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Abstract
Polysilicon thin-film transistors (TF-I's) are of great interest for their application in large area microelectronics and in particular for active
matrix liquid crystal displays. This is owing to the improved performances of polysilicon TKFs that allow the fabrication of active matrix
devices with integrated driving circuitry. The progressive improvement of this technology has been related to the optimization of the polysilicon
active layer, first deposited by LPCVD, then obtained by solid phase crystallization of amorphous silicon and, more recently, by excimer laser
crystallization of amorphous silicon. For circuit application there is a strong demand for high performances, high stability and low noise
devices. Some specific aspects of the electrical characteristics of the polysilicon TFTs and related to their circuit application are also discussed,
including the electrical instabilities induced by hot-carrier effects, the anomalous drain current increase occurring at high source-drain voltages
(called "kink" effect) and the low-frequency noise performances. © 1997 Elsevier Science S.A.
Fig. 1. Cross-sectional views of polysilicon films deposited by LPCVD at 630 °C and different silane pressures: (a) 100 mTorr; (b) 10 mTorr; (c) 1 mTorr
(by courtesy of J. Stoemenos).
/;
characteristics of TFTs obtained with different thicknesses of 1020
o
polysilicon thicknesses and after plasma hydrogenation. The (electrically inactive) is related to other defects, such as
DOS is reduced by increasing active layer thickness in agree- incoherent steps or second and higher order twins that are
ment with the structural analysis, and by plasma hydrogena- electrically active [20]. This implies that a high density of
tion, owing to the passivation of silicon dangling bonds. localised states is expected not only at the grain boundaries
Significant improvement in the grain size can be achieved but also within the grain. This explains how, even in large
by reducing the deposition pressure, as shown in Fig. l(b) grain (up to 5 pom) polysilicon TFTs, the electron field-effect
and (c) [2]. However, the presence of large grains is accom- mobility is limited to values of 120 cm 2 V s - 1 [ 19].
panied by a considerable surface roughness, which has been In Fig. 5 the transfer characteristics of polysilicon TFTs
demonstrated to degrade carrier mobility [ 11] as well as the employing SPC material deposited at 480 °C and annealed at
electrical stability [ 12,13]. Although this work [2] has con- 580 °C for 65 h are shown. As can be seen a considerable
siderably increased the understanding of the grain growth improvement in the device characteristics is obtained, if com-
mechanism the film roughness has limited its application. pared with the data reported in Fig. 2 for deposited potysili-
con. This improvement is reflected in a sensible reduction of
2.2. Solid phase crystallization of a-Si the DOS, shown in Fig. 6, if compared with the data shown
1 0 aa
. . . . . . . . . . . . . . . .
I I I
i . . . . . heat diffusion length during the laser pulse ( ~ 100 nm)
. ,ot.y ,ogena,--I I Z_ implies that high temperatures can be developed in the Si-
1 0 •' --'1 - - - o - - H y d r o g e n a t e d I---f---7[ ........ surface region, causing melting, without appreciable heating
....... i .... ;---1-- JJ ! ...........
( < 400 °C) of the substrate. This makes the ELC-process
compatible with glass substrates, one of the major advantage
";"E 1 0 ~; ..................... ~ . . . . . of this technique. Another advantage is that the polysilicon
obtained has a good crystallinity (see Fig. 7) with very few
0 018 ..................... ..r-. . . . . . . . . ~''{'. . . . . . . .
in-grain defects owing to the melt-regrowth process.
° ' . . . . . . .
. . . . . . . . . . . . . . .
T i;i
1 l
Depending on the laser energy density, different transfor-
mations can occur. As the energy density is increased above
1016 , , , , I , , , , I , , , , I , , , , l , , , , i .... the energy required to melt the surface of the Si-film the
0.1 0.2 0.3 0.4 0.5 0.6 amorphous layer undergoes partial melting. The resulting
E-E F (eV) structure consists roughly of two layers: an upper large
Fig. 6. Densityof states in the upperhalf of the polysilicongap for the TFTs grained layer (whose thickness is related to the primary melt
shown in Fig. 5 before (O) and after (O) hydrogenation. induced by the laser) and a lower fine grained layer (related
to the explosive crystallization) [27]. As the energy density
in Fig. 3. A further reduction of the DOS, especially in the is increased the grain size increases (see Fig. 7) reaching a
so-called deep states associated to silicon dangling bonds, maximum when the Si film is almost totally melted and only
can be achieved by plasma hydrogenation (see Fig. 6). few crystalline clusters, sparsely distributed, remain
unmelted. When this condition occurs the grains grow later-
2.3. Excimer laser crystallization of a-Si ally around the seeds, until they impinge on each other and
grain size in excess of 1 ~m can be reached (see Fig. 7(c) ).
