.

4
Chevitry

eec troegativity of M, 3.4. M.12,035 and

1 , then the nature
52. A diatomie moiccule has dipole moment of I2p
of wo solution will be hond distance Awlhat percenage ot electromic
(a) Aciuic, basic
respectively s

cach
(b) Jcidic, acidie CxIsts on
afom
(e basic. actdic (d) basie, basie 19% of e
a) 12% of e
45. Which of the
follawng statcmentes) is not true (C 25h of e (d) 29% ofe
tal CucT ts
more covalent than NaCT
6] HF is more
polar than HBr
53. The electonegativity ditference betwecn two aom
and 8 is 2. then percentage ot covalent character i n
e) HE is less
polar than Hir molecule1s
hemi bond lortmation tiakes place when fotces of
(a 54 (b)a6%
aftraction ovcruene the torces ot
dh. In the anson repulsiet (e),
25% (d) 72.
Hcoo the
carbon-oxygen bonds are
toun 54. Which
to be of
equal length This ts dhae to
correct
one
of the following dipoe
arrangements of molecules
the basis oI their
(a) The anion HCOO has two
resonating strcture
on
motments
(b)
The anion ts obtained by removal of (a) BENH,NE, (b) BF,NE, >NH,
acid nolecule
a
proton tron the ( e ) NH, > BF, > NF,
(d) NH, NF,> BE,
(c) Eleetronic orbitals of carbon 55, The eleetronegativity of i and Cl 21 and
(d)
are
hybridised are
3
The C0 bond is weaker then the C-0 bond respectively. The correct statement (s) about the nature of
47. A metal. M, forms ehlorides HCl is ar
in its +2 and 4 oxidation
tates, wich ot the (a) 17% ionic (6) 83% ionic
tollowng statenients abotut these
chforides is correct (e) S0a 10ne (d) lo0 1oiC
(a) MCl 1s
more easily hydrolysed than MCI, S6. Te order of inereasing polarity in HC1, C,. H,O and
) MCI, ts more volatile than MC HF molecules is
() MCl, is soluble anhydrous ethanol than (a) co, HC1, H,0, HE
more in
MCI bIE H.O, HC1. CO
(d) MCT, s more ionie than NtC () Co,. HC, HE, H,O (d) CC HE, H,0, HC
48. The
charge size ratio of a cation detemines its
po latizing
57. Out of the following which has highest dipole moment?
power which one of the
toflowing sequences represenls (a) 2.2-dimethyl propane
the mereasing order of the polanzing power (b) trans-2-pentene
Cattonhc species, K", Ca", Mg.
o the
Be (c) cis-3-hexene
(a) Mr Bee" <R <Ca (d) 2,2.3.3-tetramethyi butane
( b )Be K° * Ca* Mg
58. For the fomation of covalent bond, Ihie difterence in the
(c)KCa? Mg Be value of elcctronegativities should be

d)Ca Mg *Be*K ia) Equal to ur less than 1.7 (6) More than 1.7
49, The correct statement for the molecule Csl, is (C) 1.7 or more (d) None of these
(a) lt is a covalent molecule 59. Which of the following molecules will show dipole
(b) lt contains Cs andT moment

(e) lt contains Cs" and tons (a) Methne (b) Carbon tetrachloride
(d) lt contains Cs", I and lattice 1, moleeule (o) Chloroform (d) Carbon dioxide
60. Which bond angle 0 would resuit in the maximun
dipole
for the tniatomic molccule
Dipole Moment oment
(6) 0 = 1 2 0
R)
(a) b=9 0
50, Whuch rair of molecules will have permanet dipole (c) 0= (d) G= 180
150
nioment ior both members 61. Carbon tetrachloride hus no net dipole moment because ot
(al NO, and 0, (b) SiF, and CO,
(a) Its planar structure
te) SiF and NO (d) NO, and CO (b) Its regular tetrahedral sthucture
Sl. I e moiecule wlitch has zero dipole moment is (e) Sumilar szes of carbon and chloriie atous
a b) BE (di Similar electron aftinities of carbon and chlorine
(d)Cr
 Structure 4.3
Ciemical Bending and Molecular

structures 1s:
Whh of the toliowng has covalent bond" Tbe correct order of stability of these
31.
AIC a)1>I1>I (b)III>1>I
(d) li1 > 1>1
Nal td) MgCl fe) 1> I11I
39. Point out incorrect statement about resonance
s the dstorton ot the shape of an anion
32. Polarnzution ta) Resonance structutes should have cqual enerEy
cation Whrch of the lollowing
by an
adpK erotly placcd (b) In resonance stnuctures, the constituent atoms shoul
stalcnienits ts corrpct

