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Exergy modeling of a new solar driven


trigeneration system

Article in Solar Energy · September 2011


DOI: 10.1016/j.solener.2011.06.009

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Fahad A Al-Sulaiman Feridun Hamdullahpur


King Fahd University of Petroleum and Min… University of Waterloo
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Solar Energy 85 (2011) 2228–2243


www.elsevier.com/locate/solener

Exergy modeling of a new solar driven trigeneration system


Fahad A. Al-Sulaiman a,c,⇑, Ibrahim Dincer b, Feridun Hamdullahpur c
a
Mechanical Engineering Department, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran, Saudi Arabia
b
Faculty of Engineering and Applied Science, University of Ontario Institute of Technology Oshawa, ON, Canada
c
Mechanical and Mechatronics Engineering Department, University of Waterloo, Waterloo, ON, Canada

Received 12 November 2010; received in revised form 13 March 2011; accepted 8 June 2011
Available online 19 July 2011

Communicated by: Associate Editor S.A. Sherif

Abstract

In this paper, exergy modeling is used to assess the exergetic performance of a novel trigeneration system using parabolic trough solar
collectors (PTSC) and an organic Rankine cycle (ORC). Four cases are considered: electrical-power, cooling-cogeneration, heating-
cogeneration, and trigeneration. In this trigeneration system a single-effect absorption chiller is utilized to provide the necessary cooling
energy and a heat exchanger is utilized to provide the necessary heating energy. The trigeneration system considered is examined using
three modes of operation. They are: solar mode during the low-solar radiation time of the day, solar and storage mode during the high-
solar radiation time of the day, and storage mode during night time. The storage mode is operated through the heat collected in a thermal
storage tank during the solar and storage mode. The exergy efficiencies and exergy destruction rates are examined under the variation of
the ORC evaporator pinch point temperature, ORC pump inlet temperature, and turbine inlet pressure. This study reveals that the max-
imum electrical-exergy efficiency for the solar mode is 7%, for the solar and storage mode is 3.5%, and for the storage mode is 3%. Alter-
natively, when trigeneration is used, the exergy efficiency increases noticeably. The maximum trigeneration-exergy efficiency for the solar
mode is 20%, for solar and storage mode is 8%, and for the storage mode is 7%. Moreover, this study shows that the main sources of
exergy destruction rate are the solar collectors and ORC evaporators. Therefore, careful selection and design of these two components
are essential to reduce the exergy destructed by them and, thus, increase the exergy efficiencies of the system.
Ó 2011 Elsevier Ltd. All rights reserved.

Keywords: Trigeneration; Parabolic trough solar collectors; Organic Rankine cycle; Thermal storage tank; Exergy efficiency; Exergy destruction rate

1. Introduction trical power directly through photovoltaic solar cells or


indirectly through a solar thermal system.
Solar energy is a reliable energy source. It is a free There are several solar thermal systems that can be used
renewable energy source with no gas emissions. The num- to produce electrical power through thermal power plants;
ber of power plants operated partially or completely by these include PTSC, solar towers, and solar dishes. PTSC
solar energy has been increasing significantly (Fernndez- are the most established technology among these thermal
Garca et al., 2010). Solar energy can be used to obtain elec- solar technologies for power production and has been used
in large power plants since the 1980s. Currently, several
thermal solar power plants are under construction and most
⇑ Corresponding author. Address: Mechanical Engineering Department, of them are based on PTSC. Therefore, PTSC is selected for
King Fahd University of Petroleum and Minerals (KFUPM), Dhahran, the solar trigeneration system considered in this study.
Saudi Arabia. A thermal system that produces cooling, heating, and
E-mail addresses: fahadas@kfupm.edu.sa (F.A. Al-Sulaiman), power simultaneously from the same energy source is
Ibrahim.Dincer@uoit.ca (I. Dincer), fhamdullahpur@uwaterloo.ca (F.
defined as a trigeneration system. In trigeneration systems,
Hamdullahpur).

0038-092X/$ - see front matter Ó 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.solener.2011.06.009
F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243 2229

List of symbols

Aap aperture area, m 2 Subscripts


Ac area of the receiver cover, m2 0 atmospheric conditions
Ar area of the receiver, m2 a ambient
Cp specific heat, kJ/kg K aam average temperature above the ambient
Coln total number of collectors per single row chst charging hot storage tank
Colr total number of solar collectors rows cog, c cooling cogeneration
D diameter, m cog, h heating cogeneration
ex specific exergy, kJ/kg cst cold storage tank
Ex exergy, kJ dhst discharging hot storage tank
Ex_ exergy rate, kW d destruction
FR heat removal factor e exit
F1 collector efficiency factor ev evaporator
Gb solar radiation, W/m2 ex exergy
hc convection heat coefficient, kW/m2 K g generator
hr radiation heat coefficient, kW/m2 K h heating
k thermal conductivity, W/m hp heating process
m mass, kg hst hot storage tank
M mass of the oil in the tank, kg i inlet
Nus Nusselt number l, hst heat lost from the hot storage tank
P pressure, kPa m motor
Pv vapor pressure, kPa o organic
Q heat, kJ oe organic cycle evaporator
Q_ heat rate, kW op organic cycle pump
rel,h electrical to heating energy ratio ot organic cycle turbine
rel,c electrical to cooling energy ratio sol, p pump of the solar system
T temperature, °C or K sp solution pump
UA overall heat coefficient and area, kW/K st1, p first pump in the thermal storage system
UL overall heat loss coefficient of the solar collector, st2, p second pump in the thermal storage system
kW/m2 K wp water pump
Uo heat loss coefficient between the ambient and re- tri trigeneration
ceiver of the solar collector, kW/m2 K u useful
w collector width, m
W_ work rate, kW Superscripts
-
molar base
.
Greek letters rate of a component
Dt change in time in second 0 at standard pressure
Dth change in time in hour
cv emittance of the receiver cover Acronyms
gex exergy efficiency ORC organic Rankine cycle
r Stefan–Boltzmann constant, kW/m2 K4 PTSC parabolic trough solar collectors
q density, kg/m3

the waste heat from the plant’s prime mover, such as a gas et al. (2011). In their study, it was shown that a signifi-
turbine, is used for heating and cooling. ORC is one of the cant number of studies were conducted on trigeneration
potential subsystems that can be used in trigeneration plants that are based on internal combustion engines as
plants for mechanical power production and, then, electri- prime movers, but there are fewer studies on gas turbines
cal power production through an electrical generator. ORC and microturbines as prime movers. On the other hand,
can be integrated with a low- or medium-temperature there is a need for more research on the other three
energy source while the steam Rankine cycle can be inte- prime movers: fuel cells, Rankine cycles, and Stirling
grated with a high-temperature energy source. engines. In terms of analysis type, most of the studies
A comprehensive review of trigeneration plants based on have been conducted using energy and economical anal-
trigeneration prime movers was conducted by Al-Sulaiman yses and less attention has been given to environmental,
2230 F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243

