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DEBASHISH GOUDA ROLL NO. 201810550
B HEMANT KUMAR ROLL NO. 201810183
2021 – 2022
ABSTRACT
This research has aims to study effect between flyash , ggbs and rice husk ash to
geopolymer bricks for use in the construction sector. The manufacturing processes of
both geopolymer bricks and traditional fired bricks were investigated. For this study,
we collected and analyzed all phases of geopolymer brick production from the
on clay and waste bricks were analyzed. We considered the cost of raw materials and
waste bricks, for the same production cost, the compressive strength of the
geopolymer bricks is double that of fired bricks. Hence, this study shows the
that future research is needed that focuses on necessary changes to the current
Geopolymer bricks contain flayash as the source material and an alkaline activator for
the activation of polymerization reaction. In this study, experimental work has been
performed on geopolymer bricks with flyash and GGBS as source material and
hydroxide was maintained at 12M for all the mixtures and the ratio of sodium
hydroxide to sodium silicate was kept as 1:2.5. The brick properties such as
compressive strength, water absorption, acid resistance and efflorescence test were
conducted on the test specimens. Test results indicated that geopolymer concrete with
higher GGBS content resulted in higher compressive strength and better properties
ACKNOWLEDGEMENT
It is our proud privilege to epitomize our deepest sense of gratitude and indebtedness
to our advisor, Prof. Sujit Kumar Rout for his valuable guidance, keen and sustained
interest, intuitive ideas and persistent endeavour. His inspiring assistance, laconic
reciprocation and affectionate care enabled us to complete our work smoothly and
successfully.
Coordinator, for giving us the opportunity and motivating us to complete the project
Priyadarshi Tripathy (Principal) and Dr. Barada Prasad Sethy (HoD) N.I.S.T.
Their continued drive for better quality in everything that happens at N.I.S.T. and
We would also like to extend our heartfelt gratitude to our parents and friends for
DEBASHISH GOUDA
B HEMANT KUMAR
TABLE OF CONTENTS
ABSTRACT...................................................................................................................i
ACKNOWLEDGEMENT.............................................................................................ii
TABLE OF CONTENTS.............................................................................................iii
LIST OF FIGURES......................................................................................................iv
1. INTRODUCTION.....................................................................................................1
2. LITERATURE REVIEW..........................................................................................2
3. MATERIALS USED.................................................................................................6
3.1 FLY-ASH.....................................................................................................6
3.2 GGBS (Ground Granulated blast-furnace slag)...........................................7
3.3 Alkali Activators.........................................................................................9
4. METHODOLOGY..................................................................................................11
4.1 Consistency Test of Fly-Ash......................................................................11
4.1.1 Mould.................................................................................................12
4.1.2 Casting of Mould...............................................................................12
4.2 Testing of Brick Sample............................................................................14
5. RESULTS................................................................................................................15
6.COST ANAYISIS…………………………………………………………………
15
6.1 Geopolymer Brick……………………………………………………
16
6.2 Clay Brick…………………………………………………………….16
6.3 FLY Ash Brick………………………………………………………..16
7. CONCLUSION........................................................................................................16
REFERENCES............................................................................................................17
LIST OF FIGURES
Fig. 1 Fly-Ash................................................................................................................6
Fig. 2 Fly-Ash and GGBS..............................................................................................9
Fig. 3 Alkali Activators..................................................................................................9
Fig. 4 Mixing of NaOH and Na2SiO3...........................................................................10
Fig. 5 Vicat Apparatus.................................................................................................11
Fig. 6. Mould................................................................................................................12
Fig. 7. Casting of Mould..............................................................................................12
Fig. 8. Bricks after 7 Days of oven curing...................................................................13
Fig. 9 Digital Compression Testing Machine.........................................................................14
1. INTRODUCTION
Brick is the most commonly used building material in India for more than 1000 years. Fired
clay bricks are most commonly used in India. But nowadays fly ash bricks have been
tremendously being used due to the reduction in cost as well as its light weight. Geopolymer
bricks are the latest innovation in the brick industry which consist of supplementary
cementitious materials such as fly ash or GGBS activated by an alkaline activator .The
application of geopolymer technology gained importance due to the reduction of the CO2
been noted that geopolymer bricks made with flyash requires higher curing temperature to
achieve higher compressive strength and lower absorption. Prepared geopolymer bricks using
waste raw materials such as clay brick waste, slaked lime waste, de-aluminated kaolin and
caustic soda. They were able to produce light weight bricks with densities around 1000
kg/m3 with a compressive strength of 1.4MPa. Formulated geopolymer bricks using ceramic
dust waste. They found that the cost of the geopolymer bricks produced from ceramic waste
resulted in the reduction of production cost of bricks. Studied the durability and leaching
behavior of geopolymer bricks made from mine tailings. They found that there was
substantial reduction in the strength of the geopolymer bricks immersed in pH=4 and seven
solutions. Performed optimization studies to find the optimum curing conditions of Fired clay
bricks and Natural pozzolona based geopolymers. Their results indicated the compressive
strength of 37 to 26 MPa has been achieved when proper production conditions are adopted.
