Electro-Chemistry

 3.38810–4 3.3010–4
NaCl 3.2910–4 3.2210–4
M
. Solve : z = n×F
M
. Solve n
F=96500
'Zn'
65.4
Z= 2×96500

. Solve =3.38810–4 gC1

Ag-
0.001118 gC1 0.1118 gC1
0.00118 gC1 0.01118 gC1

. Solve : . Solve :
108
Ag ,Z=
(i) 1  96500
(ii) = 0.001118 gC1
(iii)

i ii ii iii
2.8  105 g/C 9.33  105 g/C
i iii i, ii iii 1.4  104 g/C 2.8  104 g/C
. Solve
NaCl, MgCl2, AlCl3 SnCl4
i. 1F
ii.
iii. Na Mg
Al Sn
i ii i iii . Solve
ii iii i iii
. Solve NaCl
'Zn'
 23 27
Na , Z1= = 2.3810–4 . Solve : Al , Z=
1  96500 3  96500
W1 = Z1Q = 2.3810–4 96500 = 23gm = 9.3310–4
MgCl2 W = ZQ
24 W 9
Mg , Z2= = 1.2410–4 Q= = =96500C=1F
2  96500 Z 9.3264×10-5
W2 = Z2Q = 1.2410–4 96500 = 12 gm
1 CuSO4
AlCl3
27
Al , Z3= = 9.3210–5 1F 2F
3  96500
3F 4F
W3 = Z3Q = 9.3210–596500 = 9 gm
SnCl4 . Solve :
118.7
Sn , Z4= = 3.0810–4
4  96500 Cu2+ + 2e = Cu
W4 = Z4Q = 3.0810–496500 = 29.675 gm 2F
27g Al 1 mol H2

1F 3F 1F 2F
13.5F 27F 3F 4F

. Solve : Solve
A+, B2+ C3+ 1F

i. 1 mol A+
Al3+ + 3e = Al
ii. 2 mol B2+
Al 1 27 gm
1
3F iii. mol C 3
3
27
Al , Z= = 9.326410–5
3  96500
i ii
W = ZQ
ii iii
W 27 289500
Q= Z = 9.33×10-4 =289500C= 96500 = 3F i iii
i, ii iii
Al2O3
Solve
1F 1.5 F 5A 5min CuSO4
3F 6F Cu
. Solve
9.87g 4.96g
Al3+ + 3e–→ A 9 gm Al 0.985g 0.496g

1F 3F
. Solve W = Z It
9F 27 F
 63.5 1F
= 2×96500 ×5×(5×60)
0.49 g Zn Al
AgNO3 5 amp 10 K Ca
. Solve
0.559g 1.462g
3.360g 3.388g
65.4
. Solve W = Z It Zn ,Z1= = 3.38810–4
2  96500
108
= 1×96500 ×5×(10×60) W1 = Z1Q = 3.38810–496500 = 32.7 gm
27
Al ,Z2= = 9.326410–5
3.36 g 3  96500
AgNO3 5 amp W2 = Z2Q = 9.326410–596500 = 9 gm
Ag 39
K ,Z3= = 4.041410–4
1  96500
8.766 16.812 W3 = Z3Q = 4.041410–496500 = 39 gm
20.145 24.854 40
Ca ,Z4= = 2.07310–4
. Solve W = Z It 2 96500
W4 = Z4Q = 2.07310–496500 = 20 gm
108
= 1×96500 ×5×(60×60) 5 30
20.145 g
CuSO4 0.16A 40
60 95.52
120 150
[Cu  63.5]
. Solve Q = It = 5×30=150 C
1.194 10 21
ZnSO4 1.0 C
1.342 10 21 1.546 10 21
1.92110 21 34.7g 0.00348g
. Solve 32.7g 0.0348g
3A 6 . Solve : 0.000385g
65.4
Zn , Z= = 3.38810–4
11.64 2  96500
14.21 W = ZQ = 3.38810–4×1 3.38810–4
17.46
CuSO4 1F
21.32
. Solve 23.0g 26.52g
31.75g 33.68g
Ag Cu
. Solve Cu ,
Fe Cr
63.5
. Solve Z=
2  96500
= 3.2910–4
 W = ZQ = 3.2910–4×96500 31.75 gm 
CuSO4 5000 mA 1
V)
5.5222g 5.7222g Li +3.04
5.8222g 5.9222g K +2.92
. Solve W = Z It Ca +2.87

