3

P1=100 kPa T 1=300 K P2 =1000 kPan=1.25 V 1=0.5 m

KJ
R=0.2870 ×K
Kg

( ( )) ( )=0.079 m
P1
ln
P2
ln ( 1000
100
)
n 1.25 3
V 2=V 1 × e =0.5 × e
P× V 100× 0.5
m= = =0.581 Kg
R × T 0.2870× 300

( P1 ×V 1 ) −( P2 × V 2 ) (100 × 0.5 )−( 1000 ×0.079 )

W= = =−116 KJ
1−n 1−1.25
−116 KJ KJ
w= =−199.66
0.581 Kg Kg
P ×V 1000 ×0.079
T 2= = =473.77 K
m× R 0.581 ×0.2870
T 1+ T 2 300+473.77
T media = = =386.885 K
2 2
C v ( interpolado a T media ) =0.725

Q=( m× C v ( T 2−T 1) )−W =( 0.581 ×0.725 ( 473.77−300 ) ) + (−116 )=42.80 KJ

42.80 KJ
Q= =¿
0.581 Kg

PARA NITROGENO
3
V 2=0.079m
W =−116 KJ
P× V 100× 0.5
m= = =0.562 Kg
R × T 0.2968× 300
P ×V 1000 ×0.079
T 2= = =473.62 K
m× R 0.562 ×0.2968
T 1+ T 2 300+473.62
T media = = =386.81 K
2 2
Q=( m× C v ( T 2−T 1) )−W =( 0.562 ×0.746 ( 473.63−300 ) ) + (−116 )=−43.21

PARA OXIGENO
 3
V 2=0.079m
W =−116 KJ
P× V 100× 0.5
m= = =0.642 Kg
R × T 0.2598× 300
P ×V 1000 ×0.079
T 2= = =473.64 K
m× R 0.642 ×0.2598
T 1+ T 2 300+473.64
T media = = =386.82 K
2 2

Q=( m× C v ( T 2−T 1) )−W =( 0.642 ×0.678 ( 473.64−300 ) )+ (−116 )=−40.42

PARA HIDROGENO
3
V 2=0.079m
W =−116 KJ
P× V 100× 0.5
m= = =0.0404 Kg
R × T 4.1240 ×300

P ×V 1000× 0.079
T 2= = =474.16 K
m× R 0.0404 × 4.1240
T 1+ T 2 300+474.16
T media = = =387.08 K
2 2

Q=( m× C v ( T 2−T 1) )−W =( 0.0404 × 10.321 ( 474.16−300 )) + (−116 )=−43.38