Professional Documents
Culture Documents
Department of Education
Division of Batangas
Proponent:
Advisers:
Angeline C. Pagkaliwangan
Geralyn A. Alday
S.Y 2018-2019
Abstract
Corrosion has become a wide problem all around the world. It basically does one
thing, destroy. It only destroys. Once a body or object corrodes, it is destroyed. People have
found a solution for this but this solution is not that affordable. This inspires the researcher to
The researcher decided to use calamansi peels. It is due to its availability and properties .
the calamansi is available throughout the year and everywhere around the Philippines. Mostly
The research itself aims to test the product’s significant properties: pH level, viscosity,
color, shelf life, cost and strength under water. Moreover, the new product will then be compared
to an existing one.
The calamansi fruit was peeled and boiled for 45 minutes. And then, it was placed in a
container for it to cool. The product will then be applied to the metal for testing.
After gathering data through a survey of 10 respondents, statistical table and data analysis
were done. It was proven that calamansi peel as coating is more basic than the commercial
product. In terms of viscosity, the new product is more viscous than the commercial product. In
terms of color, the new product and the commercial product are the same in color which is white.
The new product is proven to be cheaper than the commercial product. The commercial product
is also proven to last longer than the new product. Lastly, the new product is proven to be weaker
research can be improved or enhanced by recommendations and suggestions which means that it
The researcher exerted time, money and effort to accomplish the whole research.
However, it will not be possible to complete the research without the help of people that the
researcher considered his inspirations. The researcher would like to give his thanks to all the
Above everything else, the researcher wants to thank the Almighty God for giving him
the knowledge, strength, and the quality to finish the research study. It would not be complete
without it.
The researcher would also like to give thanks to his research advisers, Mrs. Angeline C.
Pagkaliwangan, and Mrs. Geralyn A. Alday for their support and guidance as well as giving the
The researcher also want to thank his parents and family for all the support given, for
their love and guidance. If not for them, this research study and research paper would not be
Moreover, the researcher wants to thank the Batangas Province Science High School
Grade 9 Students for their support. The researcher would also like to thank them because they
served as inspiration and lent a hand on all the processes needed to accomplish and complete this
Likewise, to every person who did not give up helping the researcher and still helped him
The Problem
Introduction
These days, people are using more and more metals like steels in construction. The past
generations, people use other materials like wood, stone, and gravel. But as time passed these
materials become weaker and weaker. Now because of the discovery of metals, more and more
people use it now because of its physical properties which are better than that of wood, stone and
gravel. But the properties of metals have its own weaknesses. One of these weaknesses is
corrosion.
Corrosion has become a wide problem all around the world. It basically does one thing,
destroy. It only destroys. Once a body or object corrodes, it is destroyed. It is caused by the flow
of electric current between different parts of metal serving as anodes and cathodes. It occurs
when water and oxygen are present. It is accelerated in the presence of acids and other
electrolytes. When a piece of metal corrodes, the electrolyte helps to provide oxygen to the
anode. As oxygen combines with metals, rust forms. Carbonic acid is essential to the rusting of
If one metal part of a building corrodes, everything could be affected by the corrosion.
This can make the whole building collapse or just make the building weaker. This can cause the
wastage in terms of finance and resources. This can be a major problem to the whole world.
Corrosion of metals not just cause some major problems in the field of construction, but
also in terms of health. When a person has or had an open wound, and the corroded metal
touched the open wound, this can cause some major complications. It may even cause the death
of the person that has the open wound. Bad things will happen to the human body if the corroded
is ingested.
In general, corrosion can cause a huge number of deaths to not just human but also other
creatures. There are just many bad things that can be caused by the corrosion of metals. How
worse can this case get? But, people around the world found a solution this corrosion, paint. The
paint prevents corrosion of metals by coating them. But not all people of the world can afford the
paints. That is why the researcher thought of a cheaper substitute for paint.