63.5 Na +2.71
= ×5×(60×60)
2×96500 Mg +2.37
5.9222 g Al +1.66
M (II) 0.1 A Zn + 0.76
1.0 g M M
Fe + 0.44
40
20 s Sn +0.13
1206 s Pb +0.12
24.125 s H 0.0
72.375 s Cu -0.34
. Solve Hg -0.79
FeSO 4 5A 10min Ag -0.80
Pt
0.0144 g 0.404 g
Au -1.56
0.578 g
0.868 g
. Solve Pb Cu
Ag Ca
.
Cu
Cr- 52)
17.33 g 52 g i. Fe
104 g 156 g ii. Ag
. Solve : iii. H

i ii ii iii
i iii i, ii iii
Cr3+ + 3e = Cr
3F
Al>Ni Zn>Mg
52 g
 Fe>Na Cu>Sn
. Solve
H2S H2

Ca
Mg
Zn Pb
Solve

Na Li
K Ag
. Solve :

Pt, H2/H+ Cu2+ H+

Pb2+ Na+
Zn2+/Zn Ag+/Ag . Solve
Cu2+/Cu Hg22+/Hg.
. Solve
Cu2+ H+
Au3+ Ag+
. Solve : Solve

Ag+/Ag Fe2+/Fe Cu 2 H+
Zn2+/Zn H+/H2(g), pt
Au3
. Solve
Ag
. Solve
M, N, P Q
Br
NO3  –2.92, –1.66, + 0.80 +
OH Cl 1.36
M N P Q
. Solve
. Solve
 M ii)
M
iii)
iv)

Fe/Fe 2
Hg, Au Hg, Pt
Zn/Zn2 Mg/Mg2 Pt, Au Pt.V
Al/Al3 . Solve
3
Au/Au Pt, Au
. Solve
Cu/Cu 2 H 2 /H  (Pt)
Pt(s), Fe2 /Fe3
Zn2 (aq) /Zn(s) Ag/AgCl, KCl
Fe2 (aq) /Fe(s) . Solve
Ag2 (aq) /Ag(s)
Hg2Cl2 HgCl2
H (aq) /H 2 (g), Pt Cu2Cl2 CuCl2
. Solve . Solve
Hg
Hg2Cl2
Pt, Cl2/ Cl Ag, AgCl(s)/ Cl
NaHg/Na+ Pt/Fe2+, Fe3 +
. Solve i)
Pt HgCl2 Hg2Cl2
HgF2 Hg2l2
ii) . Solve :
Pt/Fe2+, Fe3 +
iii) Pt/Fe2+, Fe3 +
HgCl2 Hg2Cl2
MnO2 NH4Cl
Ag(s), AgCl(s)/NaCl (aq) . Solve :
Hg(1), Hg2Cl2 (s)/KCl (aq)
Ag(s)/AgNO3 (aq)
Pt(s) Fe2+(aq), Fe3+ (aq)
. Solve i)
. Solve


+ 0.34V + 0.80V
+ 1.30V + 1.36V
. Solve
. Solve
–

Ag/AgCl
. Solve
Zn

Zn(s)/Zn2+(aq) Fe2+(aq)/Fe(s)
Zn(s)/Zn+(aq) Cu2+(aq)/Cu(s) . Solve
+
. Solve Pt, H2/ H (E0 = 0.0V)

 Zn2+/Zn Mg2+/Mg
Cu2+/Cu Fe2+/Fe
KCl NH4Cl . Solve
NaNO2 NaCl
. Solve
KCl, KNO3, NH4Cl, NH4
NO3

