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Geochemical and hydrological observations have been carried out at two hot spring wells in Ito
City since July 1989. Anomalous changes in water level, temperature and chemical composition were ob
served during the 1989 seismic and volcanic events off the east coast of the Izu Peninsula: a water level
rise of more than 2 m, a temperature rise of about 1'C and an increase of the S024 / Cl ratio by about
5%. Coseismic changes in these parameters were observed for two nearby earthquakes that occurred dur
ing the observation period, on February 20, 1990 (M = 6.5), and on August 5, 1990 (M = 5.1), suppor
ting that these wells are very sensitive to earthquake occurrence. Relation between amplitude of
coseismic change, magnitude and hypocentral distance indicates that the anomalous changes observed
during the 1989 events were too large to be caused by the seismic events only. It is likely that magma
movements associated with the seismic and volcanic events had a close connection with the geochemical
and hydrological anomalies observed during the 1989 events. Major part of the significant anomalies in
cluding self-spouting observed in Ito City are interpreted to be possible precursors of the 1989 sub
marine volcanic eruption.
73
74 T. Sato et al.
• Eurasian
35.5 °N
4 plate
a°
18
CL
0
9 Philippine
Sea plate
Hatsushima
Island
e
Usami
35.0 °N Earthquake
6~, Swarms
EDY f-f
HRN Ito
Teishi Knoll
3
7
lzu
Peninsula
•
• 2
8
Izu-Oshima Island
0 20km 5
•
34.5 °N
139.0 °E 139.5 °E
Fig. 1. Tectonic configuration of the Izu region and locations of observation wells EDY and HRN. The 1989
earthquake swarm started on June 30 (hatched area), followed by the submarine volcanic eruption on July 13
(solid triangle). Solid squares and solid circles show the epicenters of earthquakes with M-2:6.0 that occurred
from 1974 to July 1989 (No. 1 to 5), of the largest shock during the 1989 events (No. 6) and of earthquakes with
M>_ 5.0 that occurred from July 1989 to December 1990 (No. 7 to 9).
I
Hot spring water changes 75
Hypocenter
No. Region Date M distance (km)
Hypocentral*
lat. (°N) long. (°E) depth (km)
Before the 1989 events (M2:6.0)
1 off Izu Peninsula May 9, 1974 34.57 138.80 10 6.9 52
2 Izu-Oshima-kinkai Jan. 14, 1978 34.77 139.25 0 7.0 26
3 off the east coast of Central Izu-Peninsula June 29, 1980 34.92 139.23 10 6.7 17
4 near the boder of the Yamanashi Aug. 8, 1983 35.52 139.03 22 6.0 66
and Kanagawa Prefectures
5 near the Niijima Island Nov. 22, 1986 34.55 139.53 15 6.0 62
The largest earthquake during the 1989 events
6 off the east coast of the Izu Peninsula July 9, 1989 34.99 139.11 3 5.5 5
After the 1989 events (M? 5.0)
7 near the Izu-Oshima Island Oct. 14, 1989 34.82 139.50 21 5.7 46
8 near the Izu-Oshima Island Feb. 20, 1990 34.76 139.23 6 6.5 26
9 western part of Kanagawa Prefecture Aug. 5, 1990 35.21 139.10 14 5.1 31
21 and earthquake swarms practically ceased by swarm region, located about 3 km away. In the
the end of September 1989 (Smithsonian Institu Ito area hot spring water suddenly spouted out
tion, 1989; Japan Meteorological Agency, 1989). prior to the volcanic eruption. For example, a
Marked crustal deformations had progressed large amount of water with a temperature of
in the area prior to the submarine volcanic erup 28'C discharged at a rate of about 200 1/min at
tion. Shimada et al. (1990) detected an exten EDY (Matsubara No. 136 well; Fig. 1), which
sional displacement of 14.5 cm over a distance of was found at about six o'clock on July 10.
about 10 km (between Ito City and Hatsushima Outflow of hot spring water from a pumping
Island) in the period between July 4 and 10 by a well also occurred at HRN (Oka No. 100 well).
fixed-point GPS (Global Positioning System) net These spouts, however, stopped before the
work. Simultaneously Tsuneishi (1991) reported volcanic eruption. Similar rises in water level
similar extensions in the same direction were found in many wells in the Ito area (Mogi et
measured by an automatic electronic' al., 1990). In contrast, drops in water level and
distancemeter. Comparing the geodetic data of flow rate were found in the Usami area. Notewor
June 7-30 with those of July 10-27, 1989, a thy was a drop in water level of an artesian well,
significant uplift of over 8 cm was confirmed in Usami No. 24, of more than 18 m prior to the
the central part of Ito City (Geographical Survey volcanic eruption (Kurokawa, 1990). Such
Institute, 1990). anomalous changes had not been observed for
During the 1989 events, various geochemical other large earthquakes that occurred in the area
and hydrological anomalies were observed at since 1974.
many places in and around the Izu Peninsula,
which are summarized by Notsu et al. (1991).
