Compounds P

of
•

Py

L .

Pitz ( phosphine)

3 . Oxide ( Pee G
and Paolo )

( Pelz and Pels )

y .
Halides

P
Imps
t
-

Oxyacid of

( Pu )
Phosphorous
Sio , → Casio + Pyo ,o
Caz ( Poy )z t z

CO
Pyo , @
t C -7 Py +

RA
 go
Pu
Reactions
of S O Cl Cl

Mg3Pz
PHS t Na Hzpoz Paolo set
-

of

q
E or d,
90
4 Saclz

PCI -54 502 Sozclz

④ 02N ,
Py 06

12
Cl
2
OC
S pets or PC 's
conc .

H NOS
PCI z
t
502 t Szclz

Hzpoy
1- G
502
Pu t
S←0zCl2 → Pcl g
t

+ 4
Pu t socio -
Paz t so- t Szclz
-
 Py t NaOH - PH3 +
NaHzP0g
( disproportional on

H Ren)

p P
pH ,
" o
- P'-3k¥
\p/
→ +

Xp #
'
no H
-
/ l OH
OH
µ
O
"
l
v
P -
' H
NaOH H O I
Natlzpoz f- 3 Hz PO , H

( phosphorous
hypo
-

aced)
gorp
+ NaOH - PH g t Natta Poe
 Phosphine ( PHD

Colourless
gas
-

-
Rotten Fish odour

-
Bond
angle
= 900 ( No
hybn )
- less basic
0

Preparation

a) Phosphide ¥4 PHZ

PH ,
b) phosphide

Mgzpz t HCl → Mgclz t

PHS
c) Py t NaOH -7 PHz + NaH2POz

' Ptb
-

d) PHI + OH →

PHy+I PHZ
- -

-7
t OH

PHYI

e) 1431303
or
-17 PH z
t
Hzpoy

H3POz
 Reactions PHS
of

AGN03p
02
Paolo
Agzp Pao , or

as
Celso
y

PHY I

Cuzpz

in 's ( wars)
Note : Pitz is used Holme
Signal
(acz * Cazpz

- GHz PH3
 Oxides P
of
Pu Og Py O,o

o
.

:
Py g

→ Py + Oz Pu Og

→ Re Oo + H2O -7 Hzpoz

↳ Paolo
02

Pu 010
-

Py + Oz -7 Pu co

NOTE : Paolo also acts as

dehydrating agent
 14205 t H2O → HMOs

dehydrating
14205
(

{
agent) HNS

µ Hao

soy pyo Hypo ,

so ,

, , .
,
'
co c
3

Cao co t Py
C HGCN

Caz 0472
( peed -
Base Rxn)
 P
Halides
of
P Cl PCI
z g

Cl

j '
// Cl
l cc
c,
I a - P
-
l
C l c,

Cl

Pyramidal shape
( TBP shape )
 Pclz

Preparation :

Pu t Cl z
-4 Pelz

limited

-7 Pclz + SO t
Szclz
Py
,
t so clz
 Py Py

5042
Clz

H2O
Pclz Hzpoz t HCl

ROM Cl
2

Rcl Oz Pcl 5
Fz

Poclz pcizfz / ✓
Cl

CI - P

µ
 PC 15
"

Pclgpy
In solid state it exist as Pau and
,
( Sp3d2 Sps ) ( )

'
Py Clz Pcl 3 t Cl z

50242 D

-120
poclg H3P0y
Pcl 5
503
POC134
sack
Ag
or
S
ROH Pdz
Aga
+
CO2

NOTE g Poag
- t so Cl z
-
R - CI

Pels 2

ta
,
pool ,
you
Poclz +
2- CI
,

-
 P
Oxyacids of

phosphorous acid Hzpoz

l
Hypo
. -

-
H3PO3
2 -

phosphorous acid
-

Hzpoy
'd
3 -

phosphoric ace

aced Hypnos
phosphorous
y
Pyro
-
.

acid
pyso phosphoric
5
Hypz
-

)
+
.