KCl, KNO3, NH4Cl 1.0M 0.1 M

KCl, K2SO4, Na2SO4 0.01 M 0.001M
KCl, NH4Cl, Na2CO3 . Solve
KCl, NH4Cl, NaNO3
H+ 1M
. Solve 1 atm
25oC 298 K
KNO3 KNO2 1 3cm3
KMnO4 K2Cr2O7 0.00 V Pt, H2(g)(1 atm)/
. Solve H+ (aH+ = 1)
–
-1
(i) l mol L
CaCl2 CuCl2 (ii) l atm
KCl Al2(SO4)3 (iii) 298 K
. Solve
i ii ii iii
 i iii i ii iii
 . Solve Solve 2.303RT [Bn  ]
E cell  E 0 cell  log n 
F [A ]
Solve
+ 1.00 V – 1.34 V
0V + 0.76 V EMF

. Solve
Sn(s)/Sn 2 (aq) ║ H  (aq)/H 2 (g)(1 atm, Pt)
0
E Sn 2
(aq)/Sn(s)0.14V

Zn(s)/Zn2 (aq) 0.14 V -0.07 V

+ 0.07 V -
Ag(s)/Ag 2 (aq)
0.14 V
Cu(s)/Cu 2 (aq)
. Solve
Au(s)/Au2 (aq)

. Solve H2(g) + Cu2+(aq) 2H+(aq) +
Cu(s) E = 0.34V


e.m.f
Ecell = Eanode (OX)  Ecathode (OX) 2H++ 2e = H2 Cu = Cu2+ + 2e
Ecell = Ecathode (OX)  Eanode (OX) H2 = 2H+ + 2e Cu2+ +2e = Cu
Ecell = Eanode (Red)  Ecathode (Red)
. Solve H2 = 2H+
Ecell = Eanode (OX) + Ecathode (OX)
+ 2e Cu2+ + 2e = Cu(s)
. Solve Electromotive
ECu/Cu2+
Force EMF/emf
0.34V 0.34V
 E0cell = E0anode(ox) + E0cathode(red) 0.17V 0.17V
= E0anode(ox) E0cathode(ox) . Solve :
= E0cathode(red) E0anode(red) E 0
Eo anode (ox) + Eo cathode (red)
Cell =
n n
A (aq)  B(s)  A(s)  B (aq);
0.34 = E0H2/H+ + E0 Cu2+/Cu
0.34 = 0.00 + E0 Cu2+/Cu [E0H2/H+ =0.00 ]
RT [A n  ] E0 Cu2+/Cu = +0.34 V
E cell  E cell 
0
ln
nF [B n  ] Zn(s)Zn2+(aq) Cu2+(aq)Cu(s)
RT [B n  ]
E cell  E 0 cell  ln Zn  Zn2+ +2e Cu2+ + 2e Cu
nF [A n  ]
Zn2+ 2e Zn Cu Cu2+ +2e
2.303RT [A n  ]
E cell  E 0 cell  log n  . Solve :
F [B ]
 Zn = Zn2+ + 2e Cu2+ +
2e = Cu (s) 

+ 0.32 V 0.32V
0.76V 0.44V. + 1.20V  1.20V
. Solve Fe

Zn(s)  FeSO 4 (aq)  ZnSO4 (aq)  Fe(s)

Zn(s)  Zn 2+ (aq) + 2e( ),
Zn(s)/Zn2 (aq)  0.76V; Fe(s)/Fe2 (aq)  0.44V
E Zn / Zn = +0.76V
2+

 Ecell = Eo anode (ox) + Eo cathode (red)

. Solve = EZn/Zn2+ + E Fe2+/Fe
= (0.76 – 0.44)V
= + 0.32 V
 0.42 V
(i)
 1.20 V
 0.42 V
(ii)
 1.20 V
(iii) Zn
. Solve 0.32V
i ii ii iii
i iii i, ii iii
i.
. Solve :
ii.
iii.
(ii)
i ii (iii)
i iii ii iii
(i)
. Solve