exergy, and thermoeconomic analyses of trigeneration in the analyzed system. It can, therefore, lead to improved
plants. operation or technology (Dincer and Rosen, 2007).
A number of studies considered using solar energy and This paper presents an exergy analysis that was con-
ORC for desalination, e.g. (Delgado-Torres and Garcna- ducted to assess a new trigeneration system using PTSC
Rodrnguez, 2007; Garcna-Rodrnguez and Delgado-Torres, and ORC. The system considered consists of a solar sub-
2007; Manolakos et al., 2009; Bruno et al., 2008; Kosmadakis system, two thermal storage tanks, an ORC, a single-effect
et al., 2010; Karellas et al., 2011; Tchanche et al., 2010; absorption chiller, and a heat exchanger for the heating
Nafey and Sharaf, 2010). In contrast, a few studies exam- process. The simulation of the present system considers
ined the feasibility of using a thermal system based on solar three modes of operation: solar mode, solar and storage
energy and ORC for power production, e.g. (Prabhu, 2006; mode, and storage mode. The four specific cases that are
Jing et al., 2010; Wang and Zhao, 2009; Riffat and Zhao, considered in this study are electrical power, cooling-
2004; Zheng and Weng, 2010). Prabhu (2006) examined cogeneration, heating-cogeneration, and trigeneration
the feasibility and economic possibilities of using PTSC cases. The system is sized to produce around 500 kW of
and ORC for electrical power and water cooling produc- net electrical power. The objective of this study is to assess
tion. The author also examined the feasibility of using the exergetic performance of the four cases considered, to
the system proposed in his study for selected locations in identify and quantify the sources of the exergy destruction
the USA and in other parts of the world. In another study, in the system considered, and, hence, to help in improving
Wang and Zhao (2009) examined the energy efficiency of the system exergy efficiency. The following text presents
three zeotropic mixtures as a working fluid of an ORC. first the system description and assumptions and then sys-
They found that under specific working conditions, intro- tem modeling, results and discussion, and conclusions.
ducing an internal heat exchanger to the system can notice-
ably increase the thermal performances of the Rankine 2. System description
cycle, especially for drying and isentropic zeotropic mix-
tures. In a different study, Jing et al. (2010) conducted an The trigeneration system considered consists of a PTSC,
energy analysis to examine the integration of an ORC with an ORC, a heating process heat exchanger, and a single-
a low temperature PTSC for different locations. In their effect absorption chiller, as shown in Fig. 1. The oil heated
study, they compared first the efficiency of single-stage through PTSC is used to heat the fluid in the ORC. On the
solar collectors with two-stage solar collectors. The authors other hand, the waste heat from the ORC is used for heat-
found that the two-stage solar collectors have a higher effi- ing and cooling. The waste heat from the ORC is used to
ciency, where the improvement varies from 8.1% to 20.9%, produce steam in the heating process, using a heat exchan-
as compared to the single-stage solar collectors. Then the ger and to produce cooling using a single-effect absorption
authors compared the power output of their system at six chiller. To have an efficient ORC, the working fluid in the
different locations. ORC should have a high critical temperature, so that a
A performance assessment of cogeneration thermal sys- usable waste heat can be gained. One of the typical organic
tems was conducted by Riffat and Zhao (2004), Zheng and fluid types used to operate the ORC is n-octane, which has
Weng (2010). Zheng and Weng (2010) studied the perfor- a relatively high critical temperature, 569 K (Yaws, 1999).
mance of a cooling-cogeneration system for power and Hence, it is selected as the working fuel of the ORC (Bruno
refrigeration production, using R245fa as a working fluid et al., 2008; Vijayaraghavan and Goswami, 2005).
for the Rankine cycle. The refrigeration power is based The solar-trigeneration system is a dynamic system
on an ejector refrigeration cycle. The authors found that where the energy input varies with time. After the sunrise,
the energy efficiency of the system was 34.1% while the the solar radiation increases from zero until it reaches its
exergy efficiency of the system was 56.8%. Riffat and Zhao maximum at noon and then decreases until it reaches zero
(2004) examined the performance of a heating-cogenera- at sunset. To have a continuously operating solar plant,
tion system using solar collectors, an ORC, and a gas boi- another auxiliary subsystem is needed. A common subsys-
ler. The authors found that the electrical efficiency of their tem that is combined with a solar system, is a thermal stor-
system was 16% and the heating efficiency was 43%; and as age energy subsystem. The thermal storage subsystem
a result, the overall efficiency was 59%. In a different study, stores the excess solar energy during the day time and, thus,
energy performance assessment of a trigeneration system ensures running the system at night time. Therefore, to
using PTSC and ORC was conducted by Al-Sulaiman have a full picture of a thermal solar system performance,
(2011). In their study, it was shown that the maximum elec- it needs to be designed considering a thermal storage sub-
trical energy efficiency was 14%; alternatively, when trigen- system. Indeed, considering a thermal storage subsystem
eration was used the energy efficiency increases to 94%. is important when there is a need to have energy during
Exergy analysis, which is based on both the first law of night time, for example, which is the considered case in this
thermodynamics and the second law of thermodynamics, study. The solar trigeneration plant operating modes are
overcomes some limitations of the energy analysis. Exergy described next.
analysis indicates the locations of energy degradation in a In this study, three modes of operation are considered:
process and quantifies the irreversibility in each component solar, solar and storage, and storage modes. During the
F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243 2231

Valve I
16 17 3
Electrical
generator
24
20 Hot
storage Power
25 ORC turbine
23 tank ORC
Parabolic evaporator-b
trough Storage Storage
solar HEx pump I
collectors 2b
4
26
30
Cold
Storage storage ORC Thp,2
pump II tank evaporator-a Heating
22 29
28 27 process Thp,1=40 C
21 (313K)
19 18 2a 1 5
Valve II Solar pump
ORC pump
Condenser
Tco,2
6 Desorber
Tco,1=30 C
(303K) `

7 12 13

Refrigerant
expansion valve Solution heat
exchanger

8 11 14
Solution Solution expansion
pump valve
10 15

9
Evaporator Absorber

Tev,2 Tev,1=12 C Tab,1=30 C Tab,2


(285K) (303K)

Fig. 1. Schematic of the solar-trigeneration system.

