FINAL JEE–MAIN EXAMINATION – JUNE, 2022

(Held On Monday 27th June, 2022) TIME : 9 : 00 AM to 12 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A (A) (A) – I, (B) – (II), (C) – (III), (D) – (IV)
1. Given below are two statements : one is labelled as (B) (A) – (III), (B) – (IV), (C) – (I), (D) – (II)
Assertion (A) and the other is labelled as Reason (C) (A) – (III), (B) – (IV), (C) – (II), (D) – (I)
(R) (D) (A) – (IV), (B) – (III), (C) – (I), (D) – (II)
Assertion (A) : At 10°C, the density of a 5M Official Ans. by NTA (B)
solution of KCl [atomic masses of K and Cl are 39 Allen Ans. (B)
-1
& 35.5 g mol ]. The solution is cooled to -21°C. Sol.
The molality of the solution will remain
ClF3 BF3 SF4 XeF4
unchanged.
F F
F F F F F
Reason (R) : The molality of a solution does not
Cl–F B S Xe
change with temperature as mass remains F F F
F F F
unaffected with temperature.
In the light of the above statements, choose the
EN 3. Match List-I with List-II
correct answer from the options given below:
List-I List-II
(A) Both (A) and (R) are true and (R) is the correct
(A) Spontaneous process H < 0
explanation of (A)
LL

(B) Both (A) and (R) are true but (R) is not the
(B) Process with P = 0, GT,P < 0

correct explanation of (A) T = 0

(C) (A) is true but (R) is false (C) Hreaction (III) Isothermal and

(D) (A) is false but (R) is true isobaric process

A

Official Ans. by NTA (A) (D) Exothermic process (IV) [Bond energies of
Allen Ans. (A) molecules in reactants] -
Sol. Molality is independent of temperature and hence [Bond energies of
both assertion and reason are true. product molecules
2. Based upon VSEPR theory, match the shape Choose the correct answer from the options given below:

(geometry) of the molecules in List-I with the (A) (A) – (III), (B) – (II), (C) – (IV), (D) – (I)

molecules in List-II and select the most appropriate (B) (A) – (II), (B) – (III), (C) – (IV), (D) – (I)

option (C) (A) – (II), (B) – (III), (C) – (I), (D) – (IV)

List-I List-II (D) (A) – (II), (B) – (I), (C) – (III), (D) – (IV)

(Shape) (Molecules) Official Ans. by NTA (B)

(A) T-shaped (I) XeF4 Allen Ans. (B)

(B) Trigonal planar (II) SF4 Sol. (A) For a spontaneous process GT,P < 0

(C) Square planar (III) ClF3 (B) P = 0  Isobaric process

(D) See-saw (IV) BF3 T = 0  Isothermal process

1
 (C) Hreaction = (Bond energies of reactants) - (B) Both (A) and (R) are true but (R) is not the
(bond energies of products) correct explanation of (A)

(D) H < 0 is for exothermic reaction (C) (A) is true but (R) is false

4. Match List-I with List-II (D) (A) is false but (R) is true

List-I List-II Official Ans. by NTA (D)

(A) Lyophilic colloid (I) Liquid-liquid colloid Allen Ans. (D)

(B) Emulsion (II) protective colloid Sol. Ionic radius of O2- is more than that of Mg2+

(C) Positively charged (III) FeCl3 + NaOH Both O2- and Mg2+ are isoelectronic with 10

(D) Negatively charged (IV) FeCl3 + hot water electrons

colloid 6. Match List-I with List-II

Choose the correct answer from the options given List-I List-II

below: (A) Concentration of (I) Aniline

(A) (A) – (II), (B) – (I), (C) – (IV), (D) – (III) gold ore

(B) (A) – (III), (B) – (I), (C) – (IV), (D) – (II) (B) Leaching of alumina (II) NaOH

(C) (A) – (II), (B) – (I), (C) – (III), (D) – (IV) (C) Froth stabiliser (III) SO2
EN
(D) (A) – (III), (B) – (II), (C) – (I), (D) – (IV)
Official Ans. by NTA (A)
(D) Blister copper (IV) NaCN
Choose the correct answer from the options given

Allen Ans. (A) below.