6 . meta -

phosphoric acid ( HP g) n

acid Hypzog
7.
hypo
-

phosphoric
 Hzpoz I
-131703 H3P0y
O O O

11 11 11
p- p
P
-
-
H l OH
✓ H /
HO l Ho
l yo 1
OH OH
µ

Phosphorous phosphoric
hypo phosphorous
-

+ 5
0.5 o
+3
°
1- I

2
3

Basicity
° I
o

( bonds)
Reducing due to P -
H

Reducing g

Acidic 8 Acidic
yup
y
 WITH id
're 8 1431702 7 Hzpoz 7H3POy
209
o

of
11 11 11
P p
A A
-

P y

oµ -0/10,50
-

-0/1
"
H
(
-

H
o
conjugate
base)
-
STABLE ) e-
( cross RESONANCE

Acid → CB

( stable )
strong
 Pyro phosphorous ( Hypzos)
O O

" "

i' I?
'
'
"

OH
x

P O P
linkage
- -
-

O O

reducing
-

H H

P P -
- # n

-
dibasic acid H 11 o
I
0h
OH
 Pyro phosphoric
:
moi !? ÷ -

.
on

¥1 -I

-
Tetrabasic acid o o

K 11

p p
OH
linkage
-
p P
\o/
-

-
o -

-
HO l l
OH
OH
 meta phosphoric acid

Hz Pou -
H2O → (HP Oz )n

exist in form of Polymer

-

it the

3 it is known as teamer
if
-

n=
, O

Trimer 8 "
H3P30g -p
O

\
l
z p P
linkage
/
o -

OH
-

Tribasic g O
OH
O
=/
-

\ on
, /
o - R
'
O
 phosphoric
hypo
-

Hypz 06

O
O
P
H
P
linkage
-

H
-

p -
P -
OH
40/1 I
OH
-

tetrabasic Acid
OH
HzP03

Py Og t H2O -7 Hzpoz

Pclz + H2O →
Hzpoz

Reactions :

D
Hzpoy P
l .
Hzpoz -7 t
Hz

→
Ag
t
Hzpoy
Zo Hzpoz t
Agnos

Pcizoeg , phosphorous acid

Pyro
t →
Hzpoz
-
Hzpoy

lo Py 0,0 t H2O → Hz Poy

2 . PCI 5 + H2O
→
Hzpoy
3 . Py t conc
-
HN Oz → Hzpoy

Hzpoz D- Hz Poy PHZ

Y .
t

acid
Effect phosphoric
eating of
phosphoric acid
Hzpoy -0 ,
Pyro -1 ,

meta phosphoric
NOTE 8
( Hzpoz)
-_

phosphorous)
white P t NaOH → PH z t Na Hzpoz
( hypo -

Red P t NaOH → PH3 T Nau P2 06

( Hypzog)
( phosphoric)
hypo
-

NOTE 8
-
-

N and P are also used in fertilizers

N 8 Urea ,
Nitrolim
 Phosphorous

1 . Triple Super phosphate 8 CaCHzP0y)z T Cason

z. Triple Phosphate 8 Ca ( Hzpoy) ,

 Group 16

Properties
0
Physical
down
S
a) Size 8 Increases
group
decreases down
b) Ionisation
Energy
: gop
se

c) Point : Inc down

group
Boiling
-

Te
se > Te
d) Electron Affinity
:

(
O
s > se > Te >

PC radioactive
,
e) tonics ' " "

↳ Increases down
due to small sin
'

gsp
'
-

of O .
 Vidyamandir Classes

Aggarwal Corporate Heights, 3rd Floor, Plot No. A - 7, Netaji Subhash Place,
Pitam Pura, Delhi - 110034 Phone: 011-45221190 - 93.

Class Test p-Block Element (Group-15) Chemistry

1. Select the compound in which HCl is NOT the product of Hydrolysis

(A) NCl3 (B) PCl3 (C) AsCl3 (D) BiCl3

2. Consider the following reaction and select INCORRECT statement about gas (P) ;
Zn HNO3 (dil). Zn(NO 3 )2 P
(A) Gives neutral solution in water (B) Contains more O2 than Air
(C) Forms Brown ring with FeSO 4 solution (D) None of these

3. Conc. HNO3 is yellow coloured liquid due to:

(A) Presence of NO in conc. HNO3 (B) Presence of NO 2 in conc. HNO3
(C) Presence of N 2O in conc. HNO3 (D) Presence of N 2O3 in conc. HNO3

4. An explosive compound (A) reacts with water to produce NH 4OH and HOCl. Then, the compound (A),
is:
(A) TNG (B) NCl3 (C) PCl3 (D) HNO3

5.

