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① A chemist working in a hospital clinical laboratory obtained the following values for uric acid in blood serum :
4. 63 4.58 4.72 4. 21.4.67 and 4.65% (a) Use the 95% confidence level to test any dubious values What
. ,
,
.
.
)
(Q -
test ) If the outlier ( 4.21 ) is excluded
Qcal -
Mean
6
Goa , =
4.IO?,g4.58l=toO.3g7/=!.g4YbFsg.tgsgt! outlier
Ig I =
4.58+4.63+4,65+4.674.722
*=4
Loathing Standard Deviation
s ( x E) 2=0.0106
-
::
" " ion
i:
o
fish :/ :/
..÷:¥sx .
4.58 O O -
5=0.050
o ,g
:r I ::÷
,
: :O: : :::*
.
:: :::: .
4. 67 0.09 0.0081 s =
€344 CV=4.l5
'
CV =
0.01075 X 100%
4. 72 0.14 0.0196 S =
0.18547236991 CV=l.O8
#x)2=O.l72 5=0.190
② Quantitative analysis student Analytical analyzed an ore sample for its lead content and obtained a mean of 4.75%
Pb for five measurements .
If the certified true value is 4.50% .
what is the (a) percent error ? (b) percent accuracy ?
1454%0475/2×1004 .
% accuracy = I -
14504-54075/2 100% x
% error =
x 100% % accuracy = I
-1-4354×100 %
% error =
0.0555 X 100% % accuracy = l -
0.5555 X 100%
%error=5.56 %accuracy=9444°#
③ Identify the data set with the highest (a) precision and (b) accuracy .
}'|j8%|tif%8#g?g%
Data set ffurtifieafue Mean rsd % error
1 O 500
- 0.444 0.09 11.2%
c- highest precision
#
4 100.0 99.1 ← highest accuracy
11.2%
1.)
=
1.) rsd = =
0.0g % error = .
2.) rsd =
9.23533--0.19 2.) % error =
1.0%633/2 x 100% =
33%
3.) rsd =
047421=0--0.0009 3.) % error =
15005%405.20/2×100 % =
9.6%
4.) rsd =
}j?}= 0.03 4.) % error
=
11096%99.1/2 x 100% =
0.9%
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