H2 (g)  Cu  (aq)  2H (aq)  Cu(s) E0cell  0.34V ii iii

FeSO4
0.76V
Cu 2  2e  Cu 0.44V.
Cu  Cu 2  2e
H 2  2H   2e
2H   2e  H 2 + 0.32V 0.32V
+1.20V  1.20V
. Solve
 . Solve Zn(s)/Zn2+(aq)  Fe2+(aq) /Fe(s)
Zn(s)/Zn2+(aq)  Cu2+(aq) /Cu(s)
 Ecell = Eo anode (ox) + Eo cathode (red)
= EZn/Zn2+ E Fe2+/Fe
= (0.76 – 0.44)V
= + 0.32 V Cu(s)/Cu2+(aq) Fe(s)/Fe2+ (aq)
Cu(s)/Cu2+(aq)
(i) Fe(s)/Fe2+ (aq)
(ii) Zn(s)/Zn2+(aq)
(iii)
. Solve
i ii ii iii
i iii i, ii ii
. Solve : Solve

 +1.20+0.42V +.32V +0.42V

M2+(aq) + 2e  M(s); EM2+ (aq)M(s) = 0.34V
+ 0.32V+1.10V ─0.32V ─ 0.10V
(ii) N (s)  N2+(aq) + 2e : E N(s)N2+ (aq)
= 0.80V . Solve Zn(s)/Zn2+(aq)  Fe2+(aq) /Fe(s)
Ecell = Eo anode (ox) + Eo cathode (red)
M(s), M2+ (aq)  N2+ (aq), N(s)
= EZn/Zn2+ + E Fe2+/Fe
M(s), M2+ (aq)  N+ (s), N2(q) = (0.76 – 0.44)V
N(s), N2+ (aq)  M2+ (aq), M(s) = + 0.32 V
N(s), N2+ (aq)  M+ (s), M2+ (aq) Zn(s)/Zn2+(aq)  Cu2+(aq) /Cu(s)
. Solve E0Cell = Eo anode (ox) + Eo cathode (red)

emf = E0Zn/Zn2+ + E0 Cu2+/Cu

= 0.76 + 0.34
1.14V 0.46V
= +1.10 V
0.46V 1.14V

. Solve :
 Ecell = Eo anode (ox) + Eo cathode (red)
= EM/M2+ + E N2+/N
= (-0.34 + 0.80)V
= + 0.46V
E0Mg/Mg2+ = 2.37(V)

E0Cr/Cr3+ = 0.77(V)
Zn(s)/Zn2+(aq) E0 = + 0.76V
E0Al/Al3+ = 1.66(V)
Fe(s)/Fe2+ (aq) E0 = + 0.44V
E0Fe/Fe2+ = 0.44(V)
Cu(s)/Cu2+(aq) E0 = –0.34V
–
(i) A
(ii) B
(iii) 

i ii ii iii
i iii i, ii iii
. Solve

(i) E0cell 250C

ii)  G0 E0Zn /Zn2+ = 0.76V, E0Cd2+/Cd= 0.40V
(iii)  G 0

i ii i iii 1.16 Volt 0.76 Volt

ii iii i, ii iii 0.40 Volt 0.36 Volt

. Solve . Solve
(i) E0cell
ii)  G0 Zn(s)  Zn 2+ (aq) + 2e ( ),
E0M12+/M1 = +0.34V E0M22+/M2= – 2.30V
Zn/Zn2+  Cd2+ / Cd
E0Cell = Eo anode (ox) + Eo cathode (red)

– 1.96 V + 1.96 V = E0Zn/Zn2+ + E0 Cd2+/Cd

– 2.64 V + 2.64 V = E0Zn/Zn2+ – E0 Cd / Cd2+
= 0.76 – 0.40
. Solve = +0.36 V
–
M22+/M2 (i)
M22+/M2 M22+/M2  (ii) Zn
M12+/M1 (iii) Zn(s)/Zn2+(aq) 
E0Cell = Eo anode (ox) + Eo cathode (red) Cd(s)/Cd2+(aq)
= E0 M2/M22+ + E0M12+/M1
i ii ii iii
= –E0M22+/M2+ E0M12+/M1 i iii i ii iii
= +2.3 + 0.34
= +2.64 V . Solve
Zn/ZnSO4(1.0 M)  CuSO4(1.0 M) Cu i) Cd
Cd
Cu–2e– =Cu2+ Zn–2e– = Zn2+
Cu2++2e– = Cu Zn2+ – 2e– =Zn
. Solve ii iii
Zn(s)  Zn 2+ (aq) + 2e ( ),
 (i) Ag(s) / Ag+ (aq)H+ (1M)/H2(g); 1atm. Pt
(ii) Ag(s) /Ag+(aq)H+ (1M)/H2(g); 1atm. Pt
(iii) Ag(s) /Ag+(aq)H+ / H2(g); Pt

