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a strong base
(acid)
Problems #1 - 10
Problems #11-20
Return to a listing of many types of acid base problems and their solutions
Problem #0: When H2SO4 and NaOH is reacted, is it the H+ and OH¯ that has equal number of moles, or the H2SO4 and NaOH has equal number of moles?
Solution:
1) It will be the H+ and the OH¯ that have the equal number of moles.
This is where the 1:2 molar ratio of H2SO4 and NaOH comes from.
Notice I am treating the sulfuric acid as if it is 100% ionized in both hydrogens. This is the the true case of how sulfuric acid ionizes in solution, but I am
here more interested in the stoichiometry of the reaction between sulfuric acid and sodium hydroxide, not in how sulfuric acid ionizes by itself in solution.
2H+ from one H2SO4 and 2OH¯ from 2NaOH. The 1:2 ratio up above gets obscured here. That's because the ratio above is based on the full molecular
formula, not just the number of ions involved.
This shows that, in an acid base reaction, hydrogen ions and hydroxide ions react in equal molar amounts (which is a 1:1 molar ratio). The actual molecules
that provide the ions for reaction may, or may not, be in a 1:1 molar ratio
Problem #1: A volume of 20.00 mL of 0.250 M Al(OH)3 neutralizes a 75.00 mL sample of H2SO4 solution. What is the concentration of H2SO4?
Solution #1:
2 is to 3 as 5.00 is to x
x = 7.50 millimoles
Solution #2:
x = 0.100 M
Problem #2: A 21.62 mL sample of Ca(OH)2 solution was titrated with 0.2545 M HCl. 45.87 mL of the acid was required to reach the endpoint of the titration. What
was the molarity of calcium hydroxide solution?
Solution:
2 is to 1 as 0.011674 mol is to x
x = 0.005837 mol of Ca(OH)2
molarity of Ca(OH)2 ---> 0.005837 mol / 0.02162 L = 0.2700 M (to four sig figs)
Problem #3: Calculate the volume of NaOH necessary to neutralize 50.0 mL of a 16.0 M solution of sulfuric acid. The concentration of the NaOH is 2.50 M.
Solution:
Now look at the equation. It says that for every mole of H2SO4 you need twice that many moles of NaOH to neutralize all the H2SO4.
Now that you have moles and a concentration you can find volume:
V = moles / concentration
Note: I copied this answer from an "answers" website. The original writer wrote the molarity as 2.50 moles/L instead of 2.50 mmol/mL. While 2.50 moles/L
is exactly the same as 2.50 mmol/mL, the units in the above expression would not match. If you did that on an answer to a test, you might get a deduction for
using the wrong units on the molarity. Moles does not cancel with millimoles, although the numerical answer would be correct.
Problem #4: What is the citric acid concentration in a soda if it requires 32.27 mL of 0.0148 M NaOH to titrate 25.00 mL of soda?
Solution:
Citric acid has three acidic hydrogens, so I will use H3Cit for the formula.
MaVa MbVb
––––– = –––––
na nb
Problem #5: Consider the unbalanced molecular equation in which citric acid, H3C6H5O7, is reacted with sodium hydroxide:
If 62.7 mL of 1.20 M NaOH(aq) is titrated with 32.0 mL of H3C6H5O7(aq) what the molarity of H3C6H5O7(aq)?
Solution:
2) The key point is the 1:3 stoichiometric ratio between the citric acid and the NaOH.
You need three moles of NaOH to neutralize every one mole of citric acid.
Problem #6: Calculate the molar concentration of phosphoric acid if 90.0 mL are required to neutralize 200. mL of 0.200 M calcium hydroxide solution.
Solution:
Notice that solid calcium phosphate is formed. This is immaterial to the following calculation.
2) There is a 2:3 molar ratio between H3PO4 and Ca(OH)2.
2 is to 3 as x is to 0.04
Tetrahydroxyarsoranyl is an actual compound (I think) and its formula can be rendered as H4AsO4. The ChemTeam does not know if those four hydrogens are acidic
hydrogens, but he's going to act like they are.
Problem #7: 35.0 mL of a solution of H4AsO4 is titrated with 0.0840 M Ba(OH)2. 41.4 mL of the base is required to reach the endpoint. Calculate the molarity of the
H4AsO4 solution.
Solution:
x = 0.0497 M
Problem #8: 35.0 mL of a solution of H4AsO4 is titrated with 0.0840 M Al(OH)3. 41.4 mL of the base is required to reach the endpoint. Calculate the molarity of the
H4AsO4 solution.
Solution:
x = 0.0745 M
Problem #9: A flask containes 30.0 mL of 0.100 M hydrochloric acid and 20.0 mL of hydrobromic acid. If 50.0 mL of 0.200 M sodium hydroxide was required to
neutralize the mixture of acids in the flask, what was the concentration of the hydrobromic acid? (See important comment at end of the one equation solution.)
Solution:
NaOH and HCl react in a 1:1 molar ratio. Let's see how much NaOH is left over after reacting with the HCl.
0.0100 mol − 0.00300 mol = 0.00700 mol <--- left over NaOH
NaOH and HBr react in a 1:1 molar ratio. To achieve neutralization, 0.00700 mol of NaOH reacts with 0.00700 mole of HBr.
[(0.100 mol/L) (0.0300 L)] / 1 + [(x) (0.0200 L)] / 1 = [(0.200 mol/L) (0.0500 L)] / 1
0.02x = 0.007
x = 0.350 M
A colleague has studied the above one equation solution and has prepared some discussion of it. Here are his words to me concerning the one equation solution:
"I find the above a little misleading since it is not generally correct. That is, your first equation above seems to imply that we just divide moles by the
stoichiometric coefficients and then just add everything together for the case of two acids and one base. It turns out that numerically this is true only because
the stoichiometric coefficient of the strong base (your nb above) is the same in both of the neutralization reactions and equals 1. This is not the case in
problem #10 and no such “solution using one equation†can be given as a result.
I wrote up a detailed “Deep Dive†on this one-step method approach. It contrasts the two problems and shows that for two strong acids and one strong
base there is no single equation that one can use."
Problem #10: A flask contains 30.0 mL of 0.10 M hydrochloric and 20.0 mL of sulfuric acid. If 50.0 mL of 0.20 M sodium hydroxide was required to neutralize the
mixture of acids in the flask, what was the concentration of the sulfuric acid?
Solution:
NaOH and HCl react in a 1:1 molar ratio. Let's see how much NaOH is left over after reacting with the HCl.
0.0100 mol − 0.00300 mol = 0.00700 mol <--- left over NaOH
NaOH and H2SO4 react in a 2:1 molar ratio. To achieve neutralization, 0.00700 mol of NaOH reacts with 0.00350 mole of H2SO4.
Bonus Problem: A mixture of hydrochloric acid and sulfuric acid is prepared so that it contains 0.635 M HCl and 0.135 M H2SO4. What volume of 0.140 M NaOH
would be required to completely neutralize all of the acid in 588.8 mL of this solution?
Solution:
By the above chemical equation, HCl and NaOH react in a 1:1 molar ratio. Therefore, 0.373888 mol of NaOH is required.
The molar ratio between H2SO4 and NaOH is 1:2. Two moles of NaOH are required for every one mole of H2SO4
Problems #11-20
Return to a listing of many types of acid base problems and their solutions