Calamansi (Citrus Microcarpa) is a small and round citrus fruit found all around the
Philippines. The fruits are used when the color of the skin is still green which is the associated
The researcher used the calamansi’s peels as the substitute of paint. It is such a waste of
The calamansi peels have corrosion inhibitors. Corrosion inhibitors are chemical
compounds that are added to metallic materials to reduce their corrosion. They are chemicals
added to the chemical stream to prevent corrosion, or lower the rate of corrosion so that an
equipment will have longer lifetime. So, calamansi peels can be used as substitute for paint. Also
calamansi are available throughout the year, and if trees are not available, markets sell them at a
With this facts and information, the researcher reflected that calamansi peel is a good
Corrosion is a wide problem around the world. It only does one thing, destruction. It just
destroys everything. Any corroded material is as good as destroyed. But, people nowadays found
a solution to this. But this solution take so much as a toll from the environment. It gets so much
On the other hand, calamansi fruits are available all throughout the year. They become
ripe then they fall from the tree. This fallen fruits are a waste. But, these fruits can be useful. We
can gather the fruits and peel them off. This peels can be an ingredient for liquid coatings for
metals.
Calamansi as stated are available in the Philippines all throughout the year, it is not
seasonal. Many fruits just fall of and become rotten. People will not have any problems with the
In this times, people use paint to prevent the corrosion of metals. They coat the metal so
the rusting process could not start or if it has already started, it can prevent or stop the rusting
process.
In the world today, paper is now a must-have matter a person should have. Paper is a thin
material produced through pressing together of cellulose pulp derived from rags or grasses, but
mostly woods and drying them into flexible sheets. It is a versatile material with many uses,
processes. Therefore, paper is sustainable, renewable, recyclable, and plant-based product that
material. One of it is it can be turned into a decorative paper. With its properties such as high
strength and good elastic possessions. Moreover, pineapple leaf fiber is proven to have high
With this rationale, the researcher think of an alternative source in order to create a
decorative paper. And that is the introduction of the use of pineapple leaf fiber (PALF) as a new
raw material.
Statement of the Problem
The study will be conducted to produce a protective coating for metals from calamansi peels.
1.1 pH level?
1.2 Vicosity?
1.3 Color?
1.4 Shelfife?
1.5 Cost?
2.1 Durability?
3.1 properties
3.1.1 pH level?
3.1.2 Viscosity?
3.1.3 Color?
3.1.4 Shelflife?
3.1.5 Cost?
3.2 effectiveness
The researcher hypothesized that there is a significant difference between the new
product and the commercial product in terms of pH Level, viscosity, color, shelf life, cost
The researcher also hypothesized that the new product is less basic than the
commercial product. For the viscosity, the researcher theorized that the new product is more
viscous than the commercial product. For the color, the new product is expected to have a
greenish color because it is made from calamansi peels. For the shelf life, the commercial
product is expected to last longer than the new product. For the cost, the new product is
theorized to be cheaper because its ingredients are free and available all throughout the year.
For the strength under water, the new product is theorized to be weaker than the commercial
one.
Significance of the Study
The study was done to test the possibility of calamansi peels as protective covering for
metals. The results of the study is intended to benefit the construction industry, household
To the Environment. The study aims to just use calamansi peels and only calamansi
peels. This reduces the usage of natural resources as ingredients for paint which really are so
To the Construction Industry. Because of the price of paint, and the corrosion of metal,
this study will introduce a new source, cheap, and main ingredient for making paint for the
To the Household People. For household people, this study will introduce them to a new
cheaper way of preventing the corrosion of the metal part of their houses. They can also just pick
calamansi from their backyard if they have calamansi trees planted on it.
To the Future Researchers. This study can help other researchers to create studies
related to calamansi peels as protective covering for metals. This study can also be a reference to
future studies.
Scope and Limitations
The scope of the study includes the procedures to be performed in the study, the materials
to be used to perform the study and the time it will take to perform the study. The researcher first
liquefies the calamansi peels and then applies it to the metal. The researcher focuses on covering
the metal. The materials that the researcher will use are free, easy to get and efficient materials.
The metal is limited because only one type of metal is used which is steel. The researcher
lacks the source of other metals for the research study. The calamansi is limited to just peels
The research used the following terms selected because of their facts and concepts that
Calamansi. A small and round citrus fruit found all around the Philippines. The fruits
are used when the color of the skin is still green which is the associated color for the fruit.
Carbonic Acid. Carbonic acid is essential to the rusting of iron, rusting does not occur in
its absence.
Corrosion. Corrosion of steel caused by the flow of electric current between different
parts of metal serving as anodes and cathodes. It occurs when water and oxygen are present. It is
Corrosion Inhibitor. Corrosion inhibitors are chemical compounds that are added to
metallic materials to reduce their corrosion. They are chemicals added to the chemical stream to
prevent corrosion, or lower the rate of corrosion so that an equipment will have longer lifetime.
