RATE OF REACTION

xX + yY
ORDER OF REACTION
for : aA + bB MOLECULARITY EFFECTIVE
Sum of powers of concentration Order of a COLLISION
• Number of reacting species
− 1 d[A] − 1 d[B] 1 d[x] 1 d[y] of reactants in the rate law. Molecular collide
rate = = = = reaction may taking part in an
a dt b dt x dt y dt be whole number elementary reaction
with sufficient
kinetic energy
or a fraction. • It cannot be zero or a and proper
fraction. ical orientation
A chem occurs
aA + bB → Pr oduct Molecularity = a + b n
reactiomolecules
INSTANTANEOUS when e with
RATE
AVERAGE RATE rate = k [A]x [B] y collid ient
suffic y.
order = x + y Energ
rate =
− d[R]
=
d[P]
rate =
−∆R −([R2 ] − [R 1])
=
 cC + dD
aA + bB  COLLISI
ON
dt dt NCY
∆t t 2 − t1
FREQUE ns
r of collisio
Numbe t volume of
i
per un n mixture.
RATE CONSTANT reactio
REACTION UNIT OF RATE CONSTANT (K) RATE
UNIT FOR nTH ORDER CONSTANT (k) ON
Zero Order mol L-1s-1
REACTION
RATE COLLISI FO R B I M OLECUL
AR

THEORY
ION
EXPRESSION REACT a/RT
First Order s-1 rate = k[A]x[B]y P z E-E
k = mol 1-n
Litren sec
-1 -1
rate =
rate ∝ A] x [B]y
A B
r
mol Ls ric facto
P → ste
-1 -1
Second Order
ollision
z AB → c cy
frequen

INTEGRATED RATE EQUATION

Reaction Differential Integrated Half life

rate law rate law -Ea
slope = R

d[R] kt = [R] − [R] [R] ln A

Zero Order =−k t 1/2 = °

ln k
dt ° 2k ARRHENIUS
First Order d[R]
= − k[R]
 [R] 
kt = ln  °
 t 1/2 =
0.693 EQUATION 1
temp.
dt  [R]  k

Radioactive
decay are first
order reaction.
k  Ea T1 − T 2 
log  1  =  
ZERO ORDER FIRST ORDER  k 2  2.303  T1 T2 
Half life of nth
slope = -k order reaction
slope = -k
CHEMICAL KINETICS k = Ae-Ea/RT
Ea
ln (1/[R])

1− n
[R]
°
ln [R]
°
t1/2 ∝ [R° ] ln k = ln A −
[R]

time
RT
time

FACTORS INFLUENCING RATE

A .......B

PSEUDO FIRST ORDER (Activated complex without catalyst)

A B
REACTION
Ea(f) without X
catalyst
E’a(f) with
• are not truely first order PRESENCE OF catalyst E’a(b) without
CONCENTRATION TEMPERATURE SURFACE AREA E’a(b) with catalyst

Potential energy
reaction but in certain CATALYST catalyst
conditions behaves like those. Reactants
A+B
• hydrolysis of ethyl acetate in
Higher the concentration Rate of reaction
acidic medium` Greater is the surface Rate of reaction
of reactants, faster is increases with increases in presence Products
area, faster is the
the rate of reaction. increase in of a catalyst. AB + X
reaction rate.
temperature.
Reaction Coordinate

anand_mani16 DR. Anand Mani https://www.anandmani.com/ https://discord.io/anandmani t.me/anandmani001