the Bohr model of the atom improved Rutherford’s atomic model. ( S9MT-IIa-21) ▪Discuss the features of the atomic theory using the characteristics of Bohr’s atomic model. ▪Describe ho the Bohr Model of the atom improved Rutherford’s Atomic Model DEMOCRITUS (400 B.C.) ▪A Greek philosopher ▪Was the first person to think about an atom’s existence. ▪Believed that matter was composed of tiny indivisible particles called atoms. ▪He had no experimental evidence to support his thoughts. JOHN DALTON (1766-1844) ▪A meteorologist ▪Unlike Democritus, he had experimental evidence to support his theory. ▪Dalton had four major points (postulates) to his theory. DALTON’S THEORY 1.) All elements are 2.) Atoms of the same composed of indivisible element are identical. particles called atoms. The atoms of any one element are different from those of another. DALTON’S THEORY 3.) Atoms of different 4.) Chemical reactions elements mix or occur when atoms combine in whole separate, join, or number ratios. rearrange. Example: Oxygen In a chemical reaction, combines with hydrogen atoms of one element to form water in a 2:1 NEVER change into ratio. another. SIDE NOTE… NOT ALL OF DALTON’S POSTULATES WERE CORRECT. ▪ We now know that atoms are indeed divisible – atoms can be broken down into their subatomic particles, protons, neutrons, and electrons (and these too can be broken down even further!). ▪ Quarks and gluons are the building blocks of protons and neutrons, which in turn are the building blocks of atomic nuclei. SIDE NOTE… NOT ALL OF DALTON’S POSTULATES WERE CORRECT. ▪ We also know that not all atoms of the same element are identical. Isotopes exist for different elements.
▪ Isotopes are members of a
family of an element that all have the same number of protons but different numbers of neutrons. The number of protons in a nucleus determines the element's atomic number on the Periodic Table. CATHODE RAY TUBE EXPERIMENT ▪In the tube was an inert gas, and two plates, a positive and a negative. ▪The particles in the gas were attracted to the positive plate. ▪Therefore, the particles MUST have a negative charge. (Opposites attract.) JOSEPH JOHN (J.J.) THOMPSON (1859-1940) J.J. THOMPSON ▪Discovered the electron. ▪From his experimental evidence, he believed that the atom was a solid positive sphere with electrons shoved into the sides of it. ▪His model was said to resemble a popular English dessert called Plum Pudding, and so his model was deemed the “Plum Pudding Model.” ERNEST RUTHERFORD ▪Used the gold foil experiment to discover the nucleus. ▪Shot high energy beam of alpha particles into gold foil. ERNEST RUTHERFORD CONCLUSIONS Observation Conclusion Most of the alpha particles The atom is mostly empty went through he concluded… space Few particles were deflected The alpha particle came close at small angles he concluded… to something small and positive (nucleus) Very rarely particles were The alpha particles hit a deflected at large angles he small, very dense, and concluded… positively charged center (nucleus) EUGENE GOLDSTEIN (1850-1930) ▪ Goldstein discovered the proton.
James Chadwick (1891-1974)
▪ Chadwick discovered the neutron. NIELS BOHR ▪He proposed that electrons are arranged in concentric circular orbits around the nucleus. ▪This model is patterned on the solar system and is know as the planetary model. NEILS BOHR ▪The Bohr model can be summarized by the following four principles: (1) Electrons occupy only certain orbits around the nucleus. Those orbits are stable and are called “stationary” orbits. (2) Each orbit has an energy associated with it. The orbit nearest the nucleus has an energy of E1, the next orbit E2, etc. NEILS BOHR (3) Energy is absorbed when an electron jumps from a lower orbit to a higher one and energy is emitted when an electron falls from a higher orbit to a lower orbit. (4) The energy and frequency of light emitted or absorbed can be calculated by using the difference between the two orbital energies. ERWIN SCHRODINGER ▪Schrodinger used mathematical equations to describe the likelihood of finding an electron in a certain position. ▪This atomic model is known as the quantum mechanical model of the atom. ERWIN SCHRODINGER ▪ Unlike the Bohr model, the quantum mechanical model does not define the exact path of an electron, but rather, predicts the odds of the location of the electron. ▪ This model can be portrayed as a nucleus surrounded by an electron cloud. This model introduced the concept of sub-energy levels. Thompson’s Model Rutherford’s Model Rutherford’s Model Bohr’s Model