Sol. (A) Protective colloids are lyophilic colloids (A) (A) – (IV), (B) – (III), (C) – (II), (D) – (I)

(B) Emulsions are liquid in liquid colloidal (B) (A) – (IV), (B) – (II), (C) – (I), (D) – (III)
LL

solutions (C) (A) – (III), (B) – (II), (C) – (I), (D) – (IV)

(C) FeCl3 + hot water forms positively charged (D) (A) – (II), (B) – (IV), (C) – (III), (D) – (I)

colloidal solution of hydrated ferric oxide. Official Ans. by NTA (B)

(D) FeCl3 + NaOH forms negatively charged Allen Ans. (B)

A

colloidal solution due to preferential adsorption of Sol. Gold is concentrated by cyanidation

OH- ions Leaching of alumina is done by NaOH

5. Given below are two statements: one is labelled as Froth stabiliser is aniline

Assertion (A) and the other is labelled as Blister copper has condensed SO2 on the surface

Reason(R) 7. Addition of H2SO4 to BaO2 produces:

Assertion (A): The ionic radii of O2- and Mg2+ are (A) BaO, SO2 and H2O (B)BaHSO4 and O2

same. (C) BaSO4, H2 and O2 (D) BaSO4 and H2O2

Official Ans. by NTA (D)
Reason (R) : Both O2- and Mg2+ are isoelectronic
Allen Ans. (D)
species
In the light of the above statements, choose the Sol. BaO2 + H2SO4  BaSO4 + H2O2

correct answer from the options given below This is a common method to prepare hydrogen

(A) Both (A) and (R) are true and (R) is the correct peroxide

explanation of (A) 8. BeCl2 reacts with LiAlH4 to give

(A) Be + Li[AlCl4] + H2
(B) Be + AlH3 + LiCl + HCl
2
 (C) BeH2 + LiCl + AlCl3 Allen Ans. (C)
(D) BeH2 + Li[AlCl4] Sol. Co3+ has maximum effective nuclear charge and
Official Ans. by NTA (C) CN- is the strongest ligand in the given options
Allen Ans. (C) 12. Given below are two statements:
Sol. 2BeCl2 + LiAlH4 2 BeH2 + LiCl + AlCl3 Statement I: Classical smog occurs in cool humid
This is the method to prepare BeH2 climate. It is a reducing mixture of smoke, fog and
9. Match List-I with List-II sulphur dioxide
List-I List-II Statement II: Photochemical smog has
(Si-Compounds) (Si-Polymeric/other components, ozone, nitric oxide, acrolein,
products) formaldehyde, PAN etc.
(A) (CH3)4Si (I) Chain silicone In the light of above statements, choose the most
(B) (CH3)Si(OH)3 (II) Dimeric silicone appropriate answer from the options give below
(C) (CH3)2Si(OH)2 (III) Silane (A) Both Statement I and Statement II are correct
(D) (CH3)3Si(OH) (IV) 2D – Silicone (B) Both Statement I and Statement II are
Choose the correct answer from the options given EN incorrect
below: (C) Statement I is correct but statement II is
(A) (A) – (III), (B) – (II), (C) – (I), (D) – (IV) incorrect
(B) (A) – (IV), (B) – (I), (C) – (II), (D) – (III) (D) Statement I is incorrect but Statement II is
(C) (A) – (II), (B) – (I), (C) – (IV), (D) – (III) correct
(D) (A) – (III), (B) – (IV), (C) – (I), (D) – (II) Official Ans. by NTA (A)
LL

Official Ans. by NTA (D) Allen Ans. (A)

Allen Ans. (D) Sol. Classical smog occurs in cool humid climate. It is a
Sol. (CH3)4Si is a silane reducing mixture of smoke, fog and sulphur
(CH3)Si(OH)3 polymerise to form 2D silicone dioxide
A

(CH3)2Si(OH)2 polymerise to form chain silicone Photochemical smog has components, ozone, nitric
(CH3)3Si(OH) form dimer (CH3)3Si-O-Si(CH3)3 oxide, acrolein, formaldehyde, PAN etc.
10. Heating white phosphorus with conc. NaOH CH4 + O3  HCHO + H2O + CH2 = CH – CHO +
solution gives mainly O
(A) Na3P and H2O (B) H3PO and NaH H3C
O ONO2 (PAN - peroxyacetyl nitrate)
(C) P(OH)3 and NaH2PO4 (D) PH3 and NaH2PO2
Official Ans. by NTA (D)
Allen Ans. (D)
Sol. P4 + 3NaOH + 3H2O  3NaH2PO2 + PH3
11. Which of the following will have maximum
stabilization due to crystal field?
(A) [Ti(H2O)6]3+ (B) [Co(H2O)6]2+
(C) [Co(CN)6]3- (D) [Cu(NH3)4]2+
Official Ans. by NTA (C)

3
13. Which of the following is structure of a separating 15. The major product of the following reaction is:
funnel?