i ii ii iii
i iii i, ii iii
. Solve
(i) Ag Ag
+1.10V 0.42V
-1.10V -0.42V
. Solve (ii) Pt
(i) Ag(s) / Ag+
(aq)H+ (1M)/H2(g); 1atm. Pt
i. Zn
(iii) Ag(s) /Ag+(aq)H+ / H2(g); Pt
ii. Cu Zn
iii. Zn/Zn2 ║ Cu 2 /Cu

i ii ii
iii
i iii i, M/M2+||N+/N
ii iii EoM/M2+ =+ 0.76 Volt, EoN/N+ =  0.4
Volt
. Solve
e. m. f
E0Zn/Zn2+ = 0.76V, E0H/H+ = 0 –1.16 Volt –0.36 Volt
+0.36 Volt +1.16 Volt
Zn(s)/Zn2+║H+(aq)/H2, Pt . Solve
Zn/Zn2+(aq)║H+(aq)/H2, (1 atm), Pt E0Cell = Eo anode (ox) + Eo cathode (red)
Pt, (1 atm) H2/H+(aq)║ Zn2+(aq)/ Zn(s)
= EoM/M2+ + E0 N+/N
Pt, H2/H+(aq)║ Zn2+(aq)/ Zn(s)
= EoM/M2+ – E0 N / N +
. Solve :
= 0.76 + 0.40
i) = +1.16 V
M
(i)
(ii)
Pt (iii) N
ii) Zn(s)/Zn2+║H+(aq)/H2, (1
atm), Pt i ii ii iii
i iii i, ii iii
EAg/Ag+ = + 1.32V, EH2/ H+ = 0.0 V
. Solve M
 (ii) ( M
) NH4Cl MnO2
Zn
(i) (
(iii) N . Solve

EZn/Zn2+ = +0.76V EAg/Ag+ = 0.799V.

NH4Cl ZnCl2
1.559V 1.459V MnO2
1.669V 2.559V
e. m. f 1.5 V
. Solve
e. m. f

Zn(s)  Zn 2+ (aq) + 2e ( ), 1.1 V 1.2 V

1.5 V 1.8 V
Zn/Zn2+  Ag+ / Ag
E0Cell = Eo anode (ox) + Eo cathode (red)
. Solve Solve
= E0Zn/Zn2+ + E0 Ag+ / Ag 
=E 0
Zn/Zn–E
2+ 0
Ag / Ag+
= 0.76 + 0.7
= +1.599 V Pb/Pb2+ || Cu2+/Cu
Pb/PbSO4 || H2SO4(aq)/PbO2.Pb
+0.34 0.76 Zn/Zn2+ || Pb2+Pb
Pb/Pb2+ || H+/H2
(i) . Solve :
(ii)

(iii) Pb
PbO2 Pb
i ii ii iii 30-38% H2SO4
i iii i, ii iii
. Solve Pb/PbSO4 |
H2SO4(aq)/PbO2.Pb(s)
e. m. f 2.03V
H2 O2
H2SO4
H2SO4

e. m. f 2.03V 1.17 V


(i) Pb
(ii) PbO2 Pb
(iii) 30% H2SO4

i ii ii iii
i iii i, ii iii
. Solve
. Solve Solve

HNO3 H2SO4
Pb PbO HCl CH3COOH
PbSO 4 PbO2
. Solve : Solve
. Solve
H2SO4

1.25 1.20 pH
1.15 1.10
. Solve Solve H2SO4
. Solve
H2 O2 H2SO4
H2SO4

. Solve
H2SO4 PbSO4
– PbO PbO2
. Solve 30-38% H2SO4
Cd As
Pb Cr
. Solve
(i)
(ii)
(iii)