early time of the day, after the sunrise, and later, before the shows the change of the solar radiation density during
sunset, all the solar energy collected by the solar collectors the day time. The solar radiation variation density in this
is used to run the trigeneration system. This mode is called study is taken from Kalogirou (2009). The selected data
the solar mode (6:00 am to 8:00 am and 4:00 pm to 6:00 from Kalogirou (2009) is for full tracking of solar collec-
pm). At the other time of the day (high solar radiation tors to sun radiation and based on annual average condi-
time), part of the solar energy collected by the solar collec- tions. In this study, 70% of the solar energy collected
tors is used to run the trigeneration system. The remaining during the solar and storage mode is stored in the storage
part of the solar energy is stored in the thermal storage tank. This percentage is selected based on an initial simula-
tank. This mode is called the solar and storage mode tion that shows this percentage will result in a high energy
(8:00 am to 4:00 pm). At night time, the trigeneration sys- efficiency of the system during this mode.
tem runs using the energy stored in the thermal storage. There are commonly two thermal storage configurations
This mode is called the storage mode (6:00 pm to 6:00 in thermal solar energy applications: thermocline tank and
am). A representative diagram that shows these three two tanks. The fluid heated by the solar energy can be stored
modes of operation is shown in Fig. 2. Also, this diagram in a single tank and, in this case, it is called thermocline
2232 F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243

1.2 Table 1
Input data for solar-trigeneration system.

Solar and Data (Kalogirou) ORC


1
Solar radiation density (kW/m2)

storage mode Organic cycle turbine efficiency 80%


Organic cycle pump efficiency 80%
Effectiveness of the organic cycle 85%
0.8
evaporator
Solar mode
Baseline turbine inlet pressure 2000 kPa
0.6 Solar mode
Organic pump inlet temperature 365 K
Electrical generator efficiency 95%
Electrical motor efficiency 95%
0.4 Chilling cycle
Overall heat transfer coefficient of the 70 kW/K
Storage Storage desorber
0.2 mode mode Overall heat transfer coefficient of the 80 kW/K
condenser
Overall heat transfer coefficient of the 95 kW/K
0
2 4 6 8 10 12 14 16 18 20 22 24 evaporator
Overall heat transfer coefficient of the 75 kW/K
Time (hours)
absorber
Fig. 2. Solar radiation density variation versus time. Effectiveness of solution heat exchanger 70%
Solar subsystem
thermal storage tank. This tank would require using w 5.76 m (Zarza et al., 2006)
advanced technology to separate the hot fluid from the cold L 12.27 m (Zarza et al.,
fluid in the tank, Herrmann and Kearney (2002). The other 2006)
option is to use two thermal storage tanks. In this study, gr 0.765 (Zarza et al., 2006)
the two thermal storage tanks option is selected. The two Gba 0.5 kW/m2 (Kalogirou,
2009)
tanks option is widely used in parabolic trough solar collec- Gbb 0.85 kW/m2 (Kalogirou,
tor (Herrmann and Kearney, 2002; Kelly, 1994; Valenti, 2009)
1995; Pacheco and Gilbert, 1999; Kroizer, 1984; Herrmann r 0.92 (Montes et al., 2009)
et al., 2004). For parabolic trough solar collectors, two Colnc 50
tanks thermal storage is more cost-effective in the near term Colrc 7
m_ cr 8 kg/s
option based on the field experience and technical confi- Dr,ic 0.045 m
dent as compared with the single tank option (Herrmann a
During low sun radiation.
and Kearney, 2002). b
During high sun radiation.
The working fluid in the solar collectors receiver and c
Based on thermoeconomic optimization results.
storage tanks could be a commercial oil. Therminol-66
oil is the selected working fluid in this study for these com-
ponents. It is a commercial oil that could be used in both (1996). The single-effect absorption chiller model was vali-
thermal solar systems and thermal storage tanks (Harrison dated with (Herold et al., 1996).
and Randall, 1980). This oil has an operating temperature
ranges from 0 to 345 °C (Therminol, 2010). Furthermore, 3.1. Solar collectors
this oil has a low relative pressure and its pressure is not
sensitive to the increase in the temperature. In this study, The energy analysis of the PTSC are presented in this
the solar subsystem consists of two thermal storage tanks. subsection. The energy analysis of the PTSC in this section
One tank is used to store the hot oil; when the hot oil is is based on the equations presented in Kalogirou (2009),
used to provide the heat input to the ORC, it cools down Duffie and Beckman (2006). This energy analysis is vali-
and is stored in the second storage tank (cold storage tank.) dated with these two references and with the experimental
study by Dudley et al. (1994). The validation with (Dudley
et al., 1994) is presented at the end of this section. The use-
3. Thermodynamic modeling ful power from the collector is defined as
The mathematical modeling of the trigeneration systems Q_ u ¼ m_ r  ðCpr;o  T r;o  Cpr;i  T r;i Þ ð1Þ
considered are presented in this section. The equations
developed are programmed using Engineering Equation where Q_ u is the useful power and m_ r is the mass flow rate of
Solver (EES) software. The input data used in this model the oil in the receiver (pipe). The subscripts r, i, and o indi-
is given in Table 1. The energy analysis applied to the sin- cate receiver, inlet, and outlet, respectively. In addition,
gle-effect absorption chiller is similar to the approach used this power can be calculated from
by American Society of Heating Refrigerating and Air-
Conditioning Engineers Inc. (2005) and Herold et al. Q_ u ¼ Aap  F R  ðS  Ar =Aap  U L  ðT r;i  T 0 ÞÞ ð2Þ
F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243 2233

where Aap is the collector aperture area, FR is the heat re- The amount of the solar radiation that falls on the collector
moval factor, S is the absorbed radiation by the receiver, is calculated using this equation
Ar is the receiver area, and UL is solar collector overall heat
loss coefficient. The aperture area is defined as Q_ solar ¼ Aap  F R  S  Colr ð14Þ