Reviewed the development of geopolymer bricks using industrial wastes and reported that the
variation in the source materials can significantly affect the physical, chemical and
developing geopolymer bricks and studying its properties such as compressive strength, water
2. LITERATURE REVIEW
Subharajit Roy, Sanjith J, Jagath H R, Chethan G
Fly ash, also known as “pulverized fuel ash” in many countries such as England, Northern
Ireland, and Scotland etc. is a coal combustion product. It is composed of fine particles of
burnt fuels and fuel gases emitted from coalfired boilers. Though it was causing severe air
pollution, in the past, fly ash was usually released into the atmosphere as it is mainly a
thermal waste of coal firing thermal plants. But presently, according to air pollution control
standards, it is captured prior to release by fitting pollution control equipment. Due to its
pozzolanic nature, recycled fly ash is usually used as the production of hydraulic cement and
a complete and/or partial replacement for Portland cement in concrete production. Potential
of fly ash as a material is not only restricted to cement and concrete industries. It can be
utilized as a raw material for brick production, which will be a positive answer towards both
environmental and economic complications. The purpose of this particular study is to explore
the performance of Geopolymer brick consists of fly ash as one of its chief material. The
bricks were casted with clay soil to fly ash in the different proportion of 100:0, 80:20, 70:30,
60:40 and 50:50. Sodium fume solution was applied as an alkaline-activator and a ratio 1:2 of
water to NaOH solution was used as the binder solution. With an optimum water/binder ratio
of 0.416 and adopted dimension of (200 X 100 X 100) mm. The experimental outcomes were
In this paper, we studied an economic analysis of the use of geopolymer brick at the
industrial level. The research presents a French case study of the brickworks in the North of
France. Different geopolymer brick formulations based on clay and waste bricks were
studied. The production cost of one metric ton of bricks and the compressive strength of the
geopolymer bricks were the two parameters used to evaluate the feasibility of production of
geopolymer bricks at the industrial level. The determination of the production cost of the
geopolymer bricks was based on the annual business model of the brickworks, which was
used to find all data sources needed. The results of this study demonstrated that the
used in the formulation. The geopolymer brick based on clay gives a financial gain of 5%
compared to traditional fired brick for the same compressive strength of 20 MPa. In the case
compressive strength can be achieved with the same production cost as fired bricks. These
Solution Concentration”
Conclusions are arrived from the experimental study done on GPB with different
Geopolymer bricks can be used as a viable alternative to the conventional clay bricks.
Class F fly ash produces better strength values than the GPB specimens made with
It was concluded that the optimum results are obtained at 10M alkaline solution and
600C hot air oven curing temperature. Beyond 10M, the strength property doesn’t
show better results than other concentrations and increases the cost of GPB. Increase
in curing temperature increases the strength of GPB mixes, but 900C also doesn’t
Thermal curing temperature of 600C shows better results with the ratio of
Na2SiO3/NaOH is 2.5, whereas the previous literatures shows that the curing
temperature increases to 1000C when the ratio of alkaline activator is around 1.5.
At 7 days, the crushing strength GPB specimen with 10M and 600C is 137.01% and
77.18% higher than the specimens with room temperature and 900C respectively.
Increment in alkaline solution concentration reduces that pores on the surface of the
Generally, GPB is alkali resistive nature and shows appreciable results when the
Wan Mastura Wan Ibrahim, Kamarudin Hussin, Mohd Mustafa Al Bakri Abdullah,
Aeslina, Abdul Kadir “Geopolymer lightweight bricks manufactured from fly-ash and
foaming-agent.”
On the basis of the experimental work it is concluded that the compressive strength of
foamed geopolymer bricks foaming agent to water ratio (1:10) reduced in strength between
49.3- 68.6% while for the (1:20) ratio, the strength decreases between 66.7-72.9% of
strength. However, the strength for all samples increases as the curing temperature increased.
