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Article history: The growing interest in finding partial substitutes for cement is the result of the desire to reduce air pol-
Available online xxxx lution caused by the cement industry. One of these partial substitutes is sugarcane bagasse (SCB). SCB is a
by-product of the sugar industry extracted from sugarcane. After burning, a large volume of SCB becomes
Keywords: sugarcane bagasse ash (SCBA) to generate electricity during sugar processing. Many papers studied the
Chemical properties SCBA influences as a construction material due to having pozzolanic characteristics. This paper is a
Mechanical properties comprehensive review of the SCBA used as a supplementary cementitious material (SCMs) to produce
Microstructure
eco-friendly concretes. Firstly, treatment, physical and chemical properties of SCBA. Finally, review the
Physical properties
Sugarcane bagasse ash
concrete properties, including SCBA. The concrete properties such as slump, mechanical properties, water
Slump absorption, porosity, and microstructure. Based on the literature review, the slump increases or decreases
with increasing the SCBA percentage because of influenced treatment by heating and/or milling, and
optimum replacement ratio range of 5%–10% better mechanical properties.
Copyright Ó 2022 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Confer-
ence on Advances in Construction Materials and Structures.
https://doi.org/10.1016/j.matpr.2022.03.264
2214-7853/Copyright Ó 2022 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Conference on Advances in Construction Materials and Structures.
Please cite this article as: I. Saad Agwa, A.M. Zeyad, B.A. Tayeh et al., A comprehensive review on the use of sugarcane bagasse ash as a supplementary
cementitious material to produce eco-friendly concretes, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2022.03.264
I. Saad Agwa, A.M. Zeyad, B.A. Tayeh et al. Materials Today: Proceedings xxx (xxxx) xxx
2
I. Saad Agwa, A.M. Zeyad, B.A. Tayeh et al. Materials Today: Proceedings xxx (xxxx) xxx
Table 1
Chemical composition of SCBA after treatment [25].
Table 2
Physical properties of SCBA from various references.
Property Kazmi, S.M., et al [28] Jagadesh and. Kazmi, S.M.S., et al., [30] Ganesan et al. [31] Maldonado-García Sua-iam and
Murugesan [29] et al. [32] Makul [33]
Specific gravity 1.96 2.218 2.12 1.9 – 2.4
Density (kg/m3) 258.6 245.4 610.6 – – –
Particle size (mm) – 30 (mean size) – 5.4 (mean size) 36.9 (D50) 107.9 (D50)
Surface area – – 4532 cm2 /g 943 m2/kg 60.5 m2/g 274 cm2/g
Table 3
Chemical composition of SCBA from various references, in wt%
Authors SiO2 Al2O3 Fe2O3 CaO MgO SO3 K2O Na2O LOI SiO2 + Al2O3 + Fe2O3
Shafiq, N., et al [36] 77.2 6.3 4.2 4 2.6 0.1 2.3 1.3 – 87.7
Patel, D., et al [34] 58.6 14.9 12.2 1.9 2 2 – – 1.1 85.7
Oyejobi, and Lawal [35] 72.8 1.1 6.9 9.9 6.4 – 6.7 1.9 4.2 80.8
Kazmi, S.M., et al [28] 87.97 1.84 2.65 2.65 0.72 0.15 0.32 0.28 10.45 92.46
Kazmi, S.M.S., et al [30] 85.17 1.69 2.73 2.59 0.69 0.17 0.36 0.29 3.55 89.59
Table 4
Influence of SCBA on slump or flow from various references.
3
I. Saad Agwa, A.M. Zeyad, B.A. Tayeh et al. Materials Today: Proceedings xxx (xxxx) xxx
Table 5
Influence of SCBA on compressive strength at 28 days from various references.
4
I. Saad Agwa, A.M. Zeyad, B.A. Tayeh et al. Materials Today: Proceedings xxx (xxxx) xxx
3. Physical properties of SCBA the slump of 293 , 276 , 271 , and 269 mm, respectively [44]. Fur-
ther, they described that the slump decreases are due to the sur-
The particles shapes of SCBA as shown in Fig. 4. SCBA particles face area and volume fraction of SCBA content. SCBA adsorbed
of different morphology, namely prismatic, spherical, irregular, and the water due to a high surface area. The free water in the mortar
fibrous [26,27]. Table 2 indicates that the researched physical decreased. The higher the replacement of cement by SCBA, the
properties of SCBA are specific gravity density, particle size, and more superplasticizer was required to achieve the slump, which
surface area. Studies conducted by various researchers have shown probably was due to a large number of pores [45].
that the specific gravity of SCBA is within the range of 1.9–2.4, den-
sity is within the range of 245.4–610.6 kg/m3, mean particle size is
6. Mechanical properties
within the range of 4.5–30.5 (mm), and surface area of SCBA in a
range between 274 and 4532 cm2 /g.