Aap ¼ ðw  Dc;o Þ  L ð3Þ where Colr is the total number of the solar collectors rows.
The exergy of a solar collector is defined as Petela (2005)
where w is the collector width, Dc,o is the cover outer diam-
eter, and L is the collector length. The absorbed radiation _ coll ¼ Aap;t  Gb
Ex
by the receiver is defined as  
4
 1 þ ð1=3Þ  ðT 0 =T s Þ  ð4=3Þ  ðT 0 =T s Þ ð15Þ
S ¼ G b  gr ð4Þ
where Gb is the solar radiation in W/m2 and gr is the recei- where Ts is the sun temperature and equals to 6000 K (Pe-
ver efficiency. The heat removal factor is defined as tela, 2005). The exergy destruction of the solar collectors is
  
m_ r  Cpr Ar  U L  F 1 _ d;coll;solar ¼ ðEx
Ex _ 22  Ex
_ 16 þ Ex
_ coll ÞðDth;solar Þ=24 ½h ð16Þ
FR ¼  1  exp  ð5Þ
Ar  U L m_ r  Cpr
where Dth,solar is the total time in hour where the solar col-
where Cpr is the specific heat of the oil in the receiver and lectors are working and for the solar mode equals to
F1 is the collector efficiency factor and defined as
Dthsolar ¼ 24 ½h  Dthchst  Dthdhst ð17Þ
F 1 ¼ U o =U L ð6Þ
The solar collector heat loss coefficient between the ambi- whereas for the solar and storage mode, Dth,solar equals to
ent and receiver is defined as Dthsolar ¼ 24 ½h  Dthchst ð18Þ
 1
Ar where Dthdhst is the total time where there is a discharge
UL ¼ þ 1=hr;cr ð7Þ
ðhc;ca þ hr;ca Þ  Ac from the hot storage tank and Dthchst is the total time where
where hc,ca is the convection heat coefficient between the there is charging to the hot storage tank.
cover and the ambient and defined as
3.1.1. Validation of the solar collectors model
hc;ca ¼ ðNus  k air =Dc;o Þ ð8Þ The validation of the solar collectors model is shown in
where Nus, kair, and Dc,o are Nusselt number, thermal con- Table 2. The model is examined by considering the design
ductivity of the air, and outer diameter of the cover, respec- data for the black chrome receiver material case for a vac-
tively. The radiation heat coefficient is defined as uum space between the receiver and its cover, as in Dudley
   et al. (1994). In this study, the baseline simulation of the
hr;ca ¼ cv  r  ðT c þ T a Þ  T 2c þ T 2a ð9Þ solar-trigeneration system has an absorber fluid tempera-
ture of less than 200 °C above ambient temperature. There-
where T, cv, and rare the temperature, emittance, and Ste-
fore, the model is in good agreement with the experimental
fan–Boltzmann constant, respectively. The subscripts c and
results, as demonstrated in this table. The deviation in the
a indicate the cover and ambient, respectively. The radia-
calculations as compared to the experimental results is
tion heat coefficient between the cover and receiver is
 1 attributed to the approximation used to calculate the heat
0
r  ðT c þ T r;av Þ  T 2c þ T 2r;av loss coefficients.
hr;cr ¼ @ A ð10Þ
1=r þ Ar =Ac  ð1=cv  1Þ 3.2. Thermal storage tanks

The overall heat coefficient is defined as The modeling of the thermal storage tanks is presented
  1 in this subsection. The modeling considers charging, stor-
Dr;o Dr;o
U o ¼ 1=U L þ þ  lnðDr;o =Dr;i Þ ing, and discharging the fluid from both tanks.
hc;r;in  Dr;i 2  kr
ð11Þ
Table 2
where hc,r,in is defined as Validation of the current model as compared with Dudley et al. (1994):
heat losses change with the average temperature above the ambient of the
Nusr  k r
hc;r;in ¼ ð12Þ fluid inside the absorber.
Dr;i
Taam (K) Heat loss (Model) Heat loss (Exp. Dudley et al. (1994))
where the subscripts r indicates the receiver. The cover 100.6 8.7 10.6
average temperature can be calculated using this equation 149.1 19.3 19.3
196.7 34.2 30.6
hr;cr  T r;av þ Ac =Ar  ðhc;ca þ hr;ca Þ  T 0 245.8 53.0 45.4
Tc ¼ ð13Þ
hr;cr þ Ac =Ar  ðhc;ca þ hr;ca Þ 293.3 75.5 62.9
2234 F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243

3.2.1. Hot fluid tank: charging 3.3. Overall analysis of the solar-trigeneration system
The rate in which the heat enters the storage tank is
The equations used to analyze the trigeneration plant
Q_ hst ¼ Q_ 23  Q_ l;hst ð19Þ
based on the solar subsystem are presented in this subsec-
where the subscripts hst and l, hst indicate hot storage tank tion. The input energy to the plant is defined as
and lost heat from the heat storage tank, respectively. The
lost heat from the storage tank is Q_ in ¼ Q_ solar ¼ Q_ u ð31Þ

Q_ l;hst ¼ UAh  ðT hst  T 0 Þ ð20Þ where Q_ solar is the total heat collected by the solar collec-
tors. The net electrical power is defined as
where U is the overall heat transfer coefficient. The total
heat lost from the hot storage tank is W_ net ¼ gg  W_ ot  W_ op =gmotor  W_ sp =gmotor
X
Qhst ¼ Q_ hst  Dth ð21Þ  W_ sol;p =gmotor  W_ st1;p =gmotor  W_ st2;p =gmotor ð32Þ
where Dth is the total time of charging. The temperature in The exergetic efficiency of net electrical power is defined as
the storage tank can be found from
P gex;el ¼ W_ net =Ex
_ coll ð33Þ
Qhst
T hst ¼ ð22Þ
Cphst  M hst The exergetic efficiency of the heating cogeneration is de-
fined as
where Mhst is the total oil mass in the hot storage tank.
W_ net þ m_ hp  ðexhp;1  exhp;2 Þ
gex;cog;h ¼ ð34Þ
3.2.2. Hot fluid tank: storing _ coll
Ex
The change in the temperature of the tank with time can
be calculated using where exhp,1 and exhp,1 are the exergy of the stream at the
inlet and exit of the heating process heat exchanger, respec-
Dth tively. The exergetic efficiency of the cooling cogeneration

hst ¼ T hst þ  ðUAh  ðT hst  T 0 ÞÞ ð23Þ
M hst  Cphst is defined as
The total heat lost during storage is W_ net þ m_ ev  ðexev;1  exev;2 Þ
gex;cog;c ¼ ð35Þ
Qhst;tlost ¼ ðM hst  Cphst  DT hst Þ ð24Þ _ coll
Ex
where DThst is the change in the temperature during storing where exev,1 and exev,1 are the exergy of the stream at the
in the hot tank and equals to inlet and exit of the evaporator of the single-effect absorp-
tion chiller, respectively. The exergetic efficiency of the tri-
DT hst ¼ T hst  T þ
hst ð25Þ generation is defined as
W_ net þ m_ hp  ðexhp;1  exhp;2 Þ þ m_ ev  ðexev;1  exev;2 Þ
3.2.3. Hot fluid tank: discharging gex;tri ¼
_ coll
Ex
The total heat at discharging is
X ð36Þ
Q24 ¼ Qhst  Qhst;tlost ð26Þ
A discussion on various energy and exergy efficiency defini-
tions for combined cycles can be found in Khan (2006).
3.2.4. Cold fluid tank: storing The pinch point temperature for evaporator-a is defined
The total amount of heat storing in the cold tank is as Li and Priddy (1985)
Qcst;tlost ¼ ðM cst  Cpcst  DT cst Þ ð27Þ T pp ¼ T 27  T 2a ð37Þ
where the subscript cst indicates cold storage tank. DTcst is and for evaporator-b is
the change of the temperature in the cold storage tank and T pp ¼ T 18  T 2b ð38Þ
equals to
DT cst ¼ T cst  T þ
cst ð28Þ 4. Results and discussion
where Tcst+ is equal to
In this section, the results of exergy modeling of the tri-
Dtc

