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This chapter presents the detailed equipment design of various equipment’s used in the Wet
Process for DAP production.
In cylindrical vessels, this method is used when relatively small quantities (2.52 to 15
Tonnes) are to be stored.
These can be constructed at sites to hold several 1000 Tonnes of ammonia. However, very
large spheres are uncommon and most vessels are in the range of 500 to 3000 Tonnes.
Refrigeration equipments may be used to lower the temperature of the ammonia and in such
cases the vessels operate at lower temperature than ambient.
Ammonia can be stored at atmospheric pressure by reducing the temperature to -33°C. This
condition it may be contained in cylindrical flat bottomed tanks, the tank must withstand, is
only imposed by the head of liquid. In practice a slight positive pressure is maintained to
simplify the operation of refrigeration system. This method of storage is generally adopted
when quantities in excess of 3000 Tonnes are involved.
Cylindrical flat bottom tanks used for large storage of ammonia in fully refrigerated condition
may be divided in to three basic types.
This comprises of flat bottom tank with the dome roof design to withstand the stated
conditions. This type will have external surfaces insulated to minimize heat gain from the
surroundings.
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CHAPTER 6 EQUIPMENT DESIGN
b) Double Wall Tank: The outer tank is not designed to contain any escape of ammonia
from the inner tank, its function being only to support and protect the insulation. The simplest
form comprises a inner tank which is surrounded by an outer tank.
This tank consists of double wall construction with both tanks designed so that in the event
failure of inner shell the ammonia will be contained by the outer shell. The inner tank is ope
topped and the insulation be applied to the exterior of the outer tank. The inter-space be the
tanks will contain only cold ammonia vapours. This method gives more safety than othe
storage methods so we have selected this method. [16]
For the Production of 500 Tonnes/day of Di-ammonium phosphate. The amount of ammonia
required is 262.72 Tonnes (from material balance)
Considering the volume of the tank is 8600 m² and h = 35.92m = 117.84 ft [16]
r = 8.729m
D = 2r = 18m = 59.1 ft
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CHAPTER 6 EQUIPMENT DESIGN
t = 34.56 mm
The diameter of the tank is 59.1 ft which is considered to be a large tank. Hence stiffeners are
used in order to prevent bulging of the equipment and as suggested by the specifications the
min dimensions to be considered is 2.5 x 2.5 x 5/16 in.
Db = 18.33m
Design of shell:
C=0
t = 34.56 m
where P is the total load on the roof = live load + dead load
P = 10lb /ft2
sin θ = 0.7629
θ = sin-1(0.7629) = 49.72°
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CHAPTER 6 EQUIPMENT DESIGN
The mass flow rate of H3PO4 processed per day(from material balance ) = 31.553T/hr
The flow rate of H3PO4 per hour = mass flow rate/ density
= 31.553 x103/1834
= 17.204 m3/hr
The H3PO4 enters the reactor in a slurry form with 43.573 T/hr of H2O
The mass flow rate of NH3 (from material balance) = 7.6625 T/hr
∴The total flow rate entering the reactor Fo = 17.204+43.573+12.398 = 73.177 m3/hr
V τ XA
= =
F 0 C A 0 −r A
Where,
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CHAPTER 6 EQUIPMENT DESIGN
∴τ ¿ 20 min
∴ V ¿24.39m3
Assuming the volume of the reactor is 10 % higher than the calculated value due to design
considerations,
W ¿
1
4 ( √ )
3+
Rc
Rk
=1.6641mm
P Rc W
Thickness of head[10], t = +C
200 fJ
Where,
P is 10% excess of operating pressure = 1.1 x 2 = 2.2 kgf/cm2
f is the allowable stress = 13 kgf/cm2
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CHAPTER 6 EQUIPMENT DESIGN
∴ t=11.991mm
PD
Thickness of reactor, t +C ¿ 4.831 mm
200 fJ−P
Nozzle:
Hanker equation is used to determine the nozzle diameter which is given by,
W 0.45
D N =8.41×
ρ0.31
Where,
DN = nozzle diameter (mm)
W = mass flow rate (kg/hr)
ρ = fluid density (kg/m3)
The inlet flow stream of the reactor has the mole fraction composition of 0.4167 for NaHCO 3
and 0.5833 for water, obtained from material balance.
Table 6.1: Reactor- 1 Parameters
Jacket:
Total height of jacketed CSTR, H = (2 x height of head) + height of reactor + (2 x flange height)
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CHAPTER 6 EQUIPMENT DESIGN
H
=1
Dt
∴ H=Dt =5757.098 mm
The relation between total diameter of the jacketed CSTR and the jacket thickness (J) is given
by,
J 1
=
D t 12
∴ J =479.76 mm
The Table 6.2 presents the results of a reactor designed for DAP plant.