6.1. Compressive strength
4. Chemical properties of SCBA Table 5 summarizes the compressive strength at 28 days and
the optimum ratio of SCBA in earlier studies. In, Ramesh and
The bagasse ashes chemical composition obtained in previous Kishore [46], Kiran, and Kishore [47], Srinivasan and Sathiya [48],
investigations is provided in Table 3. The bagasse ashes’ chemical and Ramakrishnan, K., et al., [54], investigated the SCBA effect as
composition is influenced by treatment procedure, grinding condi- cement replacement concrete. In their study 5 to 25% SCBA was
tions, and methodology for collection [25,27]. Patel, et al [34], Oye- replaced with cement. The authors reported that 5% is an optimum
jobi, and Lawal [35], Shafiq, et al [36], Kazmi, S.M.S., et al [30], and replacement. On the other hand, in Modani, and Vyawahare [49],
Kazmi, et al [28] reported 58.6%, 72.8, and 62.44%,77.2, 85.17 and Khan, et al [50], Rerkpiboon, A., et al., [51], Priya, et al., [39],
87.97 of silica content, respectively in their studies. However, the Chamundeeswari.,[52], Ganesan, K., et al., [31]. In their study, 5
primary components, i.e., aluminum, silica, and other mineral ele- to 30% of SCBA has been replaced with cement the compressive
ments, are present in all the samples. In accordance with ASTM strength of concrete using SCBA was investigated. The authors con-
C618-08a [37] natural pozzolans in which the total mass of Al2O3 +- cluded that substitution of only 10% is necessary to obtain good
SiO2 + Fe2O3 is > 50% are classified as class C pozzolans, while those
with a total mass of > 70% are classified as class F pozzolans.
5. Slump
Table 6
Influence of SCBA on splitting tensile strength at 28 days from various references.
Table 7
Influence of SCBA on flexural strength at 28 days from various references.
5
I. Saad Agwa, A.M. Zeyad, B.A. Tayeh et al. Materials Today: Proceedings xxx (xxxx) xxx
compressive strength as shown in Fig. 7 and Table 5 . Attributed to 6.2. Splitting tensile strength
the presence of different amounts of reactive silica and aluminum
in SCBA according to chemical composition of SCBA is influenced The splitting tensile strength at 28 days, cement replacement
by various factors such as treatment procedure, grinding condi- with SCBA, and optimum ratio of SCBA were obtained in previous
tions, and methodology for collection [53]. studies in Table 5. In Srinivasan and Sathiya [48] and Kiran and
Kishore [47]examined the tensile strength of concrete after 28 days
of curing. In their study 5 to 25% SCBA was replaced with cement.
The authors reported that 5% is an optimum replacement. On the
other hand, in Ramakrishnan, et al.,[54], Dhengare, et al.,[55] and
Ganesan, [31] replacement up to 30% of cement by SCBA. In that
15% replacement gave the maximum splitting tensile strength as
shown in Fig. 8 and Table 6. May be attributed to the presence of
varying amounts of reactive silica and aluminum in SCBA.
Fig. 11. SEM of the control 0% SCBA at a) 1, b) 7, c) 28, d) 90, and e) 600 days [61].
6
I. Saad Agwa, A.M. Zeyad, B.A. Tayeh et al. Materials Today: Proceedings xxx (xxxx) xxx
10% replacement cement is optimal [42]. In Srinivasan and Sathiya 25 and 20% the saturated water absorption was 4.71% , 4.78% ,
[48], the flexural strength of concrete produced with 5%–25% SCBA 4.86% , 4.90% , 5.16% , 5.56% , and 6.08% respectively. The increase
partially replaced with cement was investigated. The maximum in water absorption could be attributed to an increase in the col-
flexural strength was observed with 5% SCBA replacement. In Kiran lective volume of the pores [56]. In Summer and Prinya [57] show
and Kishore [47], the flexural strength of concrete with 0%–25% the high porosities of concrete containing SCBA with 10%, 20%,
SCBA as partial cement substitution was tested. From the test and 30% compared to the control mixture. For instance SCBA as
results, the maximum flexural strength was observed with 5% cement replacement of 0%, 10%, 20%, and 30% the porosities
SCBA replacement. In Dhengare, et al.,[55], the flexural strength was 7.20% , 7.22% , 8.31, and 8.50% respectively at 28 days (see
of concrete with 0%–30% SCBA as partial cement substitute was Fig. 10).
tested. The maximum flexural strength was observed at 15% SCBA
replacement. 8. Microstructure
7. Water absorption, and porosity A heterogeneous matrix can be observed in the micrographs of
the control mixture (Fig. 11a and 11b) at days 1 and 7. The C-S-H
In Le., et al., [44], and Garrett et al. [56] investigated the effect and CH phases formed by Portland cement hydration were found
of SCBA as cement replacement concrete on water absorption. In in the majority of the cementitious products [58]. The matrix of
their study 10 to 30%, SCBA was replaced with cement. Regarding the mortars was denser at 28, 90, and 600 days (Fig. 11c, 6d, and
the effect of cement replacement level, found 30% SCBA the 11e), but porous zones with cementitious components and cement
higher than the water absorption was. Ganesan et al. [31] proved particles were still visible. The micrographs of mortars with 20%
that the increasing SCBA ratio increases water absorption. For SCBA collected at 1 and 7 days (Fig. 12a and 12b) show some
instance SCBA as cement replacement of 0%, 5%, 10%, 15% ,20 , cement particles, unreacted SCBA particles, and cementitious
Fig. 12. SEM of 20% SCBA at a) 1, b) 7, c) 28, d) 90, and e) 600 days [61].
7
I. Saad Agwa, A.M. Zeyad, B.A. Tayeh et al. Materials Today: Proceedings xxx (xxxx) xxx
products on the surface of SCBA particles, similar to that in the con- Declaration of Competing Interest
trol mixture. In mixtures with replacement ratios of 20% SCBA
(Fig. 12c, 12d, and 12e) the cementitious matrices became denser The authors declare that they have no known competing finan-
than those of the control mixture as time passes. The improvement cial interests or personal relationships that could have appeared
of concrete microstructure may be attributed to two reasons. 1) to influence the work reported in this paper.
Packing efficiency was ascribed to the fineness of SCBA due to its
smaller average particle size diameter than that of cement. This References
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