When a piece of metal corrodes, the electrolyte helps to provide oxygen to the anode. As oxygen
Conceptual Literature
The following are the terms and information are what the researcher thought of as useful and
Botany of Calamansi. Kalamansi is a plant that can grow 3 to 5 meters high. Leavelets
have the shape of ellipse to oblong-ellipse growing 4 to 8 cm long. Flowers are auxiliary,
solitary, rarely in pairs, white and short stalked. Fruit is almost a sphere, 2 to 3.5 centimeters in
diameter. The skin color is green when raw and yellow when ripe. It contains a few light orange
seeds.
deodorant, refrigerant. Studies also show that Calamansi are antimicrobial, antianxiety,
Corrosion Inhibitor. Corrosion Inhibitors are chemical compounds that are added to
metallic materials to reduce their corrosion. They are chemicals added to a chemical stream to
prevent corrosion, or lower the rate of corrosion so that an equipment will have longer lifetime.
Rusting. Corrosion of steel caused by the flow of electric current between different parts
of metal serving as anodes and cathodes. It occurs when water and oxygen are present. It is
When a piece of metal corrodes, the electrolyte helps to provide oxygen to the anode. As oxygen
Calamansi. The calamansi is a small round citrus fruit found all around the Philippines.
The fruits are used when the color of the skin is still green which is the associated color for the
fruit.
to the Rutaceae family. It is ana intergenetic hybrid between the genes of a citrus an Kumquat.
Calamansi is widely cultivated in different countries of the world such as the Philippines,
Malaysia, Indonesia and Southern China. The fruit is available the whole year and is mostly seen
in its unripe green state. It can grow up to 25-35 mm in diameter. The pulp of the fruit is orange
in color. Each fruit bears 8-12 seed each. It has a very high Vitamin C content. It has a very thin
Kalamansi. Kalamansi is a small tree with many small leaves, white and fragrant flowers.
The green and circular fruit of this tree is commonly known and is popular as condiments, sauces
is also effective in the whitening of skin. Kalamansi is very rich in Vitamin C which is an
antioxidant. Kalamansi has different antibacterial properties so it can also be used as a deodorant
because it can kill the bacterids in our attempt that causes bad smell.
Carbonic Acid. “carbonic acid is essential to the rusting of iron, and that rusting does not
Research Literature
The following are studies that are related in the researcher’s study. The researcher based
antimicrobial properties of methanol extracts of five types of citrus peels, citrus aurantifoilia, c.
Streptococcus pyogenes, s. aureus, e. coli, and p. aeruginosa. At 20 mg/ml, three of the citrus
peels which are Citrus Microcarpa, C. reticulata and C. sinensis showed better inhibition than C.
aurantifolia and C. limon against S. aureus and E. coli. Citrus peel extracts are better to be
Potential Blood Sugar Lowering/Fruit Peels. Study showed calamansi peel extract has
potential for lowering blood sugar in Streptozotocin induced in diabetic albino rats.
silymarin preparations.
Antimicrobial. A study was conducted to see the antibacterial activity of 9 tropical plants
against 12 clinical and infectious bacterial strains. The bacterial strains include Vibrio Cholera,
Escherichia coli, Vibrio parahemolytics, salmonella and streptococcus sp. Amongst all of the
potential hemostatic agents from calamansi peels blended with polyethylene oxide. Results show
Cococnut Oil and Calamansi Peeling as an Agent for Hair Oil. The study was done to
know if coconut oil and calamansi peelings are feasible as agent for hair oil. The proponents
conducted that the product differed to a commercially available one through fragrance.
Citrus Fruits as an Antibacterial Hand Sanitizer. The study was conducted to create a
cheap but at the same time, quality hand sanitizer. This is done to help people who cannot buy an
expensive hand sanitizer. The study was a success because of the presence of ethyl alcohol which
Hypoglycemic Effect of the Mixture of Garlic, Onion, Honey, and Calamansi. The
researchers conducted this study to help people who suffer from diabetes. The significance os to
know the effects of the mixture garlic, onion, honey and calamnsi on diabetes. The study proved
that the mixture was effective in regulating blood sugar level and it is as effective as Metformin
Removing Wax. The proponents of the study wants to know if the calamansi and honey when
combined can be an alternative treatment for hair growth in the form of natural hair removing
wax. the proponents concluded that the combination of calamansi and honey are a good
conducted to be able to produce a low-cost, attainable and alternative air freshener. The
proponent wants to know if calamansi extract can be a good air freshener and it is comparable to
a commercially available air freshener. The proponents concluded that calamansi extract as air
Chapter III
Methodology
The materials that are going to be used to conduct the study are calamansi peels, stove,
First, calamansi was gathered on trees planted on the backyard of the researcher. Then,
the fruit was peeled and the peels and the fruit were separated and casted aside. The fruit was put
into a glass so it can be drunk and used again. The peels were put into the casserole.
