EndoSan 50 Revision date: 13/08/2018

Supersedes: 28/04/2016
Safety Data Sheet Version: 3

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY

Product EndoSan50

Supplier Endo Enterprises (UK) Ltd

Emergency telephone
Unit 231, Europa Boulevard,
Warrington, Cheshire
WA5 7TN
United Kingdom
enquiries@endoenterprises.com
+44(0)1925 747 101

2 HAZARDS IDENTIFICATION

Classification according to Regulation (EU) 1272/2008 (CLP)

Classification
Skin Corrosion; Category 1; (H315).
Eye damage; Category 1; (H318).
Specific target organ toxicity – singe exposure; Category 3; (H335).
Acute toxicity; Category 4; Harmful if swallowed (H302).

Hazard pictograms:

GHS05 GHS07

Signal word: Danger

Hazard statements:
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Precautionary statements:
P234 Keep only in original container.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves / protective clothing / eye protection /
face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician
if you feel unwell

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Safety Data Sheet Version: 3

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Other Hazards
Physical/Chemical Hazard: Risk of decomposition on heating. Risk of decomposition in
contact with incompatible products: metal oxides, metal ions (e.g. Mn, Fe, Cu, Ni, Cr, Zn), metal
salts, bases and reducing agents. Sustains the combustion of combustible materials.

3 COMPOSITION/INFORMATION ON INGREDIENTS

According to the EC-directives this product is a preparation. Hazardous components which must be
listed on the label:

EINECS-No. CAS-No. Components Concentration

231-765 7722-84-1 Hydrogen Peroxide < 50%

Classification Hydrogen Peroxide < 50%

Ox. Liq. 1; H271.
Acute Tox. 4; H302, H332, H335.
Skin Corr. 1A; H315, H318.

Further information product: Stabilized

4 FIRST AID MEASURES

Inhalation
Remove from exposure, lie down. Keep warm. Oxygen or artificial respiration if needed. Call a
physician immediately.
Skin contact
Wash off immediately with plenty of water removing all contaminated clothes and shoes.
Wash contaminated clothing with plenty of water to prevent fire hazard. Keep warm. If skin
irritation persists, call a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Consult a physician.
Ingestion
Rinse mouth. Give small amounts of water to drink. Do NOT induce vomiting. Never give
anything by mouth to an unconscious person. Keep warm. Call a physician immediately.

5 FIRE-FIGHTING MEASURES

Suitable extinguishing media

Water, water mist. The product itself does not burn.
Extinguishing media which shall not be used for safety reasons
Dry powder, Carbon dioxide (CO2)
Specific hazards during fire fighting
In case of fire, hydrogen can generate oxygen what can contribute to the intensity of the fire.
The product itself does not burn but it sustains the combustion of combustible material. Risk

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Safety Data Sheet Version: 3

of explosion if mixed with combustible material. Pressure build-up in confined space (risk of
decomposition).
Special protective equipment for fire-fighters
Self-contained breathing apparatus (EN 133). Complete suit protecting against chemicals
Specific methods
Cool containers / tanks with water spray.

6 ACCIDENTAL RELEASE MEASURES

Personal precautions
Avoid contact with skin, eyes and clothing. Never return spills in original containers for re-use.
Ensure adequate ventilation. Wear personal protective equipment. Remove all sources of
ignition. Keep people away from and upwind of spill/leak.
Environmental precautions
Prevent product from entering drains. Should not be released into the environment.
Methods for cleaning up
Prevent from spreading. Dam up. Very dilute solution can be washed into drains with plenty of
water. Contact the proper local authorities. Never return spills in original containers for re-use.

7 HANDLING AND STORAGE

Handling
Never return unused material to storage receptacle. Open drum carefully as content may be
under pressure. Avoid exposure. Ensure adequate ventilation, especially in confined areas.
Wear suitable protective clothing. Keep away from sources of ignition - No smoking. Keep
away from combustible material. Protect from contamination.

Storage
Keep in a cool, well-ventilated place. Keep away from heat and sources of ignition. Condition

of containers should be checked regularly. Store in original container. Store in a receptacle

equipped with a vent.

Materials to avoid: Combustible material, Reducing agents, Organic materials, Bases, metal
oxides, metal ions (e.g. Mn, Fe, Cu, Ni, Cr, Zn), metal salts, Rust, Dirt

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

General measures: Make sure there is sufficient ventilation.

Observe the directions for use.
Keep running water at hand.
Exposure limits (H2O2): MAC value: 1ppm-1,4 mg/m 3
Personal protection
Respiratory Ensure sufficient ventilation.
In case of aerosol formation: Use respiratory protective
equipment.
Hand Gloves (PVC, neoprene, natural rubber).
Skin and body Chemical resistant protective clothing. Do not wear leather
shoes. Safety shower.

Eye Tightly fitting safety goggles and face-shield. Eye wash bottle
with pure water.