. Solve :
i ii ii iii
i iii i, ii iii
 . Solve : PEMFC
H2
(i)
LiCoO2 A + nLi + + ne : A Co O2
AFC KOH Pt Ni
H2
+1 +2
+3 +4 O2
. Solve PAFC Pt
H2
LiCoO2
Co3+ Co4+ O2

Co4+ Co3+
SOFC Ni
H2
i. Co3+ Co4+
O2 Li
ii. Co4+ Co3+

iii. 1.23 V
MCFC)
i ii i iii H2
ii iii i, ii iii
O2
. Solve
LiCoO 2 ═ A  nLi   ne  ; A Co
DMFC Pt–Ru
CH3OH
+4 +3
+2 +1 O2
Pt
. Solve

(i) 60%
PEM (ii)
SVO (iii)

i ii ii iii
. Solve
i iii i, ii iii

. Solve :
(i) 90%
 ii i iii i, ii iii
. Solve
iii

iv)

i. 65 PEMFC AFC
ii. H2 PAFC MCFC
iii. . Solve PEMFC- Proton Exchange
Membrane Fuel Cells (
i ii ii )
iii AFC- Alkaline Fuel cell (
i iii i, NaOH /KOH )
ii iii MCFC-Molten Carbonate Fuel cell (
Na2CO3 /CaCO3
Solve
) PAFC-Phosphoric Acid Fuel cell
( H3PO4
) PEMFC

. Solve

. Solve :

. Solve 

(i)

(ii)
(iii)
0.76V 1.10V
(i) 1.23V 2.03V
(ii) . Solve
(iii) 2H2 +4OH 4H2O + 4e ; Eo=
+0.83 V
i ii ii iii O2 + 2H2O + 4e 4OH Eo= +0.40 V
 2H2+ O2 2H2O; Eocell = . Solve
+1.23 V

2H2+O2 → 2H2O
2H2O 2H2O +O2
2H+ O2 H2O2
H2O+ O2 H2O2
. Solve

1 1.23
2 2.5 Cd Cr
Solve Fe Pb
.
(V)

Zn Cu
–
0.1
M
0.01
M
(i)
(ii)
ZnSO4
2+
CuSO4
EFe/Fe
2+
= + 0.44V
(iii)
EZn/Zn = + 0.76V

i ii i iii
(i) Ecell = E0 Zn/Zn2+ + E0Cu/Cu2+
ii iii i ii iii
(ii) Ecell = E0 Zn/Zn2+ + E0Cu2+ /Cu
(iii) Ecell = E0Cu2+ /Cu - E0Zn2+/Zn
.

i ii ii iii
Cu Al
i iii i, ii iii
Zn Ge
.
. Solve
Fe/FeSO4

Ge B As Te Si Sb

+ 1.2  1.2
+ 0.32  0.32
. Cl2(g) + 2e–  2Cl–(aq) + 1.636 volt
Cu2+(aq) + 2e–  Cu(s) E = + 0.34 volt
–
Eo cell volt
+1.7 +1.02
–1.02 –1.7
. Solve :
 .
– E0Zn/Zn2+=0.67V –
Cu(s)/Cu+(aq) || Cl2(g)/2Cl (aq) 0 2+
(i) E Cu Cu = +0.43V
–
Pt(s),Cu(s)/Cu2+(aq)||Cl2(g)/2Cl (aq), Pt(s) (ii) Zn Cu
2+ –
Cu(s)/Cu (aq) || Cl2(g)/2Cl (aq), Pt(s) (iii)
–
Cu(s)/Cu2+(aq) || 2Cl (aq)/Cl2(g), Pt(s)
i ii iii
. Solve
i iii i, ii iii

Cu(s)/Cu+

Pt
1.

(a) KNO3 (b) Kl

(c) KBr (d) KCl
Ans. (d) Solve ..