Then, 3L of hot water will be poured into the casserole. The casserole will then be put in
on the stove so it can be boiled. Then, using the stove, the water will be boiled with the peels.
After 45 minutes, the liquid that was boiled is put on another container. The product took only
meter to determine the pH level. The process will be repeated 5 times to increase the reliability
of data. Then, using the measures of central tendencies, the pH level will be known. It will then
The product will be poured in the top of a glass. The product will be allowed to flow for 1
second. The distance will be recorded once 1 second passes. The data will be tallied to know the
viscosity of the product. The procedure will be repeated 5 times to increase the reliability of data.
The mean will be computed. It will then be compared to commercially available products.
Respondents will be gathered and asked. There will be a total of 5 respondents. Each
respondent will be asked what is the colour of the product with the following as answers, 1- dark
green, 2- green, 3- white, 4- yellow. The data will be tallied to know the colour. It will then be
The cost will be known by adding up all the expenses throughout the experiment. Labour
cost will not be included because the experiment did not require professionals to conduct. The
sum of the expenses will be compared to the cost of commercially available products.
The product will be placed in a glass container and in a dry place. It will be observed
every passing day for a week. It will be observed whether any changes to the properties and
effectiveness will occur. The same method will be done to a commercially available product.
The strength under water can be determined by placing the metal applied with the product
under running water. The procedure should be done for 15-30 minutes. The metal should be
observed whether the coating will wear off easily. The strength under water will then be
Data Analysis
The researcher used T-test to analyze the data. There was a given formula to get the
averages of the experimental and the commercial product. After getting the averages, the
researcher compared the averages and deduced on the data. The results helped the researcher to
Trials pH Level
1 7.5
2 7
3 6.5
4 7.5
5 7
Mean 7.1
The table 1.1 shows the result of 5 tests regarding the pH Level of the Calamansi Peel as
Coating. The measure of acidity is 1-6 for acidic and 8-12 for basic. 2 of the tests show that the
product is neutral, the other 2 show that the product is basic and the remaining test shows that the
product is acidic. The computed mean is 7.1 which means that the product is basic.
Table 1.2
Trials Distance
1 3 cm
2 4 cm
3 4.5 cm
4 4 cm
5 3 cm
Mean 3.7 cm
The table 1.2 shows the results of the 5 tests for viscosity. 2 of the tests show that the
distance travelled by the product in 1 second is 4 cm, the other 2 shows that the distance
travelled by the product is 3 cm, and the remaining test show that the distance travelled by the
product is 4.5 cm. the computed mean is 4.5 which means that the viscosity is 3.7 cm/s.
Table 1.3
Respondents Ratings
A 5
B 5
C 5
D 5
E 5
Mean 5
1 2 3 4 5
The table 1.4 shows the observations of 5 respondents namely Respondent A, Respondent
B, Respondent C, Respondent D, and Respondent E. the given color scheme is 1 for Dark Green,
2 for Green, 3 for Yellow, 4 for Light Yellow, and 5 for White. 100% of the respondents picked
Table 1.4
The table 1.4 shows the ingredients needed and their costs. The total cost for the product
is 0, since the calamansi peels can be gathered from calamansi fruits which are available all
Table 1.5
The table 1.5 shows the shelf life of Calamansi Peel as Coating for Metals. As the table
Table 1.6
Table 2.1
Trials pH Level
1 7.5
2 7.5
3 8
4 7.5
5 8
Mean 7.7
The table 2.1 shows the pH level of the commercial product. 3 of the tests show that the
pH Level of the commercial product is 7.5, 2 of the tests show that the pH Level of the product is
8. The computed mean is 7.7 which means that the commercial product is basic.
Table 2.2
Trials Distance
1 2 cm
2 2.5 cm
3 3
4 2 cm
5 2 cm
Mean 2.3 cm
The table 2.2 shows the viscosity of the commercial product. 3 of the trials show that the
commercial product travelled 2 cm in 1 second, the other trial shows that the commercial product
travelled 3 cm while the remaining trial shows that the commercial product travelled 2.5 cm. the
computed mean is 2.3 which means that the viscosity is 2.3 cm/s.