is broughi about by a cation of be in the same position

(a Maxamun polarization (C) In resomance structures, there should not be ihe sarme
hgh charge
is
brought about by a cation of number of clectron pars
t6 Mnimam polanzation in the location
(d) Resonance structures should differ only
low radius
ol electrons around the constituent atoms
tc) A large cation
is
likely to bring about large degree of a

polarizatio
40. In compound 0,SC(NH,), the geometry around the S, N,
large degree of and number of resonating structure are respcctively
d) A small anion is likely to
undergo a

three
polurzation (a) trigonal planar, trigonal pyramidal and
character ts assocatcd with the (b) tetrahedral. pyramidal and two
33. Maximun covalenit
(C) tngonal planar, tetrahedral and three
compouna (d) linear, pyramidal and three
Nal () Mgl
d))Al 41. Which of the following is lesser acceptable resonating
c) AICI
LiCl, RbCI, BeCl, anad MgC1, the compounds structure of N
34. Amongt
with the greatest and the least ionic character, respectively.
to-N- b N=N
(a) Licl and RbC (h) RbCl and BeC1,
(c) RhCT and MgC1, (d) MgC1, and BeC1, N N=N
is least soluble among the tuorides of alkali metals,
35.i
hecause 42. Which of the tollowing pairs constitute resomance

signilicant covalent character

(a) saaller size
Li inpart structure?
in LiF
(b) the hylralion cnergies of Li and F are quite higher (a)H,C-N and H,C-0-N=0
the smaller
c) lattice energy of LiF Is quite higher diue to
size of Li and F O
(d) LaF has strong polymeric netwoik
in solid
b) 1,C-C and HC
and H,C CH
36. SnC, s a covalent Iiquid because
to
(a) cectro clouds of the CT ions are weakly polartzed (c)H,C-C-CH and H,C-C=CH;
Cnvefop the cation.

(oj elcetron clais of the CT ons are strongly polarized OH

to cnvclop the catioL. (d) H,C CH- CH-CH, and H,C-CH,-CH= CH,
tc) its molecules are attracted lo one another by strong 43. Which ofthe following staterment about resonance energy
van der Waals forces 1s Wrong
hybrid and
energy of the
resonance
di Sn shou s (a) The difference in
37. Which of
inert
the
etiect.
pair
tollowing Lewis structure does not the most stable contributing structure (having least

contribuio in teiaiice
energy) is called resonance energy

(6) The difference in energy of the resonance hybrid and

the most stable contributing structure (having highest
energy) 1s called resonance energy
and
(c) The difference in
energy of
the expermental
calculated enthalpies (bond enthalpy. formation or

il combustion or hydrogenation) 1s called resonance

4ak
dhIN
energy which
(d) Resonance energy 1s the amout of encrgy by
i e conpound is stable.

.
Aqucous solutien of two conmpounds M, OH and
, Ol are prepared in two dtferent beakers. If the
 and Moiecular Structure 4.5
Chemical Bonding

which has 70. Orthe loliowing molccules, the one, which haa permancnt
62 Pik out the molecule zczo
dipole monent

ar NH b) iH.O Jipoie tiotnent, is.

(a) Sil, (b) BF,

c BC1 (d So.
63. whach las a E u r n dipole moment" (d)PE
b) 71. Increasing order of dipole moment is

t) CFNIl, NE,1,0
b)CFNH,H,0 NF,
(c (d) ( ) CFNE,H,O NI,
td)CF NE, NH, H,0
72. Which conitains both polar and non-polar bonds?

thoncnt ot iBr 1s 1.6 *

10 cm and () NH,CT (b) HCN

b4. The dpole
interatoniC Spacing 1s 1A. 1he a 1onic characler of HBr (C) H,O, (d) CH
73. The corect sequence of dipole moments among the
(b) 10 chlondes of nethane is
(o) 15 (d)27 (a) CHCL, CH.C1,> CH, C> CC
charge
tne konic is 48 *

to esu
65. In a
poar nhoiecuie. (b)CHC1, CH,CI>CHCI,>CCI
If the inter ionic distance is 1 A unit, then the dipole
() CH,C>CH,C1,>CHCI,>CC
(a) 418 debye
tb)4I8debye (d) CH.CL, CHCI, CHC>CC
(c)48debye (d)048 dehye 74. The geumetry of H,s and its dipole moment are:

