EXPERIMENT NO.

16

1. AIM

Equipment and Apparatus Required

Probes arrangement, sample crystal (Germanium), oven, four probes setup with digital voltmeter
(range 0 to 200 mV and 0 to 2 V) and constant current generator (range is 0 to 20 mA)

2. LEARNING OBJECTIVES

2. To study the variation of resistivity of semiconductor with temperature.

3. THEORY AND FORMULA USED

The energy band gap, E , of semiconductor is given by E = 2 . 2.3026 log10 / 1/T (in K) in eV, where
is Boltzmann constant equal to 8.6 × 10–5 eV/deg., and ‘ ’ is the resistivity of the semiconductor
crystal, given by
= 0 / (W/S) Where 0 = V/I × 2 S. For function (W/S) refers to the data table given in the
calculations. S is the distance between the probes and W is the thickness of semiconducting crystal.
V and I are the voltages and current across and through the crystal chip.

Fig. 16.1: Four probe setup

LMPHY119: Engineering Physics Laboratory 99

 4. PROCEDURE

1. Put the sample on the base plate of the four probe arrangement. Unscrew the pipe holding the
four probes and let the four probes rest in the middle of the sample. Apply a very small pressure
on the probes and tighten the pipe in this position. Check the continuity between the probes for
proper electrical contents.

the hole provided.

3. Switch on the AC main of four probe set up put the digital meter in the current measuring mode
through the selector switch. In this LED facing mA would glow. Adjust the current to a desire
value (say 5 mA).
4. Note down the readings of millivoltmeter with the rise in temperature and corresponding value
of temperature.
5. Plot the graph between 1000/T along x-axis and log10

5. OBSERVATIONS AND CALCULATIONS

Thickness of the specimen = 0.5 mm
Distance between the probes (s) = 2.4 mm

Voltage
S. No. Temperature, T(K) across inner 1000/T 0 = (V/I)2 s Log10
probes,V

100 LMPHY119: Engineering Physics Laboratory

For a given sample, W/S = .................
Correction factor, F(W/S) = ................
= 0 /F(W/S) = ................
Energy band gap = 2.303×1000×2×8.617×10–5×Slope = ............ eV
Plot the graph between 1000/T and Log10

6. PRECAUTIONS

1. The Ge crystal is very brittle. Therefore apply minimum pressure for proper electrical contacts.
2. Connect the outer pair of probes leads to the constant current power supply and the inner pair
of probes to the voltage terminals.
3. The resistivity of the material is uniform in the area of measurement.
4. Measurement should be made on the surface which has high recombination, such as mechanical
lapped surfaces.

6. The four probes used for resistivity measurement contact the surface at points that lie in a
straight line.
7. The boundary between the current carrying electrodes and the bulk material is hemispherical
and small in diameter.

Suggested Readings for Students

1. B.Sc. Practical Physics by C.L. Arora, S. Chand Publication, 20th edition (2015).
2. B.Sc. Practical Physics by Harman Singh and Dr. P.S. Hemne, S. Chand Publication, 1st edition
(2011).

LMPHY119: Engineering Physics Laboratory 101