HOT SPRING WATER OBSERVATIONS
They classified the observed changes into two
types; one is coseismic-type changes caused by We began geochemical and hydrological
the medium-sized earthquakes and the other is monitoring of hot spring water at EDY and
non-coseismic-type changes which are likely to HRN sites soon after self-spouting was found on
be precursory changes of the volcanic eruption. July 10, 1989. Water at HRN has been sampled
Many of the latter type changes were observed in periodically for chemical analysis since July 13.
the Ito and Usami hot spring areas, closest to the Water level and temperature at EDY have con
76 T. Sato et al.
n
Hot spring water changes 77
Table 2. Temporal variations in chemical compositions of hot spring water at the HRN well
Concentration (ppm)
Sampling Temp.*
Date pH SO / Cl
(°C) B Si Mg 2+ Ca 2+ Sr2+ Na+ K+ Cl SO4
July 13, 1989 55.4 8.1 0.449 20.0 0.040 64.5 0.164 155 3.4 74.4 358 4.81
July 18, 1989 55.4 8.3 0.447 19.9 0.040 64.1 0.163 155 2.9 74.3 358 4.82
July 21, 1989 55.3 8.3 0.445 20.0 0.039 63.6 0.162 153 2.8 75.2 360 4.79
Aug. 3, 1989 55.3 8.3 0.451 20.4 0.039 63.5 0.161 153 2.8 73.9 348 4.71
Aug. 11, 1989 55.4 8.6 0.450 20.1 0.045 62.9 0.159 153 2.8 76.4 357 4.67
Aug. 29, 1989 55.0 8.7 0.445 19.9 0.038 61.7 0.158 152 2.8 76.3 354 4.64
Sep. 27, 1989 55.2 7.9 0.452 20.2 0.037 61.1 0.158 155 2.8 78.2 362 4.63
Oct. 11, 1989 55.0 8.0 0.445 20.0 0.036 60.9 0.158 153 2.7 75.6 347 4.59
Oct. 20, 1989 54.9 0.441 19.9 0.037 60.9 0.158 151 2.8 75.3 348 4.62
Nov. 28, 1989 54.6 0.445 19.9 0.037 61.6 0.159 151 2.7 76.0 348 4.58
Dec. 6, 1989 54.4 0.443 19.8 0.036 61.8 0.159 150 2.7 75.3 344 4.57
Dec. 20, 1989 54.5 0.443 19.7 0.036 61.0 0.154 148 2.7 76.1 348 4.57
Feb. 2, 1990 54.5 0.448 20.2 0.037 62.5 0.160 151 76.0 348 4.58
Feb. 14, 1990 54.5 8.3 0.445 19.9 0.038 63.0 0.159 152 74.8 345 4.61
Feb. 23, 1990 54.5 8.3 0.456 20.1 0.039 65.0 0.163 156 76.6 364 4.75
Mar. 19, 1990 54.8 8.4 0.448 20.1 0.039 62.3 0.157 152 75.4 349 4.63
Mar. 26, 1990 54.7 8.2 0.447 20.3 0.039 62.4 0.156 152 75.1 346 4.61
Apr. 10, 1990 55.0 8.3 0.452 20.3 0.039 62.1 0.157 152 75.8 348 4.59
Apr. 27. 1990 55.1 8.3 0.442 20.0 0.037 61.5 0.158 151 76.4 349 4.57
May 11, 1990 54.0 8.4 0.442 19.9 0.037 61.3 0.157 151 76.6 351 4.58
June 1, 1990 55.0 8.4 0.443 19.8 0.037 62.6 0.160 153 76.3 351 4.60
June 20, 1990 54.0 0.445 19.9 0.036 62.2 0.159 152 76.5 352 4.60
July 12, 1990 54.0 8.4 0.444 20.1 0.037 63.4 0.162 153 r 76.3 351 4.60
Aug. 6, 1990 54.0 8.3 0.452 19.8 0.037 63.3 0.159 149 74.3 348 4.68
Aug. 11, 1990 54.0 8.6 0.455 20.0 0.038 63.8 0.161 147 73.8 346 4.69
Sep. 10, 1990 54.9 8.3 0.443 19.4 0.036 61.6 0.156 149 74.8 343 4.59
Oct. 10, 1990 53.8 8.5 0.454 20.1 0.038 64.6 0.160 150 73.4 337 4.59
Nov. 13, 1990 53.8 8.3 0.465 19.9 0.037 64.3 0.158 149 72.9 336 4.61
Dec. 13, 1990 53.8 8.5 0.447 19.7 0.037 64.1 0.158 150 73.6 338 4.59
70
spring water sampled at HRN. The water is
characterized by enrichment in Na+, Ca2+, S04 A B
60 • ' HRN
and Cl ions. These characteristic features of Ito U
hot spring have previously been pointed out by 50
0
0 00
b tD*(9 0
0
F
78 T. Sato et al.
0 0 40 Type A
o oozLO 41 0 Type B
3 ~C
EDY
Ito City
0
.
C
A9 I
O N
i
0
N c
0
N
h
r o 9 7 os
C~
NOO
OO'
°
00
0 0 500 1000 m
0
~p
Fig. 4. Spatial distribution of the SO 4 / C! ratios of hot spring water in Ito City. Solid and open circlesshow
the type A and B waters, respectively. The dashed line is the boundary between the two waters.
Most of the hot spring waters distributed mation which can be seen in the southern area
along the eastern coast of the Izu Peninsula are (1150,000 geologic map "Ito" provided by
