Final JEE-Main Exam July, 2022/26-07-2022/Morning Session

FINAL JEE–MAIN EXAMINATION – JULY, 2022

(Held On Tuesday 26th July, 2022) TIME : 9 : 00 AM to 12 : 00 NOON

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A 2. Match List - I with List - II.
List –I List – II
1. Match List - I with List - II.
(Processes/Reactions) (Catalyst)
List - I List – II (A) 2SO2(g)+O2(g)2SO3(g) (I) Fe(s)
(Compound) (Shape) (B) 4NH3(g)+5O2(g)4NO(g)+6H2O(g) (II) Pt(s)-Rh(s)
(A) BrF5 (I) bent (C) N2(g)+3H2(g)2NH3(g) (III) V2O5
(B) [CrF6]3– (II) square pyramidal (D) Vegetable oil(l)+H2Vegetable ghee(s) (IV) Ni(s)
(C) O3 (III) trigonal bipyramidal Choose the correct answer from the options given
(D) PCl5 (IV) octahedral below :

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Choose the correct answer from the options given (A) (A) - (III), (B) - (I), (C) - (II), (D) - (IV)
below : (B) (A) - (III), (B) - (II), (C) - (I), (D) - (IV)
(A) (A) – (I), (B) - (II), (C) - (III), (D) - (IV) (C) (A) - (IV), (B) - (III), (C) - (I), (D) - (II)
(B) (A) - (IV), (B) - (III), (C) - (II), (D) - (I) (D) (A) - (IV), (B) - (II), (C) - (III), (D) - (I)
(C) (A) - (II), (B) - (IV), (C) - (I), (D) - (III) Official Ans. by NTA (B)
(D) (A) - (III), (B) - (IV), (C) - (II), (D) - (I) Allen Ans. (B)
Official Ans. by NTA (C) V2 O5
Sol. 2SO 2  g   O 2  g    2SO 3  g  :
Allen Ans. (C)
contact process
F
 
Pt s  Rh s
F F 4NH3  g   5O 2  g   4NO  g   6H 2 O  g  :
Sol. Br Ostwald 's process
F F 
Fe s
N 2  g   3H 2  g    2NH 3  g  ; Haber 's process
(Square pyramidal) Ni(s)
Vegetable oil (l )  H 2  g     vegetable ghee
3
CrF6  :
: Hydrogenation
3–

[ [
3. Given two statements below :
F
Statement I : In Cl2 molecule the covalent radius
F F
is double of the atomic radius of chlorine.
Cr
F F Statement II : Radius of anionic species is always
F greater than their parent atomic radius.
(Octahedral) Choose the most appropriate answer from options
O3 : given below :
+ (A) Both Statement I and Statement II are correct.
O
– (B) Both Statement I and Statement II are
O O
(Bent) incorrect.
PCl5 : (C) Statement I is correct but Statement II is
Cl incorrect.
Cl (D) Statement I is incorrect but Statement II is
P Cl correct.
Cl
Cl Official Ans. by NTA (D)
(Trigonal bipyramidal) Allen Ans. (D)
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 Final JEE-Main Exam July 2022/26-07-2022/Morning Session
Sol. In Cl2 molecule, the covalent radius is half of 7. Borazine, also known as inorganic benzene, can be
the internuclear distance, so statement(I) is prepared by the reaction of 3-equivalents of "X"
with 6-equivalents of "Y". "X" and "Y",
false.
respectively are :
For the same element, anion has lower
(A) B(OH)3 and NH3 (B) B2H6 and NH3
effective nuclear charge than atom  so anion
(C) B2H6 and HN3 (D) NH3 and B2O3
is larger than atom.  statement (II) is correct. Official Ans. by NTA (B)
4. Refining using liquation method is the most Allen Ans. (B)
suitable for metals with : 
Sol. 3B2H6 + 6NH3   2B N H + 12 H
3 3 6 2
(A) Low melting point
8. Which of the given reactions is not an example of
(B) High boiling point
disproportionation reaction ?
(C) High electrical conductivity
(A) 2H2O2  2H2O + O2
(D) Less tendency to be soluble in melts than
(B) 2NO2 + H2O  HNO3 + HNO2