66. Or the ollowing conpounds, which will have a zero (a) angular and non-zeto (b) angular and zer
dpole moment (c) linear and ron-zero (d) linear and zero

(a)I,I dichloroethylene 75. Which of the following has been arranged m order o1
(b)cis-1,2 dichloroethyicne
evreasing dipole moment?
fc) trans-1, 2 dichloroethy lene
(d) None of 1hiese fa) CH,Ct> CH,F> CH,Br>CH
67. B, and NE, both molecules are covalent, but BF, is non byCH,F> CHCT CHBr CHI
polar and NF, is polar Iis reason is () CH,CT>CH,Br> CH,> CH,F
state boron ts metal and nitrogen
ay In uncombincd is
(dh CH,F>CH,CI> CHI>CH,Br
gas 76. Which of the following has the least dipole moment:
(b)B Fbund lias no dipole moment whercas N-Fbond
(a) NE, (b) CO,
has dipole moment

(c) The size of boren atom is stnaller than nirogen )SO, (d} NH
77. For which of the following moleeule significant u = 0
(d) it, is planar whercas N, 1s
pyranid
Wlichof following is the cornectorder of dipole
moment
68.

(O
(b)ll>>
(d l111
69. ATange the following compounds in order of inerCusing
m-dichlorobenzene n .
(O
poic r h e t t tolacne (h.
odihlorehenzens ill), p-dichlorobenzene tV OH SH
)IVI I1 il (a) Only ti) (b) () and (
taltINI i l
(e) Only (im (dh(it) and (iv)
 4./
Oenwal loniling ant Asiaular ftrsikar

T06, Which caunot be gplainod by VI

96 M.C, r c t wwh watcr toring propyne C} la
iaj tio s p u and tuopr bonds (a OverlaPpg
onts Bond loratiot
bj thiee suga atid one pr
(C) Paramagnctic nature ol oxyp
heids
a) twio sugn atid onit pi
nolicules
(di tao siga atid
three pi xonds (d shapes f
107. Wlichi of the following Jcad to botidng
ot honds by overlappng of ulomic orbitals s

97. The sitmgik (a

(a)2- PT P*P
c ) - p - PP (dP P P
(
be shown
98. Etiective oCrlapping will by.
VSEPR Theory and Hybridisation
a)

108. Ia which of thie folowing molecules/ions are all the bor

(c) d All the abeove
cquat
of a diatomic molecule is z, molecular orbitals
Main axis which of the orbital? (a) B b) S
P.and p, overlap to form, following
(a) t-tiolecular orhital ()o-molccular orbital Sif, Xel
thie wo spccics ate ot
bond will fom 09. In which of the ollowing pairs,
c) o-molecuiar orbital (d no
s0structural"
thie (Eof two
100. Which plot best reprevents potential energy lorrm NO, (b PCT, and SiC,
hydrogen atotns as hey approach one another to a

tayCo, and,
hytrogen molecule (e) PF, ad Br d)
Al and St
110. The hybridization of orbitals of N atom in NO, O, aid
NI, are respectively
(b)p.
(a)py
distaliccC
distanice (pp' (d)sp-pp
111. The stiucture of lF, 1s
(a) square pyratmidal o) trigonal bipyramida
(d)
(C)octahedral (d) pentagonal bipyramidal
112. The conipound in which all carbon atoms make une of s
istalice distance
bybrid orbitals for bosd ormation is
Carbon dioxide, C: Benzene.
101. A. tetacyaniometlhane, B:
(a) HCOOH tbyN.Co
D:1, 3-butadiene
Ratio of s and p bond is in order
(b)A BD C
(c)(CH),cO (d)CHCHO
(a) A BC D 113. On tybridization of one sand ome p-ortbital we get
(c1A -B C D
(dhCDAB (a) two mutually perpendicular orbitals
b) two orbitals at 180
102. How many bonds are there in | O
(c) four orbitals dirccted tetrahedrally
ta) 13 (b)23 (d) three orbitals in a plane
tc1 20 (d 26 114. Among the tollowing species, identity thic iostuctual
Tow and r-bonds thiere in salicyclic acid?
Ts. nany G- are
puits
ia) 10s, 47 tb lbo,4
N, NO, , BF, H,0 . HN,
lc 18c, 2a (d) led, 2
Jand [BF, H, O
104. The ratio ot a and bonds n benzene 1s (a) [N, N0,
cb)[NF, HN, INO, , BF
dis
() [NE, H, OJand [NO,, BF
Ts, The enokic tirn of actone contas (d)[NF,. H, o] and UN. BE

awg pnd andous paifs 115. The struc ture ot Aet

(a) tetraiedral
1 0 s t i p bond atd 1 lone paits squure pyraatidal
c) gare planar d octahedral
4 9sigs p d anl epuits
46 Oomty