Fe Al KCl KNO3 NH4NO3

Li Zn KCl
. Solve
2. 25C
(K+/ K)
(a) +2.92V (b) –2.92V
(c) +2.87V (d) –2.87V
3. 25C
(Cu/Cu2+)
(a) +0.34V (b) –0.34V
. Solve (c) –0.38V (d) +0.38V
4.

 – –
(a) OH > I > Cl > SO42–
–

– – –
(b) I > OH > Cl > SO42–
– – –
M (s) + N2+(aq) → M2+ (aq) + N (s) [E=+1.1v] (c) Cl > I > OH > SO42–
– – –
(d) SO42– > I > Cl > OH
2+ 2+
5. Fe|Fe (M)|| Cu (M)| Cu
emf = ?
(a) +0.87 volt (b) + 0.78 volt
(c) + 0.10 volt (d) –0.78 volt
 Ans. (b) Solve .. emf = E (a) Fe3O3. 3H2O (b) FeCl3
–E (c) Fe3O3. 2H2O (d) Fe3O4
1
E Fe2+/Fe = –0.44 volt Ans. (c) Solve 2Fe(OH)2 + H2O + O 
2 2
..

E Cu2+/Cu – 0.34 volt Fe3O3. 3H2O

 emf = E Cu2+/Cu – EFe2+/Fe 10.
= 0.34 – (–0.44) = 0.34 + 0.44 = 0.78 volt
6. Sn(s) + 2Ag+ (aq)  Sn2+(aq) + 2Ag(s) (a) H+(aq)/ H2(g), Pt (b) Cu2+(aq)/Cu(s)
voltage (c) Na+(aq). Na(s) (d) Pt/F2(g)/F(aq)
Ans. (d) Solve ..

(a) increase in the size of silver rod

(b) increase in the concentration of Sn2+ ions
(c) increase in the concentration of Ag+ ions 11.
(d) increase i the size of tin rod
Ans. (c) Solve Sn(s) + 2Ag+(aq) 
..

(a) Al2O3 (b) MgO

Sn2+(aq)
(c) CuO (d) Na2O
0.059 [Ag+(aq)]2
Ecell = Ecell + log 12.
2 [Sn2+(aq)]
[Ag+]
Ecell Voltage
Zn(s)+ 2H+(aq)  Zn2+(aq) + H2(1 atm)
7.
(a) Zn(s) |Zn2+(aq)| |H+(a=14)| H2(1atm)|Pt
(a) CuSO4(aq) + Zn(s)  Cu(s) + ZnSO4(aq) (b) H+(a=1) | H2 (1atm) | Pt| | Zn(s)| Zn2+(aq)
(b) Cu(s)/CuSO4(aq) | ZnSO4(aq)/ Zn(s) (c) H+(a=1) | H2(1 atm)| Pt | | Zn2+(aq)| Zn(s)
(c) ZnSO4(aq)/ Zn(s) | CuSO4(aq)/cu(s) (d) Zn2+(aq) | Zn(s) | | H+(aq) | H2 (1atm)| Pt
(d) Zn(s)/ ZnSO4(aq) | CuSO4(aq)/Cu(s) Ans. (a) Solve

..

Ans. (d) Solve ..

Zn + CuSO4  ZnSO4 + Cu (i) emf

Zn/ZnSO4 | CuSO4/Cu (ii)
8. | || ||
13.
z+ z+
Zn(s) | Zn (aq) : Cu (aq) | Cu(s)
(a) The Zn elctrode is the cathode (a) H+(aq) H2(g), Pt
(b) Oxidation takes place at the Cu electrode (b) Cu2+(aq)/Cu(s)
(c) The reaction Zn2+(aq)+ Cu(s)  Zn(s) (c) Na+(aq)/Na(s)
+ Cu2+(aq) is spontaneous (d) F–/F2,Ft
(d) Electron flows from the Zn electrode Ans. (d) Solve ..

to Cu electrode
Ans. (d) Solve ..