Table 2.3
Respondents Ratings
A 5
B 5
C 5
D 5
E 5
Mean 5
1 2 3 4 5
Respondent D and Respondent E, answered that the product is 5. The computed mean is 5 which
Product Cost
Commercial Product Php 700
The table 2.4 shows the cost of the commercial product. The cost of the commercial
Table 2.5
The table 2.5 shows the shelf life of the commercial product. As the table shows, the
Table 2.6
The table 2.6 shows the strength under water of the commercial product. As the table
Table 3.1
Table 3.2
The commercial product was hypothesized to be more basic than the new product. The
hypothesis was tested using T-test at 5% level of significance and the critical value is 2.015. The
Table 4.1
Table 4.2
The new product was hypothesized to be more viscous than the commercial product. The
hypothesis was tested using T-test at 5% level of significance and the critical value is 2.015. The
computed value is 3.88 which leads to the acceptance of the alternative hypothesis.
Table 5.1
Table 5.2
The new product is hypothesized to have a greenish color. The difference cannot be
computed by T-test. As seen from the tables, they have the same value. Thus, the alternative
hypothesis is rejected.
Table 6.1
Table 6.2
The difference cannot be computed by T-test. As seen from the two tables, the
commercial product lasts longer than the new product. Thus, the alternative hypothesis is
accepted.
Table 7.1
The Cost of Calamansi Peel as Coating
Product Cost
Calamansi Peel as Coating 0
Table 7.2
Product Cost
Commercial Product Php 700
The difference cannot be computed by T-test. As seen from the tables, the new product is
cheaper than the commercial product. Thus, the alternative hypothesis is accepted.
Table 8.1
Table 8.2
The difference cannot be computed using the T-test. As the tables show, the commercial
product is stronger than the new product under water. Thus, the alternative hypothesis is
therefore accepted.
Chapter V
Conclusions
The researcher surveyed 5 respondents in order to make a statistical table. After making
the statistical table of the Calamansi Peel as Coating and the commercial product, the researcher
Based on the statistical analysis, it can be concluded that there is a significant difference
in which one is greater than the other between the Calamansi Peel as Coating and that of
commercial product in terms of it its significant properties: pH Level, viscosity, color, shelf life,
product. There is a slight difference. The difference was caused by the ingredients used. The
calamansi peels are obtained from the calamansi fruit which are acidic.
Second, the viscosity. The viscosity of Calamansi Peel as Coating is 3.7 cm/s while the
viscosity of the commercial product is 2.3 cm/s. there is a difference between the two quantities
because of the ingredients and process of manufacturing. The Calamansi Peel as Coating is
composed mostly of water, while the commercial product is composed of many chemicals.
Moreover, the commercial product underwent many chemical processes while the new product
did not.
Third, for the color property. Based on survey, the Calamansi Peel as Coating is white,
and the same for the commercial product. The new product is the same with the color of the
Fourth, the shelf life property. Based on observations, the Calamansi Peel as Coating lasts
for 7 days and the commercial product lasts for 1 year. There is huge difference because the
Fifth, the cost of the prosucts. The Calamansi Peel as Coating is free while the
Commercial product costs Php 700. The huge difference is caused by the ingredients for the
materials and the processes that were done. The ingredients for the Calamansi peel as Coating
were free and available whole throughout the year while the ingredients of the commercial
under water while it is the opposite for the commercial product. The difference is affected by
All in all, the commercial product is better than the new product because the new product
is weak against water which is a major factor or catalyst for rusting or corrosion. On the other
hand, they are both effective because they both possess significant properties: ph Level,
Recommendations
Regarding the study, The Calamansi Peels as Protective Coverinig for Metals, the
researcher suggests that some parts and details of the study be improved.
For some methods, the researcher suggests to boil the leaves for about an hour to ensure
its effectiveness and reliability. Moreover, the researcher suggests the future researchers to use
more amount of calamansi peels for a much better product. The calamansi peels must be
carefully removed with precision and it should not have any part of the fruit left to ensure
effectiveness. The product should also be made carefully so any ingredient would not be wasted.
With these recommendations, make sure or try to follow every method to ensure a good
quality product. It will make way for more successful researches or studies related or concerning
this study.
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