considered to be mixtures of sea water and Geological Survey of Japan). Type B water may
meteoric water from the stable isotopic ratio and correspond to the meteoric water related. to
major chemical components (Matsubaya et al., Green Tuff formation.
1973). The lowest S04' / Cl ratio of type A The boundary between the type A and type B
water is equivalent to that of sea water of about waters may be located between EDY and HRN,
0.14. Type A water is distributed close to the. as shown by the dashed line in Fig. 4. Since the
ocean coast (Fig. 4). Accordingly, type A water depths of the wells in the area vary over the wide
is considered to be strongly related to sea water. range of 50-600 m, the boundary between type
On the other hand, type B water is A and type B on the ground surface can be
distributed in the southern part of the Ito area. drawn only approximately. The hot spring
Sakai and Matsubaya (1977) suggested that the waters near the boundary region are composed
meteoric water, another end member of the hot of both types of water with various mixing
spring water mixing, is related to Green Tuff for ratios. Changes in tectonic stress may change the
o
Hot spring water changes 79
a)
4.9
4,M5.5
M6.5
4.8
C3
1 M5.1
ZN 4.7
t iii
4.6 Volcanic
Eruption ,,
4.5
b)
54.2
U I M6.5
54.1 j M5.1
0 d.
E a)
f Volcanic Eruption
a~ M5.5
54.0
_~
0 c) 1 Self-spouting
E
-100
M5.1
-200 j M6.5 j
Volcanic Eruption M5
D .5
-300
d)
200
vE 150
E
100
c 50
0
6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12
1989 1990
Fig. 5. Temporal variations in observed parameters: a) SO4 / Cl ratio (HRN) , b) temperature of hot spring
(HRN), c) water level (EDY) and d) precipitations obtained at Ajiro. The data of c) are shown as the running
averages of the 25 hours' data to minimize .the tidal fluctuations. The precipitation data were provided by Japan
Meteorological Agency.
path of hot spring water in the region, which ing discussion, the S024 / Cl ratio is taken as a
results in changes in the mixing ratio. representative of the chemical composition
changes in hot spring water at HRN.
Observed changes with time Figure 5 shows the temporal variations in the
During the observation period, changes in S04 / Cl ratio and water temperature observed
the concentration of most ions were small. Never at HRN and in the water level observed at EDY
theless, some decreases which could be related to during the period from July 1989 to December
tectonic events were observed in S024-, Na+ and 1990. The temperature data were plotted only
Mgt+. In particular, chemical changes related to for the period after the continuous measurement
tectonic events become more obvious when we was started. During the previous period the
take the S024 / Cl ratio (Table 2). In the follow water temperature was measured only by a mer
W
m
80 T. Sato et al.
cury thermometer at the times of water sampling ture (No. 9). The epicenters are shown in Fig. 1.
for chemical analysis. A rise of 3% in the SO4-/C1 ratio was ob
Tidal fluctuations were observed in the water served at HRN just after the M6.5 earthquake.
level data at EDY with an amplitude of about 30 Similar changes in water temperature (HRN)
cm, but not observed in the temperature data at and water level (EDY) were also recorded with
HRN. After the 1989 events, the SO4 / Cl ratio the amplitudes of about +0.05°C and +40 cm
decreased by about 5%. The water temperature respectively (Table 3), which were large enough
also fell by about 1°C gradually, from 55.4°C to be distinguished from the background fluctua
after the eruption to 54.5'C at the end of 1989. tions due to meteorological and tidal changes.