(A) (B)
(A) (B)

(C) (D)
Official Ans. by NTA (A)
Allen Ans. (A)
Sol. It is used to separate liquid-liquid mixture which isEN
immiscible with different densities
(C) (D)
14. ‘A’ and ‘B’ respectively are:
A (1)O3
( 2) Zn H O
 Ethane-1,2-dicarbaldehyde
2

+ Glyoxal/Oxaldehyde
LL

B (1)O3
( 2) Zn H O
 5-oxohexanal
2

(A) 1-methylcyclohex-1, 3-diene & cyclopentene

(B) Cyclohex-1, 3-diene & cyclopentene
(C) 1-methylcyclohex-1,4-diene
A

& 1-methylcyclopent-1-ene Official Ans. by NTA (A)

(D) Cyclohex-1,3-diene Allen Ans. (A)

& 1-methylcyclopent-1-ene Sol.

Official Ans. by NTA (D) H3C H3C

Allen Ans. (D)

I SPh
Sol.
CHO
F   F


1.O3
2. Zn H2O
+ OHC CHO 
PhSNa
DMF
CHO (glyoxal)
ethane-1, 2-dicarbaldehyde NO2 NO2

CH3
CH3
It is bimolecular nucleophilic substitution (SN2)
O which occur at benzylic carbon by inversion in

1.O3
2. Zn H O
2 CHO
contiguration. This reaction cannot undergo
5-oxohexanal substitution at benzene ring

4
16. Which of the following reactions will yield 17. Given below are two statements:
benzaldehyde as a product? Statements-I : In Hofmann degradation reaction,
COOH the migration of only an alkyl group takes place

 
(i) SOCl2 Quinoline
(ii)H /Pd/BaSO
 from carbonyl carbon of the amide to the nitrogen
2 4
(A) atom.
CH2 OH
Statement-II : The group is migrated in Hofmann
degradation reaction to electron deficient atom.


CrO3/H2SO4
In the light of the above statement, choose the
(B)
most appropriate answer from the options given
O
below:
C OCH3
(A)Both Statement-I and Statement-II are correct

(i) NaBH4
(ii) PCC

(C) (B) Both Statement-I and Statement-II are
CH3 incorrect
(C) Statement-I is correct but Statement-II is

(i) CrO3 , (CH3CO)2 O
 incorrect
(ii) H3O , 
(D) EN (D) Statement-I is incorrect but Statement-II is
(A) (B) and (C) (B) (C) and (D)
correct
(C) (A) and (D) (D) (A) and (C)
Official Ans. by NTA (D)
Official Ans. by NTA (C)
Allen Ans. (D)
Allen Ans. (C)
Sol. R – CO – NH2 + Br2 + NaOH 
LL
Sol.
R – NH2 + Na2CO3 + NaBr + H2O
 
COOH COCl
CHO R – CO – NH2 + O H  R – CO - N H 
Br2

 

SOCl2
Quinoline
 
H2|Pd|BaSO4
(R osenmund Reduction)
 R – CO – NH – Br 
OH
 R – CO - N  Br
A

(Benzaldehyde)  

CH2OH COOH 

migration of R
 R – NCO 
2 OH
 RNH2 + CO32
In this reaction of alkyl as well as aryl group can

CrO3 |H2SO4
(oxidation)
 migrate to electron deficient nitrogen atom.
18. Match List-I with List-II
COOCH3
List-I List-II
(Polymer) (Used in)

NaBH4
No Reduction occurs
(A) Bakelite (I) Radio and television

CH3 CHO
Cabinets
CH(OCOCH3)2
(B) Glyptal (II) Electrical switches

CrO3 ,(CH3CO)2 O 
(C) PVC (III) Paints and Lacquers

H3O

(Benzaldehyde) (D) Polystyrene (IV) Water pipes
Choose the correct answer from the options given
below:

5
 (A) (A) – (II), (B) – (III), (C) – (IV), (D) – (I) Sol.
(B) (A) – (I), (B) – (II), (C) – (III), (D) – (IV) H O
COOH
(C) (A) – (IV), (B) – (III), (C) – (II), (D) – (I) HO H
HO H
(D) (A) – (II), (B) – (III), (C) – (I), (D) – (IV) HO H

