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LAKSHYA JEE (2024)

Solutions DPP-09

1. Colligative properties of the solution depend upon 6. Which of the following can be measured by the
(1) Nature of the solution ostwald – walker method?
(2) Nature of the solvent (1) V.P. of the solvent.
(3) Number of solute particles (2) Relative lowering of V.P.
(4) Number of moles of solvent (3) Lowering of V.P.
(4) All of these
2. 30 g of a non-volatile solute is dissolved in 360 g of
water at 100°C. If vapour pressure of solution is 7. A solution is obtained by dissolving 12 g of urea
570 mm of Hg, find molar mass of solute (M = 60) in one litre of solution. Another solution is
(1) 5.5 g (2) 4.5 g made by dissolving 68.4 g of cane sugar (M = 342) in
(3) 6.5 g (4) 7.5 g a litre of solution at the same temperature. The
lowering of vapour pressure in the first solution is
3. The vapour pressure of water at 20°C is 18 mm. When (1) Nearly 5 times that of second solution
20 g of a non-ionic substance is dissolved in 100 g of (2) Same as that of second solution
water the vapour pressure is lowered by 6 mm. What (3) Double that of second solution
is the molar mass of the non-ionic substance? (4) Nearly one fifth of the second solution
(1) 10.8 g (2) 7.2 g
(3) 4.4 g (4) 6.4 g 8. The vapour pressure lowering caused by the addition
of 100g of sucrose (molecular mass = 342) to 1000g
4. Calculate the relative lowering in vapour pressure of water if the vapour pressure of pure water at 25oC
(RLVP) if 100 g of a non-volatile solute of molar is 23.8 mm Hg
mass 100 g/mol is dissolved in 432 g of water. (1) 1.25 mm Hg (2) 0.125 mm Hg
(1) 0.04 (2) 0.07 (3) 1.15 mm Hg (4) 0.012 mm Hg
(3) 0.06 (4) 0.09

5. The vapour pressure of water at room temperature is 9. Which one is a colligative property?
23.8 mm of Hg. The vapour pressure of an aqueous (1) Boiling point
solution of sucrose with mole fraction 0.1 is equal to: (2) Vapour pressure
(1) 23.9 mm Hg (2) 24.2 mm Hg (3) Osmotic pressure
(3) 21.42 mm Hg (4) 31.44 mm Hg (4) Freezing point
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Answer Key
1. (3) 6. (2)
2. (2) 7. (2)
3. (2) 8. (2)
4. (1) 9. (3)
5. (3)

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