(A) (X) = Pyrophoshoric acid (liquid), (Y) = Metaphosphoric acid (liquid)

(B) (X) = Pyrophosphoric acid (liquid), (Y) = Metaphosphoric acid (solid)
(C) (X) = Pyrophosphoric acid (solid), (Y) = Metaphosphoric acid (solid)
(D) (X) = Pyrophosphoric acid (solid), (Y) = Metaphosphoric acid (liquid)

6. H3 PO2 (X) PH 3 ; is
(A) Dehydration reaction (B) Oxidation reaction
(C) Disproportion reaction (D) Dephosphorelation reaction

7. An inorganic salt (A) is decomposed at about 523 K to given products (B) and (C). Compound (C) is a
liquid at room temperature and is neutral to litmus paper while oxide (B) on burning with white
phosphorous, given a dehydrating agent (D). Compounds (A), (B), (C) and (D) will identified as
(A) NH 4 NO3 , N 2O,H 2O, P2O5 (B) NH 4 NO2 , K 2 O,H 2O, P2O5
(C) CaCO3 ,CaO, H 2O,CaCl2 (D) CaCO3 ,CaO, H 2O,Ca(OH)2

8. A tetra-atomic molecule (A) on reaction with nitrogen (l) oxide, produces two substances (B) and (C). (B)
is dehydrating agent in its monomeric form while substance (C) is a diatomic gas which shows almost inert
behaviour. The substances (A) and (B) and (C) respectively will be :
(A) P4 , P4O10 , N 2 (B) P4 , N 2O5 , N 2 (C) P4 , P2O3 ,Ar (D) P4 ,P2O3 , H 2

VMC | Chemistry 1 Class Test | p-Block Elements

 Vidyamandir Classes

9. Nitrogen dioxide is dissolved in water to produce

(A) HNO3 and HNO2 (B) Only HNO3
(C) Only HNO2 (D) HNO 2 and N 2

10. Which one of the following compounds on heating evolves ammonia gas ?
(A) (NH 4 ) 2 SO 4 (B) HNO3 (C) (NH 4 ) 2 Cr2O7 (D) NH 4 NO3

11. In a molecule of phosphorus (V) oxide, there are

(A) 4P P,10P O and 4P 0 bonds (B) 12P O and 4P O bonds
(C) 2P O and 4P P bonds (D) 6P P,12P O and 4P P bonds

12. Concentrated HNO3 reacts with iodine to give

(A) HI (B) HOI (C) HOIO2 (D) HOIO3
13. Ammonia can be dried by
(A) conc. H 2SO 4 (B) P4O10 (C) CaO (D) anhydrous CaCl2

14. When chlorine reacts with a gas X, an explosive ionorganic compound Y is formed. Then X and Y will be:
(A) X O2 and Y NCl3 (B) X NH3 and Y NCl3 ]
(C) X O2 and Y NH 4Cl (D) X NH 3 and Y NH 4 Cl

15. When AgNO3 is heated strongly, the products formed are

(A) NO and NO 2 (B) NO 2 and O2 (C) NO 2 and N 2 O (D) NO and O 2

16. HNO3 P4 O10 HPO3 A ; the product A is :

(A) N 2O (B) N 2 O3 (C) NO 2 (D) N 2 O5

N2
17. Ca C CaC 2 A
Compound (A) is used as a/ an
(A) Fertilizer (B) Dehydrating agent `
(C) Oxidising agent (D) Reducing agent

18. One mole of calcium phosphide on reaction with excess water gives :
(A) One mole of phosphine (B) Two moles of phosphoric acid
(C) Two moles of phosphine (D) One mole of phosphorus penta-oxide

