Names: Dumalan Melchior 07/02/2021

Gamboa Jayson
Guiang Alled
Villanueva Michael
Guimawa Roselyn
Quiambao Ashley

12-Alcala THERMOCHEMISTRY_integration

Solve the following worded problems: PROBLEM SOLVING RUBRICS:

5 pts – complete and correct solution and final answer

4 pts – incomplete solution but correct final answer
3 pts – incomplete solution and final answer
2 pts – incorrect solution but correct final answer
1 pt – incorrect solution and final answer
0 pt – no attempt to answer

1. What would be its change in enthalpy?

HO Values: S Values:
MgO = -601.7 MgO = 26.94 J/K mol
HF= -271.1 HF= 173.779 J/K mol
MgF2= -1123.4 MgF2= 57.24 J/K mol
H2O = -285.83 H2O = 69.91 J/K mol

𝐌𝐠𝐎 + 𝐇𝐅 → 𝐌𝐠𝐅𝟐 + 𝐇𝟐 𝐎

Balancing the Equation (𝟏)𝐌𝐠𝐎 + (𝟐)𝐇𝐅 → (𝟏)𝐌𝐠𝐅𝟐 + (𝟏)𝐇𝟐 𝐎

Identifying product reactant and product: Reactant → product

Compound ∆𝑯 ∆𝑺
MgO -607.7 kJ/mol 26.94 J/K mol
HF -271.1kJ/mol 173.779 J/K mol
MgF2 -1123.4kJ/mol 57.24 J/K mol
H2O -285.83kJ/mol 69.91 J/K mol
𝐚. 𝐄𝐧𝐭𝐚𝐥𝐩𝐡𝐲 ∆𝑯 = ∑ 𝐧 (𝐩𝐫𝐨𝐝𝐮𝐜𝐭) − ∑ 𝐧 (𝐫𝐞𝐚𝐜𝐭𝐚𝐧𝐭)

[𝟏𝐌𝐠𝐅𝟐 + 𝟏𝐇𝟐 𝐎] − [𝟏𝐌𝐠𝐎 + 𝟐𝐇𝐅]

𝐤𝐉 𝐤𝐉 𝐤𝐉 𝐤𝐉
= [(−𝟏𝟏𝟐𝟑. 𝟒 ) + (−𝟐𝟖𝟓. 𝟖𝟑 )] – [(−𝟔𝟎𝟕. 𝟕 ) + 𝟐 (– 𝟐𝟕𝟏. 𝟏 )]
𝐦𝐨𝐥 𝐦𝐨𝐥 𝐦𝐨𝐥 𝐦𝐨𝐥
𝐤𝐉 𝐤𝐉
= (−𝟏𝟒𝟎𝟗. 𝟐𝟑 ) − (−𝟏𝟏𝟒𝟑. 𝟗 )
𝐦𝐨𝐥 𝐦𝐨𝐥
=
−𝟐𝟔𝟓. 𝟑𝟑 𝐤𝐉/𝐦𝐨𝐥

b. 𝐄𝐧𝐭𝐫𝐨𝐩𝐡𝐲 ∆𝑺 = ∑ (𝐩𝐫𝐨𝐝𝐮𝐜𝐭) − ∑ 𝐧 (𝐫𝐞𝐚𝐜𝐭𝐚𝐧𝐭)

[𝟏𝐌𝐠𝐅𝟐 + 𝟏𝐇𝟐 𝐎] − [𝟏𝐌𝐠𝐎 + 𝟐𝐇𝐅]

𝐉 𝐉 𝐉 𝐉
= [(𝟓𝟕. 𝟐𝟒 ) + (𝟔𝟗. 𝟗𝟏 )] – [(𝟐𝟔. 𝟗𝟒 ) + 𝟐 (𝟏𝟕𝟑. 𝟕𝟕𝟗 )]
𝐊 𝐦𝐨𝐥 𝐊 𝐦𝐨𝐥 𝐊 𝐦𝐨𝐥 𝐊 𝐦𝐨𝐥
𝐉 𝐉
= (𝟏𝟐𝟕. 𝟏𝟓 ) − (𝟑𝟕𝟒. 𝟒𝟗𝟖 )
𝐊 𝐦𝐨𝐥 𝐊 𝐦𝐨𝐥
=
-247.35 J/K mol

c. ∆𝑮 = ∆𝑯 − 𝐓 ∆𝑺

Convertion

−𝟐𝟒𝟕. 𝟑𝟓 𝐉 𝟏 𝐤𝐉 𝐤𝐉
𝐱 = −𝟎. 𝟐𝟓
𝐊 𝐦𝐨𝐥 𝟏𝟎𝟎𝟎 𝐉 𝐤𝐦𝐨𝐥

𝐓 = 𝟐𝟓𝟎℃
𝐓 = 𝟐𝟓𝟎 + 𝟐𝟕𝟑. 𝟏𝟓
= 𝟓𝟐𝟑. 𝟏𝟓 𝐊

∆𝑯 − 𝐓 ∆𝑺
𝐤𝐉 𝐤𝐉
= −𝟐𝟔𝟓. 𝟑𝟑 − [(𝟓𝟐𝟑. 𝟏𝟓 𝐊) (−𝟎. 𝟐𝟓 )]
𝐦𝐨𝐥 𝐤𝐦𝐨𝐥
𝐤𝐉
= −𝟐𝟔𝟓. 𝟑𝟑 − (−𝟏𝟑𝟎. 𝟕𝟖𝟕𝟓)
𝐦𝐨𝐥
=

-134.54 kJ/mol
2. What would be the internal heat change value if an engine releases 14kJ of heat and does 10
kJ of work ?
-14kJ=q
-10kJ=w

∆𝐄 = 𝐪 + 𝐰
∆𝐄 = −𝟏𝟒𝐤𝐉 + (−𝟏𝟎𝐤𝐉)
=
-24 kJ

3. What would be value of the work done if the internal heat change value ∆𝐄 = 𝟐𝟓𝐤𝐉 in an
engine that releases 14kJ of heat?
25kJ= ∆𝐄
-14kJ=q
∆𝐄 = 𝐪 + 𝐰
𝐰 = ∆𝐄 − 𝐪
𝐰 = 𝟐𝟓𝐤𝐉 − (−𝟏𝟒𝐤𝐉)
=
39 kJ