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impurities
Official Ans. by NTA (A) (C) MnO4– + 4H+ + 3e–  MnO2 + 2H2O
Allen Ans. (A) (D) 3MnO42– + 4H+  2MnO4– + MnO2 + 2H2O
Sol. Liquation is used to purify metals having Official Ans. by NTA (C)
lower melting point than impurities present in Allen Ans. (C)
1 2 0
them. Sol. 2H 2 O 2 
 2H 2 O  O2 : Disproportionation
5. Which of the following can be used to prevent the 4 5 3
2NO 2  H 2 O  HNO 3  HNO 2 : Disproportionation
decomposition of H2O2?
(A) Urea MnO 4  4H   3e   MnO 2  2H 2O : reduction
6 7
(B) Formaldehyde 4
3MnO24  4H   2MnO 4  MnO 2  2H 2O : Disproportionation
(C) Formic acid
9. The dark purple colour of KMnO4 disappears in
(D) Ethanol
the titration with oxalic acid in acidic medium.
Official Ans. by NTA (A)
The overall change in the oxidation number of
Allen Ans. (A)
manganese in the reaction is :
Sol. Urea acts as stabiliser for H2O2. (A) 5 (B) 1
6. Reaction of BeCl2 with LiAlH4 gives : (C) 7 (D) 2
(A) AlCl3 Official Ans. by NTA (A)
(B) BeH2 Allen Ans. (A)
(C) LiH Sol. In acidic medium,
(D) LiCl 7

(E) BeAlH4 MnO4  Mn 2

Choose the correct answer from options given change in ox. no. = 5

below :
10. C l  CH 4  A  B
(A) (A), (D) and (E)
A and B in the above atmospheric reaction step are
(B) (A) , (B) and (D)

(C) (D) and (E) (A) C2H6 and Cl2 (B) C HCl2 and H 2
(D) (B) , (C) and (D) 
(C) C H3 and HCl (D) C2H6 and HCl
Official Ans. by NTA (B)
Official Ans. by NTA (C)
Allen Ans. (B)
Allen Ans. (C)
Sol. 2BeCl2 + LiAlH4  2BeH2 + LiCl + AlCl3
 
Sol. Cl CH 4 
 CH3  HCl

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 Final JEE-Main Exam July 2022/26-07-2022/Morning Session
11. Which technique among the following, is most
appropriate in separation of a mixture of 100 mg of
p-nitrophenol and picric acid ? Sol.
(A) Steam distillation
(B) 2-5 ft long column of silica gel
(C) Sublimation
(D) Preparative TLC (Thin Layer Chromatography)
Official Ans. by NTA (D)
Difference in reactions is observed due to solvent
Allen Ans. (D)
Sol. polarity, which

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(i) Ionizes phenol to make more reactive

phenoxide ion

(ii) Increases electrophilicity of bromine.

13. Which of the following compounds is not

aromatic?

(A)

Solvent polarity has been related to Rf value of

nitrocompounds. (B)

100 mg p-nitrophenol and picric acid have

different Rf value on silica gel plate

 Preparative TLC is best to separate 100 mg of (C)

para nitrophenol and picric acid

12. The difference in the reaction of phenol with
(D)
bromine in chloroform and bromine in water
medium is due to :
Official Ans. by NTA (C)
(A) Hyperconjugation in substrate
(B) Polarity of solvent Allen Ans. (C)

(C) Free radical formation Sol. [10] Annulene, although follow (4n + 2) electron
(D) Electromeric effect of the substrate rule, but it is non-aromatic due to its non planar
Official Ans. by NTA (B)
nature. It is nonplanar due to repulsion of C – H
Allen Ans. (B)
bonds present inside the ring.

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 Final JEE-Main Exam July 2022/26-07-2022/Morning Session
14. The products formed in the following reaction, A 15. Which reactant will give the following alcohol on
and B are reaction with one mole of phenyl magnesium
bromide (PhMgBr) followed by acidic hydrolysis ?

(A) CH3 – C  N
(B) Ph – C  N

(A) (C)
(D)

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Official Ans. by NTA (D)
Allen Ans. (D)
(B)

Sol.