Further improvement in the polysilicon TFTs perform- This particular condition is often referred to as super lateral
ances has been obtained by the introduction of ELC polysil- growth (SLG) [28]. At higher energy densities the film
icon active layers leading to electron field-effect mobilities completely melts and substantial undercooling of the liquid
> 100 cm 2 V s - i [21-26]. Excimer lasers emit in the UV occurs before solidification via homogeneous nucleation and
region (output wavelengths 193 nm, 248 nm and 308 nm for growth can take place, resulting in a small grain structure
ArF, KrF and XeCI gas mixtures, respectively) with a short [28].
pulse duration (10--30 ns). The combination in Si of strong Since in polysilicon TFTs electron field-effect mobility is
optical absorption of the UV light (oe> 106 c m - 1) and small found to increase with increasing grain size [ 29] it is obvious
Fig. 7. SEM images of Secco etched 80 nm thick polysiliconfilms for differentexcimerlaser irradition conditions: (a) 360 mJ cm-2; (b) 460 mJ cm-2 and
(c) 520 mJ cm-a. During laser irradiation the substratetemperaturewas kept at 340 °C.
86 G. Fortunato / Thin Solid Films 296 (1997) 82-90
1°11
the same, therefore, insensible to pulse-to-pulse fluctuations
or beam non-uniformities. This should allow a large process
window and TFT fabrication to verify this point are currently
104 s
in progress [38].
-20 -15 -10 -5 0 5 10 15 20
Vg, PC]
Fig, 8, Transfer characteristics of both n- and p-channeI TFTs fabricated on
3. Some relevant electrical characteristics of polysilicon
polysilicon film obtained by ELC in the SLG regime (after Ref. [30] ).
TFTs for circuit application
that the most attractive regime is represented by the SLG. In
For circuit application there is a strong demand for high
fact, excellent performances in TFTs employing such mate-
performance, high stability and low-noise devices. We have
rial can be obtained, as shown in Fig. 8, with electron-field
already discussed in the previous section how the material
effect mobilities in the 300-400 cm 2 V s-1 range [30-32].
properties can influence the device characteristics as well as
However, owing to its peculiar mechanism, the SLG regime
the technological aspects to achieve high performances.
corresponds to a narrow processing window and large non- Some specific aspects of the electrical characteristics of the
uniformities in the grain size distribution and, consequently, polysilicon TFTs and related to their circuit application will
in the device performances are observed. In fact, when be now discussed. It should be pointed out that a successful
unmelted crystalline clusters are sufficiently apart, homoge- circuit design clearly relies on the understanding of the elec-
neous nucleation will be triggered between the grains leading trical properties. The results presented here are relative to
to a situation depicted in Fig. 7(c) with a mixture of very TFTs employing SPC-polysilicon, which represent the
large grains and small grains. devices currently more established and well characterized,
Several approches to control the lateral solidification by made at THOMSON-CSF, according to a fabrication process
inducing lateral thermal gradients [33,34] or by sequential described in Ref. [ 39]. The devices used for the experiments
lateral solidification [ 35 ] have been recently reported. These were not post-hydrogenated and the transfer characteristics
techniques, often directly related to techniques developed in have been already shown in Fig. 5.
the middle 1980s for SOI devices [36], although have pro-
duced further insight on the SLG-process, are still far from 3.1. Hot-carrier effects
representing practical solutions for large area fabrication.
Another very promising approach is the combined use of Since supply voltages applied to circuits employing poly-
SPC and ELC techniques [37]. When very large and highly silicon TFTs tend to be relatively high (10-30 V), the pres-
defected grains, obtained by SPC, are partially melted by ence of high electric fields can induce hot-carrier effects
excimer laser irradiation, the bottom unmelted layer will act (HCE). The HCE in polysilicon TFTs have been recently
as seed during the regrowth process. Most of the in-grain investigated, both in n-channel [40-43] and p-channel
defects are eliminated in the melted region by the melt- devices [44,45], and appear to be the predominant mecha-
regrowth process, as shown in Fig. 9, while the grain size nism for device degradation. In view of the application of
remains unaffected. In this way large grains with good crys- such devices in active matrix LCD driving circuitry or
tatlinity, extending from the free-surface down to the melt- SRAMs, the stability of the electrical characteristics becomes
depth, can be obtained, as shown in Fig. 9, combining the an important issue. Therefore, it is mandatory to investigate
beneficial aspects of the two techniques. It should also be the HCE in order to determine the long-term reliability of
pointed out that, since in field-effect devices the channel polysilicon TFTs. Indeed, the application of prolonged bias-
region is confined within a few nanometers beneath the insu- stress in n-channel TFTs, operated at high source/drain volt-
lator/semiconductor interface, the two-step annealing proc- age, Vds, and different gate voltage, Vv can greatly affect the
ess appears to be a very robust process for TFT fabrication. transconductance gm as well as the off-current [41]. Tran-
In fact, as long as the melt-depth is larger than a few nano- sconductance degradation is commonly related, in n-channel
meters and smaller than the film thickness, the top-surface MOSFETs, to a negative effective oxide charge, controlled
structure and defect density of the polysilicon film should be by the generation of acceptor-type interface states
G. Fortunato / Thin Solid Films 295 (1997) 82-90 87
3.2. "Kink"effect
10.7
10000
,,,f
1000
;zl0,t
100
,,/
10.,0t
,/'"
10 10"N [ ~ ~ t ) ,
1040 104 I04 I0"(
I d (A)
1
Fig. 13. Normalizeddrain current spectraldensity, (S~/Ia)2, at 20 Hz vs. the
o.~.o~ie.,.o~o,.4.o~io~.~.o~ioo mean value of the drain current, Id, for TFTs with channel lengthL = 5 ~m
E (V/cm) (0), L=20 txm (11) and L=40 ~m ( • ). Continuous line are the best fit
Fig. 12. E l e c t r o n i m p a c t i o n i z a t i o n rate, G, vs. electric field, E, for c-Si
to Eq. (2).