It is also analysed that water absorption of foamed geopolymer bricks for samples with 1:10
ratio of foaming agent to water was increases about 56-66% from the control samples without
foaming agent added and 62-63% more as compared to the control samples when 1:20 of
foaming agent to water ratio was used. The samples obtained in present work shows promise
This paper deals with the development of lightweight geopolymer bricks by using foaming
agent and flyash. The mix parameters analysed through a laboratory experiment with fix ratio
of sodium silicate/sodium hydroxide solution mass ratio 2.5, fly ash/alkaline activator
solution mass ratio 2.0, foaming agent/paste mass ratio 1:2 and molarity of sodium hydroxide
solution used was 12M. Different curing temperature (Room Temperature,60, 80) and
foaming agent/water mass ratio (1:10 and 1:20) were studied. Compressive strength, density
analysis, and water absorption has been investigated. The results show that the foamed
geopolymer bricks with a lowerfoam/water mass ratio (1:10)and high curing temperature
(80°C) leading to a better properties. Mixtures with a lowdensity of around 1420 kg/m3 and a
Arya K.C., Alester Joseph Vanreyk and Chinku Alphons Tom “A REVIEW ON GGBS,
Compressive strength of bricks made with Lime:GGBS and PC:GGBS shows higher
strength and less water absorption rate for 28days. Bricks made with sand and GGBS
shows better compressive strength, lesser water absorption rate and thermal
Bricks made with paper sludge shows better compressive strength upto 5-15% and the
paper sludge.
Bricks made with laterite soil shows improved compressive strength and water
absorption rate. Laterite soils have similar properties to that of clay whereas laterite-
clay bricks show more water absorption than that of clay bricks.
With GGBS.
Good quality bricks can be produced from stipulated proportions of slag, lime mixture and
sand. The strength characteristics of the unfired bricks tested in this study were improved
The amount of the clay is reduced to 20% of total use. The manufacturing process of
the bricks is simple and does not require any firing or autoclaving, specialized plant or
machinery. Therefore, the energy consumption will be much less compared with
Brick production using GGBS as the main stabilising agent will reduce the energy and
cost of the firing process. Appropriate research and development into new
technologies that reduce energy usage and carbon dioxideemissions are vital for
new materials will help the construction industry meet global challenges and develop
business.
A. Sumathi, K. Saravana, Raja Mohan “Compressive Strength of Fly Ash Brick with
Based on the experimental study, following conclusions can be drawn regarding the strength
behavior of flyash brick.The study was conducted to find the optimum mix percentage of
flyash brick. However the brick specimen of size 230mm x 110mm x 90mm were cast for
different mix percentage of Flyash (15 to 50%), Gypsum (2%), Lime (5 to 30%) and Quarry
dust (45 to 55%). However the specimens have been tested for seven mix proportions. The
mechanical properties such as compressive strength were studied for different mix
proportions, at different curing ages. From the results it was inferred that, among the seven
proportions the maximum optimized compressive strength is obtained for optimal mix
3. MATERIALS USED
3.1 FLY-ASH
Fly ash is a fine gray powder consisting mostly of spherical, glassy particles that are
produced as a byproduct in coal-fired power stations. Fly ash has pozzolanic properties,
meaning that it reacts with lime to form cementations compounds. It is commonly known as a
Fly ash is a residue generated in combustion and comprises the fine particles that rise with the
flue gases. Ash that does not rise is called bottom ash. In an industrial context, fly ash usually
refers to ash produced during combustion of coal. Fly ash is a heterogeneous material. The
1. Silicon dioxide
2. Aluminum oxide
3. Ferric oxide
Fly ash material solidifies while suspended in the exhaust gases and is collected by
electrostatic precipitators or filter bags. Since the particles solidify rapidly while suspended in
the exhaust gases, fly ash particles are generally spherical in shape and range in size from 0.5
µm to 300 µm.
Fig. 1 Fly-Ash
iron slag (a by-product of iron and steel-making) from a blast furnace in water or steam, to
produce a glassy , granular product that is then dried and ground into a fine powder. Ground-
granulated blast furnace slag is highly cementitious and high in calcium silicate hydrates
(CSH) which is a strength enhancing compound which improves the strength, durability and
A. COMPOSITION
The main components of blast furnace slag are CaO (30-50%), SiO2 (28-38%), Al2O3 (8-
24%), and MgO (1-18%). In general increasing the CaO content of the slag results in raised
slag basicity and an increase in compressive strength. The MgO and Al2O3 content show the
same trend up to respectively 10-12% and 14%, beyond which no further improvement can
be obtained. Several compositional ratios or so-called hydraulic indices have been used to
correlate slag composition with hydraulic activity the latter being mostly expressed as the
B. APPLICATION
GGBS cement can be added to concrete in the concrete manufacturer's batching plant, along
with Portland cement, aggregates and water. The normal ratios of aggregates and water to
cementitious material in the mix remain unchanged. GGBS is used as a direct replacement for
Portland cement, on a one-to-one basis by weight. Replacement levels for GGBS vary from
C. DURABILITY
GGBS cement is routinely specified in concrete to provide protection against both sulfate
attack and chloride attack. GGBS has now effectively replaced sulfate-resisting Portland
cement (SRPC) on the market for sulfate resistance because of its superior performance and
including Spencer Dock are using GGBS in subsurface concrete for sulfate resistance.