16. The major product of the following reaction is

(C)

(D)
(A) (B)

Official Ans. by NTA (C)

Allen Ans. (C)
Sol. (C) (D)

Official Ans. by NTA (A)

Allen Ans. (A)

Sol.
NaBH4 does not reduce carboxylic acid.

Given reaction is an example of birch reduction.

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 Final JEE-Main Exam July 2022/26-07-2022/Morning Session
17. The correct stability order of the following 18. Stearic acid and polyethylene glycol react to form
diazonium salt is which one of the following soap/s detergents ?
(A) Cationic detergent (B) Soap
(C) Anionic detergent (D) Non-ionic detergent
Official Ans. by NTA (D)
Allen Ans. (D)
Sol.
CH 3(CH2) 16 COOH + OH(CH2CH2O) n CH2CH2OH
Stearic acid Polyethylene glycol
– H2O

O
CH 3(CH2) 16 – C – O – (CH 2CH2O) n CH2CH2OH

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Non-ionic detergent
19. Which of the following is reducing sugar?

(A) (A) > (B) > (C) > (D)

(B) (A) > (C) > (D) > (B)
(C) (C) > (A) > (D) > (B) (A)

(D) (C) > (D) > (B) > (A)

Official Ans. by NTA (B)
Allen Ans. (B)

(B)
Sol.

(C)

(D)
Since diazonium ion is a cation hence it is
stabilized by electron donating groups and
destabilized by electron withdrawing group.
Hence Stability order should be A > C > D > B. Official Ans. by NTA (A)
Allen Ans. (A)

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 Final JEE-Main Exam July 2022/26-07-2022/Morning Session
Sol. If any sugar is having free –OH group at anomeric SECTION-B
carbon then it will be a reducing sugar 1. Chlorophyll extracted from the crushed green
leaves was dissolved in water to make 2 L solution
of Mg of concentration 48 ppm. The number of
atoms of Mg in this solution is x × 1020 atoms. The
value of x is________. (Nearest Integer)
(Given : Atomic mass of Mg is 24 g mol–1,
NA = 6.02 × 1023 mol-1)
Official Ans. by NTA (24)
Allen Ans. (24)
20. Given below are two statements : one is labelled as
WMg
Assertion (A) and the other is labelled as Reason Sol. ppm =  106  48
Vsoln
(R).

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48  2  1000
Assertion (A) : Experimental reaction of CH3Cl  WMg =
10 6
with aniline and anhydrous AlCl3 does not give o
= 48  2  10–3 g
and p-methylaniline.
WMg 48  2  103
Reason (R) : The — NH2 group of aniline nMg = 
24 24
becomes deactivating because of salt formation = 4 × 10–3
with anhydrous AlCl3 and hence yields m-methyl Number of Mg atoms = 4  10–3 × 6.02 × 1023
aniline as the product. = 4  6.02 × 1020
In the light of the above statements, choose the = 24.08 × 1020
most appropriate answer from the options given  x = 24.08
below : 2. A mixture of hydrogen and oxygen contains 40%
(A) Both (A) and (R) are true and (R) is the correct hydrogen by mass when the pressure is 2.2 bar.
explanation of (A). The partial pressure of hydrogen is bar.
(B) Both (A) and (R) are true but (R) is not the (Nearest Integer)

correct explanation of (A). Official Ans. by NTA (2)

Allen Ans. (2)
(C) (A) is true, but (R) is false.
40
(D) (A) is false, but (R) is true. Sol. Let WH 2  40 g  n H2   20
2
Official Ans. by NTA (C)
60 15
Allen Ans. (C) WO2  60g  n O2  
32 8
 