( c o n t i n u o u s line, after Ref. [ 5 4 ] ) a n d for p o l y s i l i c o n ( d a s h e d line), as
deduced by 2-D simulations. in the system. In order to discriminate between the two mech-
anisms the normalized drain current spectral density can be
fitting the experimental transfer characteristics, measured at analysed. In fact, according to the carrier number fluctuations,
low source/drain voltage Vd~ [53]. Fig. 11 shows both the at low values of the drain current (S~/Id) 2 shows a plateau
experimental and simulated output characteristics of the before decreasing as I~-2 as the TFT is turned on [57]. Vice
device, which are largely influenced by impact ionization versa, in the case of mobility fluctuations, (S~/Id) 2 is expected
occurring at the drain end of the channel, for different values to be inversely proportional to Id [57]. Fig. 13 shows (SI/
of Vg. The optimised impact ionization rate, modelled accord- Id) 2 vs. Id for different channel lengths [55]. From the shape
ing to the Chynoweth expression [53] and shown in Fig. 12, of the (S~/Id) 2 the noise in polysilicon TFTs can be ascribed
was found to give a good agreement with experimental data. to carrier number fluctuations [55]. In order to confirm this
It is worth pointing out that, in order to fit the data at different point we have fitted the experimental data with the theoretical
temperatures, there was no need to modify the room temper- expression for the (S~/I~) 2 in the case of carrier number
ature impact ionization parameters. In particular, this is in fluctuations [57]:
contrast with the temperature dependence usually observed
S I / I 2 = ( 1 + a~effld/gm)a(gm/Id)ZSvfb (2)
for the impact ionization rate in c-Si [54], where increasing
temperature implies a rate decrease, as a result of increased where a is a constant, tzoffis the effective carrier mobility in
thermal scattering. A possible explanation could be related to the channel, Cox is the gate oxide capacitance per unit area,
the relatively lower impact ionization rate found in polysili- gm is the device transconductance (evaluated from the exper-
con than in c-Si, as shown in Fig. 12. This suggests that the imental data) and Svrb is the fiat-band voltage spectral den-
scattering with defects (such as silicon dangling bonds, impu- sity. The continuous lines shown in Fig. 13 represent the best
rities, etc.) is the limiting process of impact ionization in fit of the data to Eq. (2) and, as can be easily recognized, a
polysilicon. very good agreement is observed. The mean value of the
fitting parameter oewas found 1.2 × 104 V s C - 1, close to that
3.3. Noise performances reported for c-Si MOSFETs ( 104 V s C - 1 [57] ), while the
value of the fitting parameter Svfb was around 1.2 X 10 - s V a
Although the noise performance is a critical device param- Hz - 1 for L = 20 tam. The noise in polysilicon TFTs appears
eter for analogue circuits, the noise characterization of poly- much higher than in c-Si MOSFETs [58] and such a higher
silicon TFTs has received little attention. It has been recently noise level could be related to fluctuations of the barrier
shown that polysilicon TFTs are characterized by a strong 1/f heights present at the polysilicon grain boundaries or to a
noise [55], commonly observed in c-Si MOSFETs [56,57]. higher density of traps in the oxide close to the interface.
The origin of the low frequency noise in MOSFETs has Further investigations are needed to clarify the microscopic
been related to either carrier, fluctuation or carrier mobility mechanisms causing the excess noise observed in polysilicon
fluctuation. In the carrier number fluctuation model, based on TFTs.
the Mc Worther theory [56], the fluctuations of the drain
current are induced by fluctuations of the interfacial oxide
charge owing to the dynamic trapping and detrapping of free 4. Conclusions
carriers into slow oxide traps. In other words, owing to the
interface charge fluctuations the flat-band voltage, V~, fluc- The technological evolution of the formation process of
tuates and, therefore, also the charge induced in the semicon- polysilicon active layer for TFTs application has been pre-
ductor fluctuates. In the mobility fluctuation model, the sented. The technique that currently produces the best quality
fluctuations of the drain current arise from the fluctuations of polysilicon is ELC of a-Si, enabling the fabrication of TFTs
the carrier mobility possibly through a fluctuation of the scat- with electron field-effect mobility in excess to 100 cm 2 V
tering cross-section. This results in a 1/fnoise whose inten- s - i. The achievement of such performances opens the doors
sity is inversely proportional to the total number of carriers to the fabrication of driver-monolithic AMLCD devices.
G. Fortunate / Thin Solid Films 296 (1997) 82-90 89
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