9 PHYSICAL AND CHEMICAL PROPERTIES

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Safety Data Sheet Version: 3

Appearance Liquid
Colour Colourless
Odour Odourless, slightly pungent
Density: (20 °C) 1195 – 1200 kg/m3
pH (100%) 0.5 – 1.5
Flash point Not flammable
Explosive properties Not applicable
Viscosity < 1 - 2 mPa s (20 °C)
Solubility in water Complete
Boiling point/range 114 °C
Melting point/range -52 °C

10 STABILITY AND REACTIVITY

Conditions to avoid
High temperatures. UV light. Protect from contamination. Thermal decomposition > 114 °C.
Materials to avoid
Combustible material, Reducing agents, Organic materials, Bases, metal oxides, metal ions
(e.g. Mn, Fe, Cu, Ni, Cr, Zn), metal salts, Rust, Dirt).
Hazardous decomposition products
Oxygen, water vapour.

11 TOXICOLOGICAL INFORMATION

Acute toxicity
LD50/Oral/rat: > 1 193 - 1 270 mg/kg Remarks:(35% H2O2)
LC50/Inhalation/4 h/rat: 2 mg/l Remarks: (100% H2O2)
LD50/Dermal/rabbit: > 4.000 mg/kg Remarks: (50% H2O2)
Harmful if swallowed. Ingestion causes burns of the stomach and upper digestive tract.
Inhalation of aerosols may cause irritation of mucous membranes, inflammation and lung
oedema.
Irritation and corrosion
Skin: Contact with skin causes blanching and erythema. Irritating to skin.
Eyes: Liquid causes severe inflammation of conjunctiva and may cause severe damage of the
cornea. May cause irreversible eye damage.
Respiratory system: Irritating to respiratory system.
Sensitization
Did not cause sensitization on laboratory animals.
Long term toxicity
Carcinogenicity: Not classified by IARC, NTP, OSHA or ACGIH.
Mutagenicity: Metabolic activation: no. Experiments showed mutagenic effects in cultured
bacterial cells. Did not show mutagenic effects in animal experiments.
Toxicity to reproduction: Animal testing did not show any effects on fertility.
Teratogenicity: Animal testing did not show any effects on foetal development.
Human experience
Inhalation: Irritating to respiratory system.
Skin contact: Contact with skin causes blanching and erythema.
Eye contact: Liquid causes severe inflammation of conjunctiva and may cause severe
damage of the cornea.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

12 ECOLOGICAL INFORMATION

Aquatic toxicity

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LC50/48 h/Leuciscus idus (Golden orfe): 35 mg/l

LC50/96 h/Pimephales promelas (fathead minnow): 22 - 33 mg/l
LC50/168 h/Oncorhynchus mykiss (rainbow trout): 38.5 mg/l
EC50/Daphnia: 2.4 – 7.7 mg/l
LC50/Microcystis aeruginosa (algae): > 1.7 mg/l
Mobility
Vapour pressure: 24 hPa (30 °C)
Water solubility: completely soluble
Bioaccumulative potential
Bioaccumulation is unlikely to occur
Partition coefficient: n-octanol/water: no data available

13 DISPOSAL CONSIDERATIONS

Product The product can be used completely. Rinse empty packaging

with water prior to disposal. The rest of the product can be
flushed away with much water.
Packaging The product will be delivered in a polyethylene can. After use
the rinsed packaging can be treated as normal waste.
Remainder of this product is chemical waste.
National authorities Remainder of this product is chemical waste: see BAGA; STb.
617 (1993)

14 TRANSPORT INFORMATION

UN-Number 2014
Rail/Road (RID/ADR)
Danger class: 5.1
Packaging group: II
Danger number: 58
Name of product: UN 2014 Hydrogen peroxide, aqueous solution, 5.1 (8), II

Inland waters transport (ADNR)

Danger class: 5.1

Packaging group: II
Danger number: 58
Name of product: UN 2014 Hydrogen peroxide, aqueous solution, 5.1 (8), II

Sea (IMDG)
IMDG-class 5.1
Packaging group: II
Danger labeling: 5.1 + 8
Name of product: UN 2014 Hydrogen peroxide, aqueous solution, 5.1 (8), II
Marine pollutant: None
EMS-number: 5.1 - 03
MFAG-number: 735

Air transport (ICAO/IATA) Not allowed.

15 REGULATORY INFORMATION

For classification and labeling according to Regulation (EU) 1272/2008 (CLP), see section 2.

The additional H-phrases mentioned in section 3:

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Safety Data Sheet Version: 3

H271 May cause fire or explosion; strong oxidizer.

H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.

Classification system
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.

Special labelling of certain preparations:

Use biocides safely. Always read the label and product information before use.

16 OTHER INFORMATION

This information only concerns the above mentioned product and does not need to be valid if used
with other product(s) or in any process. The information is to our best present knowledge correct and
complete and is given in good faith but without warranty. It remains the user's own responsibility to
make sure that the information is appropriate and complete for his special use of this product.

It is recommended that the information of this safety data sheet is handed to all personnel.

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