 20 
PH 2    2.2
15 
Sol.  20  
 8 
20
  2.2
20  1.875
20
  2.2
21.875
Friedel Craft Alkylation does not occur on this
= 2.0114
deactivated ring.
 2.01 bar
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 Final JEE-Main Exam July 2022/26-07-2022/Morning Session
3. The wavelength of an electron and a neutron will 5. When 800 mL of 0.5 M nitric acid is heated in a
become equal when the velocity of the electron is x beaker, its volume is reduced to half and 11.5 g of
times the velocity of neutron. The value of x nitric acid is evaporated. The molarity of the
remaining nitric acid solution is x × 10–2 M.
is__________. (Nearest Integer)
(Nearest Integer)
(Mass of electron is 9.1 × 10–31 kg and mass of
(Molar mass of nitric acid is 63 g mol–1)
neutron is 1.6 × 10–27 kg)
Official Ans. by NTA ( 54)
Official Ans. by NTA ( 1758) Allen Ans. (54)
Allen Ans. (1758) Sol. n HNO3  0.5  0.8
Sol. e  x  N
= 0.4 mole
e   N 11.5
(n HNO3 )remains  0.4 
h h 63
 

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me  e m N  N = 0.4 – 0.1825
= 0.2175
m
 e  N . N 0.2175
me Molarity =  1000
400
1.6  1027 0.2175
= N =
9.1  1031 0.4
e = 1758.24 × N = 0.5437 mole/lit.
 x = 1758.24  0.54 mole/lit.
4. 2.4 g coal is burnt in a bomb calorimeter in excess = 54 × 10–2 mol/lit.
6. At 298 K, the equilibrium constant is 2 × 1015 for
of oxygen at 298 K and 1 atm pressure.
the reaction :
The temperature of the calorimeter rises from
 Cu2+(aq) + 2Ag(s)
Cu(s) + 2Ag+(aq) 
298 K to 300 K. The enthalpy change during the
The equilibrium constant for the reaction
combustion of coal is – x kJ mol–1. The value of x
1 2  1 Cu(s)  Ag  (aq)
is___________. (Nearest Integer) Cu (aq)  Ag(s) 
2 2
(Given : Heat capacity of bomb calorimeter 20.0 kJ
is x × 10–8. The value of x is_______.
–1
K . Assume coal to be pure carbon) (Nearest Integer)
Official Ans. by NTA (200) Official Ans. by NTA (2 )
Allen Ans. (200) Allen Ans. (2)
Sol. C (s) + O2 (g)  CO2 (g) ; H = -x kJ/mole 1 1
Sol. K 'eq    x  108
15
Q = CT = 20 kJ × 2 K eq 2  10
40 kJ heat is released for 2.4 g of C 1 1
  7  x  108
40 20 10
For 1 mole ‘C’ : Q  12
2.4 1
  107  x 108
20
400
  12 = 200 kJ/mole
24 10
x
20
Q=E = H = 200 kJ ( ng = 0)
x = 200 10
x  5  2.236
2
 2.24
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 Final JEE-Main Exam July 2022/26-07-2022/Morning Session
7. The amount of charge in F (Faraday) required to 9. The difference between spin only magnetic
moment values of [Co(H2O)6]Cl2 and
obtain one mole of iron from Fe3O4 is _____.
[Cr(H2O)6]Cl3 is___________.
(Nearest Integer)
Official Ans. by NTA (0)
Official Ans. by NTA (8) Allen Ans. (0)

Allen Ans. (3)

Sol. [Co(H2O)6]2+
3d 4s 4p
8e 
Sol. Fe3O4 
 3Fe Co+2 :

Charge for 1 mole Fe = 8/3 F number of unpaired e– = 3

  15BM
= 2.67 F
[Cr(H2O)6]3+

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8. For a reaction A  2B + C the half lives are 100 s 3d 4s 4p

and 50 s when the concentration of reactant A is Cr+3 :

number of unpaired e– = 3
0.5 and 1.0 mol L–1 respectively. The order of the
  15BM
reaction is___ _____. (Nearest Integer)
Difference in spin only magnetic moment = 0
Official Ans. by NTA (2)

Allen Ans. (2) 10. In the presence of sunlight, benzene reacts with Cl2

1
to give product, X. The number of hydrogens in X
t1 
Sol. 2
[A 0 ]n 1 is_________.
Official Ans. by NTA (6)
1 Allen Ans. (6)
[100] 
(0.5)n 1

1
(50) 
(1)n 1 Sol.

n 1
1 1 
[2]   
 0.5 

[2]1 = [2]n–1

n–1=1

n=2

order = 2