Valence Bond Tomation of fhotne tmoiccule will be

Theory (VBT) 87. The bond in the
(a) Dic lo s Overlapp
8. oh FE, and NF, are covalent cotpounds BP, Is
anon
poiat conipond but Nf iNpolar The reason is that (b)Due to s-poverlappng
(c) Due top poverlappin
Boun na soihd and itrogen ts a gas tn free state
hy bridization
(d) Duc to
iiB, panar hat Ni,is pyramdal in shape are wrong
88. Which of the foilowing
tiuron bs & ntalloid wile rittogen is a not-metal not exist
(a) SH, and BCI, do
d) Atomic sue of toroti amaller than that of ittogen are two dn bonds m SU
(6) There pt
79. In whuch of the ollowing species, is the underlincd tetralbedral ion.
() Sel, and CH, are
carban bas s hybridisation
(d1" is a linear molecule wiüh sp'd by bridisation
bond with r as
tay CH,COO (bCHCH.OH 89. which of the folowing overlaps gives
a a

cjCH,cOcCH,
d CH,-CH-CH nteruclear axis?

80. Among the followmg compounds, the one that is potar (b)s and p,
(a) andp
and as cezitral atom with spr bybridisation is
(C)saand p, (did and d
() li,CO, (b) SiF 0. Which of the staletnents is correct about S0,
Jone ot eevtros
tc) BE (d)HCto w o a n u t nio pair
ta to 6,
81.The hont between tao dentical noD-mctal atoms has two one
a
6 d and
puir of clectrons (C) two G, wo * and oe Jone pair

al uncqualy sharcd betwcen thie two (dy none of these

would give the strongest
b) trasterrcd fully from one atom fo nother 91. Which -orbitals ovetlapping
bond"
tcj with identicaB spins
tdi cqually sharcd between them

82. Which of the tollwing will provide the most cticient

b
averlap
a b)s

tw0 carton afoms

83. The nunber and type of honds tetwecn

in Cat ( ) bonds
92. Ratio of a and n bonds is maxinurni in

ta) one suga (oj and one pi (b) tetracyano niethane

(a) nuphthalene
honids
sagma fo) anid twopi
(a)
(bj one (o) enolic fom of urca ( d ) cqua
and aie halt pr (7) onds
tcj one siga (o) 93. Which of the followig is true staleneri

one stgma (gj bond are in

(a (a) All the carbon in HCC-CuC-C-CH,
84. Which is not truc accoding to VBT?
a) A covalent bond is fomcd by the overlapping ef
s
rbitats wanh uiyaircdl clectrotts
o oppAe hybridesaton.
the ot (b) In CHCN),, there are six 'a bonds
covalerit bond iIs tomed by overlapparng
A
t6)obitals wath wnpaircd electronts of sane spns. ()In C all Care sp hy bridized
the stronger is
tie exlel of everlapping (d) In C,O,. all the carbons are in sp hybridisation.
e
The grcaler
ihe oat. 4. HCN and HNC molecules have equal number of
only the directon of
dhOerlayping takes place in a) lone pair and o bonds

aNiun eletrom denuty of hie 0zbital. (b)a bonds and n bonds

bond of
carton atoms mC-¬ Stngle
AS. The by brviizalion of (c) bonds and lone pairs
I-CCCHCH,Is (dlone puirs, a bonds and bonds
(al
b 95. Alyl cyanide has
(a) 9 sigma bonds and 4 pi bonds

(5)9 sigma bonds, pi

bonds and 1lone pair
(e) 8 sigma bonds and 5 pi bonds
(d) 8 signa bunds, 3 pi bonds
d
CHAPTER Chemical Bonding and
Molecular Structure

SECTION A: TOPICWISE QUESTIONS

3s
lonic, Covalent and
Coordinate Bonds X:
L2 2p 3y"4
Lattice Energy, Y.L 2 2p' 3s 3
dioxide. One
are wo forms of nitrogen
L. NO. and N,O, while other in liquid state. The
The expected compound formed by combination of Xand
exists tn gaseous state w i l l be expressed as
nature ot NO, and N,O, torms are

