Problems

ractice 3.0

States Of Matter
JPP 1

Ashwani Tyagi
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 Problems
ractice 3.0

States Of Matter
JPP 1

Ashwani Tyagi
The pressure exerted by 1 mole of a gas contained in 0.4 L vessel at 300 K
is
[Given a = 1.4 atm L2 mol–1, b = 0.024 L mol–1]
A. 56.6 atm
B. 148 atm
C. 182.3 atm
D. 364 atm
In van der Waals’ equation of state for non-ideal gas, the constant that
accounts for intermolecular force is
A. nb
B. (RT)–1

A. A

A. RT
A quantity of hydrogen gas occupies a volume of 30.0 mL at a certain
temperature and pressure. What volume would half this mass of hydrogen
occupy at triple the absolute temperature if the pressure were one ninth
to that of the original gas?
A. 270 mL
B. 90 mL
C. 405 mL
D. 137 mL
At a moderate pressure, the van der Waals’ equation is written as

The compressibility factor is equal to

A. B.

C. D.
In two vessels of 1 L each at the same temperature, 1 g of H2 and 1 g CH4
are taken. For these
A. vrms values will be same
B. Kinetic energy per mole will be same
C. Total kinetic energy will be same
D. Pressure will be same
Which of the following volume (V)-temperature (T) plots represents the
behaviour of one mole of an ideal gas at one atmospheric pressure?

A. B.

C. D.
An LPG cylinder, contaiing 15 kg butane at 27°C and 10 atm pressure, is
leaking. After one day, its pressure decreased to 8 atm. The quantity of
gas leaked is
A. 1 kg
B. 2 kg
C. 3 kg
D. 4 kg
If the pressure and temperature of 4 dm3 of carbon dioxide gas are
doubled, then volume of carbon dioxide would be
A. 2 dm3
B. 3 dm3
C. 4 dm3
D. 8 dm3
The root mean square velocity of one mole of a monoatomic gas having
molar mass M is Urms. The relation between the average kinetic energy (E)
of the gas and Urms is

A. B.

C. D.
The volume-temperature graphs of a given mass of an ideal gas at
constant pressre are shown below.
What is the correct order of pressures?
A. p1 > p3 > p2
B. p1 > p2 > p3
C. p2 > p3 > p1
D. p2 > p1 > p3
Dominance of strong repulsive forces among the molecules of the gas
(Z = compressibility factor)
A. Depends on Z and indicated by Z = 1
B. Depends on Z and indicated by Z > 1
C. Depends on Z and indicated by Z < 1
D. Is independent of Z
The kinetic energy of two moles of N2 at 27°C is (R = 8.324 JK–1 mol–1)
A. 5491.6 J
B. 6491.6 J
C. 7491.6 J
D. 8882.4 J
Which of the following equation shows correct form of Berthelot
equation?

A. B.

C. D.
At 298 K equal volumes of SO2, CH4 and O2 are mixed in empty container.
The total pressure exerted is 2.1 atm. The partial pressure of CH4 in
mixture is :
A. 0.6 atm
B. 1.2 atm
C. 2.4 atm
D. 3.6 atm
A gas cylinder containing cooling gas can withstand a pressure of 14.9
atmosphere. The pressure gauge of cylinder indicates 12 atmosphere at
27°C. Due to sudden fire in the building the temperature starts rising. The
temperature at which cylinder explode is
A. 87.5°C
B. 99.5°C
C. 115.5°C
D. 135.5°C
Which of the following gas molecules have equal total kinetic energy and
translation kinetic energy?
A. O2
B. He
C. CH4
D. N2
The temperature, at which the density of O2 at 1 atm, is the same as that
of CH4 at S.T.P., is
A. 273°C
B. 100°C
C. 546°C
D. 150°C
Two different gases enclosed in different flasks A and B at same
temperature and pressure were found to contain same number of
molecules. The ratio of volumes of the flasks A and B must be
A. 1 : 3
B. 1 : 1
C. 1 : 4
D. 1 : 2
Which of the following gases will have the highest rate of diffusion?
A. CO2
B. N2
C. NH3
D. O2
A. B.

C. D.
A. B.

C. D.
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