cst ¼ T cst þ  ðUAcv  ðT cst  T 0 ÞÞ ð29Þ generation system using solar energy are presented and dis-
M cst  Cpcst cussed. In this study, the effects of the ORC evaporator
pinch point temperature, pump inlet temperature, and tur-
3.2.5. Cold fluid tank: discharging bine inlet pressure are examined. The range of the ORC
The heat rate discharges from the cold tank is evaporator pinch point temperature (Li and Priddy,
X 1985) and pump inlet temperature (Herold et al., 1996;
Q28 ¼ Qcst  Qcst;tlost ð30Þ Thermax Inc, 2010) considered here are taken from the
F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243 2235

literature. In the calculations, the mass flow rate of the 4.1. Effect of the ORC evaporator pinch point temperature
organic fluid is kept constant. For the solar and storage
subsystems, the mass flow rates of the Therminol-66 are The effect of the pinch point temperature on the exerget-
kept constant for each operating mode. The thermody- ic performance of the solar trigeneration system is exam-
namic properties of the stations for the baseline case for ined through Figs. 3–6. The effect of the ORC evaporator
all the three modes are shown in Tables 3–5. pinch point variation on the exergy efficiency is shown in

Table 3
Thermodynamic properties of the stations for the solar mode.
State no. Fluid m_ ðkg=sÞ T (K) P (kPa) Pv (kPa)a h (kJ/kg) ex (kJ/kg)
1 n-octane 7 365.0 35.77 157.5 15.6
2 n-octane 7 365.9 2000.00 161.3 18.8
3 n-octane 7 549.0 2000.00 891.8 294.0
4 n-octane 7 498.7 35.77 782 167.7
5 n-octane 7 365.0 35.77 185.9 20.8
6 Water 0.067 336.5 5.44 2618 78.3
7 Water 0.067 307.5 5.44 144 0.5
8 Water 0.067 278.2 0.87 144 6.0
9 Water 0.067 278.2 0.87 2509.7 176.0
10 LiBr–water 0.34 303.4 0.87 67.3 11.1
11 LiBr–water 0.34 303.4 5.44 67.3 11.1
12 LiBr–water 0.34 332.2 5.44 128.3 71.8
13 LiBr–water 0.273 365.0 5.44 244.5 117.3
14 LiBr–water 0.273 321.9 5.44 168.5 41.6
15 LiBr–water 0.273 329.0 0.87 168.5 41.6
16 therminol-66 7.1 600.0 54.1 1601.7 689.8
17 therminol-66 7.1 600.0 54.1 1601.7 689.8
18 therminol-66 7.098 405.0 0.200 788.8 158.5
19 therminol-66 7.1 405.0 0.200 788.8 158.5
22 therminol-66 7.1 405.0 0.200 788.8 158.5
a
The data available in the literature and that is used by EES can calculate only the vapor pressure for therminol-66.

Table 4
Thermodynamic properties of the stations for the solar and storage mode.
State no. Fluid m_ ðkg=sÞ T (K) P (kPa) Pv (kPa)a h (kJ/kg) ex (kJ/kg)
1 n-octane 7 365.0 35.77 157.5 15.6
2 n-octane 7 365.9 2000.00 161.3 18.8
3 n-octane 7 549.0 2000.00 749.1 228.0
4 n-octane 7 447.5 35.77 658.5 122.0
5 n-octane 7 365.0 35.77 185.9 20.8
6 Water 0.067 336.5 5.44 2618 78.3
7 Water 0.067 307.5 5.44 144 0.5
8 Water 0.067 278.2 0.87 144 -6.0
9 Water 0.067 278.2 0.87 2509.7 -176.0
10 LiBr–water 0.34 303.4 0.87 67.3 11.1
11 LiBr–water 0.34 303.4 5.44 67.3 11.1
12 LiBr–water 0.34 332.2 5.44 128.3 71.8
13 LiBr–water 0.273 365.0 5.44 244.5 117.3
14 LiBr–water 0.273 321.9 5.44 168.5 41.6
15 LiBr–water 0.273 329.0 0.87 168.5 41.6
16 therminol-66 13.9 600.0 54.1 1601.7 689.8
17 therminol-66 4.2 600.0 54.1 1601.7 689.8
18 therminol-66 4.2 405.0 0.200 788.8 158.5
19 therminol-66 4.2 405.0 0.200 788.8 158.5
20 therminol-66 9.7 600.0 54.1 1601.7 689.8
21 therminol-66 9.7 444.4 0.868 929.1 241.6
22 therminol-66 13.9 433.1 0.580 887.9 216.7
23 therminol-66 10 467.0 27.0 1442.1 578.1
28 therminol-66 10 404.37 0.195 786.6 157.3
29 therminol-66 10 404.37 0.195 786.6 157.3
30 therminol-66 10 404.37 0.195 786.6 157.3
a
The data available in the literature and that is used by EES can calculate only the vapor pressure for therminol-66.
2236 F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243

Table 5
Thermodynamic properties of the stations for the storage mode.
State no. Fluid m_ ðkg=sÞ T (K) P (kPa) Pv (kPa)a h (kJ/kg) ex (kJ/kg)
1 n-octane 7 365.0 35.77 157.5 15.6
2 n-octane 7 365.9 2000.00 161.3 18.8
3 n-octane 7 549.0 2000.00 676.1 194.6
4 n-octane 7 421.0 35.77 598.6 103.3
5 n-octane 7 365.0 35.77 185.9 20.8
6 Water 0.067 336.5 5.44 2618 78.3
7 Water 0.067 307.5 5.44 144 0.5
8 Water 0.067 278.2 0.87 144 6.0
9 Water 0.067 278.2 0.87 2509.7 176.0
10 LiBr–water 0.34 303.4 0.87 67.3 11.1
11 LiBr–water 0.34 303.4 5.44 67.3 11.1
12 LiBr–water 0.34 332.2 5.44 128.3 71.8
13 LiBr–water 0.273 365.0 5.44 244.5 117.3
14 LiBr–water 0.273 321.9 5.44 168.5 41.6
15 LiBr–water 0.273 329.0 0.87 168.5 41.6
24 therminol-66 6.7 571.6 30.2 1466 594.9
25 therminol-66 6.7 571.6 30.2 1466 594.9
26 therminol-66 6.7 571.6 30.2 1466 594.9
27 therminol-66 6.7 405 0.200 788.8 158.5
a
The data available in the literature and that is used by EES can calculate only the vapor pressure for therminol-66.

