CHRULUGY& S

BIRLA INSTITUTE OF TECHNOLOGY AND

SCIENCE, Pilani
Pilani Campus
Department of Chemistry, Semester 1, 2021-22

Name Maamk Garg ID 2021 tBPSIL74f Sec/ Class 19

EXPERIMENT: ESTIMATION OF COPPER(II) BY IODOMETRY

Observations:
(A) Strength of standard copper sulphate Solution:
The equivalent weight of copper sulphate (CuSO4. SH;0) is 249.7 g. If the amount of copper sulphate
weighed is Wg. then the strength of the standard solution in 100 mL flask is
W = 5.D2
W= $
24.9724.97 M a So 5 wou 0. 02d
[IM 241.7

Strth duso,bol mouu uso, Sh d

(B) Standardization of hypo solution:

0.2 M
Herethe volume (Vi) ofstandardcopper sulphate solution pipetted out= 9..m
Observation Table:
S. No. Initial burette Final burette Volume of hypo
reading (mL) reading (mL) added (mL)

1. O.0 3.9 3.9

2. 3.9 7.8 3.1

3. 78 3.8
Concordant reading from the data set is ........3.....mL.. ° ° *

If N is the strength of standard copper sulphate; Vi is the volume of this solution pipetted out and V2

1S the volume of hypo solution required from the burette, then the normality of the sodium
thiosulphate solution is

N NXV (N)
V2
[2M
N 0.2 X20
3.9
1 . 02 SC N

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 BIRLA INSTITUTE OF TECHNOLOGY AND SCIENCE, Pilani
Pilani Campus
Department of Chemistry, Semesterl, 2021-22

(C) Determination of the unknown strength of supplied copper sulphate solution:

Here, volume (i) of copper sulphate solution of unknown strength pipetted out. ml
Observation Table:

S. No. Initial burette Final burette Volume of hypo

reading (mL) reading (mL) added (mL)

1 0. 0 6. 2 6.2
2.
6.2 2. 5 6 3
3. 12.5 18.7 6.2
Concordant reading from the above data set is .... 2m .
Similarly, if Vi is the volume of supplied copper sulphate solution pipette out and V'2 is the volume of
hypo of strength Na required to titrate, then the normality (N) of unknown solution is

NV I.0256 x6.2
N- Vi
25
[2M
O. 2 54 M

Melani Mlaculan wt.

O. 254x 244 7
Conclusion 3 . 423 m/L
be S . 2 . 3 . g/L [IM]
Strength ofthe unknown copper sulphate solution was observed to