n = A - Z = 63 – 29 = 34 neutrones para el 63Cu

n = A - Z = 65 – 29 = 36 neutrones para el 63Cu

𝑃𝑒𝑠𝑜𝐴𝑡ó𝑚𝑖𝑐𝑜 = 62.9296𝑢𝑚𝑎 ∗ 0.6917 + 64.9278𝑢𝑚𝑎 ∗ 0.3083 = 63.55𝑢𝑚𝑎

Metales de transición

n=4 l=2 ml = -2,-1,0,+1,+2 5 – 3d

n=5 l=2 ml = -2,-1,0,+1,+2 ms = ±1/2 5 – 4d

 1 1
(
= 𝜎 = 𝜇 𝑒𝑁 ) 𝜇=
𝜌 𝜌(𝑒𝑁)
𝑒 = 1.6022 ∗ 10−19 𝐶𝑜𝑢𝑙𝑜𝑚𝑏𝑠
Densidad
𝑔 1𝑚𝑜𝑙 6.022 ∗ 1023 á𝑡𝑜𝑚𝑜𝑠 á𝑡𝑜𝑚𝑜𝑠
𝑁 = 10.49 3 ( )( ) = 5.855 ∗ 1022
𝑐𝑚 107.9𝑔 1𝑚𝑜𝑙 𝑐𝑚3
1 1
𝜇= =
(
𝜌 𝑒𝑁 ) á𝑡𝑜𝑚𝑜𝑠
1.617 ∗ 10−6 𝛺𝑐𝑚 ∗ 1.6022 ∗ 10−19 𝐶𝑜𝑢𝑙𝑜𝑚𝑏𝑠 ∗ 5.855 ∗ 1022
𝑐𝑚3
𝑐𝑚3 𝑐𝑚2
𝜇 = 65.92 = 65.92
𝐶 (𝐴𝑚𝑝 ∗ 𝑠) 𝑉∗𝑠
Celda Unitaria
4 28
á𝑡𝑜𝑚𝑜𝑠
𝑁= = 5.865 ∗ 10
(4.0857 ∗ 10−10 𝑚)3 𝑚3

3
28
á𝑡𝑜𝑚𝑜𝑠 1𝑚 22
á𝑡𝑜𝑚𝑜𝑠
5.865 ∗ 10 ( ) = 5.865 ∗ 10
𝑚3 1003 𝑐𝑚3 𝑐𝑚3

1 1
𝜇= =
𝜌(𝑒𝑁) 1.617 ∗ 10−6 𝛺𝑐𝑚 ∗ 1.6022 ∗ 10−19 𝐶𝑜𝑢𝑙𝑜𝑚𝑏𝑠 ∗ 5.865 ∗ 1022 á𝑡𝑜𝑚𝑜𝑠
𝑐𝑚3

𝑐𝑚3 𝑐𝑚2
𝜇 = 65.81 = 65.81
𝐶 (𝐴𝑚𝑝 ∗ 𝑠) 𝑉∗𝑠

−3 𝑚2 −31
|𝑒 | ∗ 𝜏 𝜇∗𝑚 6.582 ∗ 10 ∗ 9.11 ∗ 10 𝑘𝑔
𝐶 (𝐴𝑚𝑝 ∗ 𝑠) −14
=𝜇 𝜏= = = 3.7 ∗ 10 𝑠
𝑚 𝑒 1.6022 ∗ 10−19 𝐶𝑜𝑢𝑙𝑜𝑚𝑏𝑠
 𝜎 = 𝜎𝑒𝑖𝑛𝑡 + 𝜎ℎ𝑖𝑛𝑡
𝜎 = 𝑁𝑒 ∗ |𝑒|𝜇𝑒 + 𝑁ℎ |ℎ|𝜇ℎ
𝜎 = 𝑁ℎ,𝑒 ∗ |𝑒 ó ℎ|(𝜇𝑒 + 𝜇ℎ )
−𝐸
( 𝑏)
𝑁𝑒 = 𝑁𝑐 ∗ 𝑒 2𝑘𝑇
2𝜋𝑚𝑒∗ 𝑘𝑇 3/2
𝑁𝑐 = 2 ∗ ( )
ℎ2
3
𝐽 2
2 ∗ 𝜋 ∗ 9.11 ∗ 10−31 𝑘𝑔 ∗ 1.38 ∗ 10−23 ∗ 300𝐾 𝑒
𝑁𝑐 = 2 ∗ ( 𝐾 ) = 2.503 ∗ 1025 3
(6.63 ∗ 10−34 𝐽 ∗ 𝑠)2 𝑚
3
25
𝑒 1𝑚 19
𝑒
2.503 ∗ 10 ( ) = 2.503 ∗ 10
𝑚3 1003 𝑐𝑚3 𝑐𝑚3
−0.67𝑒𝑉
( 𝑒𝑉 )
2∗8.63∗10−5 ∗300𝐾
𝑁𝑒 = 2.503 ∗ 1025 ∗ 𝑒 𝐾 = 6.011 ∗ 1019 𝑒/𝑚3
 2 2
𝑒 𝑐𝑚 𝑐𝑚
𝜎 = 6.011 ∗ 1019 3 ∗ |1.60 ∗ 10−19 𝐶 |(3800 + 1820 )
𝑚 𝑉∗𝑠 𝑉∗𝑠
2 2
𝑒 𝑐𝑚 𝑐𝑚 1
𝜎 = 6.011 ∗ 1013 ∗ | 1.60 ∗ 10−19 |
𝐶 (3800 + 1820 ) = 0.0541
𝑐𝑚3 𝑉∗𝑠 𝑉∗𝑠 𝛺 ∗ 𝑐𝑚
1 1
𝜌= = = 18.5𝛺 ∗ 𝑐𝑚
𝜎 0.0541 1
𝛺 ∗ 𝑐𝑚