 Br2|H2O
HO H
Official Ans. by NTA (A) OH
OH
Allen Ans. (A) L-isomer optically active
Sol. Bakelite- It is thermosetting polymer used for
H O
making electrical switches. COOH

Glyptal – manufacture of paints and lacquers HO H HO H

HO H con.HNO3
HO H
PVC – manufacture of water pipes, rain coats,
COOH
hand bags OH
optically inactive
Polystyrene – manufacture of radio and television L-isomer
cabinets 20. Match List-I with List-II
19. L-isomer of a compound ‘A’ (C4H8O4) gives a
List-I
positive test with [Ag(NH3)2]+. Treatment of ‘A’
EN (A)
with acetic anhydride yield triacetate derivative.
+
Compound ‘A’ produces an optically active CH3
compound (B) and an optically inactive compound CH3 (CH2 )15 - N - CH3 Br-
(C) on treatment with bromine water and HNO3 CH3
respectively, compound (A) is:
LL

(A) (B) CH 3 - (CH2)11 SO3 Na 

(B)
CHO CHO
(C) C17 H35COO Na   Na 2CO3  Rosinate
HO H H OH
(D) CH3(CH2)16COO(CH2CH2O)nCH2CH2OH
HO H HO H
A

CH2OH CH2OH
List-II
(I) Dishwashing powder
(C) (D)
(II) Toothpaste
CHO CHO
(III) Laundry soap
H OH OH H
(IV) Hair conditioner
H OH H OH
(A) (A) – (III), (B) – (II), (C) – (IV), (D) – (I)
CH2OH CH2OH
(B) (A) – (IV), (B) – (II), (C) – (III), (D) – (I)
Official Ans. by NTA (A) (C) (A) – (IV), (B) – (III), (C) – (II), (D) – (I)
Allen Ans. (A) (D) (A) – (III), (B) – (IV), (C) – (I), (D) – (II)
Official Ans. by NTA (B)
Allen Ans. (B)

6
Sol. (A) CH3 (CH2 )15  N(CH3 )3  Br 
 h
 mV.x 
4
is cationic detergents used in hair conditioner
6.626  10 34
 m  2.4  10 26  10 7 
 4 
CH3 (CH 2 )11 SO3 Na
6.626
(B) m  101
9.6  
Is anionic detergent used in tooth pastes
m = 0.02198 kg
 
(C) C17 H35COO Na  Na 2CO3  Rosin ate is m = 21.98 gm
used as laundary soap nearest integer = 22
(D) CH3 (CH2 )16 COO(CH2CH2O) N CH2CH2OH 3. 2g of a non-volatile non-electrolyte solute is
is non-ionic detergents formed from stearic acid dissolved in 200 g of two different solvents A and
and poly ethylene glycol used as liquid B whose ebullioscopic constants are in the ratio of
dishwashing detergents 1 : 8. The elevation in boiling points of A and B
SECTION-B x
are in the ratio (x : y). The value of y
y
1. Metal deficiency defect is shown by Fe0.93O. In the
crystal, some Fe2+ cations are missing and loss of
positive charge is compensated by the presence of
EN is_________ (Nearest integer)
Official Ans. by NTA (8)
Fe3+ ions. The percentage of Fe2+ ions in the Allen Ans. (8)
Fe0.93O crystals is _________ . (Nearest integer) (K b )A 1
Sol. Given : 
Official Ans. by NTA (85) (K b )B 8
LL

Allen Ans. (85) (TB )A (K b )A .m 1 x

   
(TB )B (K b )B .m 8 y
Sol. In Fe0.93O for every 93 Fe ions 14 are Fe+3 and (93
– 14) = 79 are Fe+2 ions x 1

y 8
79
A

 % Fe+2 =  100 = 84.9%

93  y  8 (nearest integer)
  nearest integer = 85% 4. 2NOCl(g) 2NO(g) + Cl2(g)
2. If the uncertainty in velocity and position of a In an experiment, 2.0 moles of NOCl was placed in
minute particle in space are, 2.4 × 10-26 (ms-1) and a one-litre flask and the concentration of NO after
10-7(m) respectively. The mass of the particle in g equilibrium established, was found to be 0.4
is _________ (Nearest integer) mol/L. The equilibrium constant at 30°C is ______
-34
(Given : h = 6.626 × 10 Js) × 10-4.
Official Ans. by NTA (22) Official Ans. by NTA (125)
Allen Ans. (22) Allen Ans. (125)
-26 -1
Sol. V = 2.4 × 10 ms Sol. 2NOCl(g) 2NO(g) + Cl2(g)
-7
x = 10 m t=0 2M - -
h x
p. x  t=teq (2-x)M xM M
4 2

