)5 complex
compound?
(A) HOMO of CO ligand i.e. non-bonding molecular orbital having slightly antibonding character.
(B) LUMO of CO ligand i.e.  antibonding molecular orbital.
(C) Non-axial d-orbital of central metal.
(D) Axial d-orbital having two nodal plane of central metal.
Q.7 Correct order of C – O bond length for compounds :

(I) H3BCO (II) [Fe(CO)4]2– (III) [Co(CO)4]–
(A) I > II > III (B) II > III > I (C) II > I > III (D) III > I > II
Q.8 Statement-1 : In Zeise's salt C – C bond order regarding ethylene molecule is less than two.
Statement-2 : Ethylene accepts electron pair from filled d-orbital of Pt2+ into its vacant
bonding M.O.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
16

Chemistery Experts: Basics of Coordination Compounds

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Chemistery Experts: Basics of Coordination Compounds

Uploaded by

Copyright:

Available Formats

@PMSSIR

Piyush Maheshwari @PMSSIR

To get extra 10% discount on uncademy subscription use code PMSSIR

S Species O.S. of Configuration Charge on C.N. ligand Denticity EAN

S.No. ligand Name of Ligand Comments (Flexidentate/Ambidentate/

19. N3¯ , [NNN]¯

S.No. ligand Name of Ligand Comments (Flexidentate/Ambidentate/

78. [CH2 CH CH2]

79. CH2 CH CH CH2

38. [Cr(CO)5(PPh3)]  Pentacarbonyltriphenylphosphinechromium (O)

46.  –amido –superoxo bis tetraamminedicobalt (III) ion

IUPAC Naming - III

34. NH4[Cr(NCS)4(NH3)2]  Ammonium diamminetetrathiocyanato–N chromate (III)

Q.2 Decrease in bond order of ligand is higher in :

Q.3 CO bond length is longest in

Q.7 Correct order of C – O bond length for compounds :

You might also like