Fig. 3. Effect of the ORC evaporator pinch point temperature on the exergy efficiency at P3 = 2000 kPa, T1 = 365 K.

Fig. 3. This figure shows that the exergy efficiency is low. 15% at 60 K. Similarly, the trigeneration-exergy efficiency
As reported in the literature, the exergy efficiency of a solar decreases from almost 20% at 10 K to 16.5% at 60 K. This
system is considerably less than the energy efficiency decrease is due to the decrease in the amount of the heat
(Petela, 2005). This decrease is attributed to the large tem- input to the ORC as the pinch point temperature increases.
perature difference between the sun temperature and fluid Now, consider the solar and storage mode, as shown in
temperature in the collectors (Petela, 2005). Fig. 3 shows this figure. This figure illustrates that the electrical and
that for the solar mode the electrical-exergy efficiency is cooling-cogeneration efficiencies are around 3% and 3.5%,
between 6% and 6.6% and the cooling-cogeneration exergy respectively. The drop in the exergy efficiency of this
efficiency is between 6.1% and 6.7%. This small improve- mode, as compare to the solar mode, is because part of
ment in efficiency is attributed to the small size of the sin- the solar energy collected during this mode is stored in
gle-effect absorption chiller as compared to the electrical the storage tank, as discussed in Section 2. Therefore, the
system. This chiller was selected from the industry (Thermax exergy efficiency for this mode is lower than the solar
Inc, 2010). On the other hand, the heating-cogeneration mode. Alternatively, using heating cogeneration or trigen-
exergy efficiency decreases from around 19% at 10 K to eration, this efficiency increases to around 7.5% or 8%,
F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243 2237

700
1400

. 600
1200
.Ex d, hp
Exergy destruction rate (kW)

Exergy destruction rate (kW)


Ex .
. d, coll, solar 500 Ex d, hst
1000 Ex d, ot .
.
Ex d, ev, b .Ex d, hp
400 Ex
. d, ot
800
Ex d, ev, a

300
600

400 200

200 100

0 0
10 20 30 40 50 60 10 20 30 40 50 60
Tpp (K) Tpp (K)

Fig. 4. Effect of the ORC evaporator pinch point temperature on the Fig. 6. Effect of the ORC evaporator pinch point temperature on the
exergy destruction rate at P3 = 2000 kPa, T1 = 365 K, for solar mode. exergy destruction rate at P3 = 2000 kPa, T1 = 365 K, for storage mode.

5000
reveals that most of the destructed exergy is destroyed by
. the solar collectors. The exergy destructed by this compo-
Ex
. d, hst nent is around 1400 kW. This figure shows that the exergy
Ex
. d, hp destructed by the solar collectors increases marginally as
4000
Exergy destruction rate (kW)

.Ex d, coll, solar, charging the pinch point temperature increases. This increment is
.Ex d, ot
Ex d, ev, b because of the increase in the exergy difference between
3000 the inlet and exit of the solar collectors as the pinch point
temperature increases. Similarly, the destructed exergy by
evaporator-b increases as the pinch point temperature
2000 increases. It increases from 450 kW at 10 K to 550 kW at
60 K. This increase in the destructed exergy is owing to
the increase in exergy difference between the inlets and exits
1000 of evaporator-b. Also, this figure illustrates that the des-
tructed exergy by the heating-process heat exchanger
decreases as the pinch point temperature increases. It
0 decreases from 350 kW at 10 K to 200 kW at 60 K. This
10 20 30 40 50 60
Tpp (K)
decrement is due to the decrease in the available exergy
in the ORC as the pinch point increases and, thus, less exer-
Fig. 5. Effect of the ORC evaporator pinch point temperature on the gy is available for the heating process. In addition, this fig-
exergy destruction rate at P3 = 2000 kPa, T1 = 365 K, for solar and ure shows that as the pinch point temperature increases,
storage mode. the destructed exergy by the turbine decreases. This des-
tructed exergy decreases from 120 kW at 10 K to 115 kW
respectively. Considering the storage mode in this figure, it at 60 K. Again, this decrease in the destructed exergy by
can be observed that for this mode the exergy efficiencies the turbine is due to the decrease in the available exergy
decrease further more. This decrement is because there is in the ORC as the pinch point temperature increases, as
less energy input from the storage tank, as compared to well as to the decrease in the turbine power output.
the energy inputs from the other two modes. The electrical Fig. 5 illustrates the solar and storage mode. This figure
and cooling-cogeneration exergy efficiencies are around shows that the destructed exergy of the solar collectors
2.5% and the heating-cogeneration and trigeneration exer- increases significantly as compared to the solar mode. This
gy efficiencies are around 6%. increase is mainly due to the increase in the solar radiation
The effect of the ORC evaporator pinch point on the during this mode. The definition of the exergy of the solar
exergy destruction rate is shown in Figs. 4–6. Only the collectors indicates that it increases linearly as the solar
components that have high exergy destruction rates are radiation increases as shown in Eq. (15). The destructed
presented. Fig. 4 illustrates the exergy destruction rate of exergy rate by the solar collectors is around 4700 kW. On
the heating-process heat exchanger, solar collectors, tur- the other hand, the other components destroy considerably
bine, and evaporator-b for the solar mode. This figure less exergy. The destructed exergy by evaporator-b is
2238 F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243

Fig. 7. Effect of the ORC pump inlet temperature on the exergy efficiency at P3 = 2000 kPa, Tpp = 40 K.

around 500 kW. Fig. 6 shows the storage mode case. It can temperature increases, the electrical-exergy efficiency drops
be observed that the significant source of the destructed from 7% at 345 K to 5% at 380 K. This drop is due to the
exergy is evaporator-a. The destructed exergy by this com- decrease in the electrical power as this temperature
ponent is around 600 kW. One the other hand, the des- increases. Using cooling cogeneration, the exergy efficiency
tructed exergies by the turbine, heating-process heat improves by less than 0.5%. However, using heating cogen-
exchanger, and hot storage tank are around 100 kW, eration or trigeneration, the exergy efficiency improves sig-
70 kW, and 30 kW, respectively. nificantly to 18% or 18.5%, respectively. Considering the
solar and storage mode, it is shown that the electrical, cool-
4.2. Effect of the ORC pump inlet temperature ing-cogeneration, heating-cogeneration, and trigeneration
efficiencies are around 3%, 3.5%, 7%, and 7.5%, respec-
The effect of the ORC pump inlet temperature variation tively. Considering the storage mode, it is shown that the
on the plant’s exergetic performance is presented in Figs. 7– electrical, cooling-cogeneration, heating-cogeneration,
10. The effect of the ORC pump inlet temperature on the and trigeneration efficiencies are around 2.5%, 3%, 6%,
exergy efficiency is presented in Fig. 7. Considering the and 6.5%, respectively. It can be noticed from this figure
solar mode as shown in this figure, it is shown that as this that the exergy efficiencies for the solar mode are the