𝑔 1𝑚𝑜𝑙 6.022 ∗ 1023 á𝑡𝑜𝑚𝑜𝑠 4𝑒 23

𝑒
𝑁 = 5.323 3 ( )( )( ) = 1.766 ∗ 10
𝑐𝑚 72.61𝑔 1𝑚𝑜𝑙 1á𝑡𝑜𝑚𝑜 𝑐𝑚3
𝑒
6.011 ∗ 1013 3
𝑃𝑟𝑜𝑝𝑜𝑟𝑐𝑖ó𝑛 = 𝑐𝑚 = 3.4 ∗ 10 −10
𝑒
1.766 ∗ 1023
𝑐𝑚3
 𝜎 = 𝜎𝑖𝑛𝑡 + 𝜎𝑒𝑥𝑡

10 ∗ 10−6 á𝑡𝑜𝑚𝑜𝑠 𝑑𝑒 𝑃 22
𝑆𝑖 17
𝑃
𝑁𝐷 = ( ) 5 ∗ 10 á𝑡𝑜𝑚𝑜𝑠 𝑑𝑒 3 = 5 ∗ 10
1 á𝑡𝑜𝑚𝑜𝑠 𝑑𝑒 𝑆𝑖 𝑐𝑚 𝑐𝑚3
2
17
𝑃 −19
𝑐𝑚 1
𝜎𝑥𝑆𝐷 = 5 ∗ 10 |1.60 ∗ 10 𝐶 | ∗ 1900 = 152
𝑐𝑚3 𝑉∗𝑠 𝛺 ∗ 𝑐𝑚

0.044𝑒𝑉
(− )
17
𝑒 8.63∗10−5 𝑒𝑉
∗300𝐾 16
𝑒
𝑁𝑥𝑒 = 5 ∗ 10 𝑒 𝐾 = 9.14 ∗ 10
𝑐𝑚3 𝑐𝑚3
 2
16
𝑒 −19 |
𝑐𝑚 1
𝜎𝑥𝐷 = 9.14 ∗ 10 | 1.60 ∗ 10 𝐶 ∗ 1900 = 27.8
𝑐𝑚3 𝑉∗𝑠 𝛺 ∗ 𝑐𝑚

1
27.8
%𝜎300𝐾 = 𝛺 ∗ 𝑐𝑚 ∗ 100 = 18.3%
1
152
𝛺 ∗ 𝑐𝑚
a)
𝜎𝑎 = 1758(2 ∗ 107 )−0.0977 = 340.2𝑀𝑃𝑎
b)
𝜎𝑎 = (1758 − 175)(2 ∗ 107 )−0.0977 = 306.3 𝑀𝑃𝑎
c)
𝜎𝑎 = (1758 + 175))(2 ∗ 107 )−0.0977 = 374.0 𝑀𝑃𝑎
 ∆𝜖𝑝
= 0.95(2 ∗ 1000)−0.64 = 0.00733
2

∆𝜖𝑒 828
= 5
(2 ∗ 1000)−0.11 = 0.00171
2 2.10 ∗ 10
𝐷𝑒𝑓𝑜𝑟𝑚𝑎𝑐𝑖ó𝑛 𝑇𝑜𝑡𝑎𝑙 𝑝𝑜𝑟 𝑐𝑖𝑐𝑙𝑜 = 0.00733 + 0.00171 = 0.00904

𝐼𝑛𝑡𝑒𝑟𝑣𝑎𝑙𝑜 𝑇𝑜𝑡𝑎𝑙 = 2 ∗ 0.00904 = 0.0181

 a)
𝑙𝑜𝑔𝑡𝑟 − 𝑃𝑆−𝐷 𝑙𝑜𝑔30 − (−18.5) 𝐶𝑎𝑙
𝑄= = = 84879
1 1 𝑚𝑜𝑙
0.217 ( ) 0.217 ( )
𝑇 922𝐾
b)
𝑙𝑜𝑔𝑡𝑟 − 𝑃𝑆−𝐷 𝑙𝑜𝑔300 − (−15.8) 𝐶𝑎𝑙
𝑄= = = 84647
1 1 𝑚𝑜𝑙
0.217 ( ) 0.217 ( )
𝑇 1005𝐾
 2
𝐾𝐼𝐶 40𝑝𝑖𝑒 − 𝑙𝑏
( ) = 5[ − 0.05]
𝜎𝑟𝑓 120𝑘𝑠𝑖
𝐾𝐼𝐶 2
( ) = 1.417 𝐾𝐼𝐶 = 120 ∗ √1.417 = 143𝑘𝑠𝑖 √𝑝𝑙𝑔
𝜎𝑟𝑓
a) Solo fase sólida
%Sb = 40 % %Bi = 60%
b) 2 fases
%Sb = 70% %Bi = 30%
a) Solo fase líquida
%Sb = 50 % %Bi = 50%

LÍQUIDA
43%Sb 57%Bi

SOLIDA
86%Sb 14%Bi
 86 − 70
𝐹𝑟𝑎𝑐𝑐𝑖ó𝑛 𝑒𝑛 𝑝𝑒𝑠𝑜 𝐿í𝑞𝑢𝑖𝑑𝑜 = = 0.372
86 − 43
70 − 43
𝐹𝑟𝑎𝑐𝑐𝑖ó𝑛 𝑒𝑛 𝑝𝑒𝑠𝑜 𝑆ó𝑙𝑖𝑑𝑜 = = 0.628
86 − 43