𝑅𝑎 = 𝑁𝑂3

𝑅𝑑 = 𝒂𝒄𝒆𝒕𝒂𝒕𝒐
𝑅𝑐 = 𝑎𝑚𝑜𝑛𝑖𝑜
𝑅𝑒 = 𝑅𝑎 − 𝑅𝑑

1 6 1 3
𝑅𝑎 → 𝑁𝑂3 + 𝐻 + 𝑒 → 𝑁2 + 𝐻2 𝑂 𝐺𝑎 = −72.2
5 5 10 5
1 3 1 1
𝑅𝑑 → 𝐶𝐻3 𝐶𝑂𝑂 + 𝐻2 𝑂 → 𝐶𝑂2 + 𝐻𝐶𝑂3 + 𝐻 + 𝑒 𝐺𝑑 = 27.4
8 8 8 8
1 1 1 1 9 1 1
𝑅𝑒 = 𝑁𝑂3 + 𝐻 + 𝐶𝐻3 𝐶𝑂𝑂 → 𝑁2 + 𝐻2 𝑂 + 𝐻𝐶𝑂3 + 𝐶𝑂2
5 5 8 10 40 8 8

Rs=Rc-Rd

𝐶5 𝐻6.2 𝑂1.8 𝑁0.4

𝑛 = 5; 𝑎 = 6.2; 𝑏 = 1.8; 𝑐 = 0.4

𝑑 = 4(5) + 6.2 − 2(1.8) − 3(0.4) = 21.4
4.6 0.4 0.4 1 8.6
𝑅𝑐 → 𝐶𝑂2 + 𝑁𝐻4 + 𝐻𝐶𝑂3 + 𝐻 + 𝑒 → 𝐶5 𝐻6.2 𝑂1.8 𝑁0.4 + 𝐻 𝑂
21.4 21.4 21.4 21.4 21.4 2
1 3 1 1
𝑅𝑑 → 𝐶𝐻3 𝐶𝑂𝑂 + 𝐻2 𝑂 → 𝐶𝑂2 + 𝐻𝐶𝑂3 + 𝐻 + 𝑒
8 8 8 8
1 1
𝑅𝑠 → 0.089𝐶𝑂2 + 0.0187𝑁𝐻4 + 𝐶𝐻3 𝐶𝑂𝑂 → 𝐶 𝐻 𝑂 𝑁 + 0.027𝐻2 𝑂 + 0.106 𝐻𝐶𝑂3
8 21.4 5 6.2 1.8 0.4

Calcular A
 𝜀 = 0.3
𝑮𝒑 = 𝟑𝟎. 𝟗 − 𝑮𝒄; 𝑮𝒄 = 𝑮𝒅 → 𝑮𝒑 = 𝟑𝟎. 𝟗 − 𝑮𝒅 → 𝑮𝒑 = 𝟑𝟎. 𝟗 − 𝟐𝟕. 𝟒 = 𝟑. 𝟓
𝒏=𝟏
𝐺𝑝𝑐 = 3.33 × 𝑚 → 𝑚 = 𝑃𝑀𝑐𝑒𝑙𝑢𝑙𝑎𝑠 × 𝑐𝑜𝑒𝑓𝑖𝑐𝑖𝑒𝑛𝑡𝑒 𝑒𝑠𝑡𝑒𝑞𝑖𝑜𝑚𝑒𝑡𝑟𝑖𝑐𝑜
𝑃𝑀 = 100.6 𝑔/𝑚𝑜𝑙
1
𝑚 = 100.6 × = 4.7𝑔 𝑐𝑒𝑙𝑢𝑙𝑎𝑠
21.4
𝐺𝑝𝑐 = 3.33 × 4.7 = 15.51
𝐺𝑟 = 𝐺𝑎 − 𝐺𝑑 → −72.2 − 27.4 = −99.6
3.5 15.51
0.31 + 0.3
𝐴=− = 2.14
0.3 ∗ −99.6
1 1
𝑓𝑠 = = = 0.32; 𝑓𝑒 = 1 − 𝑓𝑠 = 1 − 0.32 = 0.68
1 + 𝐴 1 + 2.14

𝑓𝑒 𝑅𝑒 = 0.136𝑁𝑂3 + 0.136𝐻 + 0.085𝐶𝐻3 𝐶𝑂𝑂 → 0.068𝑁2 + 0.153𝐻2 𝑂 + 0.085𝐻𝐶𝑂3 + 0.085𝐶𝑂2

𝑓𝑠 𝑅𝑠 = 0.02848𝐶𝑂2 + 0.006𝑁𝐻4 + 0.04𝐶𝐻3 𝐶𝑂𝑂 → 0.015𝐶5 𝐻6.2 𝑂1.8 𝑁0.4 + 0.009𝐻2 𝑂 + 0.034 𝐻𝐶𝑂3
𝑅 = 0.136𝑁𝑂3 + 0.136𝐻 + 𝟎. 𝟏𝟐𝟓𝑪𝑯𝟑 𝑪𝑶𝑶 + 0.006𝑁𝐻4
→ 0.068𝑁2 + 0.162𝐻2 𝑂 + 0.119𝐻𝐶𝑂3 + 0.057𝐶𝑂2 + 0.015𝐶5 𝐻6.2 𝑂1.8 𝑁0.4

𝑔𝑐𝑒𝑙𝑢𝑙𝑎𝑠 100.6 ∗ 0.015

𝑌( )= = 0.179 𝑔𝑐𝑒𝑙𝑢𝑙𝑎𝑠/𝑔𝑎𝑐𝑒𝑝𝑡𝑜𝑟
𝑔𝑎𝑐𝑒𝑝𝑡𝑜𝑟 0.136 ∗ 62
𝑔𝑐𝑒𝑙𝑢𝑙𝑎𝑠 100.6 ∗ 0.015
𝑌( )= = 0.201
𝑔𝑑𝑜𝑛𝑎𝑑𝑜𝑟 0.125 ∗ 60