5000

1400 .
4000 .Ex d, hst
Exergy destruction rate (kW)

Ex
. d, hp
1200 .
Exergy destruction rate (kW)

Ex d, coll, solar
. .Ex d, coll, solar, charging
Ex
. d, hp .Ex d, ot
1000 3000 Ex d, ev, b
Ex
. d, ot
Ex d, ev, b
800

2000
600

400 1000

200

0
0 345 350 355 360 365 370 375 380
345 350 355 360 365 370 375 380 T1 (K)
T1 (K)
Fig. 9. Effect of the ORC pump inlet temperature on the exergy
Fig. 8. Effect of the ORC pump inlet temperature on the exergy destruction rate at P3 = 2000 kPa, Tpp = 40 K, for solar and storage
destruction rate at P3 = 2000 kPa, Tpp = 40 K, for solar mode. mode.
F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243 2239

700
1400

600 .
1200 Ex

Exergy destruction rate (kW)


. d, coll, solar
Exergy destruction rate (kW)

Ex
. d, hp
500 Ex
. d, ot
1000
Ex d, ev, b
Ex d, hst
400 Ex d, ot
800
Ex d, ev, a

300 600

200 400

100 200

0
0 2000 3000 4000 5000 6000 7000
350 360 370 380
T1 (K) P3 (kPa)

Fig. 10. Effect of the ORC pump inlet temperature on the exergy Fig. 12. Effect of the turbine inlet pressure on the exergy destruction rate
destruction rate at P3 = 2000 kPa, Tpp = 40 K, for storage mode. at T1 = 365 K, Tpp = 40 K, for solar mode.

highest while for the storage mode are the lowest. This of the ORC pump inlet temperature, T1, and T18. There-
difference is because there is more energy input to the fore, as T1 increases, T18 increases and, thus, the inlet tem-
ORC for the solar mode and less for the storage mode. perature to the solar collectors increases. This figure shows
The effect of the ORC pump inlet temperature on the that as T1 increases, the exergy destruction rate of evapora-
exergy destruction rate is presented in Figs. 8–10. These fig- tor-b decreases marginally. This decrease is due to the
ures present only the components that have high exergy decrease in the available exergy in evaporator-b as T1
destruction rates. Fig. 8 presents the solar mode. This fig- increases. The exergy destruction rate of evaporator-b is
ure shows the exergy destruction rate of the solar collec- around 550 kW. The exergy destructed by the heating-pro-
tors, heating-process, turbine, and evaporator-b. It can cess heat exchanger increases as T1 increases. This increase
be noticed that the solar collectors have the highest exergy is owing to the increase in the available heat energy and the
destruction rate, around 1400 kW. The exergy destruction decrease in the heating-cogeneration exergy efficiency. The
rate of the solar collectors increases marginally as the exergy destruction rate increases from 100 kW at 345 K to
ORC pump inlet temperature increases. This increase is 360 kW at 380 K. The exergy destruction rate of the tur-
attributed to the increase in the temperature at the exit of bine is around 120 kW. The exergy destruction rate of
evaporator-b, T18, as the ORC pump inlet temperature the turbine decreases as T1 increases. This decrement is
increases. That is, the pinch point temperature is a function owing to the decrease in the power produced by the turbine

Fig. 11. Effect of the turbine inlet pressure on the exergy efficiency at T1 = 365 K, Tpp = 40 K, for solar mode.
2240 F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243

as this temperature increases. Fig. 9 presents the solar and 5000


storage mode. This figure reveals that the destructed exergy
.
rate by the solar collectors for this mode are significantly
.Ex d, hst

Exergy destruction rate (kW)


high, around 4800 kW. The reason for this was discussed 4000
Ex
. d, hp
above. This figure shows that as the ORC pump inlet tem- Ex
. d, coll, solar, charging
perature increases, the destructed exergy by the solar col- Ex
. d, ot
lectors increases. It increases from 4700 kW at 348 K to 3000 Ex d, ev, b
4800 kW at 380 K. The exergy destruction rate of evapora-
tor-b decreases from 530 kW to 490 as this temperature
2000
increases. The exergy destruction rate of the turbine
decreases from 125 kW to 90 kW as this temperature
increases. The exergy destruction rate of the heating-
1000
process heat exchanger increases from almost zero to
220 kW as this temperature increases. The exergy destruc-
tion rate of the hot storage tank decreases from 22 kW to
0
20 kW as this temperature increases. Fig. 10 presents the 2000 3000 4000 5000 6000 7000
storage mode. This figure illustrates that as the ORC pump P3 (kPa)
inlet temperature increases, the exergy destruction rate by
evaporator-a decreases. It decreases from 650 kW at Fig. 13. Effect of the turbine inlet pressure on the exergy destruction rate
at T1 = 365 K, Tpp = 40 K, for solar and storage mode.
345 K to 550 kW at 380 K. The exergy destruction rate
by the turbine decreases from 120 kW to 80 kW as this
temperature increases. The exergy destruction rate by the
heating-process heat exchanger increases from almost zero 700

to 150 kW as this temperature increases. The exergy


destruction rate of the hot storage tank is almost constant 600
Exergy destruction rate (kW)

and around 30 kW.