(a) both are parumagnetnc

(b)A1
e) (dy
bi both are dramagnetic
its outer
8. An atom of an element 4 has three electrons
in
is diamagnctic
(c) NO, is paramagnetic while N.O, shell and B has six electrons in Tie
oulermost shell.
(d) NO, is diumagnetc while N,O, 1s pararnagnetic
1ormula of the compound fomed between these two wil
elements has the tendeney to
2. Which anong the tollowing
Torii covalent compounds?
(b) Be (a) 4,,
(a) Ba
(d) Ca A td)
(C) Mg
electron The electronic configuration of four elements L., P. Q and
KO, AIO, Ba0, and NO, unpaircd
is 9.
3. Among .

R are given in brackets

present in
(a) No, and Ba0, (b) KO, and Alo, L(1s.2s.2p): P(1s, 282p, 3s')
(d) Ba0, only 00,22p", 3 3p': R(1,2 2.3
CKO,only
4. TThe strangest bond is The formulac of ionic compounds that can be lomci
(b) Cs C
(a} Na-C between these elements are
(C) both (a) and (b) (d) Nonc (a) LP. Rl, PQ nd R,O (b)LP, RL, PQ and RO
5. The valeney of C in CO, 1
() PL, Rl, PO and RO (d)LP, RL, P,Qand RO
(a)2 (6)3
D
10. The electronic structure of four elements 4, B, C,
are
c)4 (d)-5
G, which combination will give the strongest ionic bond? (a) Is (b) I, 2 2/
(u) Na andC (b) Mg and CT (C) I2 2p (d) Is 2 2
ic) Na" and (d) Mg and O The tendency to form electrovaient bond is largest in

o
elemenis and have following elcctronc (a) A b)B
7.Two
Centigurations (c)C (d) D
 42 y
Chemat ewmula tor ak
Te imm psrephwphate sCa, 20. The number of nie, covalent amd coordinaie
nds
T ula fw ttte phehesphate w e
NTae repectney
ibPeP ta) 1, ad 1 )1,3 and 2
l e e,IO,
, td)1.1and 3
12. hit ihe
tollowingt. whih ompound will have 21. The bmds present mN,O, (g) are
ehtevalunt tyomdfint
Annts t4) enly one b)covalent and coordinae
Water
(Cal chlwke tul Chlormethane
( o n y covalent (d) covafent and ionie
, For SacL lattee 22. of the follow ing does o t contan
eners I s e keal mol, the sulvatio Which a
coordin
ceraty f Na anl CT are 97 anl 8s keal mole bond
e nely Therefore fix NaCt (s) (a) , o b) BF
tal enthalpy of sluton (d) NH
esothermic
eeic
is and
magnite
qual t 4 keal mel
25, Tattice energs compound depends upon:
b) enthalpy of mulutien
exothermie is
and
o an onie

eualt es keat magnitude (a) Charge on the ions only

8 endethermie and magnitude Size of the ions only

() Packing of the
inns only
enthapy o wluto is endothermmc and magnitude (dhCharge and size of the ions

14. The compounf

onlinate 1ond is
which contans both covalcnt and co-
Bond (Fajans
Resonance and Polarity of Covalent
Charge,Rule)
(a) CH,NNC b) CH,CN
24. In the eyanide ion. the formal negative charge is on
(dh None of these
(a) C
IS, Which of the
bond?
tollow ing contiains a coordinate covalent (b} N

a) N,o, (c)Both C and N

BaCl, Resonate betw C and N
(CHcT
H,O
25.
(d
The
cen

T6. The tormal charge O-atoms the

cmpound contaming coordinate bond is of the in 1on [: N =0:]is
SO, a) (b)*
tcl,so, (d)All of these ( (d)0
17. The structure 26. Which
of
orthophosphorne acid s of thhe following is insoluble n water?
(a) AgF b),)Agl
( ) RBr
(a)11-0- P -0- H b) o P-0-H (d) CaCl,
27.
Acompound with the maximum ionic character is formed
from
(a) Na andF (b) Cs andF
(e)Cs andi (d) Na and Cl
28. Which of the
tollowing has the highest ionic character"
( ) 0P-O-H () H- 0- P =O
MgC1, 6) CaC
H (e) BaCl, (d) BeC1,
9. which of the lolow
T8. Whch of the lollowin8 have t h
polar and
non-Olar
ing compounds has the
maximum
cOvaleit nature"