Bulk Electrical Resistivity is a test method that can measure the resistivity of concrete
samples. (ASTM 1876-19) The higher electrical resistivity can be an indication of higher ion
transfer resistivity and thus higher durability. By replacing up to 50% GGBS in concrete,
To protect against chloride attack, GGBS is used at a replacement level of 50% in concrete.
Instances of chloride attack occur in reinforced concrete in marine environments and in road
bridges where the concrete is exposed to splashing from road de-icing salts. In
most NRA projects in Ireland GGBS is now specified in structural concrete for bridge piers
and abutments for protection against chloride attack. The use of GGBS in such instances will
increase the life of the structure by up to 50% had only Portland cement been used, and
GGBS is also routinely used to limit the temperature rise in large concrete pours. The more
gradual hydration of GGBS cement generates both lower peak and less total overall heat than
Portland cement. This reduces thermal gradients in the concrete, which prevents the
occurrence of micro cracking which can weaken the concrete and reduce its durability, and
D. APPEARANCE
In contrast to the stony grey of concrete made with Portland cement, the near-white color of
GGBS cement permits architects to achieve a lighter color for exposed fair-faced concrete
finishes, at no extra cost. To achieve a lighter color finish, GGBS is usually specified at
between 50% to 70% replacement levels, although levels as high as 85% can be used. GGBS
cement also produces a smoother, more defect-free surface, due to the fineness of the GGBS
particles.
E. STRENGTH
Concrete containing GGBS cement has a higher ultimate strength than concrete made with
hydrates (CSH) than concrete made with Portland cement only, and a reduced content of free
lime, which does not contribute to concrete strength. Concrete made with GGBS continues to
gain strength over time, and has been shown to double its 28-days.
Geopolymericaction was induced in the brick element through alkaline activators such as
NaOH and Na2SiO3 which are commercially available ,by taking into account the high cost
of K-based chemicals. NaOH with 98% purity have been dissolved in distilled water to make
such.
Alkaline activator binder is a solution of sodium hydroxide and sodium silicate. The ratio of
4. METHODOLOGY
Different priliminary properties such as specific gravity, water absorption etc of fly
Consistency of flyash and ggbs was found out to determine the water required for
paste.
Initial and final setting time of fly ash was found out to find out whether mix sets at a
Batching for different combinations of rice husk ash, flyash, ggbs and wooden
Then thereafter they were put in oven at a temp of 100 degree celcius for curing
purpose.
Compressive strength was found out after 7, 14 & 28 days of curing respective.
paste that provides sufficient viscosity and desirable strength for different type of structural
work. Adding less or excess amount of water in flyash causes reduction in its strength.
4.1.1 Mould
Fig. 6. Mould
Dimension – (70.6mmx70.6mmx70.6mm)
load a material can bear before fracturing. The test piece, usually in the form of a cube,
5. RESULTS
CS – Compressive Strength
6. COST ANALYSIS
From above cost analysis it is clear that geopolymer bricks are more cost effective
as compare to both Clay Brick and Flyash brick.
6. CONCLUSION
Highest compressive is exhibited by the geopolyer brick with the F/A -50%, RHA – 20% and
GGBS – 30% (with a constant solid to liquid ratio 1.5) shows better result compared to other
trial mixes.
REFERENCES
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accomplishing hypo sludge fly ash brick in Indian context”, International Journal of
Engineering Trends and Technology, 10, 361-365.
[2] Cusido J. A., Cremades L. V., Soriano, C. and Devant, M.(2015). “Incorporation of
paper sludge in clay brick formulation”: Ten years of industrial experience, Applied
Clay Science, 108, 191–198.
[3] Okunade E. A, (2008). “The effect of wood ash and sawdust admixture on the
engineering properties of a burnt laterite” – clay brick, Journal of Applied Science 8,
(1042-1048).
[4] Gaurav Goel and Ajay S Kalamdhad, (2017). “An investigation on use of paper mill
sludge in brick manufacturing”, Construction and Building Materials, 148, 334–343.
[5] Malhotra, S. K. and Tehri, S. I (1996). “Development of bricks from granulated blast
furnace slag, Construction and Building Materials”, 10, 191-1