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CHAPTER 6 EQUIPMENT DESIGN
The mass flow rate of H3PO4 processed per day(from material balance ) = 9.456T/hr
The flow rate of H3PO4 per hour = mass flow rate/ density
= 9.456 x103/1834
= 5.156 m3/hr
The H2O enters the reactor in a slurry form with 18.3T/hr of H2O
The mass flow rate of NH3( from material balance) =3.284 T/hr
V τ XA
= =
F 0 C A 0 −r A
Where,
V = volume of the reactor
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CHAPTER 6 EQUIPMENT DESIGN
τ = residence time
-rA = k × CA
k = 0.0825
CA = CA0 (1-XA)
∴τ ¿ 22 min
∴ V ¿17.286m3
Assuming the volume of the reactor is 10 % higher than the calculated value due to design
considerations,
W ¿
1
4( √ )
3+
Rc
Rk
=1.663 mm
P Rc W
Thickness of head[10], t ¿ +C
200 fJ
Where,
P is 10% excess of operating pressure = 1.1 x 1.7 = 2.2 kgf/cm2
f is the allowable stress = 13 kgf/cm2
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CHAPTER 6 EQUIPMENT DESIGN
∴ t=4.884 mm=5 mm
Reactor thickness:
PD
Thickness of reactor, t ¿ +C = 2.14+2 = 4.14mm
200 fJ−P
Nozzle:
Hanker equation is used to determine the nozzle diameter which is given by,
W 0.45
D N =8.41× 0.31
ρ
Where,
DN = nozzle diameter (mm)
W = mass flow rate (kg/hr)
ρ = fluid density (kg/m3)
The inlet flow stream of the reactor has the mole fraction composition of 0.126 for NH 3 and
0.6638 for water, 0.063 for H3PO4, 0.1472 for DAP obtained from material balance.
Table 6.3: Reactor -2 parameter
Jacket:
Total height of jacketed CSTR, H = (2 x height of head) + height of reactor + (2 x flange height)
41
CHAPTER 6 EQUIPMENT DESIGN
The relation between the total height of the reactor and the total diameter of the jacketed
CSTR (Dt) is given by,
H
=1
Dt
∴ H=Dt =5286.098 mm
The relation between total diameter of the jacketed CSTR and the jacket thickness (J) is given
by,
J 1
=
D t 12
∴ J =440.508mm
The Table 6.4 presents the results of a reactor designed for DAP plant.
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CHAPTER 6 EQUIPMENT DESIGN
Hot air outlet temperature = 80°C assumed (normally difference in solid inlet and outlet air is
30 °C we assume 20°C)
Design of rotary dryer on the basis of fundamental principal is very difficult, few relations for
the design are derived from the experimental trials .A large number of variables are involved
in the drier design such as inlet moisture, outlet moisture, critical moistures, equilibrium
moisture gas velocity, temperature, humidity.
To design a rotary dryer the whole length of the drier is divided into 3 zones as shown in the
figure. Very or little moisture movement occurs at zone l and zones 3.Major drying occurs in
zone 2 and considering as constant drying conditions.
After granulation process moisture content in DAP 6-12% but we considered 8% [34]
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CHAPTER 6 EQUIPMENT DESIGN
Assumption:
After granulation process moisture content in DAP 6-12% but we considered 8% [34]
Ms = (1 - 0.08) x 52862.33
Ms = 48633.714 kg/hr
Humidity calculation
For air:
Wet bulb temperature and dry bulb temperature is = 16°C and 25°C respectively
1.Material Balance
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CHAPTER 6 EQUIPMENT DESIGN
48633.714(0.08695-0.010) = Gs (Y1-0.008)
4228.701 = GSY1-0.008Gs
GsY2= 4228.701+0.008Gs
2. Heat balance
Gs(HG₂-HG₁)=Ms(HS₂-HS₁)
Cpair = 1 kJ/kg k
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CHAPTER 6 EQUIPMENT DESIGN
HG1 = 80 + 2459.3Y1
DRYER
HS1= 107.643 kJ/kg HS2 = 147.187 kJ/kg
3. Enthalpy balance
PV = nRT
V= nRT/P
4. Humid volume (volume occupied by unit mass of dry gas and its accompanying vapor at
given temperature and pressure)
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CHAPTER 6 EQUIPMENT DESIGN
= GsxVH2
= 1097.46179×1.299
= 172561.0218 m3/hr
= 39.6 m³/sec
Operating velocity= 1.5 m/s (assumed) in order to avoid dust carry over and DAP loss)
= Gs xVH1
= 109746.749 x 1.067
= 117099.7761 m3/hr
D = √ (26.4x 4 /π)
D = 5.797m
5.Length calculation
47
CHAPTER 6 EQUIPMENT DESIGN
In zone l and zone 3 only heat transfer and negligible mass transfer. In zone 2 large mass
6.Zone 3 Calculation
48
CHAPTER 6 EQUIPMENT DESIGN
7.Zone 1 Calculation
49
CHAPTER 6 EQUIPMENT DESIGN
NTG1= 0.8549
Calculate zone 2 temperature are shown in below Figure 6.6
8. Zone 2 Calculation
ΔTln= 40.84◦C
NTG2 = 1.628
9.Net NTG
= 0.216+1.628+0.8549 = 2.6989
Us = 237 (G)0.67/D
M1 = 109746.744x1.0677x 0.8029
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CHAPTER 6 EQUIPMENT DESIGN
M1 = 94967.918 kg /hr
M2 = 109746.744x1.299 x 0.9611
M2 = 136430.8977 kg /hr
Us = (237 x(1.217)0.67)/5.797
= 46.63W/m2
L= GCsAvg / Us
L = 27.325 m
LT = Net NTG x L
LT = m
LT = 1.6x27.325= 43.72m (Total Length of the dryer is more so that we taking 3 Rotary dryer
in parallel for drying.)
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CHAPTER 6 EQUIPMENT DESIGN
Blower - input
Q = 142561.0218 m3/h r
= 77.5531kW = 103.921 hp
= 3.702 kW = 85.361 hp
t = (PDi)/(200 - fj- P) + C
D = 5.797m
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CHAPTER 6 EQUIPMENT DESIGN
C = 2 mm
= (4.136x3.829)/(200 x16.5x0.85-1.336) +2
t = 2.0023mm
NOTE: Total Length of the dryer is more so that we taking 3 Rotary dryer in parallel for
drying. D = 3.8298 m Total length of dryer =12.3 m
53