Pass guaranty Questions, IPE-2023(100% Syllabus)

Chemistry,Paper-I

Long answer questions (8 Marks)

1. Write the postulates of Bohr’s theory of hydrogen atom. Discuss the importance of this model to
explain various series of line spectra in hydrogen atom.
2. What are quantum numbers? Explain significance of different quantum numbers.
3. a) What are the limitations of Bohr’s model of an atom?
b) Explain the differences between emission and absorption spectra.
c) state Pauli’s exclusion principle, Aufbau principle and Hund’s rule.
4. Write an essay on s,p,d and f block elements.
5. What is periodicity? How the following properties vary in a group and in a period?
a) Atomic radius b) Electron gain enthalpy or Electron Affinity(EA) c)Ionisation energy(IE)
d) Electronegativity(EN) e)nature of oxides f) Metallic nature or Electropositivity(EP)
6. Define IE1 and IE2 .Why is IE2>IE1 for a given atom? Discuss the factors that effect IE of an atom.
Short answer questions( 4 Marks)
7. Explain the hybridisation involved in PCl5 molecule and SF6 molecule.
8. What is Hydrogen bond? Explain different types of Hydrogen bonds with examples.
9. Explain the formation of coordinate covalent bond with one example.
10. Write the important postulates of kinetic molecular theory of gases.
11. State and explain Graham’s law of diffusion.
12. Deduce a) Boyle’s law b) Charle’s law c) Graham’s law of diffusion d) Dalton’s law from kinetic
gas equation.
13. State and explain the Hess law of constant heat summation with example.
14. What is entropy? Explain .
15. Define standard enthalpy of formation, combustion, heat of solution and heat of dilution with an
Example.
16. Derive the relation between KP and Kc for the equilibrium reactions (various examples)
17. What is a conjugate acid-base pair? Illustrate with examples.
18. write the conjugate acid and conjugate base of each of the following a)OH- b)H2O c)HCO3- d)H2O2
e)HSO4- f)NH3
19. Explain the terms hard and soft water. write a note on a) ion –exchange method and
b) calgon method for removal of hardness of water.
20. Write any two oxidising and reducing properties of hydrogen peroxide.
21. Explain the structure of diborane.
22. Explain borax bead test with a suitable example.
23. Give two methods of preparation of diborane. How does it react with
a) H2O b )CO c) N(CH3)3 d) NH3
24. What are electron deficient compounds? Is BCl3 an electron deficient compound. Explain.
Very short answer questions (2 Marks)
25. What is Boltzmann constant? Give its value.
26. Calculate kinetic energy of 5 moles of Nitrogen at 270C. (Relevant problems)
27. What is the effect of temperature on surface tension and viscosity? Give reason.
28. What are disproportination and comproportination reactions ? Give example.
29. What are COD and BOD?
30. Name the major particulate pollutants present in Troposphere.
31. Which gases causes green house effect? Write any two adverse effects of green house effect.
32. Which oxides causes acid rains? What is its PH? Write any two adverse effects of acid rains.
33. Define receptor and sink.
34. What is PAN? What effect is caused by it?
35. What is ozone hole or depletion of ozone ? Write any two its harmful effects.
36. Name the common components of photochemical smog.
37. Define TLV?
38. Define pollutant and contaminent.
39. What is allotropy? Give the crystalline allotropes of carbon.
40. Give the hybridization of carbon in a) CO3-2 b) diamond c) graphite d) fullerene e) CO2
41. Why is CO poisonous?
42. Name any two man made silicates.
43. What are silicones? Give one example. Write any two uses of silicones.
44. Diamond has high melting point. Explain.
45. Write the use of ZSM-5.
46. Why graphite used as lubricant ?
47. Why is diamond hard?
48. Graphite is a good conductor –explain.
49. SiF6-2 is known while SiCl6-2 is not-explain
50. Why are alkali metals not found in the free state in nature.
51. Why is KO2 paramagnetic?
52. What is plaster of paris? Write its importance.
53. Why are IA group elements called as alkali metals?
54. Describe the important uses of caustic soda and sodium carbonate.
55. Which of the gases diffuses faster among N2, O2 and CH4 why?
Prepared by
T.Prasad, JL in chemistry
GJC, Gurla, VZM dt.