Zn – 2e–  Zn2+..... Na > H > Cu > F

Cu2+ + 7e  Cu..... E(V)
Zn + Cu2+ + Zn2+ + Cu Na+/Na –2.71
9. H+/H2, Pt 0.00
 Cu2+/Cu +0.34 (c) (d)
F–/F2, Pt +2.87 21.
14.
(a) K, Zn, Ag, Na (b) K, Zn, Ag, Cu
(a)  (b) (c) K, Cu, Zn, Ag (d) K, Zn, Cu, Ag
(c) (d) 22. KBr
15.
(a)
(a) Zn (b)
(b) Cu (c)
(c) Zn2+(aq) + Cu(s)  Zn(s) + Cu2+(aq) (d) 
Ans. (d) Solve ..

(d) Zn Cu

16. 23.
(a) Hg2+ (b) Ag|Ag
(a) H (aq)/H2(g), Pt (b) Pt/Cl2(g)/Cl–(aq)
+ –
(c) Cl |AgCl|Ag
–
(d) F |Hg2Cl2|H
(c) Cu+(aq)/ Cu(s) (d) Ca2+(aq)/Ca(s) Ans. (d) Solve ..

Ans. (c) Solve

Hg|Hg2Cl2(s), KCl(1 mole)
..

Pt|H2(g) (1 atm)|H+ (aq) (1M/a =

Pt/Cl2(g)/Cl–(aq) 1), E = 0V
17. 24.
(a) NH4OH (b) HCl
2NaOH + Cd + 2H2O  2Ni(OH)2 + (c) H2SO4 (d) NaOH
Cd(OH)2 25.
2+ 3+
(a) Ni (b) Ni
(c) Cd (d) Cd2+ (a)
Ans. (c) Solve 2NaOH + Cd + 2H2O 
..

(b)
2Ni(OH)2 + Cd(OH)2 (c)
Cd Cd2+ (d) 
18. 26. (EMF)

(a) Ecell = Eox(anode) – Eox(cathode) 

(a) I– (b) OH– (b) Ecell = Eox(anode) – Ered(cathode)
(c) Br– (d) NO3– (c) Ecell = Eox(anode) + Eox(cathode)
19. 2+ 2+
Zn + Cu = Zn Cu (d) A B
27. E
(a) Zn (b) Cu 
2+

(c) (d)
(a) 
20.
(b)
(c) E
(a)  (b)
(d)
28. Ans. (b) Solve .. Zn
Zn  Zn2+ 2e
(a) (b)  Zn Cu
(c) (d)
29. 35.
(a) (b)
(c) (d)  (a) ZnCl2 (b) NH4Cl
(c) H2O (d)
Ans. (d) Solve ..

Ans. (b) Solve ..

NH4Cl MnO2
36. CuSO4
30.

(a)
(a) Zn3(PO4)2 (b) ZnCO3
(c) ZnSO4 (d) Zn(HCO3)2 (b)
31. (c)
(a) pt, H2(g)/H+ (d)
(b) Hg/Hg2Cl2(s), KCl (1mole) (d)
(c) Zn/ Zn2+/ Cu2+Cu Ans. (a) Solve Zn + CuSO4  ZuSO4 +
..

(d) Mg(s)/Mg2+/Ag+/Ag(s) Cu
Ans. (c) Solve ..

37.
Hg|Hg2(s), KCl(1mole)
Pt|H2(g) (a) (b) 
+
(1atm)|H (aq) (1M/a = 1), E = 0V (c) (d)
32. 38.
(a) Cu Zn (b) Cu Ag
(c) Cu Fe (d) Zn Fe (a) (b) 
Ans. (a) Solve ..
(c) (d)
Cu Zn CuSO4 ZnSO4
33.

(a) Pt, H2(g)/H+(aq) (b) Zn/ZnSO4(aq)

(c) Ag/AgCl(s), 0.1 M HCl 1.
(d) Hg/Hg2Cl2(s), 1 M KCl
34. (a) Co (b) Ni
(c) Cu (d) Sn
(a) Zn 2. H2O
(b) Cu
(c) Zn2+(aq) + Cu(s)  Zn(s) + Cu2+(aq) (a) Mg (b) Al
(c) Mn (d) Sn
(d) Zn Cu 3.

(a) (b) 
(c) (d)
Ans. (b) Solve ..