a) LicT (b) NaCT

aC NH,CI
( ) KCT
(d) AIC (d CsCT
19. Blue vitrol has 30. Among he foliowing the maximum covalent character
a) lonte bond
sown by the
conipound
is
b Comdinate bond
} TdrOgn bond (a) FeCl, b) SnCT,
(d) All the above
(c) ACI,
(d MgCl,
 4.B Chemstry
molecules ts planar?
Tl6. The hybridization of sulphur dioxde 1s: 127. Which one
of the following
(b)sp (a) N )NC
(c) PH
(d) BF
(C) sp (d) ds has maxamun number of lone
128. Which of the following
molecules, the type of
7 . In which of the following assocated with Xe?
iits
bybridization changes when
(a) Xe0, XeF;
(b)All, combines H
(a) NH, combines with (d) XeF,
(d) in none of the above (C) Xet,
(c) in both cases both sp and sp'f
129. The molecule which
possesses
in which the
cetral atom uses sy-bybrid
18. The species hybridisation is
orbitals in its bonding S (b) gaseous PCL
(a) solud PCl
(a) P (b) NH,
(d) PC
) PCI
(c) CH (d Sb, has
s
130. Which one of the following compounds
stnucture is:
119, The molecule that has linear
(b) NO, hybridizatron
(a) CO (a) CO (b) SO
(c) SO (d) Sio, (0 Co
and () NO
in 1, 1, 2, 2, tetrachloroethene
120. The CI-C-Cl angle
tetrachloromethane respectively will be about: 131. Which of the following have linear shape?
(6) NO,
(a) 120 and 109.5 (b) 90" and 109.5° (a) SnC,
90° (d) 1095 and 120" (e) FNO (d So,
(C) 109.5° and bornds, two z bonds and
contains two a
has different 132. A molecule NY,
121. In the following. which central atom
of clectrons in the valence shell of X. Them
y bridisation than others.
one lone pur
as well as bond pairs i1s
arrangement of lone paur
(a) C1,0 (b) OF
(a) Square pyramidal (b) Linear
(C)10 SO. (d) Unpredictable
(c) Tngonal planar
have undistorted octahedal
122. Which of the following number of angles between bond paiz
135. The maximum
90
structures bond pair of elcctron is observed in:
() SF, (2) PE, (G) SiF, (4) Xef,
below ()sp' hybridisation (b)sp'd hybridisation
Select the correct answer using the codes given (d) dsp hybridisation
() dsp hybridisation
(b) I, 3 and 4 atom in
(a) 2, 3 and4
134. The correct order of hybridization of the cenral
(d) 1, 2 and the following species NH, [PC1JPCl, and BC1, 1s
(C) 1,2 and3
123. The molecule which has pyramidal shape i
(a) dspr, dsp'. sp and sp (b) sp, dsp. sp'd and sp
b) SO
(a) PC1, (C) dspr. sp sp, ap (d) dsp. sp.sdsp
(C) CO (d) NO, of the following has a 3 centred 2 electron bond
orbitals used by the chlorine atom in 3 wich
124. The type of hybrid (a) B (b) NH
CIO, 18:
(c) CO (d) B.H,
(a) sp (b) sp 136. Which species has the maximum number of lone puir
of
(d) none o tnese
electrons on the central atom?
and are:
125. Molecular shapes ofl SF, CF, XeF , (a) [C1ol (b) Xe
of electrons
(a) the same with 2, 0 and I lone pair (C)S
(b) the same with 1, 1 and T lone pair of electrons 137. Amongst Cif,, B , and NH, molecules the one with n o n

(o) diferent with 0, I and 2 lone pair of electrons planar geometry 1s

(d) diferent with 1,0 and 2 lone pair of electrons (a) CIF (b) NH,
126. In which of the tollowing compounds carbon atom
(C) BF (d) None of these
undergoes hybridisation of more than one type I38. Specify the coordination geometry uroundard
() CH,cH,CH,CH, y bridization of N and Batons n a1:l comples of B

() CH,-CH-CH-CH, and NH,:

(ii) CH,=CH-CH,-CH, (a) N: tetrahedral, sp B: tetrahedral. sp*

(v) HC»C-H (b) N: pyramidal. sp B: pyramidal. sp
(a) ( ) and (v) tb(0and (iv) (c) N pyramkdal, sp?; B: planar, sp
(c) () and ( ) (J Only (i) (d) N: pyramidal, sp'; B: vetnahedrul, sp