7
 x  0.4 M EA
Sol. ln k = ln A 
RT
 [NOCl]eq = 1.6 M
[NO]eq = 0.4 M 2.0  10 4
Given: ln k = 33.24 
T
[Cl2]eq = 0.2 M
EA
[NO]2[Cl2 ] [0.4]2[0.2]  on comparing = 2.0 × 104
 Kc   R
[NOCl]2 [1.6]2
 EA = 2.0 × 104 × R
32
Kc   103  EA = 2.0 × 104 × 8.3 J
2.56
Kc = 12.5 × 10-3  EA = 16.6 × 104J = 166 kJ

Kc = 125 × 10-4 7. The number of statement(s) correct from the

Integer answer is 125 following for copper (at no. 29) is/are ______

5. The limiting molar conductivities of NaI, NaNO3 (A) Cu(II) complexes are always paramagnetic
and AgNO3 are 12.7, 12.0 and 13.3 mS m2 mol-1, (B) Cu(I) complexes are generally colourless
respectively (all at 25°C). The limiting molar (C) Cu(I) is easily oxidized
conductivity of AgI at this temperature is _____
EN (D) In Fehling solution, the active reagent has
mS m2 mol-1
Cu(I)
Official Ans. by NTA (14)
Official Ans. by NTA (3)
Allen Ans. (14)
Allen Ans. (3)
Sol. Given
Sol. A,B,C are correct and D is incorrect because
LL
(1)  m 2
(NaI) = 12.7 mS m mol -1
Fehling solution has Cu(II)
(2)  m (NaNO3) = 12.0 mS m2 mol-1 8. Acidified potassium permanganate solution

(3)  m (AgNO3) = 13.3 mS m2 mol-1 oxidises oxalic acid. The spin-only magnetic
moment of the manganese product formed from
 m (Ag I) = (1) + (3) - (2)
A

the above reaction is ______ B.M. (Nearest

= 12.7 + 13.3 – 12.0
Integer)
= 26.0 – 12.0
Official Ans. by NTA (6)
 m (Ag I) = 14.0
Allen Ans. (6)
6. The rate constant for a first order reaction is given Sol. 2KMnO4 + 5H2C2O4 + 3H2SO4  K2SO4
by the following equation: + 2MnSO4 + 10CO2 + 8H2O
2.0  10 4 K Mn2+ has 5 unpaired electrons therefore the
ln k = 33.24 -
T magnetic moment is 35 BM
The Activation energy for the reaction is given by
______ kJ mol-1. (In Nearest integer)
(Given: R = 8.3 J K-1 mol-1)
Official Ans. by NTA (166)
Allen Ans. (166)

8
9. Two elements A and B which form 0.15 moles of CH3
A2B and AB3 type compounds. If both A2B and
AB3 weigh equally, then the atomic weight of A is
_____ times of atomic weight of B.
CH3
Official Ans. by NTA (2) 1,3-dimethylcyclopentane
will show stereo isomerism, Its stereo isomers are
Allen Ans. (2)
Sol. Given : Molar mass of A2B = AB3 CH3 CH3

 A  Atomic wt.of A 
 (2A + B) = (A + 3B)  
=
 B  Atomic wt.of B  (identical)
 A = 2B CH3 CH3
 atomic wt. of A is 2 times of atomic wt. of B
CH3
Integer answer is 2 CH3

10. Total number of possible stereoisomers of

EN CH3
(enantiomers)
dimethyl cyclopentane is ___________ CH3
Official Ans. by NTA (5)
Allen Ans. (6)
Sol. Dimethyl cyclopentane
LL

CH3
H3C

1,1-dimethylcyclopentane
A

no stereoisomer
CH3

CH3
1,2-dimethylcyclopentane
will show stereo isomerism, Its stereo isomers are
CH3
CH3
CH3
CH3
=
(identical)

CH3 CH3

CH3 CH3

(enantiomers)