500 .
.Ex d, hst
4.3. Effect of the turbine inlet pressure
.Ex d, hp
400 Ex
. d, ot
The effect of the turbine inlet pressure variation on the Ex d, ev, a
plant’s exergetic performance is presented in Figs. 7–10. 300
The effect of the turbine inlet pressure on the exergy effi-
ciency is illustrated in Fig. 11. It can be observed that the 200
effect of this pressure is insignificant on the exergy effi-
ciency. This insignificant change is attributed to the insig- 100
nificant change in the powers and temperatures as this
pressure changes. Considering the solar mode in this figure, 0
the exergy efficiencies for the electrical, cooling cogenera- 2000 3000 4000 5000 6000 7000

tion, heating cogeneration, and trigeneration are around P3 (kPa)


6%, 6.5%, 17.5%, and 18%, respectively. Considering the
Fig. 14. Effect of the turbine inlet pressure on the exergy destruction rate
solar and storage mode as shown in this figure, the exergy at T1 = 365 K, Tpp = 40 K, for storage mode.
efficiencies for the electrical, cooling cogeneration, heating
cogeneration, and trigeneration are around 3%, 3.5%, 7%,
and 7.5%, respectively. Considering the storage mode in rates of the solar collectors, evaporator-b, heating-process
this figure, the exergy efficiencies for the electrical, cooling heat exchanger, and turbine are around 1400 kW,
cogeneration, heating cogeneration, and trigeneration are 520 kW, 260 kW, and 130 kW, respectively. Fig. 13 illus-
around 2.5%, 3%, 6%, and 6.5%, respectively. It can be trates the solar and storage mode. This figure shows that
observed that the efficiencies for the solar mode are higher there is a considerable increase in the exergy destructed
than in the other two modes. The reason for that was dis- by the solar collectors for this mode, as compared to the
cussed above. solar mode. This increase is owing to the increase in the
The effect of the turbine inlet pressure on the exergy solar energy radiation during this mode, as mentioned
destruction rate is shown in Figs. 12–14. Fig. 12 presents above. The variation of the exergy destruction rate is
the solar mode. It can be noticed that effect of varying this within 15 kW. The exergy destruction rates of the solar col-
pressure on the exergy destruction ratio is insignificant lectors, evaporator-b, heating-process heat exchanger, tur-
since the change in the exergy streams is negligible. The bine, and hot storage tank are around 4800 kW, 500 kW,
variation in the exergy destruction rate with the change 115 kW, 110 kW, and 21 kW, respectively. Fig. 14 presents
in this pressure is within 30 kW. The destructed exergy the storage mode. This figure illustrates that the change in
F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243 2241

exchanger, turbine, and hot storage tank are around


585 kW, 70 kW, 100 kW, and 30 kW, respectively.

4.4. Overall exergy destruction

The overall exergy destruction rate and its percentage


for the solar trigeneration system is shown in Fig. 15.
The baseline values considered here are 40 K for the
ORC evaporator pinch point temperature, 365 K for the
pump inlet temperature, and 2000 kPa for the turbine inlet
pressure. It should be noticed that each sector in these three
figures presents the exergy destruction rate value and its
percentage of the total exergy destructed and not the avail-
able exergy in the system. Fig. 15a illustrates the solar
mode. This figure shows that the major sources of the exer-
gy destruction are the solar collectors and evaporator-b.
The solar collectors destroy 1400 kW of exergy (59%) and
evaporator-b destroys 530 kW of exergy (23%). In contrast,
the destructed exergy by the heating-process heat exchan-
ger and turbine are lower. The exergy destructed exergy
by the heating-process heat exchanger is 260 kW (11%)
and the exergy destructed by the turbine is 115 kW (5%).
The other components of the system destroy 38 kW of
exergy (2%). Fig. 15b illustrates the solar and storage
mode. This figure demonstrates that most of the destructed
exergy is destroyed by the solar collectors, which is around
4750 kW (86%). Conversely, the other components have
less destruction of exergy. The exergy destructed by evapo-
rator-b, turbine, heating process, and hot storage tank are
510 kW (9%), 110 kW (2%), 115 kW (2%), and 21 kW,
respectively. The other components of the system destroy
42 kW (1%). Fig. 15c illustrates the storage mode. This fig-
ure shows that during this mode the significant source of
exergy destruction is evaporator-a, which destroys
590 kW of exergy (71%). The other components that have
a relatively high destruction rate of exergy are the turbine
(96 kW, 12%), heating process (70 kW, 8%), and hot stor-
age tank (30 kW, 4%). The remaining components of the
system destroy 42 kW (5%). The above three figures dem-
onstrate that the most significant components that have
high destruction rates are the solar collectors and the ORC
evaporators. Therefore, in designing a solar-trigeneration
system, the most significant components that require
careful design and selection are the solar collectors and
ORC evaporators.

5. Conclusions

In this study, the exergy modeling of the solar-trigeneration


system is conducted considering three modes of operation:
solar, solar and storage, and storage modes. The exergy
modeling of this system is examined by varying the ORC
Fig. 15. Overall exergy destruction rates and percentages (P3 = 2000 K, evaporator pinch point temperature, ORC pump inlet
T1 = 365 K, and Tpp = 40 K). temperature, and turbine inlet pressure. Moreover, overall
the exergy destruction rate is within 15 kW. The exergy exergy destruction modeling is conducted under the
destruction rates of evaporator-a, heating-process heat selected baseline operating values that are taken from
2242 F.A. Al-Sulaiman et al. / Solar Energy 85 (2011) 2228–2243

literature. The following remarks can be concluded from Harrison, T.D., Randall, R.A., 1980. Thermal storage experience at the
this study. msstf and plans for the future. Thermal Energy Storage: Fourth
Annual Review Meeting, NASA CP-2125, pp. 125–130.
Herold, K.E., Radermacher, R., Klein, S.A., 1996. Absorption Chillers
 The solar mode has the highest exergy efficiency as com- and Heat Pumps. CRC Press.
pared with the other two modes. The maximum electri- Herrmann, U., Kearney, D.W., 2002. Survey of thermal energy storage for
cal-exergy efficiency for the solar mode is 7%, for the parabolic trough power plants. Journal of Solar Energy Engineering,
solar and storage mode is 3.5%, and for the storage ASME Transactions 124, 145–152.
Herrmann, U., Kelly, B., Price, H., 2004. Two-tank molten salt
mode is 3%. In contrast, when trigeneration is used, storage for parabolic trough solar power plants. Energy 29 (5-6),
the exergy efficiency increases noticeably. The maximum 883–893.
trigeneration-exergy efficiency for the solar mode is 20%, Jing, Li, Gang, Pei, Jie, Ji, 2010. Optimization of low temperature solar
for solar and storage mode is 8%, and for the storage thermal electric generation with organic rankine cycle in different
mode is 7%. areas. Applied Energy 87 (11), 3355–3365.
Kalogirou, Soteris, 2009. Solar energy engineering: processes and systems.
 The main sources of exergy destruction rate are the solar Elsevier.
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tial to reduce the exergy destructed by them and, thus, desalination system. the Chalki island case. Renewable Energy 36 (2),
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Kelly, Bruce D., Lessley, Robert L., 1994. Investigation of commercial
 The effect of the turbine inlet pressure variation is insig- central receiver thermal storage and steam generator issues. In: ASME-
nificant on the exergetic performance. That is, the ORC JSES-JSME International Solar Energy Conference, San Francisco,
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Acknowledgements
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