Similarly the water level at EDY fell by about 2 The amplitudes of coseismic changes for the
m. It should be noted that the decreasing pat M5.1 earthquake were +3% (SO 4 / Cl ratio),
terns of the three different parameters resemble +0.05'C (water temperature) and + 60 cm
one another. Even though the S024 / Cl ratio (water level). The observed coseismic changes
measurements were intermittently done, the can be interpreted to be caused by enhancement
trend is more or less similar to that of the water of pore pressure in the aquifers due to changes in
level change on a continuous basis. tectonic stress.
The decreasing rates of the parameters in the Earthquakes causing geochemical anomalies
autumn of 1989 became smaller with time. It ap have empirically been discussed in terms of
peared that the enhanced levels of the SO' / CY magnitude and distance (e.g., Kawabe, 1987;
ratio, water temperature and water level gradual Igarashi and Wakita, 1990). Figure 6 shows the
ly approached normal levels. The decreasing magnitude-hypocentral distance diagram for
trends can be interpreted to be caused by a proc earthquakes with M::_ 2.0 and D:5 100 km during
ess of relaxation of the accumulated stress in the our observation period. Coseismic anomalies
region. The process would also have lowered were observed at HRN and EDY only for the ear
pore pressure in the aquifers. During the subse thquakes shown by solid circles. The solid line is
quent calm period, two large changes associated an extended line indicating a threshold relation
with earthquakes are notable. for appearance of groundwater radon anomaly
(Igarashi and Wakita, 1990). The strainmeter
Coseismic changes and possible precursors of observations of coseismic strain steps analyzed
volcanic eruption by Wideman and Major (1967) are also plotted
Coseismic hot spring water changes are ob as dashed lines. A threshold relation for the
served at some sensitive observation wells. In coseismic anomalies observed at HRN and EDY
this study two coseismic signals were detected as seems to be consistent with the solid and dashed
shown in Fig. 5. One is for the M6.5 earthquake (10-8) lines.
that occurred near the Izu-Oshima Island (No. 8 On July 9, 1989, an M5.5 earthquake occur
in Table 1), and the other is for the M5.1 earth red only 5 km away. Several hours later, self
quake in the western part of Kanagawa Prefec spouting occurred at EDY. Since we had not
Table 3. Amplitude of observed changes associated with seismic and volcanic events
HRN
EDY
Event Date Water level Water temperature
(cm) SO4 /Cl
(°C)
events, anomalous rises in the S024 / C1 ratio, Volcanic Eruption 44, 23-44 (Japanese).
temperature and water level of hot springs were Kawabe, I. (1987) Identification of seismogeochemical
observed in the Ito area. These changes are infer anomalies in subsurface gas CH4/Ar ratio:
red to be caused by increases of pore pressure in Geochemical filtering of earthquakes. Geochem. J.
21, 105-117.
the aquifers, which originated from crustal defor Kurokawa, Y. (1990) Precursor changes in the Usami
mations due to uprising magma. Major parts of No. 24 well associated with the 1989 earthquake
the observed anomalies are interpreted to be swarm and the volcanic eruption. Bull. Hot Springs
possible precursors of the 1989 submarine Res. Inst. Kanagawa Pref. 21, 39-46 (Japanese).
volcanic eruption. Continuous and careful obser Mashiko, Y. and Kanroji, Y. (1965) Geochemical
vation of hot spring water will be useful to studies on mineral springs. XI. On change of
chemical components with lapse of years in Ito Spa.
increase knowledge on seismic and volcanic ac J. Balneological Soc. Japan 15, 113-124, (in
tivities. This study will also contribute to predic Japanese with English abstract).
ting volcanic eruptions. Matsubaya, 0., Sakai, H., Kusachi, I. and Satake, H.
(1973) Hydrogen and oxygen isotopic ratios and ma
Acknowledgments-We thank Mr. F. Saito and Mr. jor element chemistry of Japanese thermal water
F. Tanabe for allowing us to use their wells for our systems. Geochem. J. 7, 123-151.
observations. Matsumura, S., Ohkubo, T. and Imoto, M. (1991)
Seismic swarm activity in and around the Izu Penin
sula preceding the volcanic eruption of July 13,
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