19. Three allotropes (A), (B) and (C) of phosphorous in the following change are respectively:

(A) White, black, red (B) black, white, red

(C) red, black, white (D) red, violet, black
20. As molecular weight increases in 15th group hydrides then which of the following property increases
regularly:
(A) Boiling point (B) Melting point
(C) Thermal stability (D) Reducing nature
21. In which of the following acids, P–P bond is present?
(A) hypophosphoric acid (H 4P2O6 ) (B) Pyrophosphoric acid (H 4P2O7 )
(C) Orthophosphoric acid (H3PO4 ) (D) Polymetaphosphoric acid (HPO3 )n

VMC | Chemistry 2 Class Test | p-Block Elements

 Vidyamandir Classes

22. Which statement regarding phosphine is NOT CORRECT ?

(A) It possess of rotten fish smell
(B) It is obtained in Holme’s signal by hydrolysis of Ca 3P2
(C) It is combustile in nature due to presence of impurity of P2 H4 along with it
(D) It is more soluble in water than ammonia
23. Nitrogen gas is not obtained by heating solid form of :
(A) NaN3 (B) NH 4ClO 4
(C) (NH 4 ) 2 Cr2O7 (D) Na(NH 4 )HPO 4 4H 2 O

24. Select INCORRECT Match :

(A) P : Paramagnetic gas (B) Q : Colourless species

(C) R : Oxidising agent (D) T : sp 2 Hybridize central atom

25. Which of the following does not contain PX 4 type cation in solid phase ? (X = halogen)
(A) PF5 (B) PCl5 (C) PBr5 (D) None of these

26. Which one of the following is a tetra basic acid?

(A) Hypo phosphorus acid (B) Ortho phosphoric acid
(C) Metaphosphoric acid (D) Pyrophosphoric acid
low temp.
*27. 2NO2 N 2 O4 The dimerization of NO 2 is accompanied with
R.T.
(A) decreases in paramagnetism (B) change in colour
(C) increase in temperature (D) increase in paramagnetism

*28. PCl5 (g) Ag x y

Where product ‘x’ is water insoluble but ‘y’ reacts with water, then product ‘x’ is soluble in solution of :
(A) KCN (B) Na 2S2O 3 (C) H 2O (D) NH 3

*29. Which of the following reaction is/are correct ?

(A) PCl3 3H 2O H3PO3 3HCl (B) NCl3 3H 2O NH3 3HOCl
(C) SbCl3 3H 2O H3SbO3 3HCl (D) BiCl3 H 2O BiOCl 2HCl

*30. CaCN 2 H 2O solid + gas

Same gas can also be produced from
(A) (NH 4 ) 2 S (B) (NH 4 ) 2 SO 4

(C) Na(NH 4 )HPO4 .4H 2O (D) (NH 4 ) 2 Cr2O7

31. What products do you expect in the following reaction?

AIN NaOH H 2O A B
(A) (A) : Na 2 AlO2 , (B) ; N2H4 (B) (A) : NaAlO2, (B): NH3
(C) (A) : Al2O3, (B) : NH3 (D) (A): Na3AlO2, (B) : N2H4

VMC | Chemistry 3 Class Test | p-Block Elements

 Vidyamandir Classes

*32. Which is true about N2O5

(A) It is anhydride of HNO3 (B) in solid state it exists as NO 2 NO 3
(C) it is structurally similar to P2O5 (D) it can be prepared by heating HNO3 over P2O5

33. Superphosphate of lime is :

(A) Ca 3 (PO 4 ) 2 CaSO4 (B) Ca(H 2PO 4 )2
(C) Ca(H 2PO4 )2 CaSO 4 (D) Ca(H 2PO 4 )2 H 2O 2CaSO 4 2H 2O

34. Which one of the oxides of nitrogen dimerises into colourless solid/liquid on cooling ?
(A) N2 O (B) NO (C) N2 O3 (D) NO2

35. Ammonia reacts with Nessler’s reagent to give :

(A) deep blue precipitate (B) white precipitate
(C) green precipitate (D) brown precipitate

VMC | Chemistry 4 Class Test | p-Block Elements